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1.
This paper,based on the fundamental inorganic chemical and organic geochemical characteristics of oilfield waters from the Turpan Depression,presents the contents of organic matter,the distribution of low-carbon fatty acids and the contents of aromatic hydrocarbons as well as their principal ultraviolet absorption spectral and fluorescence spectral characteristics in oilfield waters from different oil/gas-bearing areas.The oil/gas reservoirs in this depression are classified in terms of their conserving conditions.In additon,the paper also discusses the chemical characteristics of oilfield waters from different types of oil/gas reservoirs with an emphasis on the characteristics of their localization in the γNa/γCa-γN a/γCl correction diagram.On this basis it is attempted to expound the fundamental geochemical characteristics of oilfield waters from the Turpan Depression and their geological significance.  相似文献   

2.
<正>So far there has been no common opinion on oil source of the Chepaizi swell in the Junggar Basin.Therefore,it is difficult to determine the pathway system and trend of hydrocarbon migration, and this resulted in difficulties in study of oil-gas accumulation patterns.In this paper,study of nitrogen compounds distribution in oils from Chepaizi was carried out in order to classify source rocks of oils stored in different reservoirs in the study area.Then,migration characteristics of oils from the same source were investigated by using nitrogen compounds parameters.The results of nitrogen compounds in a group of oil/oil sand samples from the same source indicate that the oils trapped in the Chepaizi swell experienced an obvious vertical migration.With increasing migration distance,amounts and indices of carbazoles have a regular changing pattern(in a fine linear relationship).By using nitrogen compounds techniques,the analyzed oil/oil sand samples of Chepaizi can be classified into two groups.One is the samples stored in reservoir beds of the Cretaceous and Tertiary,and these oils came from mainly Jurassic source rock with a small amount of Cretaceous rock;the other is those stored in the Jurassic,Permian and Carboniferous beds,and they originated from the Permian source.In addition,a sample of oil from an upper Jurassic reservoir(Well Ka 6), which was generated from Jurassic coal source rock,has a totally different nitrogen compound distribution from those of the above-mentioned two groups of samples,which were generated from mudstone sources.Because of influence from fractionation of oil migration,amounts and ratios of nitrogen compounds with different structures and polarities change regularly with increasing migrating distance,and as a result the samples with the same source follow a good linear relationship in content and ratio,while the oil samples of different sources have obviously different nitrogen compound distribution owing to different organic matter types of their source rocks.These conclusions of oil source study are identical with those obtained by other geochemical bio-markers. Therefore,nitrogen compounds are of great significance in oil type classification and oil/source correlation.  相似文献   

3.
Three dumping sites have been formed at the northern region of Fushun City, Liaoning Province, for a large number of gangues including much oil shale that had been piled onto ground as gangue during long-term coal exploitation at West Fushun Open-pit Mine. Under appropriate conditions, self-combustion occurs after long-term exposure of oil shale and consequently such phenomena could be found almost everywhere at the three dumping sites. Much polycyclic aromatic hydrocarbons （PAHs） must be generated through oil shale self-combustion, a kind of incomplete combustion. In this paper, in order to make clear the PAHs distribution in oil shale and its self-combustion and their potential effects on surrounding environment, coal, low-grade oil shale, high-grade oil shale, burning oil shale, burnt oil shale and shaly soil collected from West Fushun Open-Pit Mine and West Dumping Site were analyzed quantitatively in 16 US EPA priority PAHs for the first time. Results showed that 16 PAHs in all samples were less than those in some bitumites and carbonaceous coals and were as much as those in lignites and anthracites from some Chinese mining areas. Coal and low-grade oil shale were abundant in lower molecular-weighted PAHs in contrast to high-grade oil shale with rich higher molecular-weighted PAHs. They had more benzo[a] pyrene than the highest background value in soils in Liaoning Province. So PAHs in these crude oil shales could cause potential effects on environment. There were at least 5121.40 p.g/kg PAils generated and at least 3976.70 μg/kg PAHs released into environment in the period from combustion beginning to sampling on the basis of calculation. Furthermore, the concentrations of 3-4 ring PAHs among them were very high. Therefore it could be said that oil shale self-combustion aggravated the environmental impacts of PAHs in oil shale. The low concentrations of PAHs in shaly soil showed that much PAHs had been released through recultivation and biodegradation.  相似文献   

4.
Forty-six crude oil samples were selected from the Ordovician in the northwestern part of the Tahe oilfield for detailed molecular geochemical and isotopic analysis, including group compositions, carbonhydrogen isotopes and gas chroma-tograms of saturated hydrocarbons, as well as the characteristics of terpane, sterane and other biomarkers, indicating that crude oils are of the same origin from different districts in the Tahe oilfield and were derived from the same source kitchen (or oil source formation), i.e., mainly stemming from marine hydrocarbons. Detailed studies of oil physical properties of 25-honpane revealed that such oils have heavy or thick oil qualities due to biodegradation. Comprehensive assessment in terms of five maturity parameters shows that the oils from the Ordovician with Ro values varying from 0.80% to 1.59% are widely distributed in the northwest of the Tahe oilfield.  相似文献   

5.
Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gaswater interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule uplift and the Tahe Oilfield are assemblages of various types of reservoirs, which have an overall oH-bearing potential and obvious uneven distribution. Testing and producing tests are the major means to evaluate this type of reservoirs and acid fracturing improvement is a key link in petroleum exploration and development.  相似文献   

6.
The GOI(grains containing oil inclusions) index is used to distinguish oil zones,oil-water zones and water zones in sandstone oil reservoirs.However,this method cannot be directly applied to carbonate rocks that may not have clear granular textures.In this paper we propose the Effective Grid Containing Oil Inclusions(EGOI) method for carbonate reservoirs.A microscopic view under10× ocular and 10 x objective is divided into 10×10 grids,each with an area of 0.0625 mm×0.0625 mm.An effective grid is defined as one that is cut(touched) by a stylolite,a healed fracture,a vein,or a pore-filling material.EGOI is defined as the number of effective grids containing oil inclusions divided by the total number of effective grids multiplied by 100%.Based on data from the Tarim Basin,the EGOI values indicative of the paleo-oil zones,oil-water zones,and water zones are 5%,l%-5%,and 1%,respectively.However,the oil zones in young reservoirs(charged in the Himalayan) generally have lower EGOI values,typically 3%-5%.  相似文献   

7.
Abundant organic inclusions are present in the Qinglong antimony deposit. However, the source rocks of these organic matters have not been reliably identified. Recently, a paleo–oil reservoir was found in the Qinglong antimony deposit. In view of similar components of gaseous hydrocarbon, we propose that the organic matters observed in inclusions in Qinglong antimony deposit would come from this paleo–oil reservoir. We used the Re–Os dating method to determine the age of the bitumen from this paleo–oil reservoir, and obtained an isochron age of 254.3±2.8 Ma. The age indicates that the oilgeneration from source rock occurred in the early Late Permian, earlier than the Sb mineralization age(~148±8.5 Ma) in the Qinglong antimony deposit area. After oil generation from Devonian source rock, first and secondary migration, the crude oil have probably entered into the fractures and pores of volcanic rocks and limestone and formed a paleo–oil reservoir in the western wing of Dachang anticline. As burial process deepened, the crude oil has turned into natural gas, migrates into the core of Dachang anticline and formed a paleo–gas reservoir. The hydrocarbons(including CH_4) in the reservoirs can serve as reducing agent to provide the sulfur required for Sb mineralization through thermal chemical reduction of sulfates. Therefore, the formation of oil–gas in the area is a prerequisite for the Sb mineralization in the Qinglong antimony deposit.  相似文献   

8.
The Chinese landmass, as a composite region, consists of multiple small continental blocks, such as Sino-Korea, Yangtze, Tarim, etc., and orogenic belts. Because of its distinctive tectonosedimentary evolution, China’s oil/gas-bearing regions differ remarkably from that elsewhere in the world. For instance, in comparison to the Middle East oil/gas-bearing regions which are characterized by Mesozoic-Cenozoic marine oil/gas-bearing beds, early oil and gas discoveries in China are distributed mainly in Mesozoic-Cenozoic continental sedimentary basins. Generation of oil from terrestrial organic matter, or terrestrial oil generation, and the formation of large oil/gas fields in continental sedimentary basins were previously the major characteristics of petroleum geology of China. However, in the past 20 years, a series of major oil and gas discoveries from marine strata have been made. Marine oil/gas fields in China are mainly distributed in the Tarim, Sichuan, and Ordos basins, which are tectonically stable and covered with Mesozoic-Cenozoic deposits. In these basins, hydrocarbon-bearing strata are of old age and the oil/gas fields are commonly deeply-buried. Cumulatively, 995 oil/gas fields have been found so far, making China the fourth largest oil-producing country and the sixth largest gas-producing country in the world. In terms of petroleum and natural gas geology, theories of hydrocarbon generation from continental strata, such as terrestrial oil generation and coal-generated hydrocarbons, etc., have been established. Significant progress has been made in research on the sequence stratigraphy of continental strata, formation mechanisms of ultra-deep clastic reservoirs, and hydrocarbon accumulation in the continental subtle reservoir. Regarding research on the marine petroleum geology of China, with respect to the major characteristics, such as deeply-buried reservoirs, old strata, and multiple phases of transformation, important advances have been made, in areas such as the multiple-elements of hydrocarbon supply, formation of reservoirs jointly controlled by deposition, tectonic activities, and diagenetic fluid-rock reactions, and oil/gas reservoirs formed through superimposed multi-stage hydrocarbon accumulation. As more and more unconventional hydrocarbon resources are discovered, unconventional oil and gas reservoirs are under study by Chinese petroleum geologists, who endeavor to come up with new discoveries on their formation mechanisms.  相似文献   

9.
It is not occasional that uranium deposits and oil accumulation occur in the same depression in the Erlian basin, Inner Mongolia. Some evidences show certain relations between uranium and oil in origin. This paper discusses and analyses the evidence for the relations between uranium deposits and oil and gas accumulation in terms of spatial distribution, geology, hydrochemistry and geochemistry. The paper also deals with the mechanism of the formation of uranium deposits and points out that it is of significance to use uranium as an indicator to search for oil and vice versa.  相似文献   

10.
Measurements of the absolute and relative concentrations of nitrogen-containing compounds in crude oils from different reservoir strata (Ordovician, Silurian and Carboniferous) in the Tazhong region of the Tarim Basin, Xinjiang, China, showed that even though there are quite a number of factors affecting the distributional and compositional characteristics of neutral nitrogen-containing compounds in crude oils, the distributional and compositional characteristics of crude oils whose source conditions are approximate to one another are influenced mainly by the migration and fractionation effects in the process of formation of oil reservoirs. In addition, crude oils in the Tazhong region show obvious migration-fractionation effects in the vertical direction. Carboniferous crude oils are characterized by high migration parameters and low compound concentrations, just in contrast to Ordovician crude oils. This indicates that crude oils from shallow-level oil reservoirs were derived from those of deep-level oil reservoirs via faults, unconformable contact or carrier beds. Crude oils from the Tazhong region show some migration-fractionation effects in the lateral direction, but mixing of crude oils derived from different hydrocarbon source rocks in the process of formation of oil reservoirs made it more complicated the migration and accumulation of crude oils, as well as the formation of oil reservoirs.  相似文献   

11.
<正>1 Introduction The study area of Northern Honggang is located in the Daan-Honggang terrace in the central depression of the southern Songliao basin,covering an area of 110km2.The oil field is categorized as an ultra-low permeability reservoir and the target horizon is the Fuyu oil layer.The reservoir is characterized as poor physical property,strong  相似文献   

12.
检出于侏罗系沉积岩的一类新标志化合物——苯并藿烷   总被引：1，自引：0，他引：1  
Reported in this paper is a novel family of blomarker compounds -benzohopanes, which were detected in .the extracts of Lower Jurassic black mudstone samples from the Junggar Basin, Xinjiang Autonomous Region. These compounds are described as hexacyclic terpenoids (C33--C35) related to the hopane series. The maSs spectrograms of the four compounds are highly consistent with the data reported by G. Husell et al. (1984). The homologues of benzohopane can be used as an indicator of immature sedimentary rocks in the coal-bearing strata.  相似文献   

13.
<正>Exploration and development experience show that there is obvious oil gravity difference between the southern part and northern part of the"M1"reservoir in the Fanny oil field in the slope of the Oriente Basin,Ecuador.The American Petroleum Institute Gravity(API) values of oils in the northern part are higher than the one in the southern part of the Fanny oil field,with the values of 20°and 10.0°-13.0°,respectively.So the primary purpose of this study was to analyze the heavy oil characteristics of biodegradation and the oil-oil correlation according to the biomarker data and theδ~(13)C signature of oil samples from T block.The results of the hydrocarbon gas chromatography fingermark and the inversion attribute characteristics indicated that there are fluid compartments between the"M1"reservoir of Fanny south.Finally,the models of oil-gas accumulation under the control of multiple-activities of complicated fault systems,as well as the origin of heavy oil,are contended.The early stage oils from the western part of the basin were biodegraded heavily in varying degrees in the whole basin,and the later stage oils were derived from the southern part in a large scale and were mature and lighter.Generally,oil mixing is the primary control of net oil properties,such as API gravity in Oriente Basin.We therefore predicted that the API gravity variation of oil pools radically depends on the injection amount of the later stage oil.Because of the shale barrier in the"M1"reservoir of Fanny south,the later stage hydrocarbon could not pass through and contribute to increase the oil API value.  相似文献   

14.
Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gas-water interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule upli  相似文献   

15.
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16.
Petroleum geologists have debated whether the hydrocarbons from Jurassic coal measures are derived from the coals, carbonaceous mudstones or coal-measure mudstones in the Turpan Basin. Based on the geochemistry analysis of the 20 crude oils and 40 source rocks from the Turpan Basin, some data have been obtained as follows: carbon preference index and methylphenanthrene index of the Jurassic oils are 1.16–1.45 and 0.28–0.80, and the ααα C29 sterane 20S/(20S+20R) and C29 sterane ββ/(ββ+αα) are 0.44–0.51 and 0.4–0.54 respectively, which show the normal maturity of oils; the vitrinite reflectance of the source rocks from the Xishanyao to Badaowan Formations range from 0.47% to 0.97%, which indicate immature to mature thermal evolutionary stage and sufficient conditions for generating mass mature oil. The effect of hydrocarbon expulsion should be considered when studying the source of coal-derived oil by using Biomarkers. Biomarkers in the Jurassic oils from the basin are similar to those in the coals and carbonaceous mudstones, with a strong predominant content of pristane, relatively high ratio of C15/C16 sesquiterpenoids (>1), a relatively high content of low carbon number tricyclic terpanes and C24 tetracyclic terpane, little gammacerane and C29 Ts detected, an absolute predominant content of C29 sterane and a relatively high content of diasterane. However, the opposite characteristics are shown in mudstones, with an approximately equal content of pristane and phytane, relatively low ratio of C15/C16 sesquiterpenoids (<1), a relatively high content of high carbon number tricyclic terpanes and a low content of C24 tetracyclic terpane, peaks of gammacerane and C29 Ts detected obviously and an increasing C27 sterane content. All of these characteristics identify the coals and carbonaceous mudstones as the possible major oil source rocks in this area, and they were formed in the stronger oxidizing environment with shallower water than mudstones.  相似文献   

17.
A total of 6 oil samples were systematically selected from six Asmari Reservoir wells in the Cheshmeh-Khush Oilfield for geochemical evaluation of the hydrocarbon system, based on reservoir geochemistry and oil fingerprints. An investigation of the distribution patterns of normal alkanes and tricyclic and tetracyclic terpanes along with characteristic biomarkers of the depositional environment and sedimentary facies, indicated that the source rock of the studied hydrocarbons was deposited in a reducing aquatic environment with a low input of terrigenous material and predominantly carbonate lithology derived from organic algal matter. The studied oil samples exhibited moderate maturity, as was further confirmed by the parameters extracted from the light hydrocarbons. Statistical clustering based on different biomarker parameters indicated the presence of two oil families. Additionally, the application of branched and cyclic compounds in the light hydrocarbons (C5–C11) to evaluate lateral continuity of the Asmari reservoir further supported the presence of the two oil families. Other evidence proved the presence of a NE–SW trending fault separating wells X5 and X6 from the other wells in the field. In other wells across the field, good lateral reservoir continuity was observed, despite the presence of faults on the northern and southern plunges of the structure.  相似文献   

18.
Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gas-water interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule upli  相似文献   

19.
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20.
Abstract: The Ordos Basin is an important intracontinental sedimentary basin in western China for its abundant Mesozoic crude oil resources. The southern part of the Tianhuan Depression is located in the southwestern marginal area of this Basin, in which the Jurassic and Triassic Chang-3 are the main oil-bearing strata. Currently, no consensus has been reached regarding oil source and oil migration in the area, and an assessment of oil accumulation patterns is thus challenging. In this paper, the oil source, migration direction, charging site and migration pathways are investigated through analysis of pyrrolic nitrogen compounds and hydrocarbon biomarkers. Oil source correlations show that the oils trapped in the Jurassic and Chang-3 reservoirs were derived from the Triassic Chang-7 source rocks. The Jurassic and Chang-3 crude oils both underwent distinct vertical migration from deep to shallow strata, indicating that the oils generated by Chang-7 source rocks may have migrated upward to the shallower Chang-3 and Jurassic strata under abnormally high pressures, to accumulate along the sand bodies of the ancient rivers and the unconformity surface. The charging direction of the Jurassic and Chang-3 crude oils is primarily derived from Mubo, Chenhao, and Shangliyuan, which are located northeast of the southern Tianhuan Depression, with oils moving toward the west, southwest, and south. The results show that an integration of biomarker and nitrogen-bearing compound analyses can provide useful information about oil source, migration, and accumulation.  相似文献   

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