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1.
Lead isotopic composition and lead source of the Tongchanghe basalt-type native copper-chalcocite deposit in Ninglang, western Yunnan, China 总被引：1，自引：0，他引：1
1 Introduction The native copper-chalcocite deposits associated with the Emeishan basalt have attracted great attention of many scientists engaged in ore deposits in recent years, but their focus is more put on the deposits hos- ted in the high-Ti basalt … 相似文献
2.
Lead Isotopic Composition and Lead Source in the Bainiuchang Ag-polymetailic Deposit,Yunnan Province,China 总被引：1，自引：1，他引：0
ZHU Chaohui 《《地质学报》英文版》2008,(4)
The Bainiuchang deposit in Yunnan Province,China,is located geographically between the Gejiu ore field and the Dulong ore field.In addition to the>7000 t Ag reserves,the deposit also boasts of large-scale Pb,Zn and Sn reserves with a lot of dispersed elements(In,Cd,Ge,Ga,etc.).We have determined systematically the Pb isotope composition of the deposit.The Pb isotope ratios of the ores that are of sea-floor exhalative sedimentary origin in the northwest of the mining district,are ~(206)Pb/~(204)Pb=17.758-18.537,~(207)pb/~(204)pb=15.175-15.862 and ~(208)pb/~(204)pb=37.289-39.424,while those of ores that are of magmatic hydrothermal superimposition origin in the southeast of the mining district, are ~(206)Pb/~(204)Pb=17.264-18.359,~(207)Pb/~(204)Pb=14.843-15.683 and ~(208)Pb/~(204)Pb=36.481-38.838, respectively.In terms of the Pb isotope composition of feldspar in magmatic rocks or magmatic whole- rock samples from the mining district,we have determined the Pb isotope composition and acquired the Pb isotope ratios as:~(206)Pb/~(204)Pb=18.224-18.700,~(207)Tpb/~(204)Pb=15.595-15.797 and ~(208)Pb/~(204)Pb= 38.193-39.608.Then,in the light of the Pb isotope composition of metamorphic rock samples from the Proterozoic basement exposed in the Dulong ore field,we have determined the Pb isotope composition and obtained the isotope ratios as:~(206)Pb/~(204)Pb=18.434-19.119,~(207)Pb/~(204)Pb=15.644-15.693,and ~(208)Pb/~(204)Pb=38.514-38.832.And the Pb isotope ratios of Cambrian sedimentary rocks,which are exposed in the Bainiuchang mining district,are ~(206)Pb/~(204)Pb=18.307-19.206,~(207)Pb/~(204)Pb= 15.622-15.809,and ~(206)Pb/~(204)Pb=38.436-39.932.By comparing the two types of ores with respect to their Pb isotope compositions,it is indicated that lead in the Bainiuchang deposit was derived largely from the lower-crust granulite which is earlier than Neoproterozoic in age,but the Yanshanian magmatic hydrothermal fluids probably provided a part of ore-forming elements such as Sn for the ore blocks in the south of the mining district. 相似文献
3.
东天山康古尔金矿床成矿物源的同位素地球化学特征 总被引：5，自引：0，他引：5
康古尔金矿床属晚古生代火山岩区剪切带蚀变岩型金矿。同位素地球化学研究表明,矿石中铅为正常铅,热液系统硫同位素组成为陨石硫型,矿石中碳、钕同位素组成具深源特征,同时矿石与火山岩围岩中的Ｓｉ、Ｓｒ、Ｓ、Ｐｂ等同位素组成相近,说明成矿物质主要来自矿体围岩———火山岩,晚期有少量来自矿区附近的侵入岩。铅、锶同位素组成反映成矿过程中也有少量壳源物质的加入。 相似文献
4.
本文在系统的野外地质工作基础上,对舍索与拉屋矿床的矿石硫化物铅同位素组成进行综合分析,进而示踪其成矿物质来源。结果显示,舍索矿区矿石硫化物铅的206Pb/204Pb值为18.517~18.776,207Pb/204Pb值为15.671~15.756,208Pb/204Pb值为38.955~39.33;拉屋矿区矿石硫化物铅的206Pb/204Pb值为18.651~18.757,207Pb/204Pb值为15.707~15.823,208Pb/204Pb值为39.183~39.561。研究表明,舍索与拉屋矿床矿石硫化物铅同位素含量比值具有明显的上地壳特征,指示两个矿床成矿物质主要来自上地壳。其中舍索矿床成矿物质富集受燕山期岩浆作用影响,而拉屋矿床部分成矿物质由晚石炭纪地幔物质的喷流沉积作用提供。 相似文献
5.
PENGRunmin ZHAIYusheng 《《地质学报》英文版》2004,78(2):534-547
Most ore-forming characteristics of the Langshan-Zha‘ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha‘ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical zonation of sulfides; (5) The Cu/(Pb Zn Cu) ratio of the large and thick Pb Zn Cu orebodies gradually decreases from bottom to top; and (6) barite is interbedded with pyrites and sometimes with sphalerite. However, some characteristics such as the Co/Ni radio of the pyrites, the volcanism, for example, of the Langshan-Zha‘ertalshan metallogenic belt, are different from those of the typical SEDEX deposits of the world. The meta-basic volcanic rock in Huogeqi, the sodic bimodal volcanic rocks in the Dongshengmiao and potassic bimodal-volcanic rocks with blastoporphyfitic and blasto-glomeroporphyritic texture as well as blasto-amygdaloidal structure in the Tanyaokou deposits have been discovered in the only ore-bearing second formation of the Langshan Group in the past 10 years. The metallogeny of some deposits hosted in the Langshan Group is closely related to syn-sedimentary volcanism based on the following facts: most of the lead isotopes in sphalerite, galena, pyrite, pyrrhotite and chalcopyrite plot on both sides of the line for the mantle or between the lines for the mantle and lower crust in the lead isotope composition diagram; cobalt content of some pyrites samples is much higher than the nickel content (Co/Ni= 11.91-12.19). Some volcanic blocks and debris have been picked out from some pyritic and pyrrhotitic ores. All Zn-Pb-Cu-Fe sulfide orebodies in these deposits occur in the strata overlying metamorphic volcanic rocks in the only ore-bearing second formation. In the Jiashengpan deposit that lacks syn-sedimentary volcanic rocks in the host succession only Pb and Zn ores occur without Cu ore, but in the Dongshengmiao, Tanyaokou and Huogeqi deposits with syn-sedimentary volcanic rocks in the host succession Cu ores occur. This indicates a relatively higher ore-forming temperature. The process of synsedimentary volcanic eruption directly supplied some ore-forming elements, and resulted in secular geothermal anomaly favorable for the circulation of a submarine convective hydrothermal system, which accounts for the precipitation of deep mineralizing fluids exhaling into anoxidic basins along the syn-sedimentary fault system in the Langshan-Zha‘ertai rift. The Dongshengmiao, Tanyaokou, and Huogeqi deposits hosted in the Langshan Group appear to be a transitional type of mineral deposit between SEDEX and VMS-types but with a bias towards SEDEX, while the Jiashengpan deposit hosted in the Zha‘ertai Group is of a characteristic SEDEX type. This evidence, together with other new discoveries of Mesoproterozoic volcanic rocks and the features of lithogeny and metallogeny of the Bayun Obo deposit in the neighborhood emphasize the diversity, complexity and uniqueness of the Mesoproterozoic Langshan-Zha‘ertal-Bayun Obo ore belt. 相似文献
6.
Lead Isotopic Composition and Lead Source in the Bainiuchang Ag-polymetallic Deposit, Yunnan Province, China 总被引：2，自引：0，他引：2
The Bainiuchang deposit in Yunnan Province, China, is located geographically between the Gejiu ore field and the Dulong ore field. In addition to the 〉7000 t Ag reserves, the deposit also boasts of large-scale Pb, Zn and Sn reserves with a lot of dispersed elements （In, Cd, Ge, Ga, etc.）. We have determined systematically the Pb isotope composition of the deposit. The Pb isotope ratios of the ores that are of sea-floor exhalative sedimentary origin in the northwest of the mining district, are 206pb/204pb = 17.758-18.537, 207pb/204pb = 15.175-15.862 and 206pb/204pb = 37.289-39.424, while those of ores that are of magmatic hydrothermal superimposition origin in the southeast of the mining district, are 206pb/204pb = 17.264-18.359, 207pb/204pb = 14.843-15.683 and 208pb/204pb = 36.481-38.838, respectively. In terms of the Pb isotope composition of feldspar in magmatic rocks or magmatic whole- rock samples from the mining district, we have determined the Pb isotope composition and acquired the Pb isotope ratios as： 206pb/204pb -- 18.224-18.700, 207pb/204pb -- 15.595-15.797 and 208pb/204pb -- 38.193-39.608. Then, in the light of the Pb isotope composition of metamorphic rock samples from the Proterozoic basement exposed in the Dulong ore field, we have determined the Pb isotope composition and obtained the isotope ratios as： 206pb/204pb -- 18.434-19.119, 207pb/204pb -- 15.644-15.693, and 208pb/204pb = 38.514-38.832. And the Pb isotope ratios of Cambrian sedimentary rocks, which are exposed in the Bainiuchang mining district, are 206pb/204pb = 18.307-19.206, 207pb/204pb = 15.622-15.809, and 208pb/204pb = 38.436-39.932. By comparing the two types of ores with respect to their Pb isotope compositions, it is indicated that lead in the Bainiuchang deposit was derived largely from the lower-crust granulite which is earlier than Neoproterozoic in age, but the Yanshanian magmatic hydrothermal fluids probably provided a part of ore-forming elements such as Sn for the ore blocks in the south of the mining district. 相似文献
7.
内蒙古狼山—渣尔泰山中元古代被动陆缘热水喷流成矿特征 总被引：22，自引：1，他引：21
狼山—渣尔泰山中元古代被动陆缘产有东升庙、炭窑口、霍各乞和甲生盘等热水喷流沉积矿床 ,与世界中元古代的SEDEX型矿集区有许多相似之处 :①矿床的产出受华北古陆北缘裂陷槽内三级断陷盆地控制 ;②各大矿床都具有鲜明的层控特征 ,所有矿体总体呈层产在中元古界的白云石大理岩、碳质千枚岩 (或片岩 )中 ;③矿石具有细纹层状、条带状构造 ,喷流沉积成矿特征十分明显 ;④成矿过程中伴有明显的同生断裂活动 ,它在一定程度上控制了矿体的空间分布及其组合 ;但不同矿床同生断裂活动的强度、时限、规模都不同 ,从而导致不同矿床在相同含矿岩组中矿体产出的先后顺序不同和大量层间砾岩与同生角砾状矿石的形成 ;⑤厚大Zn ,Pb ,Cu复合矿体具有明显的分带性 ,自下至上 ,Cu/ (Zn +Pb +Cu)比值由高→低 ;⑥重晶石层发育 ,多与黄铁矿层互层状产出 ,也有与闪锌矿层互层 ,但与世界典型SEDEX型矿床又有重要差别。成矿期间火山活动明显 ,在霍各乞、东升庙、炭窑口矿床惟一容矿的狼山群第二岩组中先后发现了具有变余斑状或聚斑状结构、变余杏仁构造的基性火山岩、钠质“双峰式”火山岩和钾质“双峰式”海相火山岩及凝灰岩夹层。结合①各种硫化物的铅同位素主要分布在地幔和下地壳铅演化曲线附近 ;②部分黄铁矿的Co/Ni值远 相似文献
8.
通过研究两个已知隐伏矿床(新疆金窝子金矿床、内蒙古拜仁达坝—维拉斯托多金属矿床)不同介质(地气、细粒级土壤、围岩、矿石)中的铅、硫同位素特征,探讨铅、硫同位素对地气、土壤中异常物质来源的示踪,得到以下结论:(1)两矿床的介质从地气、矿石、围岩到土壤,铅同位素比值(208Pb/204Pb、207Pb/204Pb、206Pb/204Pb)一般依次增加;土壤异常区相对土壤背景区,δ34S偏高。但对两个矿床背景区、异常区地气中的铅同位素组成、土壤中的铅、硫同位素组成进行方差分析后发现,数据均没有明显的差异,从统计学的角度初步证明研究区不适宜用铅、硫同位素示踪地气、土壤中异常物质的来源。(2)两个矿床的矿石、围岩中铅同位素组成均有明显差异,即围岩中明显有放射成因铅的积累。但这种差异没有显著地反映到背景区、异常区的地气中,原因有待进一步查证。仅从捕获剂的角度初步探讨了其原因。用土壤全量中铅、硫同位素组成特征来示踪土壤异常源,并没有成功,建议采用偏提取的方法测量其中活动态中的铅、硫同位素组成,在深穿透地球化学研究中更合理。 相似文献
9.
Mesozoic and Cenozoic ore deposits in the Chilean Andes between La Serena (~30°S) and Santiago (~34°S) include polymetallic vein, low- and high-sulfidation epithermal vein, skarn, porphyry copper-molybdenum and porphyry copper-gold. These deposits are associated with volcanic and plutonic complexes emplaced in eastward-migrating longitudinal arcs which formed during subduction along the continental margin of South America since the Middle Jurassic. Stratabound, but epigenetic, volcanic rock- and sedimentary rock-hosted manto deposits contain additional copper resources. Lead isotopic compositions in ore minerals from 29 deposits vary with age and geographic location, and hence with basement and host rocks. Lead in most ore deposits is derived from temporally related igneous rocks, except for the manto deposits whose lead is derived from host volcanic and sedimentary rock sequences. Lead in the ore deposits is dominated by two crustal sources. Low 207Pb/204Pb characterizes one source whereas high 207Pb/204Pb characterizes the second source. Lead isotopic compositions of Jurassic and Miocene ore minerals (206Pb/204Pb>18.50; 207Pb/204Pb>15.61) lie along the average crustal growth curve. By contrast, most Cretaceous deposits have ore minerals with lower 206Pb/204Pb (<18.39) and 207Pb/204Pb (<15.58) than Jurassic ore minerals. The shift in lead isotopic composition to lower lead isotopic values precludes derivation of lead from a source of similar composition to those in the Jurassic or Tertiary deposits. For Cretaceous deposits, polymetallic and low-sulfidation epithermal veins and a skarn have lower 206Pb/204Pb than a porphyry copper-gold system and peripheral gold veins at Andacollo (18.43-18.50). Late Cretaceous veins from the Bellavista deposit have the lowest 206Pb/204Pb (18.33) of all deposits. Ore minerals in Miocene and Pliocene porphyry copper-molybdenum deposits have higher 206Pb/204Pb (18.58-18.67) than Cretaceous deposits, consistent with their age being younger. The Miocene and Pliocene ore minerals also have higher 207Pb/204Pb (15.58-15.66) than Cretaceous ore minerals, thereby requiring an additional input from the high-207Pb/204Pb source into the younger deposits. Miocene auriferous deposits in the north have similar 206Pb/204Pb values as the Miocene and Pliocene porphyry copper-molybdenum deposits in the south, but they are distinguished by higher and variable 207Pb/204Pb (15.61-15.66) and 208Pb/204Pb (38.54-39.01), which are arrayed along steep mixing trends. These ore minerals have the largest input of high-207Pb/204Pb material in the deposits studied. By contrast, lead in the epigenetic manto deposits appears to be derived from the host volcanic or sedimentary rock-dominated sequences, and locally exhibits large-scale isotopic heterogeneity within a deposit. Overall, the lead isotopic compositions of ore minerals mimic the values and variations established in age-equivalent rock sequences. The low-207Pb/204Pb material in the deposits is derived from Cretaceous igneous rocks or their sources as they evolved with time; low 207Pb/204Pb characterizes these rocks. By contrast, high-207Pb/204Pb material is likely derived from Carboniferous to Triassic igneous rocks or their sources, as this lead isotopic characteristic dominates these rocks. 相似文献
10.
Summary The Dachang Sn-polymetallic ore district is one of the largest tin producing districts in China. Its origin has long been
in dispute between magmatic-hydrothermal replacement and submarine exhalative-hydrothermal origin. The Dachang ore district
comprises several types of ore deposits, including the Lamo magmatogenic skarn deposit near a granite intrusion, the Changpo-Tongkeng
bedded and vein-type sulfide deposit, and the Gaofeng massive sulfide deposit. Sulfide minerals from the Lamo skarn ores show
δ34S values in the range between −3 and +4‰ with a mean close to zero, suggesting a major magmatic sulfur source that likely
was the intrusive Longxianggai granite. Sulfide minerals from the Gaofeng massive ores show higher δ34S values between +5 and +12‰, whereas sulfide minerals from the Changpo-Tongkeng bedded ores display lighter δ34S values between −7 and −0.2‰. The difference in the sulfur isotope ranges in the two deposits can be interpreted by different
degrees of inorganic thermochemcial reduction of marine sulfate using a one-step batch separation fractionation model. Sulfur
isotopic compositions from the vein-type ores at Changpo-Tongkeng vary widely from −8 to +4‰, but most of the data cluster
around −2.9‰, which is close to that of bedded ores (−3.6‰). The sulfur in vein-type ores might be derived from bedded ores
or it represents a mixture of magmatic- and sedimentary-derived sulfur. Pb isotopic compositions of sulfide minerals in the
Dachang ore district reveal a difference between massive and bedded ores, with the massive ores displaying more radiogenic
Pb isotope ratios. Correlations of 206Pb/204Pb and 207Pb/204Pb or 208Pb/204Pb for the massive and bedded ores are interpreted as two-component mixing of Pb leached from sedimentary host rocks and from
deep-seated Precambrian basement rocks composed of metamorphosed volcano-sedimentary rocks. Pb isotopic compositions of sulfide
minerals from vein-type ores overlap with those of bedded sulfides. Similar to the sulfur, the lead in vein-type ores might
be derived from bedded ores. Skarn ores at Lamo show very limited variations in Pb isotopic compositions, which may reflect
a major magmatic-hydrothermal lead source. Helium isotope data of fluid inclusions trapped in sulfides indicate that He in
the massive and bedded ores has a different origin than He in fluorite of granite-related veins. The 3He/4He ratios of 1.2–2.9 Ra of fluid inclusions from sulfides at Gaofeng and Changpo-Tongkeng imply a contribution of mantle-derived
fluids. Overall our data support a submarine exhalative-hydrothermal origin for the massive and bedded ore types at Dachang.
Supplementary material to this paper is available in electronic form at
Appendix available as electronic supplementary material 相似文献
11.
Neodymium, Sr and Pb isotopic compositions, along with rare earth element (REE) concentrations were determined for twelve black ores and one yellow ore from twelve localities of the Kuroko deposits, Japan. The ores were generated by submarine hydrothermal activity during the Miocene age. Neodymium isotopic compositions of the ores (Nd: –4.9 to +6.5) mostly overlap with spatially associated igneous rocks. On a Nd versus Sr isotopic correlation diagram, however, 87Sr/86Sr ratios are shifted from the associated igneous rocks towards the higher contemporaneous seawater ratio. REE patterns are highly variable, ranging from light REE enriched to depleted, and show no Ce anomalies, as would be expected if they were derived from seawater. These results suggest that the REEs contained in ores were mainly derived from the associated igneous rocks, but that the ore Sr is a mixture derived from both seawater and the igneous rocks. Most Pb isotopic compositions fall within the range defined by the associated igneous rocks (206Pb/204Pb=18.35–18.84, 207Pb/204Pb=15.59–15.97 and 208Pb/204Pb=38.53–39.90), although several samples have very radiogenic compositions that were most likely derived from basement rocks. Our new Pb isotopic results display greater variation, and have a larger range of more radiogenic compositions than has been noted previously for these ores. In addition, the black ore with the most radiogenic Pb isotopic composition also has the least radiogenic Nd isotopic composition. This suggests that at least some of the Pb contained in the ores was derived mainly from older basement rocks. The large positive Eu anomalies for some black ores are consistent with a high-temperature origin for the parental fluids, irrespective of the source rock. The single yellow ore examined, however, has a small negative Eu anomaly, which may indicate derivation from a lower temperature fluid. Previous studies suggested that the Kuroko ores were formed in the presence of organic materials in an anoxic basin. Combined Nd, Sr, Pb and Os isotopic and REE abundance data indicate that multiple sources were involved in the genesis of Kuroko ores. 相似文献
12.
内蒙古白音诺尔铅锌矿铅同位素研究 总被引：1，自引：0，他引：1
内蒙古白音诺尔铅锌矿床是大兴安岭地区储量最大的铅锌矿床,矿体主要沿花岗闪长（斑）岩与大理岩接触带产出。为了查明成矿物质来源,对矿石中的硫化物和矿区内及外围主要侵入岩开展了铅同位素示踪分析。测试结果表明：矿石中硫化物的N（206Pb）/N（204Pb）为18.266～18.372,平均值18.296,N（207Pb）/N（204Pb）为15.501～15.579,平均值15.536,N（208Pb）/N（204Pb）为38.016～38.339,平均值38.138。铅同位素年龄校正计算结果表明：矿石中硫化物的Pb同位素比值与大理岩和花岗闪长（斑）岩非常相似,表明矿石中的铅主要来自花岗闪长（斑）岩和大理岩,说明成矿物质也主要来自这两类岩石,进一步证明了白音诺尔铅锌矿床的成矿与花岗闪长（斑）岩和大理岩有关,属于矽卡岩型矿床,与喷流沉积型和火山岩块状硫化物矿床有明显的差别。与区域上其他银多金属矿床对比发现,本区银多金属矿床的Pb同位素组成非常相似,其组成范围多有重叠,暗示这些矿床的矿石铅来源也非常相似,可能表明有一个共同的富银的基底或地层为这些银多金属矿床的形成提供了成矿物质来源。 相似文献
13.
PENG Runmin ZHAI YushengKey Laboratory of Lithospheric Tectonics Lithoprobing Technology China University of Geosciences Ministry of Education Beijing 《《地质学报》英文版》2004,78(2)
Most ore-forming characteristics of the Langshan-Zha'ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha'ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical 相似文献
14.
PENG Runmin ZHAI YushengKey Laboratory of Lithospheric Tectonics Lithoprobing Technology China University of Geosciences Ministry of Education Beijing 《《地质学报》英文版》2004,78(2)
Most ore-forming characteristics of the Langshan-Zha'ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha'ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical 相似文献
15.
Lead isotope ratios of galena from the carbonate-hosted massive sulphide deposits of Kabwe (Pb-Zn) and Tsumeb (Pb-Zn-Cu)
in Zambia and Namibia, respectively, have been measured and found to be homogeneous and characteristic of upper crustal source
rocks. Kabwe galena has average isotope ratios of 206/204Pb = 17.997 ± 0.007, 207/204Pb = 15.713 ± 0.010 and 208/204Pb = 38.410 ± 0.033. Tsumeb galena has slightly higher 206/204Pb (18.112 ± 0.035) and slightly lower 207/204Pb (15.674 ± 0.016) and 208/204Pb (38.276 ± 0.073) ratios than Kabwe galena. The isotopic differences are attributed to local differences in the age and
composition of the respective source rocks for Kabwe and Tsumeb. The homogeneity of the ore lead in the two epigenetic deposits
suggests lead sources of uniform isotopic composition or, alternatively, thorough mixing of lead derived from sources with
relatively similar isotopic compositions. Both deposits have relatively high 238U/204Pb ratios of 10.31 and 10.09 for Kabwe and Tsumeb galenas, respectively. These isotope ratios are considered to be typical
of the upper continental crust in the Damaran-Lufilian orogenic belt, as also indicated by basement rocks and Cu-Co sulphides
in stratiform Katangan metasediments which have a mean μ-value of 10.25 ± 0.12 in the Copperbelt region of Zambia and the
Democratic Republic of Congo (formerly Zaire). The 232Th/204Pb isotope ratios of 43.08 and 40.42 for Kabwe and Tsumeb suggest Th-enriched source regions with 232Th/235U (κ-values) of 4.18 and 4.01, respectively. Model isotopic ages determined for the Kabwe (680 Ma) and Tsumeb (530 Ma) deposits
indicate that the timing of the mineralisation was probably related to phases of orogenic activity associated with the Pan-African
Lufilian and Damaran orogenies, respectively. Galena from the carbonate-hosted Kipushi Cu-Pb-Zn massive sulphide deposit in
the Congo also has homogeneous lead isotope ratios, but its isotopic composition is comparable to that of the average global
lead evolution curve for conformable massive sulphide deposits. The μ (9.84) and κ (3.69) values indicate a significant mantle
component, and the isotopic age of the Kipushi deposit (456 Ma) suggests that the emplacement of the mineralisation was related
to a post-tectonic phase of igneous activity in the Lufilian belt. The isotope ratios (206/204Pb, 207/204Pb, 208/204Pb) of the three deposits are markedly different from the heterogeneous lead ratios of the Katangan Cu-Co stratiform mineralisation
of the Copperbelt as well as those of the volcanogenic Nampundwe massive pyrite deposit in the Zambezi belt which typically
define radiogenic linear trends on lead-lead plots. The host-rock dolomite of the Kabwe deposit also has homogeneous lead
isotope ratios identical to the ore galena. This observation indicates contamination of the Kabwe Dolomite Formation with
ore lead during mineralisation.
Received: 8 September 1997 / Accepted: 21 August 1998 相似文献
16.
江西相山铀矿田成矿物质来源的Nd、Sr、Rb同位素证据 总被引：14，自引：0，他引：14
对相山大型火山岩型铀矿田中邹家山和沙洲铀矿床及其赋矿围岩（碎斑熔岩及次花岗闪长斑岩）进行了Nd、Sr、Pb同位素研究。结果表明：成矿期萤石的εNd(t)值（－6．7～-8．3）和初始^87Sr/^86Sr比值（0．7145－0．7207）与赋矿围岩的εNd(t) 值（－6．2～－9．4）和初始^87Sr/^86Sr比值（0．7121－0．7192）相似。在εNd(t)-tl图上，成矿期萤石数据点的投影域与赋矿围岩的基本吻合，均落在相山元古宙基底演化域范围内。成矿期黄铁矿的铅组成在^206Rb/^204Pb-^207Pb/^204Pb关系图上呈线性分布，而火山岩的铅同位素组成位于此相关线低值一端。利用异常铅线的斜率及成矿年龄计算出富铀体质体的形成年龄为144Ma，这与赋矿围岩的成岩年龄（135－140Ma)接近。因此，相山铀矿田成矿物质主要来自富铀的火山－侵入杂岩,而火山－侵入杂岩则是由类似于地表出露的元古宙基底变质岩部分熔融形成的。由引可见，相山铀矿田的成矿物质主要来源于地壳。 相似文献
17.
云南鲁春铜矿位于“三江”地区金沙江造山带内的鲁春—红坡牛场裂谷盆地。研究发现,鲁春铜矿赋存于一套以长英质为主的双峰式火山岩中,矿体分布呈“上层下脉”状,具有“上黄下黑”的金属分带特征,矿石矿物以方铅矿、闪锌矿和黄铜矿为主。而地球化学特征显示矿石与蚀变围岩及矿区火山岩的微量元素配分特征具有良好的相似性。矿石硫化物的δ34S值为115‰~178‰,矿石铅同位素比值为206Pb/204Pb=18498~18626,207Pb/204Pb=15588~15760, 208Pb/204Pb=38430~38974。阐述了鲁春—红坡牛场裂谷盆地的演化历史以及盆地内大量双峰式火山岩具有洋脊或板内拉张的特征,陆缘火山弧中重新拉张塌陷形成裂谷盆地,造成基底玄武岩浆上侵,从而导致大规模双峰式火山岩的喷发,这一系列特殊的构造背景和成矿环境促进了地壳内热液循环系统的形成,含矿热液的上升喷流和矿质沉淀集积,最终导致矿床形成。 相似文献
18.
19.
Geology and Lead-Isotope Study of the Baiyinnuoer Zn-Pb-Ag Deposit, South Segment of the Da Hinggan Mountains, Northeastern China 总被引：6，自引：0，他引：6
Qingdong Zeng Jianming Liu Zuolun Zhang Changshun Jia Changming Yu Jie Ye Hongtao Liu 《Resource Geology》2009,59(2):170-180
The Baiyinnuoer deposit (32.74 Mt ore with grades of 5.44% Zn, 2.02% Pb and 31.36 g t?1 Ag), the largest Zn‐Pb‐Ag deposit in northern China, is hosted by crystalline limestone and slate of the Early Permian Huanggangliang Formation. Detailed cross‐section mapping indicates stratigraphic and fold structural controls on the mineralization. The Zn‐Pb‐Ag mineralization is hosted predominantly by skarn, which occurs as bedding‐parallel lens that pinch out at the margins of the main economic zone. Three skarn stages are identified at the deposit: (i) garnet‐clinopyroxene; (ii) sulfides; and (iii) carbonate‐epidote. Lead isotopic compositions were determined for galena and sphalerite of the ores, whole rock samples of the Yanshanian granite and granodiorite, Permian marble and tuff, and Jurassic volcanic and subvolcanic rocks in and around the Baiyinnuoer area in order to discuss the sources of ore‐forming materials and the relationship between the ore formation and these whole rocks. Galena and sphalerite of the Baiyinnuoer ore have uniform isotopic ratios (206Pb/204Pb, 18.267–18.369; 207Pb/204Pb, 15.506–15.624; 208Pb/204Pb, 38.078–38.394) consistent with the granite and granodiorite (206Pb/204Pb, 18.252–18.346; 207Pb/204Pb, 15.504–15.560; 208Pb/204Pb, 38.141–38.320), whereas the ratios for Jurassic volcanic and subvolcanic rocks are variable and radiogenic (206Pb/204Pb, 18.468–18.614; 207Pb/204Pb, 15.521–15.557; 208Pb/204Pb, 38.304–38.375). These results indicate that the mineralization was not related to the Jurassic volcanism, but to the Yanshanian magmatism. The Permian strata may have a slight contribution to the mineralization. All features show that the Baiyinnuoer deposit is related to the Yanshanian granitic magmatism, and can be classified as a zinc‐lead‐silver skarn deposit. 相似文献
20.
E. Marcoux 《Mineralium Deposita》1997,33(1-2):45-58
Lead isotope analyses were performed on 26 polymetallic massive sulphide deposits of the Iberian Pyrite Belt, as well as on overlying gossans and associated volcanic rocks. All the massive sulphide deposits (except for Neves-Corvo), and nearly all the volcanic rocks show very similar isotopic compositions grouped around 18.183 (206Pb/204Pb), 15.622 (207Pb/204Pb) and 38.191 (208Pb/204Pb), indicating that most of the ore deposit lead was derived from the same continental crust environment as the associated volcanic rocks. The isotopic compositions are representative of the average south Iberian crust during the Devonian to Early Carboniferous (Dinantian), and their constancy implies a homogenization of the mineralizing fluids before the deposition of the massive sulphides from hydrothermal fluids circulating through interconnected regional fracture systems. This isotopic constancy is incompatible with multiple, small, independent hydrothermal cells of the East Pacific Rise type, and fits much better with a model of hydrothermal convections driven by “magmatic floor heating”. Neves-Corvo is the only south Iberian massive sulphide deposit to have a heterogeneous isotopic composition with, in particular, a highly radiogenic stanniferous ore (206Pb/204Pb of the cassiterite is >18.40). A model of lead mixing with three components is proposed to explain these variations: (1) one derived from the Devonian to Early Carboniferous (Dinantian) continental crust that generated all the other massive ores; (2) an Eohercynian stanniferous mineralization partly remobilized during the formation of the massive sulphides, but independent of them; and (3) a Precambrian continental crust component. The juxtaposition of three different sources places Neves-Corvo in a specific paleogeographic situation that could also explain its mineralogical specificity. The geodynamic context that best explains all the obtained isotopic results is one of an accretionary prism. The fact that lead isotope signatures of the gossans are almost identical to those of the underlying massive sulphides means that this technique could be a useful exploration tool for the Iberian Pyrite Belt. 相似文献