共查询到13条相似文献,搜索用时 171 毫秒
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采用CM12透射电镜,对我国四川昌北M稀土矿床中的氟碳钙矿微结构特征作了电子衍射分析和晶格象观察,揭示出氟碳钙铈矿晶体中混合多型体的堆垛序列,在不同部分观测到不同的多型体,其中以氟碳钙铈矿6R多型为常见普通多型体。本次工作发现42R,48R和16H三种新多型,并进一步证明,氟碳钙铈矿晶体中存在的多型结构相当复杂,但以长周期堆垛形成的多型体出现的几率要比短周期堆垛的多型体少得多。 相似文献
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氟碳钙铈矿结构中晶体缺陷的高分辨电镜研究 总被引:1,自引:1,他引:1
用高分辨电子显微术(HREM)研究了氟碳钙铈矿(BS)晶体结构中的无序堆垛和体衍交生现象,结果表明该矿物的衍生多晶体是由钙-铈氟碳酸盐矿物中不同组分的氟碳铈矿(B)和直氟碳钙铈矿(S)结构单元层沿c方向无序堆垛而成。高分辨结构象揭示出氟碳钙铈矿衍生多晶体的微结构特征。讨论了氟碳钙铈矿结构中的堆垛层错等晶体缺陷现象。 相似文献
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运用透射电镜技术,发现了三方晶系直氟碳钙铈矿(Synchysite)多型和微孪晶的存在,确定其中的多型有两种,即6R和3R多型,在3R多型中发现有微孪晶存在,这种微孪晶属(0001)孪晶面的面律(旋转)孪晶。由于直氟碳钙铈矿是钙铈氟碳酸盐系列矿物的一个端员组分,因此,对其多型和微孪晶的研究,有助于揭示该系列中间组分矿物多型和微孪晶的形成机理。 相似文献
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钙稀土氟碳酸盐矿物中新多型体的HREM研究 总被引:1,自引:0,他引:1
利用高分辨电子显微术(HREM)研究了钙稀土氟碳酸盐矿物系列中氟碳铈矿(B)/直氟碳钙铈矿(S)的混层结构。发现并确定了B_5S_2(IH,3R)、B_5S_4(3R,6R)和B_(18)S_(10)(IH)规则混层矿物中5种新多型的晶体结构类型、晶胞参数以及理论晶体化学式等。HREM研究揭示出,在B_mS_n(m>n)型规则混层矿物新多型体的结晶过程中,成矿地质环境是复杂的。阐明了这些多型体是由该系列矿物中的氟碳铈矿(B)和直氟碳钙铈矿(S)结构单元层以不同比例沿c轴方向的有序堆垛构成。 相似文献
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钙-铈氟碳酸盐矿物系列中新规则混层矿物的晶格象研究 总被引:5,自引:2,他引:5
本文用电子衍射和晶格象技术研究钙-铈氟碳酸盐矿物微结构特征。除确定有氟碳铈矿(B),氟碳钙铈矿(BS)、伦琴矿(BS_2)和B_3S_2规则混层矿物外,还首次发现了9种B_mS_n(m≥++n)型新的规则混层矿物。这些新规则混层矿物,往往以共格的形式共存于一个自然晶粒之中。大量的SAED和晶格象揭示了这类稀土矿物各成员之间的相互结构关系。研究表明:钙-铈氟碳酸盐矿物系列中矿物衍生体的微结构特征及其变化是相当复杂的,它们是由不同组分的氟碳铈矿(B)和直氟碳钙铈矿(S)的结构单元层在c轴方向通过不同比例堆垛方式,形成一系列新规则混层矿物及多型。 相似文献
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四川冕西霓石碱性花岗岩中的稀土矿物主要为钙稀土氟碳酸盐矿物系列,通过选区电子衍射(SAED)和高分辨透射电子显微术(HRTEM)研究发现该系列矿物晶体结构中广泛发育复杂多样的微观地质异常现象,其主要类型有:(1)由该系列两个端员矿物氟碳铈矿结构层(B)与直氟碳钙铈矿结构层(S)以不同比例沿C轴方向有序堆垛形成的BmSn型规则混层结构;(2)无序堆垛形成的有序一无序结构晶畴;(3)由堆垛层错形成的无序混层结构,氟碳钙铈矿中不同多型体间的共格连生结构和相转变等;(4)氟碳铈矿结构中的平行于[001]方向的平移畴及一维无公度调制结构,该类调制结构可能是由于矿物中原子占位有序度的变化而形成的无序结构状态。 相似文献
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Andrew G. Christy 《Physics and Chemistry of Minerals》1989,16(4):343-351
The concept of short-range interlayer interactions, fundamental to spin-analogue models for polytypism, is examined in the case of sapphirine. Consideration of interactions out to fourth-nearest neighbours provides a rationale for the difference between the polytype suites observed for sapphirine and wollastonite. In each case, the observed long-period structures are consistent with those predicted to be stable by the appropriate mappings onto the axial next-nearest neighbour model. Short-range interaction parameters may also be used to express stacking fault energies. This approach, combined with a simple nucleation-andgrowth model, is used to examine the possibility of metastable generation of complex polytypes in sapphirine. Statistical analysis of defect distributions and frequencies in sapphirine suggests that interactions over several hundred Ångstroms must be considered if the stacking energetics are to be accurately modelled. 相似文献
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Dozent Dr. Siegfried Haussühl Dozent Dr. German Müller 《Contributions to Mineralogy and Petrology》1963,9(1):28-39
Summary Argillaceous sediments of jurassic and lower cretaceous age in NW-Germany contain in several localities authigenous ZnS-polytypes. The crystals with a maximum height of 2 mm exhibit hexagonal-pyramidal and trigonal-pyramidal habit.With X-ray rotation and precession technique the following polytypes could be identified: Sphalerite (3 R = 3 C) 211, 411, 6H 9R, 12R, 15R and 21R.The 9 R-, 12 R- and 21 R-polytypes have not until now been described elsewhere.The structures of the new polytypes were determined as 9R=(21), 12R=(13) and 21R=(3112).Oriented intergrowths of R- and H-polytypes were frequently observed. From the intergrowth-phenomena arguments for the environmental conditions of formation can be deducted.[/p] 相似文献
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M. B. Geilikman 《Physics and Chemistry of Minerals》1982,8(1):2-7
Two mechanisms of solid-state formation of polytypes are suggested. The first is structural-kinetic by nature, the stabilization of short-period polytype (for example, 4H) being due to the fact that there are two possible structural types of nuclei in the wurtzite structure: when new phase growth takes place by means of two-dimensional nucleation, these short-period polytypes become kinetically stable although they do not correspond to the minimum of free energy, and appear as transitional phases. The second mechanism of polytype formation below the transition temperature is influenced by impurities which stabilize the hexagonal modification, in which case polytypes may arise as states that are stable with respect to a diffusionless structural wurtzite-sphalerite transformation and metastable relative to small fluctuations of impurity concentration. 相似文献