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1.
苏鲁造山带超高压变质岩岩石学、氧同位素、流体包裹体和名义上无水矿物的研究表明,流体-岩石相互作用在大陆地壳的俯冲与折返过程中起到多重的重要作用,并形成了复杂的流体演化过程:(1)大陆表壳岩通过与高纬度大气降水的交换作用被广泛水化,并获得了异常低的氧同位素成分;(2)在水化陆壳物质的俯冲过程中发生了一系列的进变质脱水反应,所释放的流体主要结合进了高压、超高压含水矿物和名义上无水超高压矿物;(3)在超高压变质过程中,以水为主的变质流体通过选择性的吸收使其盐度逐渐升高,并在峰期出现高密度、高盐度的H2O或CO2-H2O流体。有机质的分解反应在局部形成了以CO2、N2、CH4或它们的混合物为主要成分的变质流体;(4)名义上无水超高压矿物的结构水出溶是早期退变质流体的主要来源,并在局部富集形成了高压变质脉体;(5)透入性的中、低盐度水流体活动使超高压变质岩通过一系列的水化反应转变成角闪岩相变质岩;(6)沿韧性剪切带和脆性破碎带的强烈水流体活动为绿片岩相退变质作用和低压石英脉的形成提供了变质流体;(7)可变盐度的H2O或CO2-H2O流体是整个超高压变质岩形成与折返过程中的主要流体,但局部的流体.岩石相互作用形成了非极性的变质流体。  相似文献   

2.
郑永飞 《地球学报》2005,26(Z1):94-97
对大别-苏鲁造山带超高压变质岩矿物稳定同位素的系统研究发现,超高压变质过程中存在少量含水流体,但是流体的活动性很小,在不同岩相界面之间缺乏明显的流体渗透;超高压榴辉岩中的石英脉是蜂期变质后含水矿物降压分解和羟基出溶引起的流体流动结果,不是板块俯冲过程中进变质作用的产物;超高压变质岩经历了广泛的角闪岩相退变质作用,退变质流体主要来源于板块折返过程中超高压矿物中溶解经基的降压出溶。  相似文献   

3.
利用中国大陆科学钻探工程连续取样的优势,对主孔200~4000m超高压变质岩进行了系统的地球化学研究,结果对大陆俯冲带变质的化学地球动力学提供了新的制约。目前取得的主要成果如下:(1)建立了200~4000m深度的超高压矿物氧同位素变化剖面,发现~(18)O亏损深度达3300m。结合大别-苏鲁造山带地表露头岩石达30000km~2的~(18)O亏损,表明扬子陆块北缘曾发生三维空间巨量物质(~100000km~3)的~(18)O亏损;(2)钻孔超高压变质岩的原岩形成于新元古代中期(~780Ma),属于双重双峰式岩浆活动的产物;原岩既有中元古代晚期新生地壳,也有古元古代中期古老地壳。这种双重双峰式岩浆活动出现在弧-陆碰撞带基础上发育的裂谷构造带,是对Rodinia超大陆开始裂解的响应;(3)高压榴辉岩相重结晶作用发生在216±3Ma,高压榴辉岩相重结晶作用持续的时间为1.9~9.3Myr或更短;(4)不同岩性接触带的矿物O同位素、H同位素、全水含量以及羟基含量的研究表明,退变质流体在同位素组成上是内部缓冲的,且退变质流体主要来自于名义上无水矿物中结构羟基和分子水的出溶。定量计算表明,这些出溶的结构羟基和分子水能为角闪岩相退变质作用提供足够的流体来源;(5)在不同岩性接触带,稳定同位素、水含量及岩相学上出现同步变化,表明不同岩性接触带可能是流体活动最剧烈的地方。对于远离榴辉岩-片麻岩接触带的榴辉岩,退变质流体主要来自榴辉岩内部名义上无水矿物中结构羟基和分子水的出溶。对于靠近接触带的榴辉岩,则可能主要受来自比榴辉岩更富水的片麻岩中矿物的脱水作用。根据相邻样品之间的距离、岩相学和δ~(18)O值,可以确定出不同岩性和相同岩性之间氧同位素不均一性的尺度为20到50cm,对应于大陆碰撞过程中流体活动的最大尺度;(6)对两个连续岩芯段的主量和微量元素剖面研究表明,在大陆俯冲带变质过程中,大离子亲石元素(LILE)和轻稀土(LREE)具有较高的活动性,而高场强元素(HFSE)和重稀土(HREE)是不活动的。这些元素的活动可能是由折返过程中大陆地壳的部分熔融导致的,因此指示了超临界流体的出现。折返过程中大陆地壳的这种部分熔融作用导致了不同板片组分之间的质量迁移,但是这种有效的迁移只发生在很小的尺度范围内,在岩相学接触带和裂隙带的局部开放系统中。  相似文献   

4.
苏鲁造山带浅变质岩的成因及其大地构造意义   总被引:2,自引:0,他引:2       下载免费PDF全文
苏鲁造山带超高压变质带内部及其北缘,出露仅经过绿片岩相变质作用的浅变质岩系。通过对该浅变质岩的区域分布、地质特征及地球化学的综合研究,表明这些浅变质岩系与大别-苏鲁造山带大陆板块俯冲存在密切的成因关系,为扬子板块俯冲过程中被刮削下来的构造残片,构成大陆板块俯冲过程中形成的构造加积杂岩。在此基础上,厘定了苏鲁造山带的构造成因模型,并对苏鲁造山带的东延问题进行了讨论。  相似文献   

5.
田野  黄建  回迎军  肖益林 《岩石学报》2015,31(7):1818-1840
高压-超高压变质岩中的变质脉能够反映俯冲带变质流体的组成和演化。为了探究大陆俯冲带超临界流体活动及伴随的元素迁移,本文系统地研究了苏鲁造山带南部江苏东海池庄地区的超高压榴辉岩及变质脉。变质脉主要是由石英、石榴石、绿辉石、多硅白云母、蓝晶石、黝帘石、金红石和锆石等矿物组成,与寄主榴辉岩的矿物组成类似。相比于榴辉岩,脉体中的石榴石更加富集重稀土元素(HREE);黝帘石强烈富集轻稀土元素(LREE)。变质脉和榴辉岩中各主要矿物的氧同位素组成在误差范围内一致(石英的δ18O分别为2.42‰和2.79‰;石榴石为-0.30‰和0.010‰;绿辉石为0.25‰和0.071‰),说明变质脉的形成与榴辉岩释放的内部流体有关。综合已有的研究,发现大别-苏鲁造山带不同地区的变质脉和榴辉岩具有极不均一的氧同位素组成,说明在陆壳深俯冲和折返过程中,流体活动有限。利用矿物温压计得到变质脉的峰期变质温压条件为692±65℃和3.6±0.3GPa,脉体中锆石U-Pb定年结果表明锆石的形成时代为218±2.4Ma,指示变质脉形成于深俯冲陆壳折返初期的超高压变质阶段。变质脉中矿物组合和矿物的主微量元素特征说明成脉流体富集Si、Al、Ca、K、LILE、REE和HFSE等元素,表明成脉流体可能是溶解能力极强的超临界流体。  相似文献   

6.
中国大别-苏鲁造山带为大陆板块俯冲形成的碰撞造山带,该带北缘和内部产有原岩时代为新元古代-晚古生代的浅变质岩。这些浅变质岩对应于扬子板块北缘前寒武变质基底和扬子板块北缘古生代大陆架沉积物,形成过程于印支期扬子板块向北俯冲过程中的刮削作用密切相关,与大洋板块俯冲过程中刮削形成的加积楔具有类似的动力学过程。对大别-苏鲁造山带浅变质岩的深入研究,不仅有助于揭示大陆板块俯冲过程中高压-超高压岩石形成与折返过程,而且确定了扬子板块与华北板块之间的缝合线位置位于大别造山带北淮阳带的北部和苏鲁造山带的五莲-蓬莱群的北侧。  相似文献   

7.
闫伟豪  王勤  李伟强 《地质学报》2022,96(2):500-516
碳酸盐岩和碳酸盐化岩石是俯冲带中碳的主要地质载体.俯冲-折返的超高压变质岩记录了俯冲隧道中流体-岩石的相互作用与元素迁移,是研究地球内部元素循环的重要媒介.本文采集了大别造山带罗家岭互层状产出的大理岩和榴辉岩,建立了横跨岩性界面的矿物组成、显微结构和Mg-Fe-C-O同位素剖面.大理岩中主要组成矿物为白云石,其次为方解...  相似文献   

8.
许志琴 《岩石学报》2007,23(12):3041-3053
中国大陆科学钻探工程和苏鲁高压-超高压变质带为大陆岩石圈的深俯冲与折返动力学的研究提供了以下制约:(1)苏鲁高压/超高压变质地体迭置于南、北苏鲁两个不同时代及属性的基底之上;(2)苏鲁巨量表壳岩石深俯冲至200km以下的上地幔深度,并经历超高压变质作用;(3)根据不同类型超高压变质岩石锆石的SHRIMP-U/Pb原位精确定年,获得超高压变质岩石的深俯冲-折返全过程(240~252Ma→230~237Ma→207~218Ma)时限.并建立了新的深俯冲-折返全过程的P-T-t轨迹;(4)富钛铁的辉长岩在大陆地壳的深俯冲过程中,经历了超高压变质作用并转变成了富含金红石的榴辉岩,形成了超高压变质的钛矿床;(5)通过榴辉岩和石榴石橄榄岩的显微构造分析及石榴石、绿辉石和橄榄石EBSD测量,确定深俯冲过程中绿辉石和橄榄石的组构运动学和流变学特征;(6)在大陆的深俯冲过程中,强烈水化的陆壳岩石经历了进变质脱水过程,巨量的地表水带入到>100~200Km的地幔深处,在超高压变质峰期的极端条件下,通过含水超高压变质矿物的分解形成超临界的含水熔体,导致有效的壳-幔物质交换和岩石圈物质分异;(7)苏鲁超高压变质地体在折返阶段形成挤出纳布构造,与岩石圈深俯冲管道流的折返挤出机制有关;(8)提出新的深俯冲-折返动力学模式:陆.陆碰撞的深俯冲剥蚀模式及大陆地壳多重性、分层型和穿时性的俯冲和折返模式.  相似文献   

9.
超高压变质岩生成问题中解决低密度大陆地壳深俯冲力学机制是一个关键问题。虽然俯冲地幔岩石可以裹携十几千米乃至几十千米尺度的陆壳块体到超高压变质深度,大规模的陆壳深俯冲需要特殊的构造条件。新西兰南岛北端研究表明,俯冲大洋板块能携带宽度达150km左右的窄条陆壳克服浮力达到超高压变质深度,而大陆板块碰撞的主体则浮在岩石圈上形成走滑断层。苏鲁-大别可能曾存在类似的构造条件:苏鲁西侧俯冲海洋板片首先拖曳苏鲁陆壳俯冲到超高压变质深度;随后大别以西俯冲大洋板片拖曳大别至超高压变质深度,而陆壳浮力导致苏鲁陆壳停止俯冲,飘浮的陆壳被北推而形成郯庐断裂;秦岭陆陆碰撞造山后大别超高压陆壳也折返;秦岭作为典型造山带,虽然不排除零星超高压变质的可能,但不具备大规模超高压变质的条件。  相似文献   

10.
超高压变质岩的塑性流变学   总被引:1,自引:1,他引:0  
钟增球  索书田 《现代地质》2007,21(2):203-212
岩石流变作用是大陆造山作用的基本特征,超高压岩石的形成和折返过程也是大陆深俯冲带内物质的复杂流变过程。要深入理解大陆造山带的造山作用和大陆壳岩石的深俯冲和折返动力学过程,必须对大陆地壳及地幔岩石的流变学进行深入研究。岩石圈流变学的主要研究内容主要包括流变学分层性、变形分解和应变局部化及大陆壳岩石部分熔融作用的流变学效应等。应用岩石圈流变学的基本原理和方法,分析了大别-苏鲁超高压变质带中超高压变质岩的塑性流变特点,探讨了超高压变质岩形成和折返过程的塑性流变学。  相似文献   

11.
大别山超高压硬玉石英岩中的水: 来自红外光谱的证据   总被引:2,自引:0,他引:2  
为了探讨大别山“名义上无水矿物”(NAMs)中结构水的分布特征, 研究相关的流体活动、矿物变形以及板块俯冲和折返动力学过程提供重要的微观信息.对大别山双河和碧溪岭地区超高压硬玉石英岩中的石英、硬玉、石榴石和金红石进行了傅立叶变换红外光谱(FTIR)分析, 研究结果显示这些矿物都含有以OH-或者H2O形式存在的氢, 硬玉中结构水平均含量在1000×10-6左右; 石榴石结构水含量在(900~1600)×10-6之间, 各样品颗粒结构水的分布不均匀; 副矿物金红石结构水含量在2000×10-6以上, 而石英结构中基本不含或仅含微量水(< 4×10-6).双河和碧溪岭地区的硬玉石英岩全岩含水量分别为(490~600)×10-6和545×10-6, 不同地区同一种NAMs中结构水含量基本相同.表明在高压-超高压变质岩的形成过程中, 地壳或原岩中的水可以通过这些超高压变质岩中的NAMs携带到地球深部.   相似文献   

12.
By taking advantage of having depth profiles between contrasting lithologies from core samples of the Chinese Continental Scientific Drilling (CCSD) project, a combined study was carried out to examine changes in mineral H isotope, total water and hydroxyl contents in garnet and omphacite across the contacts between ultrahigh-pressure (UHP) eclogite and gneiss in the Sulu orogen, east-central China. The samples of interest were from two continuous core segments from the CCSD main hole at depths of 734.21-737.16 and 929.67-932.86 m, respectively. The results show δD values of −116‰ to  − 64‰ for garnet and −104‰ to −82‰ for omphacite, consistent with incorporation of meteoric water into protoliths of UHP metamorphic rocks by high-T alteration. Both equilibrium and disequilibrium H isotope fractionations were observed between garnet and omphacite, suggesting fluid-assisted H isotope exchange at local scales during amphibolite-facies retrogression. While bulk water analysis gave total H2O concentrations of 522-1584 ppm for garnet and 1170-20745 ppm for omphacite, structural hydroxyl analysis yielded H2O contents of 80-413 ppm for garnet and 228-412 ppm for omphacite. It appears that significant amounts of molecular H2O are present in the minerals, pointing to enhanced capacity of water storage in the UHP eclogite minerals. Hydrogen isotope variations in the transition between eclogite and gneiss show correlations with variations in their water contents. Petrographically, the degree of retrograde metamorphism generally increases with decreasing distance from the eclogite-gneiss boundary. Thus, retrograde metamorphism results in mineral reactions and H isotope variation. Because hydroxyl solubility in nominally anhydrous minerals decreases with dropping pressure, significant amounts of water are expected to be released from the minerals during decompression exhumation. Decompression exsolution of structural hydroxyl from 1 m3 volume of eclogite composed of only garnet and omphacite results in release of a quantitative estimate of 3.07-3.44 kg water that can form 140-156 kg amphibole during exhumation. Therefore, it is concluded that fluid for retrogression of the eclogites away from the eclogite-gneiss boundary was derived from the decompression exsolution of structural hydroxyl and molecular H2O in nominally anhydrous minerals. For the eclogites adjacent to gneiss, in contrast, the retrograde metamorphism was principally caused by aqueous fluid from the gneiss which is relatively rich in water. Consequently, both the origin and availability of metamorphic fluid during exhumation of deeply subducted continental crust are deciphered by this combined study focusing on the transitions and the retrograde processes between the felsic and mafic UHP rocks.  相似文献   

13.
大别山双河超高压榴辉岩中的水: 微区红外光谱分析   总被引:9,自引:2,他引:7  
大陆深俯冲板块到一定深度后(约90~110km), 几乎没有含水矿物存在, 超高压岩石中名义上无水矿物(NAMs) 成为俯冲板块中水的主要载体, 是示踪超高压变质流体的重要途径.对大别山双河地区超高压榴辉岩中的石榴石和绿辉石进行了详细的微区傅立叶变换红外光谱(MicroFTIR) 分析.FTIR结果显示所有石榴石和绿辉石颗粒都含有结构水, 以OH的形式存在, 其含量范围分别为(30~1860)×10-6和(360~620)×10-6.榴辉岩全岩水含量为(300~750)×10-6, 表明即使是在超高压变质作用的温压条件下, 榴辉岩也可以至少携带数百10-6的水进入深部地球.对石榴石颗粒内部的多点观察发现, 结构水含量的分布出现2种情况: (1) 颗粒内部的均一分布; (2) 核部水含量高而边部低.石榴石颗粒边部的低水含量可能是抬升过程中由于压力降低引起的H扩散所致, 扩散出来的H可能构成了早期退变质流体的重要来源.对于同一样品来说, 结构水含量在绿辉石和石榴石之间的比值为0.5~3.5.   相似文献   

14.
名义上无水矿物的水含量研究对于认识俯冲带流体活动和地球动力学具有重要意义.对大别山金河桥榴辉岩中石榴石进行了傅里叶变换红外光谱分析和主微量元素分析,结果表明石榴石含有分子水和结构羟基,分别为 < 1×10-6~1 946×10-6和< 1×10-6~1 347×10-6.石榴石羟基含量与Ca、Na、Ti、Zr和Pr正相关,而与Si负相关,表明羟基结合机制以水榴石替代为主并伴有其他机制.分子水主要为初始水或折返过程中羟基转化形成.石榴石总水含量为 < 1×10-6~3 293×10-6,最大值对应于峰期超高压石榴石水储存能力.水在峰期石榴石中可达到饱和.石榴石变化的水含量受原岩性质、流体可获得性、压力和温度等多种因素控制,但主要由折返过程中降压脱水导致.石榴石平均总水含量为749×10-6~1 164×10-6,是俯冲板片向地幔水传输的重要介质.   相似文献   

15.
Fluid availability during high‐grade metamorphism is a critical factor in dictating petrological, geochemical and isotopic reequilibration between metamorphic minerals, with fluid‐absent metamorphism commonly resulting in neither zircon growth/recrystallization for U‐Pb dating nor Sm‐Nd isotopic resetting for isochron dating. While peak ultra‐high pressure (UHP) metamorphism is characterized by fluid immobility, high‐pressure (HP) eclogite‐facies recrystallization during exhumation is expected to take place in the presence of fluid. A multichronological study of UHP eclogite from the Sulu orogen of China indicates zircon growth at 216 ± 3 Ma as well as mineral Sm‐Nd and Rb‐Sr reequilibration at 216 ± 5 Ma, which are uniformly younger than UHP metamorphic ages of 231 ± 4 to 227 ± 2 Ma as dated by the SHRIMP U‐Pb method for coesite‐bearing domains of zircon. O isotope reequilibration was achieved between the Sm‐Nd and Rb‐Sr isochron minerals, but Hf isotopes were not homogenized between different grains of zircon. The HP eclogite‐facies recrystallization is also evident from petrography. Thus this process occurred during exhumation with fluid availability from decompression dehydration of hydrous minerals and the exsolution of hydroxyl from nominally anhydrous minerals. This provides significant amounts of internally derived fluid for extensive retrogression within the UHP metamorphosed slabs. Based on available experimental diffusion data, the consistent reequilibration of U‐Pb, Sm‐Nd, Rb‐Sr and O isotope systems in the eclogite minerals demonstrates that time‐scale for the HP eclogite‐facies recrystallization is c. 1.9–9.3 Myr or less. This provides a maximum estimate for duration of the fluid‐facilitated process in the HP eclogite‐facies regime during the exhumation of deeply subducted continental crust.  相似文献   

16.
苏北青龙山超高压变质榴辉岩流体包裹体特征与流体演化   总被引:3,自引:7,他引:3  
根据青龙山超高压变质榴辉岩中流体包裹体的化学成分、矿物中的分布特征将岩石中的流体包裹体分为五类,即富N2包裹体、高盐度(22.4-略大于23.2wt%NaCl)的NaCl CaCl2 H2O体系流体包裹体、中高盐度(12.6-16.0wt%NaCl)的含Mg2 或Fe2 的NaCl H2O体系流体包裹体、中等盐度(6.4-10.5wt%NaCl)水溶液包裹体和低盐度(3.3-0.2wt%NaCl)的水溶液包裹体。富N2包裹体形成于超高压变质峰期阶段,高盐度的流体包裹体形成于超高压变质岩折返早期固体出溶体出溶阶段,中高盐度的流体包裹体形成于高压变质重结晶作用阶段,中等盐度的流体包裹体形成于角闪岩相变质重结晶作用阶段,低盐度的流体包裹体形成于折返晚期的绿片岩退变质作用阶段。超高压变质峰期阶段和折返早期的高盐度流体和中高盐度的流体主要来自继承原岩中的流体(如含NH4 矿物分解或片麻岩原岩中的有机质分解,名义上无水矿物中羧基水的出溶),晚期角闪岩相退变质阶段的中等盐度的流体除名义上无水矿物中羟基水的出溶外还有外来流体的加入,绿片岩相退变质作用阶段的流体主要为外来流体。  相似文献   

17.
自20世纪80年代在大陆地壳岩石中发现柯石英和金刚石等超高压变质矿物以来,大陆深俯冲和超高压变质作用就成为了固体地球科学研究的前沿和热点领域之一。经过三十余年的研究,已经在大陆地壳的俯冲深度、深俯冲岩石变质P-T-t轨迹、俯冲地壳岩石的折返机制、深俯冲岩石的原岩性质、大陆碰撞过程中的熔/流体活动与元素活动性、俯冲隧道内部不同类型壳幔相互作用、碰撞后岩浆岩的成因、大陆碰撞造山带成矿作用等方面取得了许多重要成果。本文重点对大陆俯冲带超高压岩石部分熔融和不同类型壳幔相互作用近十年来的研究进展进行回顾和总结,并对存在的相关科学问题和未来的研究方向进行了展望。深俯冲大陆地壳的部分熔融主要出现在两个阶段:折返的初期阶段和碰撞后阶段,前者产生了碱性熔体,后者产生了钙碱性熔体。大陆俯冲带壳幔相互作用有两种类型,涉及地幔楔与两种俯冲带流体的交代反应:一是来自深俯冲陆壳的变质脱水/熔融,二是来自先前俯冲古洋壳的变质脱水/熔融。  相似文献   

18.
The Dabie–Sulu orogenic belt of east-central China has long been a type location for the study of geodynamic processes associated with ultrahigh-pressure (UHP) tectonics. Much of our understanding of the world's most enigmatic processes in continental deep-subduction zones has been deduced from various records in this belt. By taking advantage of having depth profiles from core samples of the Chinese Continental Scientific Drilling (CCSD) project in the Sulu orogen, a series of combined studies were carried out for UHP metamorphic rocks from the main hole (MH) at continuous depths of 100 to 5000 m. The results provide new insights into the chemical geodynamics of continental subduction-zone metamorphism, especially on the issues that are not able to be resolved from the surface outcrops. Available results from our geochemical studies of CCSD-MH core samples can be outlined as follows. (1) An O isotope profile of 100 to 5000 m is established for the UHP metamorphic minerals, with finding of 18O depletion as deep as 3300 m. Along with areal 18O depletion of over 30,000 km2 along the Dabie–Sulu orogenic belt, three-dimensional 18O depletion of over 100,000 km3 occurs along the northern margin of the South China Block. (2) Changes in mineral O isotope, H isotope and water content occur in eclogite-gneiss transitions, concordant with petrographic changes. The contact between different lithologies is thus the most favorable place for fluid action; fluid for retrogression of the eclogites away from the eclogite-gneiss boundary was derived from the decompression exsolution. For the eclogites adjacent to gneiss, in contrast, the retrograde metamorphism was principally caused by aqueous fluid from the gneiss that is relatively rich in water. Inspection of the relationship between the distance, petrography and δ18O values of adjacent samples shows O isotope heterogeneities between the different and same lithologies on scales of 20 to 50 cm, corresponding to the maximum scales of fluid mobility during the continental collision. (3) Studies of major and trace elements in the two continuous core segments indicate high mobility of LILE and LREE but immobility of HFSE and HREE. Some eclogites have andesitic compositions with high SiO2, alkalis, LREE and LILE but low CaO, MgO and FeO contents. These features likely result from chemical exchange with gneisses, possibly due to the metasomatism of felsic melt produced by partial melting of the associated gneisses during the exhumation. On the other hand, some eclogites appear to have geochemical affinity to refractory rocks formed by melt extraction as evidence by strong LREE and LILE depletion and the absence of hydrous minerals. These results provide evidence for melt-induced element mobility in the UHP metamorphic rocks, and thus the possible presence of supercritical fluid during exhumation. In particular, large variations in the abundance of such elements as SiO2, LREE and LILE occur at the contact between eclogite and gneiss. This indicates their mobility between different slab components, although it only occurs on small scales and is thus limited in local open-systems. (4) Despite the widespread retrogression, retrograde fluid was internally buffered in stable isotope compositions, and the retrograde fluid was of deuteric origin and thus was derived from the decompression exsolution of structural hydroxyl and molecular water in nominally anhydrous minerals. (5) A combined study of petrography and geochronology reveals the episode of HP eclogite-facies recrystallization at 216 ± 3 Ma, with timescale of 1.9 to 9.3 Myr or less. Collectively, the Dabie–Sulu UHP terrenes underwent the protracted exhumation (2–3 mm/yr) in the HP-UHP regime. (6) Zircon U–Pb ages and Hf isotopes indicate that mid-Neoproterozoic protoliths of bimodal UHP metaigneous rocks formed during supercontinental rifting along preexisting arc-continent collision orogen, corresponding to dual bimodal magmatism in response to the attempted breakup of the supercontinent Rodinia at about 780 Ma. The first type of bimodal magmatism was formed by reworking of juvenile Late Mesoproterozoic crust, whereas the second type of bimodal magmatism was principally generated by rifting anatexis of ancient Middle Paleoproterozoic crust. In conclusion, the geochemical studies of CCSD-MH core samples have placed important constraints on the nature and scale of fluid action and element mobility during the continental subduction and UHP metamorphism.  相似文献   

19.
Coesite is typically found as inclusions in rock‐forming or accessory minerals in ultrahigh‐pressure (UHP) metamorphic rocks. Thus, the survival of intergranular coesite in UHP eclogite at Yangkou Bay (Sulu belt, eastern China) is surprising and implies locally “dry” conditions throughout exhumation. The dominant structures in the eclogites at Yangkou are a strong D2 foliation associated with tight‐to‐isoclinal F2 folds that are overprinted by close‐to‐tight F3 folds. The coesite‐bearing eclogites occur as rootless intrafolial isoclinal F1 fold noses wrapped by a composite S1–S2 foliation in interlayered phengite‐bearing quartz‐rich schists. To evaluate controls on the survival of intergranular coesite, we determined the number density of intergranular coesite grains per cm2 in thin section in two samples of coesite eclogite (phengite absent) and three samples of phengite‐bearing coesite eclogite (2–3 vol.% phengite), and measured the amount of water in garnet and omphacite in these samples, and also in two samples of phengite‐bearing quartz eclogite (6–7 vol.% phengite, coesite absent). As coesite decreases in the mode, the amount of primary structural water stored in the whole rock, based on the nominally anhydrous minerals (NAMs), increases from 107/197 ppm H2O in the coesite eclogite to 157–253 ppm H2O in the phengite‐bearing coesite eclogite to 391/444 ppm H2O in the quartz eclogite. In addition, there is molecular water in the NAMs and modal water in phengite. If the primary concentrations reflect differences in water sequestered during the late prograde evolution, the amount of fluid stored in the NAMs at the metamorphic peak was higher outside of the F1 fold noses. During exhumation from UHP conditions, where NAMs became H2O saturated, dehydroxylation would have generated a free fluid phase. Interstitial fluid in a garnet–clinopyroxene matrix at UHP conditions has dihedral angles >60°, so at equilibrium fluid will be trapped in isolated pores. However, outside the F1 fold noses strong D2 deformation likely promoted interconnection of fluid and migration along the developing S2 foliation, enabling conversion of some or all of the intergranular coesite into quartz. By contrast, the eclogite forming the F1 fold noses behaved as independent rigid bodies within the composite S1–S2 foliation of the surrounding phengite‐bearing quartz‐rich schists. Primary structural water concentrations in the coesite eclogite are so low that H2O saturation of the NAMs is unlikely to have occurred. This inherited drier environment in the F1 fold noses was maintained during exhumation by deformation partitioning and strain localization in the schists, and the fold noses remained immune to grain‐scale fluid infiltration from outside allowing coesite to survive. The amount of inherited primary structural water and the effects of strain partitioning are important variables in the survival of coesite during exhumation of deeply subducted continental crust. Evidence of UHP metamorphism may be preserved in similar isolated structural settings in other collisional orogens.  相似文献   

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