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1.
The paper presents data on inclusions in minerals of the least modified potassic lamprophyres in a series of strongly carbonatized potassic alkaline ultramafic porphyritic rocks. The rocks consist of diopside, kaersutite, analcime, apatite, and rare phlogopite and titanite phenocrysts and a groundmass, which is made up, along with these minerals, of potassic feldspar and calcite. The diopside and kaersutite phenocrysts display unsystematic multiple zoning. Chemically and mineralogically, the rock is ultramafic foidite and most likely corresponds to monchiquite. Primary and secondary melt inclusions were found in diopside, kaersutite, apatite, and titanite phenocrysts and are classified into three types: sodic silicate inclusions with analcime, potassic silicate inclusions with potassic feldspar, and carbonate inclusions, which are dominated by calcite. Heating and homogenization of the inclusions show that the potassic lamprophyres crystallized from a heterogeneous magma, with consisted of mixing mafic sodic and potassic alkaline magmas enriched in a carbonatite component. The composition of the magmas was close to nepheline and leucite melanephelinite. The minerals crystallized at 1150–1090°C from the sodic melts and at 1200–1250°C from the potassic ones. The sodic mafic melts were richer in Fe than the potassic ones, were the richest in Al, Mn, SO3, Cl, and H2O and poorer in Ti and P. The potassic mafic melts were not lamproitic, as follows from the presence of albite in the crystallized primary potassic melt inclusions. The diopside, the first mineral to crystallize in the rock, started to crystallize in the magmatic chamber from sodic mafic melt and ended to crystallize from mixed sodic–potassic melts. The potassic mafic melts were multiply replenished in the chamber in relation to tectonic motions. The ascent of the melts to the surface and rapidly varying P–T parameters of the magma were favorable for multiple separations of carbonatite melts from the alkaline mafic ones and their mixing and mingling.  相似文献   

2.
The ocellar lamprophyre dyke (ENE-WSW) is recorded at Wadi Nugrus, Eastern Desert, Egypt. It cuts porphyritic biotite granites and varies in thickness from 0.5 to 1.5 m and up to 3 km in length. The lamprophyre dyke has been altered, and it is characterized by porphyritic and panidiomorphic textures with plagioclase, olivine, and augite constituting the porphyritic phase in a fine groundmass of the same composition. Rutile, titanite, apatite, fluorite, graphite, calcite, allanite, autunite and Fe-Ti oxides are accessory minerals. Kaolinite, chlorite and epidote are secondary minerals. Carbonitization and hematitization are common. Rounded to sub-rounded porphyritic and zoned ocelli with radiate or brush-like shapes are generally common and represent physical traps for mineralization. The ocellar features are interpreted to represent the late stage of magmatic segregation or magmatic crystallization involving two immiscible magmatic liquids.  相似文献   

3.
作为最早被识别出的碱性岩石之一,煌斑岩因富含金和金刚石等矿产资源以及对理解深部地球动力学过程的重要作用而受到广泛重视,但是目前对于煌斑岩的成因还存在不同的认识。本文基于近年来对煌斑岩的研究成果,对它们的分类、特征以及岩石成因进行综述。根据国际地科联(IUGS)的分类标准,煌斑岩可以分为超镁铁质煌斑岩、钙碱性煌斑岩和碱性煌斑岩。研究发现,超镁铁质煌斑岩往往是伸展环境下岩浆作用的产物,与金伯利岩和碳酸岩有密切的成因关系;钙碱性煌斑岩通常发育在汇聚或被动大陆边缘环境,其岩石成因可能有多种机制(如基性岩浆的分异、岩浆混合以及交代富集地幔的部分熔融);碱性煌斑岩出露在离散型大陆边缘和板内构造环境,通常和碱性玄武质岩浆作用密切相关。不管岩石的形成环境和过程如何,超镁铁质煌斑岩、钙碱性煌斑岩和碱性煌斑岩被普遍认为是来自于经历了交代富集作用的地幔源区。最后,文章指出了煌斑岩研究过程中存在的一些科学问题,如富集的地幔源区存在的矿物相(金云母和角闪石)对产生钠质还是钾质岩浆的影响,控制岩浆在结晶过程中影响含水矿物斑晶形成的因素以及部分煌斑岩中碳酸岩球粒和钠长石的形成原因等。  相似文献   

4.
Three distinct alkaline magmas, represented by shonkinite, lamprophyre and alkali basalt dykes, characterize a significant magmatic expression of rift-related mantle-derived igneous activity in the Mesoproterozoic Prakasam Alkaline Province, SE India. In the present study we have estimated emplacement velocities (ascent rates) for these three varied alkaline magmas and compared with other silicate magmas to explore composition control on the ascent rates. The alkaline dykes have variable widths and lengths with none of the dykes wider than 1 m. The shonkinites are fine- to medium-grained rocks with clinopyroxene, phologopite, amphibole, K-feldspar perthite and nepheline as essential minerals. They exhibit equigranular hypidiomorphic to foliated textures. Lamprophyres and alkali basalts characteristically show porphyritic textures. Olivine, clinopyroxene, amphibole and biotite are distinct phenocrysts in lamprophyres whereas olivine, clinopyroxene and plagioclase form the phenocrystic mineralogy in the alkali basalts. The calculated densities [2.54–2.71 g/cc for shonkinite; 2.61–2.78 g/cc for lamprophyre; 2.66–2.74 g/cc for alkali basalt] and viscosities [3.11–3.39 Pa s for shonkinite; 3.01–3.28 Pa s for lamprophyre; 2.72–3.09 Pa s for alkali basalt] are utilized to compute velocities (ascent rates) of the three alkaline magmas. Since the lamprophyres and alkali basalts are crystal-laden, we have also calculated effective viscosities to infer crystal control on the velocities. Twenty percent of crystals in the magma increase the viscosity by 2.7 times consequently decrease ascent rate by 2.7 times compared to the crystal-free magmas. The computed ascent rates range from 0.11–2.13 m/sec, 0.23–2.77 m/sec and 1.16–2.89 m/sec for shonkinite, lamprophyre and alkali basalt magmas respectively. Ascent rates increase with the width of the dykes and density difference, and decrease with magma viscosity and proportion of crystals. If a constant width of 1 m is assumed in the magma-filled dyke propagation model, then the sequence of emplacement velocities in the decreasing order is alkaline magmas (4.68–15.31 m/sec) > ultramafic-mafic magmas (3.81–4.30 m/sec) > intermediate-felsic magmas (1.76–2.56 m/sec). We propose that SiO2 content in the terrestrial magmas can be modeled as a semi-quantitative “geospeedometer” of the magma ascent rates.  相似文献   

5.
The Afyon stratovolcano exhibits lamprophyric rocks, emplaced as hydrovolcanic products, aphanitic lava flows and dyke intrusions, during the final stages of volcanic activity. Most of the Afyon volcanics belong to the silica-saturated alkaline suite, as potassic trachyandesites and trachytes, while the products of the latest activity are lamproitic lamprophyres (jumillite, orendite, verite, fitztroyite) and alkaline lamprophyres (campto-sannaite, sannaite, hyalo-monchiquite, analcime–monchiquite). Afyon lamprophyres exhibit LILE and Zr enrichments, related to mantle metasomatism.  相似文献   

6.
The Serra da Graciosa Granites and Syenites comprise five distinct plutons in the Brasiliano/Pan-African Graciosa A-type Province, southern Brazil. Six petrographic series can be identified in these plutons: (1) Alkaline series 1, composed of amphibole-bearing alkali feldspar syenites with varied mafic mineralogy and quartz contents, from alkali feldspar syenites with calcic amphibole, clinopyroxene, olivine and allanite to alkali feldspar quartz syenites with sodic–calcic amphibole and chevkinite–perrierite and to alkali feldspar granites with sodic amphibole; (2) Alkaline series 2, characterized by amphibole-bearing alkali feldspar granites, with limited modal variations but amphibole compositions also varying from calcic to sodic; (3) Alkaline series 3, of limited occurrence, which includes alkali feldspar syenites with olivine and clinopyroxene and no amphibole; (4) Aluminous series 1, of widespread occurrence, with various petrographic facies of biotite granites with amphibole; (5) Aluminous series 2, characterized by alkali feldspar granites with biotite and only minor amphibole; (6) Monzodiorites, typically with biotite, calcic amphibole and augitic clinopyroxene, partially mingled with granitic magmas. The mafic minerals present are, in general, Fe-rich with correspondingly low Mg and Al contents. In Alkaline series 1, amphiboles crystallized in progressively more oxidizing and alkaline conditions, while in Alkaline series 2, the initial conditions were somewhat more oxidizing and shifted to reducing in the final stages. In Aluminous series 1 and Aluminous series 2, amphiboles are calcic and comparatively homogeneous. The amphiboles in the monzodioritic rocks, while also homogeneous, are more Mg-rich and show compositions quite distinct from the calcic varieties in the other associations, and this is also the case for clinopyroxene. Mg# in biotite decreases from the monzodioritic rocks to Aluminous series 1 and further to Aluminous series 2. Contrasting evolution of the various associations suggests that several coeval magmatic series are present in the Serra da Graciosa granites.  相似文献   

7.
Chromian spinels from the Staré Ransko gabbro-peridotite, Czech Republic, display a distinct development trend: from primary Cr-rich spinels towards ferro-ferri (Ti-enriched magnetite) and magnesio-alumina (spinel sensu stricto) spinels. Zoning in the spinels is thought to be the result of a combination of exsolution, postdepositional diffusion and replacement processes. Multiphase, globular silicate inclusions — mainly biotite and amphibole, also orthopyroxene, serpentine and chlorite — are present in euhedral, largely homogeneous chromian spinels which occur in a matrix of poikilitic amphibole. The enclosed minerals have similar compositions to the minerals in the host rock. These silicate inclusions are interpreted as being due to a late magmatic introduction of a hydrous K-Ca-rich melt phase, contaminated by wall-rock interaction, into a semi-solidified olivine (± pyroxenes) cumulate.The composition of the chromian spinel may be used as an indicator for sulfide mineralization conditions (Johan 1979). The data reported in this paper are compatible with Johan's model.  相似文献   

8.
N.M.S. Rock 《Earth》1977,13(2):123-169
Lamprophyres are porphyritic dyke-rocks, readily recognisable in the field, which seemed to have become enveloped in petrological mystery because of their scattered and often contradictory literature. Important characteristics common to all members of this extremely heterogeneous group are suggested to include their intrusion at a late stage in any igneous event, the presence of essential amphibole or biotite coupled with peculiar chemistry, and their lack of felsic phenocrysts. Panidiomorphic texture is usual, though by no means exclusive to lamprophyres.At least four lamprophyre subgroups may be recognised; these are quite distinct in petrology, chemistry, paragenesis and petrogenesis although individual members of each subgroup are closely similar. Thealkaline lamprophyre subgroup is considered in detail: new definitions ofcamptonite andmonchiquite are proposed which are believed to reconcile majority usage whilst accomodating existing analytical data; the termouachitite is reassessed andfourchite suggested to be superfluous;sannaite, an alkali feldspar-rich alkaline lamprophyre, may be more abundant than its frequency within the literature implies — some “minettes” and “vogesites” are more correctly termed sannaite, particularly those occurring in carbonatite complexes.Camptonites most probably represent alkali basalt magmas which became unusually hydrous through influence of an alkaline pluton, and then evolved at relatively low pressures. Varied evidence is considered to suggest that the nearly isotropic base in monchiquites typically consists of altered glass rather than analcime; where analcime is present it probably formed along with zeolites by secondary processes. “Monchiquitic” is not an appropriate synonym for “analcime-bearing”, as in some literature. Field, chemical and statistical evidence is taken to suggest that many monchiquites are either chilled heteromorphs of camptonites or camptonitic magmas which crystallised under high CO2 activities. Liquid immiscibility seems to be more extensively developed in camptonites and monchiquites than in any other igneous rocks, and is probably governed by their hydrous state.The genetic connotations of lamprophyre names, asserted early in their history but later questioned, are here modified but reaffirmed: broadly minettes and related lamprophyres connote post-orogenic granites or mildly potassic (shoshonitic) alkaline rocks, alkaline lamprophyres connote alkali basalts or sodic alkaline rocks, and alnoites connote carbonatites.  相似文献   

9.
Essentially two types of ultramafic inclusions occur in the basanitic lavas and ejecta deposits of the northwestern Grand Canyon, Arizona. Abundant, olivine-rich nodules contain an emerald green, chrome-rich diopside and chrome-rich spinels. A much less common group of inclusions generally containing poikilitic kaersutite have more variable modal compositions, more variable but iron-rich and chrome-poor mineral compositions, and are characterized by the presence of a titaniferous clinopyroxene which appears black in hand specimen. The nature and petrologic significance of these black clinopyroxene-bearing inclusions, together with megacrysts of kaersutite and black clinopyroxene, are discussed in this paper.Petrographic aspects indicate an origin as cumulates of fractionating basaltic magma. Compositions of pyroxenes suggest high pressures of crystallization. The co-precipitation of orthopyroxene, clinopyroxene, olivine and Mg-spinel from what in all probability was under-saturated magma, together with the total absence of feldspar as a cumulate or intercumulate phase, is compatible with crystallization near 10 kb, on the basis of quite limited experimental data on anhydrous basaltic compositions. Pressures of this sort are attained at depths close to the mantle-crust boundary in the western Grand Canyon. By way of comparison, cumulate-textured inclusions from central Nevada containing rare orthopyroxene, widespread plagioclase, and more Fe-enriched clinopyroxenes, kaersutites, olivines and spinels are postulated to have crystallized at lower temperatures (or at a more advanced stage of fractionation) and possibly at lower pressures.Numerous occurrences, worldwide, of kaersutite-bearing inclusions, always in undersaturated host rocks, have recently been reported. Compositionally, the kaersutites are quite uniform, whether coexistent with pyropic garnet-clinopyroxene (Kakanui, New Zealand), with ortho-pyroxene-clinopyroxene-olivine-Mg spinel (Grand Canyon), or with plagioclase-clinopyroxene-olivine-magnetite. The last assemblage is found in shallow-seated igneous bodies of alkalic, mafic composition, as well as in inclusions within basaltic rocks. These occurrences imply the precipitation of kaersutite amphibole over a broad range of pressures, and as high as those prevailing in the upper mantle.  相似文献   

10.
Summary The metabasites of Montiggiu Nieddu occur as a lenticular body in the Hercynian migmatite complex of NE Sardinia and consist of two major lithological associations: ultramafic amphibolites and plagioclase-banded amphibolites, which are genetically related by processes of cumulate differentiation of an original tholeiitic magma. The ultramafic amphibolites consist of relics of igneous phases (anorthite, olivine, orthopyroxene, and clinopyroxene) and metamorphic minerals (orthopyroxene, clinopyroxene, plagioclase, garnet, chlorite, and amphibole) in variable proportions. Based on the distribution of the relics of igneous minerals three main compositional layers (A, B, C) have been identified in the ultramafic amphibolites. The plagioclase-banded amphibolites consist of dark-green and white bands made up of plagioclase, amphibole, garnet, and rare pyroxene in variable proportions. No relics of magmatic minerals were observed. The trace element patterns of the Montiggiu Nieddu metabasites are characterised by selective enrichment of incompatible elements of low ionic potential, such as Sr, Rb, Ba, and Th, and low abundance of K, Cr, Ni, and elements of high ionic potential (from Ta to Yb), which define a relatively flat trend similar to MORB composition. Ti, Y, and heavy rare earth elements are all positively correlated with Zr. This correlation suggests that no significant transport of these elements took place during metamorphism. The metabasites of Montiggiu Nieddu are characterised by low Ti, Ti/V, and Ti/Zr content, low rare earth and high-field strength element concentrations, and moderate selective enrichment in large-ion lithophile elements. They also show geochemical features similar to those of supra subduction zone tholeiites. The CaO-MgO diagram displays a segmented trend, which provides powerful evidence in favour of crystal-liquid separation during magmatic evolution. Received December 4, 2000; revised version accepted January 29, 2001  相似文献   

11.
Three varieties of alpine-type ultramafic rocks are distinguish in the Norwegian Caledonides associated Basal Gneiss Complex. Type one rocks have primary (magmatic) olivine, clinopyroxene, orthopyroxene and chromite, and are partly or completely serpentinised. They are found exclusively in rocks of Cambro-Silurian age. Type two are polymetamorphic metaperidotites or sagvandites consisting of olivine, enstatite and carbonate minerals, with talc and amphibole commonly being present. They are found in medium- to high-grade metamorphic rocks. Type three also show a metamorphic mineral association of olivine, orthopyroxene and minor chromite, while clinopyroxene, amphibole and chrome-bearing chlorite may also be present in some samples. Garnet may or may not occur and, where present, is often surrounded by reaction rims of spinel and amphibole. The type three ultramafic bodies are serpentinised to varying degrees and occur in high-grade metamorphic gneisses which may also contain eclogites and anorthosites. Distinction of these three varieties of ultramafic body may be useful for correlation purposes and for more detailed studies on the nature of their metamorphism.  相似文献   

12.
Geological mapping and diamond exploration in northern Quebec and Labrador has revealed an undeformed ultramafic dyke swarm in the northern Torngat Mountains. The dyke rocks are dominated by an olivine-phlogopite mineralogy and contain varying amounts of primary carbonate. Their mineralogy, mineral compositional trends and the presence of typomorphic minerals (e.g. kimzeyitic garnet), indicate that these dykes comprise an ultramafic lamprophyre suite grading into carbonatite. Recognized rock varieties are aillikite, mela-aillikite and subordinate carbonatite. Carbonatite and aillikite have in common high carbonate content and a lack of clinopyroxene. In contrast, mela-aillikites are richer in mafic silicate minerals, in particular clinopyroxene and amphibole, and contain only small amounts of primary carbonate. The modal mineralogy and textures of the dyke varieties are gradational, indicating that they represent end-members in a compositional continuum.

The Torngat ultramafic lamprophyres are characterized by high but variable MgO (10–25 wt.%), CaO (5–20 wt.%), TiO2 (3–10 wt.%) and K2O (1–4 wt.%), but low SiO2 (22–37 wt.%) and Al2O3 (2–6 wt.%). Higher SiO2, Al2O3, Na2O and lower CO2 content distinguish the mela-aillikites from the aillikites. Whereas the bulk rock major and trace element concentrations of the aillikites and mela-aillikites overlap, there is no fractional crystallization relation between them. The major and trace element characteristics imply related parental magmas, with minor olivine and Cr-spinel fractionation accounting for intra-group variation.

The Torngat ultramafic lamprophyres have a Neoproterozoic age and are spatially and compositionally closely related with the Neoproterozoic ultramafic lamprophyres from central West Greenland. Ultramafic potassic-to-carbonatitic magmatism occurred in both eastern Laurentia and western Baltica during the Late Neoproterozoic. It can be inferred from the emplacement ages of the alkaline complexes and timing of Late Proterozoic processes in the North Atlantic region that this volatile-rich, deep-seated igneous activity was a distal effect of the breakup of Rodinia. This occurred during and/or after the rift-to-drift transition that led to the opening of the Iapetus Ocean.  相似文献   


13.
Ilmenite is one of the common kimberlitic indicator minerals recovered during diamond exploration, and its distinction from non-kimberlitic rock types is important. This is particularly true for regions where these minerals are present in relatively low abundance, and they are the dominant kimberlitic indicator mineral recovered. Difficulty in visually differentiating kimberlitic from non-kimberlitic ilmenite in exploration concentrates is also an issue, and distinguishing kimberlitic ilmenite from those derive from other similar rocks, such as ultramafic lamprophyres, is practically impossible. Ilmenite is also the indicator mineral whose compositional variety has the most potential to resolve provenance issues related to mineral dispersions with contributions from multiple kimberlite sources.

Various published data sets from selected kimberlitic (including kimberlites, lamproites, and various ultramafic lamprophyres) and non-kimberlitic rock types have been compiled and evaluated in terms of their major element compositions. Compositional fields and bounding reference lines for ilmenites derived from kimberlites (sensu stricto), ultramafic lamprophyres, and other non-kimberlitic rock types have been defined primarily on MgO–TiO2 graphs as well as MgO–Cr2O3 relationships.  相似文献   


14.
矿物微量元素组成用于火成岩构造背景判别   总被引：1，自引：0，他引：1  
火成岩中的矿物,特别是稳定副矿物的微量元素组成可用于火成岩构造–岩浆背景的判别。产于不同构造背景火成岩中单颗粒锆石原位微量元素含量的准确测定,积累了大量资料。本文介绍了用锆石微量元素含量的二维核密度分布投影,构建了U/Yb-Nb/Yb、Sc/Yb-Nb/Yb和U/Yb-Sc/Yb构造背景判别图解,可以区分洋中脊、地幔柱影响的洋岛及俯冲有关的弧(大陆弧)等不同构造背景形成的火成岩。单斜辉石、尖晶石、黑云母和角闪石的微量元素或主量元素组成同样可用于构造背景识别。  相似文献   

15.
《地学前缘(英文版)》2020,11(3):925-942
The Pb isotope composition of the upper mantle beneath Central Europe is heterogeneous due to the subduction of regionally contrasting material during the Variscan and Alpine orogenies.Late Variscan to Cenozoic mantlederived melts allow mapping this heterogeneity on a regional scale for the last ca.340 Myr.Late Cretaceous and Cenozoic anorogenic magmatic rocks of the Bohemian Massif(lamprophyres,volcanic rocks of basanite/tephrite and trachyte/phonolite series) concentrate mostly in the Eger Rift.Cretaceous ultramafic lamprophyres yielded the most radiogenic Pb isotope signatures reflecting a maximum contribution from metasomatised lithospheric mantle,whereas Tertiary alkaline lamprophyres originated from mantle with less radiogenic ~(206)Pb/~(204)b ratios suggesting a more substantial modification of lithospheric source by interaction with asthenosphericderived melts.Cenozoic volcanic rocks of the basanite/tephrite and trachyte/phonolite series define a linear mixing trend between these components,indicating dilution of the initial lithospheric mantle signature by upwelling asthenosphere during rifting.The Pb isotope composition of Late Cretaceous and Cenozoic magmatic rocks of the Bohemian Massif follows the same Pb growth curve as Variscan orogenic lamprophyres and lamproites that formed during the collision between Laurussia,Gondwana,and associated terranes.This implies that the crustal Pb signature in the post-Variscan mantle is repeatedly sampled by younger anorogenic melts.Most Cenozoic mantle-derived rocks of Central Europe show similar Pb isotope ranges as the Bohemian Massif.  相似文献   

16.
Abstract: The Mamut deposit of Sabah, East Malaysia, is a porphyry type Cu‐Au deposit genetically related to a quartz monzonite (“adamellite”) porphyry stock associated with upper Miocene Mount Kinabalu plutonism. The genesis of the Mamut deposit is discussed based on petrology of the intrusives in the Mount Kinabalu area combined with ore– and alteration–petrography, fluid inclusion and sulfur isotope studies. Groundmass of the adamellite porphyry at Mamut is rich in K which suggests vapor transport of alkaline elements during the mineralizing magmatic process, while the groundmass of the post‐ore “granodiorite” porphyry at Mamut contains small amounts of normative corundum suggesting depletion in alkaline elements at the root zone of the magma column. Sub‐dendritic tremolitic amphibole rims on hornblende phenocrysts in the Mamut adamellite porphyry suggest interaction between the mineralizing magma and the exsolved fluids. Occurrences of clinopyroxene microphenocrysts and pseudomor‐phic aggregates of shredded biotite and clinopyroxene after hornblende phenocrysts in the barren intrusives imply lower water fugacity and decreasing in water fugacity, respectively. Compositional gap between the core of hornblende phenocrysts and the tremolitic amphibole rims and those in the groundmass of the Mamut adamellite porphyry suggests a decrease in pressure. Higher XMg (=Mg/(Mg+Fe) atomic ratio) in the tremolitic amphibole rims in the Mamut adamellite porphyry compared to those of the barren intrusions suggests high oxygen fugacity. High halogen contents of igneous hydrous minerals such as amphiboles, biotite and apatite in the Mamut adamellite porphyry suggest the existence of highly saline fluids during the intrusion and solidification of the mineralizing magma. Fluid inclusions found in quartz veinlet stockworks are characterized by abundant hypersaline polyphase inclusions associated with subordinate amounts of immiscible gaseous vapor. Both Cu and Au are dispersed in disseminated and quartz stockwork ores. Chalcopyrite and pyrrhotite as well as magnetite are the principal ore minerals in the biotitized disseminated ores. Primary assemblage of intermediate solid solution (iss) and pyrrhotite converted to the present assemblage of chalcopyrite and pyrrhotite during cooling. Subsequent to biotitization, quartz veinlet stockworks formed associated with retrograde chlorite alteration. The Cu‐Fe sul–fides associated with stockwork quartz veinlet are chalcopyrite and pyrite. Overlapping Pb and Zn and subsequent Sb mineralizations were spatially controlled by NNE‐trending fractures accompanying the phyllic and advanced argillic alteration envelope. Sulfur isotopic composition of ore sulfides are homogeneous (about +2%) throughout the mineralization stages. These are identical to those of the magmatic sulfides of Mount Kinabalu adamellitic rocks.  相似文献   

17.
PP3超镁铁岩主要岩石类型有纯橄岩和石榴石橄榄岩,两者为渐变,主要矿物为橄榄石、铬尖晶石、石榴石、单斜辉石和斜方辉石.铬尖晶石的Cr#[Cr/(Cr+Mg) ×100]从51~89变化,TiO2和MnO2值分别低于0.26%和0.46%.铬尖晶石矿物表现为4期次演化的特点,反映了从岩浆期、榴辉岩相、角闪岩相和绿片岩相演化特征.随着超镁铁岩的演化,铬尖晶石表现为Cr#不断增大,而Mg#[Mg×100/(Mg+Fe2+) ]不断减少、氧逸度不断增加的过程.PP3铬尖晶石反映了地幔来源,为大陆岩石圈超镁铁岩特征,后期随折返而演化.从石榴石与铬尖晶石相互转变过程看出,PP3超镁铁岩经历了深度加大的过程,超镁铁岩曾经到达100km以上的岩石圈地幔深处.在绿片岩相-绿片角闪岩相变质过程中,铬尖晶石中Cr、Mg和Al减少,Fe相对增加,产生富Cr尖晶石变质作用样式.晚期剪切变形等次生变化影响了铬尖晶石矿物成分.   相似文献   

18.
Kimberlites, carbonatites and ultramafic, mafic and potassic lamprophyres have been produced in West Greenland in recurrent events since the Archaean. Five distinct age groups are recognised: Archaean (>2500 Ma). Early Proterozoic (1700–1900 Ma), Middle Proterozoic (Gardar, c. 1100–1300 Ma), Late Proterozoic (600 Ma) and Mesozoic-Tertiary (200-30 Ma) The rocks comprise two large and four small carbonatite occurrences, four kimberlite dyke swarms, one lamproite dyke swarm and one lamproite pipe, one dyke swarm of potassic lamprophyre (shonkinite) and some ten dyke swarms of ultramafic lamprophyre and monchiquite. Geochemical data for the various rock groups are presented. Some of the carbonatites may represent relatively unmodified mantle-derived melts. The kimberlites range from primitive to differentiated compositions, and there are regional differences between kimberlites within Archaean and Proterozoic basement. The ultrapotassic lamproites and shonkinites have strong negative Nb spikes in their trace element spectra. The ultramafic and monchiquitic lamprophyres encompass a large compositional variation; however, several of the dyke swarms have individual chemical characters.

The rocks are very unevenly distributed in West Greenland, indicating a lithospheric control, probably by old weakness zones providing access to the surface. The kimberlites are considered to be mainly of asthenospheric derivation. The regional differences are interpreted in terms of melting with phlogopite as a residual phase, with smaller degrees of melting at deeper levels beneath the Archaean lithosphere than beneath the Proterozoic. The ultrapotassic lamproites and shonkinites occur almost exclusively within a continental collision zone with possible two-way subduction and they are interpreted as mainly of lithospheric derivation, with a contribution from a subducted slab. Data for the other rock types are equivocal.

Except for the Archaean rocks, the age groups can be related to major geotectonic events. The Early Proterozoic group is related to continental collision at 1850 Ma and subsequent rifting; the Middle Proterozoic group is related to continental rifting (Gardar) and the Mesozoic group is likewise related to continental rifting prior to continental break-up in the Tertiary. The 600 Ma kimberlites and carbonatite are envisaged as cratonic, extra-rift activity in relation to continental break-up and formation of the Iapetus ocean further south, perhaps with a common cause in a broad, impinging mantle plume.  相似文献   


19.
角闪石和黑云母是含稀有稀土金属矿物的高分异碱性花岗岩中常见的暗色矿物。角闪石和黑云母对不同元素(尤其是Nb、Ta、Zr、REE等稀有稀土金属元素)的相容性特点使它们的主微量元素特征成为岩浆演化的"日志",对构建含矿岩浆的成岩成矿模型具有一定意义。本文针对新疆拜城波孜果尔碱性花岗岩体中的角闪石和黑云母,利用电子探针(EPMA)和激光剥蚀电感耦合等离子体质谱仪(LA-ICP-MS)等分析技术,开展精细的矿物学研究,综合厘定Nb、Ta等元素在岩浆结晶过程中的富集和分配过程。波孜果尔岩体中的角闪石均为亚铁钠闪石,总体表现为较高的Na和Fe含量,而相对贫Ca(0.15 apfu)、Mg(0.06 apfu)和Ti(0.07 apfu),成分的均一性以及轻稀土元素的亏损特征暗示了角闪石较晚结晶且角闪石结晶前大量富轻稀土元素矿物结晶分离。根据共生关系黑云母可分为A、B两类,它们显示出不同的化学成分。A类黑云母具有相对较高的F含量(A类为3.81%～4.82%,B类为1.68%～3.65%)和SiO_2含量(A类为41.5%～43.3%,B类为35.9%～38.5%),相对较低的TFeO含量(A类为28.0%～31.4%,B类为32.2%～35.7%)和Al_2O_3含量(A类为6.45%～7.62%,B类为9.70%～11.00%)。黑云母与角闪石中氟的含量变化指示了氟在结晶过程中的富集、饱和过程以及氟饱和引起的稀有稀土金属矿物大量结晶现象。由于在主要矿物中的不相容性,成矿元素Nb、Ta在熔体中含量逐渐上升,但主要矿物及大部分副矿物中均高于全岩的Nb/Ta值产生了"Ta丢失"现象。结合前人研究,本文认为气热相带出与锆石的结晶分离两种机制共同作用导致Ta从熔体中分离。  相似文献   

20.
The ultramafic body sampled in the Chinese Continental Scientific Drilling (CCSD) Hole PP3 is located in the eastern part of the Dabie-Sulu UHP metamorphic belt near Donghai County. It is about 480 m thick, and consists chiefly of garnet peridotite, dunite and serpentinite. The principal minerals include olivine, chromium spinel, diopside, enstatite, garnet with minor secondary augite, phlogopite and amphibole. Both the olivine and orthopyroxene are highly magnesian, and the garnet is pyropic with 5.4-6.4% CaO and 0.3-3.3% Cr2O3. Two generations of clinopyroxene are present; an early diopside followed by augite. Chromium spinels are highly variable with Cr#s (100Cr / (Cr + Al)) between 51 and 89, and their compositions reflect different processes of formation, namely partial melting and eclogite, amphibole and greenschist facies metamorphism. The Mg#s (100 Mg / (Mg + Fe2+))of the spinels correlate positively with the Cr#s but negatively with oxygen fugacity. Based on the spinel compositions the ultramafic rocks originated in the shallow mantle, then subducted to depths of more than 100 km and finally exhumed to the surface. They underwent partial melting at shallow depths, mostly in the spinel facies, and were later transformed into garnet peridotites during deep subduction. All of the rocks were weakly metasomatized during exhumation and were subjected to retrograde metamorphism.  相似文献   

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