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1.
采用镍锍火试金法结合ICP-MS分析了12个北大别白垩纪镁铁-超镁铁岩样品的Ir,Ru,Rh,Pt和Pd的含量,结果显示铂族元素（PGE）的含量较低,原始地幔标准化后的PGE分布模式呈正斜率型,PPGE相对原始地幔略微亏损,而IPGE强烈亏损,Pd/Ir值远高于相应的地幔比值。这些镁铁-超镁铁岩中PGE的强烈分异是地幔低程度的部分熔融过程中,PPGE主要受硫化物控制,而Ir则存在于非硫化物相如尖晶石,可能还有合金之中造成的。同时,铂族元素的分布特征表明这些镁铁-超镁铁岩是岩浆结晶分异的产物。 相似文献
2.
新疆哈密白石泉含铜镍镁铁-超镁铁质岩体铂族元素特征 总被引：7，自引：1，他引：7
新疆哈密白石泉镁铁-超镁铁质岩体的铂族元素研究表明,岩体的铂族元素总含量较低,原始地幔标准化模式具镁铁质岩石的特征,并具Pt 正异常,且铂族元素的分异主要受结晶分异作用的影响.岩体的Cu/Pd、Se/S、Ti/Pd值表明其发生过硫化物的熔离作用.Pd/Ir、Ni/Cu特征表明了岩体系高镁玄武岩岩浆的产物.铂族元素特征揭示了白石泉岩体硫化物的熔离作用是由原始岩浆结晶分异导致的,岩体的形成是原始岩浆发生橄榄石等的结晶,导致硫化物的熔离作用后,其残余岩浆演化的结果. 相似文献
3.
阜新中生代火山岩的铂族元素特征——以碱锅和乌拉哈达为例 总被引：5，自引：0，他引：5
采用镍锍火试金法结合ICP—MS分析了碱锅玄武岩和乌拉哈达高镁安山岩样品中的Ir．Ru、Rh、Pt和Pd的含量。原始地幔标准化后的PGE分布模式呈正斜率型，Pd／Ir值高于相应的地幔比值，表明铂族元素发生了分异，这是由于在部分熔融过程中，Ir存在于地幔矿物相尖晶石和合金中，而Pd赋存于硫化物中造成的，乌拉哈达高镁安山岩中的铂族元素还可能在结晶分异过程中受到先期结晶的矿物相和合金的影响。阜新火山岩Pt的负异常可能是包含Pt的金属合金残留在地幔中造成。 相似文献
4.
提要：东波超镁铁岩体位于雅鲁藏布江缝合带的西段,在中国是一个不多见的面积超过400 km2的大型超镁铁岩体。已有的岩石学和矿物学特征表明,该岩体与同一带中含有大型铬铁矿的罗布莎岩体可以对比,是一个寻找铬铁矿床的远景区。本文开展了东波超镁铁岩的主要组成岩石类型——方辉橄榄岩的铂族元素（PGE）研究,并结合主量和稀土元素（REE）组成,探讨岩体的成因。东波超镁铁岩中方辉橄榄岩具有相当高的Os含量（3.52×10-9~4.36×10-9）,亏损的主量元素组成和低于原始地幔的稀土元素含量（0.89×10-6~1.37×10-6）,指示东波超镁铁岩为经历过部分熔融和熔体抽取的亏损残余地幔岩石。东波超镁铁岩的PGE总含量为23.97×10-9~31.98×10-9,高于原始地幔的含量;PGE配分型式为左倾的正斜率型,相对Ir亚组铂族元素（IPGE）亏损钯亚组铂族元素（PPGE）,Pd/Ir=1.49~2.65;REE配分型式为中稀土亏损的“V”型或“U”型,原始地幔标准化元素比值（La/Sm）m 为 1.05~3.37,（Gd/Yb）m=0.28~0.64;这些数据揭示东波超镁铁岩经历过交代作用,交代物质应富集不相容元素,高PGE含量,相对IPGE富集PPGE;较低的Cu/Pd比值（1226~3448）要求交代物质还应富含硫化物;推测交代物质可能来源于俯冲带构造环境下所产生岩浆熔离出的富硫化物熔体/流体。 相似文献
5.
黔西玄武岩铂、钯地球化学特征与存在状态 总被引：1，自引：0，他引：1
黔西玄武岩中铂族元素丰度较高，其含量变化顺序为Pt〉Pd〉Ru〉Ir〉Rh，表现为Pt、Pd富集，而Os、Ir、Ru、Rh亏损，说明在地幔熔融形成玄武岩的过程中，铂族元素已发生了明显的分异。在分析黔西玄武岩中Pt、Pd岩石载体所处的大地构造背景、含铂（族）矿床的可能类型和岩石化学特征与Pt、Pd可能存在状态的关系的基础上，研究了黔西玄武岩中Pt、Pd存在状态。结果表明，其状态分属硫化物态．金属互化物态、类质同像亲石态和吸附态，且各状态丰度值依次减少。 相似文献
6.
华北克拉通北缘中段大同地区发育呈岩墙形式产出的煌斑岩,该煌斑岩为超钾质碱性岩,极度低硅低钠高镁高钙高钾,且富H_2O和CO_2等流体组分。本文利用镍锍试金-电感耦合等离子体质谱法测定了这套煌斑岩的铂族元素组成,获得了其形成及演化过程的一些信息。大同煌斑岩铂族元素含量极低,∑PGE=2.14×10~(-9)~4.50×10~(-9),原始地幔标准化铂族元素配分型式为左倾型,亏损Ir亚组(IPGE),富集Pd亚组(PPGE),(Pd/Ir)_N=3.48~10.43。低铂族元素含量、高Cu/Ni比值(48101~90926)和高(Pd/Ir)_N比值指示大同煌斑岩形成于地幔低程度部分熔融(1%~13%),熔体形成时仍有部分硫化物残留于源区。岩浆演化过程中,未发生明显的结晶分异作用和地壳混染作用,硫未达到饱和-过饱和,未发生硫化物熔离作用。计算获得铂族元素在原始地幔与煌斑岩熔体间的分配系数分别为D_(Os)=35~124,D_(Ir)=13~35,D_(Ru)=34~91,D_(Rh)=5.8~10,D_(Pt)=3.1~9.7,D_(Pd)=2.2~4.5;PPGE较IPGE明显更不相容。与峨眉山大火成岩省玄武岩对比研究发现,岩浆岩中的铂族元素含量主要受源区地幔部分熔融程度和演化过程中硫化物熔离作用共同影响;而铂族元素之间的分异受源区部分熔融程度和岩浆分离结晶作用共同影响。 相似文献
7.
内蒙古柯单山蛇绿岩地幔橄榄岩铂族元素(PGEs)的分布特征及分异机制探讨 总被引：1，自引：0，他引：1
采用Carius管结合MC-ICPMS法分析了内蒙古柯单山蛇绿岩地幔橄榄岩中Ir、Ru、 Pt 和Pd 的含量,与典型的地幔橄榄岩进行对比研究,发现柯单山地幔橄榄岩中Ir和Ru明显亏损,Pt和Pd强烈富集,具有极高的Pd/Ir值,PGEs地幔标准化配分模式具有较陡的正斜率,明显不同于通常观测到的代表部分熔融残留相中铂族元素配分模式(负斜率或平坦型)。柯单山地幔橄榄岩的Ir和Ru与MgO呈正相关关系,表明Ir和Ru的亏损可能与部分熔融过程中硫化物的消耗程度有关,而与PGEs在硫化物/硅酸盐间的能斯特分配系数没有直接关系; Pt、Pd的富集表明本区的地幔橄榄岩不仅仅是经历过部分熔融的残余,而与来自深海的橄榄岩和大陆岩石圈地幔(SCLM)中的方辉橄榄岩相似,因此推测,本区地幔橄榄岩在部分熔融后又经历了富Pd的熔/流体交代,而熔/流体的来源可能是在岩浆分异演化过程中"熔离"出来的硫化物。 相似文献
8.
大别造山带祝家铺辉长岩的铂族元素特征 总被引：8，自引：2，他引：8
采用镍锍火试金法结合ICP-MS分析了祝家铺14个辉长岩样品中的Ir，Ru，Rh，Pt和Pd的含量。结果显示其PGE的含量较低，原始地幔标准化后的PGE分布模式呈正斜率型，PPGE相对原始地幔略微亏损，而IPGE强烈亏损，Pd／Ir值(22—138)远高于相应的地幔比值，表明铂族元素发生了分异。对祝家铺辉长岩的铂族元素研究表明，在其源区发生过硫化物的分异作用，地壳的混入可能促进了硫化物的饱和。祝家铺辉长岩中铂族元素的分异是因为在地幔部分熔融和岩浆演化过程中，PPGE主要受硫化物控制，而Ir则存在于非硫化物相如尖晶石、可能还有合金之中。 相似文献
9.
四川力马河镁铁-超镁铁质岩体的地球化学特征及成岩成矿分析 总被引：4，自引：3，他引：4
四川会理力马河镍矿是峨眉山大火成岩省最重要的岩浆硫化物矿床之一,成矿岩体为一小型锾铁-超镁铁岩侵入体,由含斜长石的超镁铁岩(包括舍长辉石橄榄岩和斜长橄榄辉石岩)和辉长岩类的镬铁质岩组成.矿床富含硫化物,成矿元素组合为铜、镍,铂族元素含量很低,没有铂族元素的工业富集,是蛾眉山大火成岩省中富铜镍贫铂族元素的代表性岩浆硫化物矿床.本文对力马河镍矿成矿岩体的镁铁、超镁铁岩及矿床中各种硫化物矿石进行了主量元素、微量元素及铂族元素含量分析.分析结果表明,力马河岩体的镁铁、超镁铁岩属拉斑玄武岩成因系列,岩石特征微量元素比值大致与高钛的峨眉山玄武岩相当、与低钛的峨眉山玄武岩有明显区分,但估计原始岩浆强不相容微量元素绝对含量大大低于高钛玄武岩,因此,其成矿岩体不是与一般的低钛或高钛峨眉山玄武岩(不包括苦橄岩在内)直接对应的深成相.岩体超镁铁岩及矿石铂族元素组成特征表现为无钌亏损的型式,钯/铱比值较小、在5左右,也显著不同于一般的峨眉山玄武岩,而类似于峨眉山大火成岩省苦橄岩的铂族元素组成.运用岩石地球化学研究方法计算,原始岩浆为苦橄质成分:MgO含量约17%、SiO2含量约48%.估计原始岩浆形成于130公里左右的深度,由类似于洋岛玄武岩岩浆源区成分的地幔经19%左右的部分熔融形成.超镁铁岩及硫化物矿石铂族元素含量一般在10-9～10-8暑级,铂族元素相对铜镍强烈亏损,铜/钯比值高于原始地幔10～100倍,铜镍铂族元素组成的原始地幔标准化曲线呈铂族元素显著亏损的“U“型.模式分析说明,导致铂族元素亏损的原因是岩浆成矿演化过程中多阶段硫化物熔离作用造成的,早期熔离出来的硫化物被丢失并造成岩浆中铂族元素亏损,其铂族元素亏损后的岩浆(第)二次硫化物熔离富集形成铂族元素亏损的矿石. 相似文献
10.
首次采用盐酸-过氧化氢封闭熔矿与ICP-MS相结合的方法,对金厂沟梁金(铜)矿床东、西两矿区典型矿石的铂族元素(PGE)、亲铁以及亲硫元素的含量进行了系统测定,结果显示矿石中上述元素的含量均高于实验的检测限;地球化学演化特征显示含矿流体具有岩浆性质,PGE对原始地幔/球粒陨石标准化后的配分曲线均呈强烈左倾斜的分馏模式,其配分曲线和与幔源岩浆有关的富铜硫化物和富铜镍硫化物熔体的形式相似,并与幔源玄武岩、碳酸盐熔体的配分模式基本一致,反映含矿流体具有幔源岩浆属性;从区域构造、岩浆热事件角度出发,结合典型斑岩铜(钼)矿床的PGE特征,初步确定其含矿流体形成于中生代大陆边缘环境,其直接的热动源是中生代底侵的玄武岩浆。成矿阶段富含金、铜矿石的Pd/Pt、Pd/Ir比值接近低钛玄武岩浆以及玄武安山岩,而成矿早阶段贫金、铜样品的Pd/Pt、Pd/Ir比值接近地幔;反映早期含矿流体可能是直接来自中生代幔源玄武质岩浆结晶分异,而富金(铜)流体的形成可能是玄武质岩浆演化晚期被地壳物质强烈混染后的富超临界流体岩浆(低钛熔体)发生岩浆与流体分离而产生;含矿流体演化过程的PGE地球化学行为与Cu或S(As)的饱和度有关,即主要受亲硫(铜)元素或结晶分异的硫化物矿物相所制约。 相似文献
11.
《Geochimica et cosmochimica acta》2001,65(16):2789-2806
Fourteen peridotite xenoliths collected in the Massif Central neogene volcanic province (France) have been analyzed for platinum-group elements (PGE), Au, Cu, S, and Se. Their total PGE contents range between 3 and 30 ppb and their PGE relative abundances from 0.01 to 0.001 × CI-chondrites, respectively. Positive correlations between total PGE contents and Se suggest that all of the PGE are hosted mainly in base metal sulfides (monosulfide solid solution [Mss], pentlandite, and Cu-rich sulfides [chalcopyrite/isocubanite]). Laser ablation microprobe-inductively coupled plasma mass spectrometry analyses support this conclusion while suggesting that, as observed in experiments on the Cu-Fe-Ni-S system, the Mss preferentially accommodate refractory PGEs (Os, Ir, Ru, and Rh) and Cu-rich sulfides concentrate Pd and Au. Poikiloblastic peridotites pervasively percolated by large silicate melt fractions at high temperature (1200°C) display the lowest Se (<2.3 ppb) and the lowest PGE contents (0.001 × CI-chondrites). In these rocks, the total PGE budget inherited from the primitive mantle was reduced by 80%, probably because intergranular sulfides were completely removed by the silicate melt. In contrast, protogranular peridotites metasomatized by small fractions of volatile-rich melts are enriched in Pt, Pd, and Au and display suprachondritic Pd/Ir ratios (1.9). The palladium-group PGE (PPGE) enrichment is consistent with precipitation of Cu-Ni-rich sulfides from the metasomatic melts. In spite of strong light rare earth element (LREE) enrichments (Ce/YbN < 10), the three harzburgites analyzed still display chondrite-normalized PGE patterns typical of partial melting residues, i.e., depleted in Pd and Pt relative to Ir and Ru. Likewise, coarse-granular lherzolites, a common rock type in Massif Central xenoliths, display Pd/Ir, Ru/Ir, Rh/Ir, and Pt/Ir within the 15% uncertainty range of chondritic meteorites. These rocks do not contradict the late-veneer hypothesis that ascribes the PGE budget of the Earth to a late-accreting chondritic component; however, speculations about this component from the Pd/Ir and Pt/Ir ratios of basalt-borne xenoliths may be premature. 相似文献
12.
云南鸡街碱性超基性岩铂族元素地球化学特征 总被引：1，自引：1，他引：0
本文首次报道了攀西裂谷南段云南省鸡街碱性超基性岩中铂族元素(PGE)的地球化学特征。采用改进的Carius管法测定了霞霓钠辉岩、霓霞岩和磷霞岩中的低含量PGE。PPGE与IPGE呈现强烈分馏,推断幔源岩在低程度部分熔融过程中Pt、Pd表现为相似的不相容性,而Ir、Ru表现为相容性,这种分馏效应随着结晶分异作用的进行而逐渐增强。3种岩石均出现Ru的负异常及Pt、Pd的解耦,说明母岩浆经历了早期的橄榄石晶出,在结晶分异过程中Pd较Pt更不相容。由于岩浆上升过程中的压力减小和结晶分异作用导致的成份变化使岩浆可以达到硫的局部饱和而熔离,表现为部分样品中Cu/Pd远高于原始地幔值。本文通过碱性超基性岩与金伯利岩、煌斑岩和邻区碱性、过碱性玄武岩PGE特征的对比,探讨了其岩浆源区及演化特征。 相似文献
13.
Sarah-Jane Barnes R. A. Cox M. L. Zientek 《Contributions to Mineralogy and Petrology》2006,152(2):187-200
Concentrations of Ag, Au, Cd, Co, Re, Zn and Platinum-group elements (PGE) have been determined in sulfide minerals from zoned sulfide droplets of the Noril’sk 1 Medvezky Creek Mine. The aims of the study were; to establish whether these elements are located in the major sulfide minerals (pentlandite, pyrrhotite, chalcopyrite and cubanite), to establish whether the elements show a preference for a particular sulfide mineral and to investigate the model, which suggests that the zonation in the droplets is caused by the crystal fractionation of monosulfide solid solution (mss). Nickel, Cu, Ag, Re, Os, Ir, Ru, Rh and Pd, were found to be largely located in the major sulfide minerals. In contrast, less than 25% of the Au, Cd, Pt and Zn in the rock was found to be present in these sulfides. Osmium, Ir, Ru, Rh and Re were found to be concentrated in pyrrhotite and pentlandite. Palladium and Co was found to be concentrated in pentlandite. Silver, Cd and Zn concentrations are highest in chalcopyrite and cubanite. Gold and platinum showed no preference for any of the major sulfide minerals. The enrichment of Os, Ir, Ru, Rh and Re in pyrrhotite and pentlandite (exsolution products of mss) and the low levels of these elements in the cubanite and chalcopyrite (exsolution products of intermediate solid solution, iss) support the mss crystal fractionation model, because Os, Ir, Ru, Rh and Re are compatible with mss. The enrichment of Ag, Cd and Zn in chalcopyrite and cubanite also supports the mss fractionation model these minerals are derived from the fractionated liquid and these elements are incompatible with mss and thus should be enriched in the fractionated liquid. Gold and Pt do not partition into either iss or mss and become sufficiently enriched in the final fractionated liquid to crystallize among the iss and mss grains as tellurides, bismithides and alloys. During pentlandite exsolution Pd appears to have diffused from the Cu-rich portion of the droplet into pentlandite. 相似文献
14.
Contents of platinum group elements (PGE—Os, Ir, Ru, Rh, Pt, and Pd) and rhenium in basalts of different geochemical types from the ophiolite complex of the Kamchatsky Mys Peninsula have been determined by the isotope dilution-mass spectrometry method. The total contents of PGE in different basalts are commensurate (1.4-3.6 ppb), but the element ratios vary considerably. A specific feature of the rocks is the low degree of PGE fractionation (Pd/Ir = 0.9-6.6, Pt/Pd = 1.0-7.3), which makes them similar to the Hawaiian tholeiitic basalts and picrites. The most fractionated PGE pattern is observed for alkali basalt (Pd/Ir = 6.6), and the least fractionated one, for E-MORB (Pd/Ir = 1.7). The similarity of the PGE patterns of basalts of different geochemical types suggests their similar mantle sources. We propose a model explaining the geochemical features of the basalts of the Kamchatsky Mys ophiolite complex by an impurity of the Earth’s core material in the plume source. The Ir/Pd-Ru/Pd and Pd/10-Ir-Ru discrimination diagrams can be used to identify enriched (plume) basalts based on their PGE content. 相似文献
15.
Rajesh K. Srivastava Sisir K. Mondal V. Balaram Gulab C. Gautam 《Mineralogy and Petrology》2010,98(1-4):329-345
Boninite-norite (BN) suites emplaced in an intracratonic setting in Archaean Cratons, are reported from many parts of the world. Such high-Mg low-Ti siliceous rocks are emplaced during Neoarchaean-Paleoproterozoic. The Archaean central Indian Bastar Craton also contains such a boninite-norite suite, which occurs in the form of dykes and volcanics. The spatial and temporal correlation of these high-Mg low-Ti siliceous rocks with similar rocks occurring around the northern Bastar and Dharwar Cratons probably represent a Bastar-Dharwar Large Igneous Province during the Neoarchaean-Paleoproterozoic. Platinum group element (PGE) abundances in these rocks provide constraints on their geochemical evolution during the Neoarchaean-Paleoproterozoic. The PGE geochemistry of the boninite-norite suite from the southern part of the central Indian Bastar Craton is presented to understand their behaviour during magma fractionation. In primitive mantle-normalized plots all samples have similar PGE fractionated patterns that are enriched in Pd, Pt and Rh relative to Ru. The Pd/Ru ratios for eight samples range from 2.0 to 7.0 which is higher than primitive mantle (primitive mantle Pd/Ru ≈1.2). The Pd/Pt ratios range between 0.2–2.5 with an average value of 0.7 which is near chondritic (primitive mantle Pd/Pt ≈0.5). PGE variations in these rocks together with those of major and other trace elements are consistent with a model involving olivine fractionation along with chromite as a cotectic phase. The Pt fractionation from Pd and Rh is controlled by both olivine and chromite crystallization at an early stage during high temperature crystal fractionation when the Pt was strongly compatible and Pd and Rh were incompatible. Strong negative correlations of the S content with iron and TiO2 plus lithophile element contents of the rock suggest a decrease of the S solubility in the parental high-Mg magma and separation of an immiscible sulfide liquid with decreasing temperature. Palladium plus other available chalcophile elements (e.g., Re, Au, Ag) have been fractionated in this immiscible sulfide liquid after considerable olivine fractionation of the magma. 相似文献
16.
《Russian Geology and Geophysics》2014,55(2):259-272
Data are presented on chromitites from the northern and southern sheets of the Il’chir ophiolite complex (Ospa–Kitoi and Khara-Nur (Kharanur) massifs). The new and published data are used to consider similarities and differences between ore chrome-spinel from the chromitites of the northern and southern ophiolite sheets as well as the species diversity of PGE minerals and the evolution of PGE mineralization. Previously unknown PGE minerals have been found in the studied chromitites.Ore chrome-spinel in the chromitites from the northern sheet occurs in medium- and low-alumina forms, whereas the chromitites from the southern sheet contain only medium-alumina chrome-spinel. The PGE minerals in the chromitites from the southern sheet are Os–Ir–Ru solid solutions as well as sulfides and sulfoarsenides of these metals. The chromitites from the northern sheet contain the same PGE minerals and diverse Rh–Pt–Pd mineralization: Pt–Ir–Ru–Os and isoferroplatinum with Ir and Os–Ir–Ru lamellae. Areas of altered chromitites contain a wide variety of low-temperature secondary PGE minerals: Pt–Cu, Pt–Pd–Cu, PdHg, Rh2SnCu, RhNiAs, PtAs2, and PtSb2. The speciation of the PGE minerals is described along with multiphase intergrowths. The relations of Os–Ir–Ru solid solutions with laurite and irarsite are considered along with the microstructure of irarsite–osarsite–ruarsite solid solutions. Zoned Os–Ir–Ru crystals have been found. Zone Os82–99 in these crystals contains Ni3S2 inclusions, which mark off crystal growth zones. Different sources of PGE mineralization are presumed for the chromitites from the northern and southern sheets.The stages of PGE mineralization have been defined for the chromitites from the Il’chir ophiolite belt. The Pt–Ir–Ru–Os and (Os, Ru)S2 inclusions in Os–Ir–Ru solid solutions might be relics of primitive-mantle PGE minerals. During the partial melting of the upper mantle, Os–Ir–Ru and Pt–Fe solid solutions formed syngenetically with the chromitites. During the late-magmatic stage, Os–Ir–Ru solid solutions were replaced by sulfides and sulfarsenides of these metals. Mantle metasomatism under the effect of reduced mantle fluids was accompanied by PGE remobilization and redeposition with the formation of the following assemblage: garutiite (Ni,Fe,Ir), zaccariniite (RhNiAs), (Ir,Ni,Cu)S3, Pt–Cu, Pt–Cu–Fe–Ni, Cu–Pt–Pd, and Rh–Cu–Sn–Sb. The zoned Os–Ir–Ru crystals in the chromitites from the northern sheet suggest dissolution and redeposition of Os–Ir–Ru primary-mantle solid solutions by bisulfide complexes. Most likely, the PGE remobilization took place during early serpentinization at 450–600 ºC and 13–16 kbar.During the crustal metamorphic stage, tectonic movements (obduction) and a change from reducing to oxidizing conditions were accompanied by the successive transformation of chrome-spinel into ferrichromite–chrome-magnetite with the active participation of a metamorphic fluid enriched in crustal components. The orcelite–maucherite–ferrichromite–sperrylite assemblage formed in epidote-amphibolitic facies settings during this stage.The PGE mineral assemblage reflects different stages in the formation of the chromitites and dunite-harzburgite host rocks and their transformation from primitive mantle to crustal metamorphic processes. 相似文献
17.
作为塔里木大火成岩省形成最晚的火成岩,新疆巴楚瓦吉里塔格霞石岩的岩浆源区性质的确定对于揭示塔里木大火成岩省的深部地质过程具有重要的约束作用。对瓦吉里塔格霞石岩的铂族元素地球化学特征进行了研究,铂族元素(PGE)分析结果显示,原始地幔标准化的PGE呈正斜率型分布,且Pd/Ir值高于原始地幔比值,说明霞石岩的铂族元素发生了分异。霞石岩全岩的PGE与Mg O呈正相关,Pd/Ir、Cu/Pd与Mg O则呈负相关,说明PGE的分异主要受到橄榄石的结晶分异作用控制,也是其Cu/Pd值极高及岩浆S饱和的因素之一,同时Cu/Pd值说明霞石岩岩浆为硫饱和岩浆,但是没有因素导致岩浆S过饱和进而发生硫化物的熔离。与其他大火成岩省岩石相比,瓦吉里塔格霞石岩极度亏损PGE,SCSS(硫承载量)计算结果表明母岩浆在形成之初就发生S过饱和,主要是地幔低程度部分熔融造成的,据此认为地幔源区的部分熔融程度在塔里木大火成岩省Cu-Ni硫化物铂族元素矿床形成过程中起着至关重要的作用。 相似文献
18.
金川超大型铜镍硫化物矿床的铂族元素地球化学特征 总被引：21，自引：2，他引：19
对金川超大型铜镍岩浆硫化物矿床岩石、矿石的铂族元素地球化学特征研究表明 ,金川岩体的平均Cu/Pd值远大于原生地幔岩浆的Cu/Pd值 ,说明其岩石为因硫化物析离而失去Pd的岩浆所结晶 ;且岩石的PGE具有部分熔融趋势 ,与地幔橄榄岩接近 ,这些均指示存在岩浆熔离作用。该矿床岩石、矿石的PGE球粒陨石标准化分布模式比较对应 ,均可分为两种类型 ,反映了岩浆多次侵入、熔离分异同时成岩成矿的特征。另外 ,PGE S关系分析表明其成岩成矿过程中有少量地壳物质混染。PGE地球化学特征参数还指示了其高镁拉斑玄武质母岩浆的性质。 相似文献