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1.
吉林海沟金矿床成矿流体的地球化学特征   总被引:15,自引:1,他引:15  
李荫清 《地质学报》1994,68(1):48-61
海沟金矿床石英中含丰富的三相CO2-NaCl-H2O和两相富CO2包裹体,并与两相的NaCl-H2O包裹体共生。成矿流体富含CO2,并有2种类型和来源:高盐度富CO2的NaCl-H2O溶液,来源于浆热液;低盐度NaCl-H2O溶液,来自古大气降水。成矿最佳温度为220-300℃,流体静压力为4-20MPa,矿化深度为1-3km,流体盐度为2-7ω(NaCl)/10^-2,总密度为0.644g/cm  相似文献   

2.
粤西河台金矿床的流体包裹体及成矿流体   总被引:10,自引:0,他引:10  
周永章  卢焕章 《矿物学报》1995,15(4):411-417
河台金矿床存在三种类型流体包裹体:低盐度(约1.5 ̄6wt%NaCl)H2O-CO2包裹体、中等盐度(约6 ̄14wt%NaCl)水溶液包裹体、富CO2包裹体。它们的均一化温度范围在130℃至310℃之间,捕获时的围压大约为50 ̄170MPa。初始的成矿流体是一个低盐度的以H2O-NaCl-CO2为主的化学体系,主要源于大气水与变质建造水的混合。在演化过程中,成矿热液流体发生了CO2发泡和气液两相不  相似文献   

3.
豫西上宫构造蚀变岩型金矿成矿过程中的流体—岩石反应   总被引:31,自引:8,他引:23  
范宏瑞  谢奕汉 《岩石学报》1998,14(4):529-541
上宫金矿赋存在中元古界熊耳群安山岩和玄武岩中,矿体受断裂破碎带控制。含矿热液在迁移过程中,与围岩发生了强烈的流体-岩石反应,造成Au、Ag、As、Sb等成矿及其相关微量元素和Al2O3、TiO2、Na2O等常量元素含量增加,稀土元素及其总量急剧减少。流体-岩石反应第一阶段发生的温度和压力条件为365℃~300℃和285~200MPa,而大量金沉淀成矿时的温度和压力范围则分别为325℃~240℃和160~100MPa。成矿热液类型及其演化比较简单,从初始的低盐度(9.5%~6.3%NaCl)、XCO2为0.18~0.24的含CO2流体演化为低盐度(5.9%~1.6%NaCl)的水溶液流体。流体-岩石反应是造成上宫金矿金沉淀成矿最主要的原因  相似文献   

4.
石门超大型雄黄矿床流体包裹体丰富。包裹体液相成分中富Na+、Cl-和K+、SO2-4,气相成分中H2O占绝对优势,少量CO2,成矿流体化学类型属Cl SO4 Na K型水。雄黄、雌黄形成于低温(180~90℃)、低压(20~5MPa)、浅成(175~700m)、弱酸性(pH:4.67、4.43)和弱还原(Eh:-0.265V)条件。流体包裹体氢氧同位素研究表明,成矿流体主要为古大气降水,并混有盆地建造水,大气降水下渗、循环、加热、淋滤形成了中-低盐度[w(NaCl):16.03%~4.27%],中等密度(0.863~1.065g/cm3),含矿地下热水。  相似文献   

5.
大别山榴辉岩的包裹体研究   总被引:2,自引:0,他引:2  
孙先如  李院生 《矿物学报》1995,15(3):352-359,T001
本文对大别山榴辉岩流体包裹体进行了研究。包裹体成分以NaCl-H2O、H2O、NaCl-CO2-H2O为主,是在退变质的角闪岩相和绿片岩相条件下捕获的。从变质高峰期至退变质晚期,包裹体成分演化由氧化向还原转化。熔融包裹体的发现,说明榴辉岩在形成过程中伴随局部深熔作用。通过流体包裹体研究,对大别山榴辉岩抬升过程p-T-t轨迹进行了探讨,认为是一等温降压过程。  相似文献   

6.
河北牛圈热泉型银(金)矿床成因   总被引:10,自引:0,他引:10  
牛圈银(金)矿床是冀北地区近几年来新发现的重要银矿床之一。本文从硅质角砾岩成因,成矿的阶段划分,成矿物理化学条件,矿物包裹体等方面入手探讨了该矿床成因并提出了成矿模式,该矿床成矿温度稍高(220-350℃),成矿压力很低(小于260×10^5Pa)形成深度为0.42-0.86km亚地表环境,成矿流体以低盐度(小于3.35wt%NaCl)富K^+,Cl^-,F^-,SO^2-4,贫Na^+,Ca^2  相似文献   

7.
海南抱板金矿田流体包裹体地球化学研究   总被引:4,自引:0,他引:4  
对海南抱板金矿田的外山,抱板和二甲等三个金矿进行的液体包裹体研究表明成矿流体为低盐度(0.1-6wt%NaCl),中低温(200-240℃)热液,处于中低压力(60-160MPa)下,其CO2含量较低,探针质谱分析表明流体包裹体中存在H2S,结合SO^2-4的存在,金在热液中可能是以硫氢络合物的形式迁移的。  相似文献   

8.
赣西卡林型金矿床流体包裹体地球化学   总被引:4,自引:2,他引:4  
赣西卡林型金矿床的包裹体地球化学研究表明,金矿主成矿温度为100~200℃,平均150℃左右,成矿流体盐度为1.9wt%NaCl~8.6wt%NaCl,成矿压力为247×105Pa~608×105Pa,成矿流体属K+-Ca2+-SO2-4-(F-)-CO2型,pH为3.6~4.1,是以大气降水为主,混有建造水及少量岩浆水的混合流体。研究认为,区内金矿主要是以金硫络合物形式,在较高温度(220~300℃)体系为还原态的条件下进行迁移,温度降低为150℃左右,fs2较低,有黄铁矿及富砷黄铁矿存在时,在低压较氧化的有利构造处沉淀富集成矿。  相似文献   

9.
新疆哈图金矿成矿流体地球化学   总被引:35,自引:3,他引:32  
新疆哈图金矿床赋存在石炭系基性火山岩-火山碎屑岩中,矿体受古火山口断裂系控制。矿脉内流体包裹体较为丰富,主要为气液相NaCl-H2O包裹体和少量的NaCl-CO2-H2O包裹体。成矿热液中富含CO2、N2、Na+、K+、Cl-和SO2-4,而所含的成矿元素以Au-As-Ag-Sb组合为特征。成矿热液为低盐度流体,主成矿阶段的盐度为4.1wt%~6.3wt%NaCl,密度为0.88~0.80g/cm3,fO2为10-35~10-31Pa,Eh为0.60~0.80eV,为还原环境。金沉淀成矿的最佳温度为230~260℃。哈图金矿成矿热液不是典型的岩浆热液,而是受到了古大气水混入的火山晚期热液。流体不混溶、水-岩反应及古大气水的混入是造成本区金沉淀成矿的主要因素。  相似文献   

10.
东天山康古尔金矿床成矿流体地球化学特征及其来源   总被引:15,自引:1,他引:14  
新疆康古尔金矿床是分布于晚古生代火山岩区受脆韧性剪切带控制的蚀变岩型金矿。该矿床成矿流体具有中低温度(320~100℃)、中等NaCl质量分数(114%~170%)、弱还原等特征。包裹体气相成分以H2O和CO2为主,液相成分中富Na+、Cl-,而贫K+、F-。成矿流体δD为-45‰~-66‰,δ18O为-834‰~298‰,(87Sr/86Sr)i值为07077~07106,反映了成矿流体由变质水、大气降水和岩浆水混合组成的特点  相似文献   

11.
Abstract. Denggezhuang gold deposit is an epithermal gold‐quartz vein deposit in northern Muru gold belt, eastern Shandong, China. The deposit occurs in the NNE‐striking faults within the Mesozoic granite. The deposit consists of four major veins with a general NNE‐strike. Based on crosscutting relationships and mineral parageneses, the veins appear to have been formed during the same mineralization epochs, and are further divided into three stages: (1) massive barren quartz veins; (2) quartz‐sulfides veins; (3) late, pure quartz or calcite veinlets. Most gold mineralization is associated with the second stage. The early stage is characterized by quartz, and small amounts of ore minerals (pyrite), the second stage is characterized by large amounts of ore minerals. Fluid inclusions in vein quartz contain C‐H‐O fluids of variable compositions. Three main types of fluid inclusions are recognized at room temperature: type I, two‐phase, aqueous vapor and an aqueous liquid phase (L+V); type II, aqueous‐carbonic inclusions, a CC2‐liquid with/without vapor and aqueous liquid (LCO2+VCC2+Laq.); type III, mono‐phase aqueous liquid (Laq.). Data from fluid inclusion distribution, microthermometry, and gas analysis indicate that fluids associated with Au mineralized quartz veins (stage 2) have moderate salinity ranging from 1.91 to 16.43 wt% NaCl equivalent (modeled salinity around 8–10 wt% NaCl equiv.). These veins formatted at temperatures from 80d? to 280d?C. Fluids associated with barren quartz veins (stage 3) have a low salinity of about 1.91 to 2.57 wt% NaCl equivalent and lower temperature. There is evidence of fluid immiscibility and boiling in ore‐forming stages. Stable isotope analyses of quartz indicate that the veins were deposited by waters with δO and δD values ranging from those of magmatic water to typical meteoric water. The gold metallogenesis of Muru gold belt has no relationship with the granite, and formed during the late stage of the crust thinning of North China.  相似文献   

12.
The Kendekeke polymetallic deposit, located in the middle part of the magmatic arc belt of Qimantag on the southwestern margin of the Qaidam Basin, is a polygenetic compound deposit in the Qimantag metallogenic belt of Qinghai Province. Multi-periodic ore-forming processes occurred in this deposit, including early-stage iron mineralization and lead-zinc-gold-polymetallic mineralization which was controlled by later hydrothermal process. The characteristics of the ore-forming fluids and mineralization were discussed by using the fluid inclusion petrography, Laser Raman Spectrum and micro-thermometry methods. Three stages, namely, S1-stage(copper-iron-sulfide stage), S2-stage(lead-zinc-sulfide stage) and C-stage(carbonate stage) were included in the hydrothermal process as indicated by the results of this study. The fluid inclusions are in three types: aqueous inclusion(type I), CO2-aqueous inclusion(type II) and pure CO2 inclusion(type III). Type I inclusions were observed in the S1-stage, having homogenization temperature at 240–320oC, and salinities ranging from 19.8% to 25.0%(wt % NaCl equiv.). All three types of inclusions, existing as immiscible inclusion assemblages, were presented in the S2-stage, with the lowest homogenization temperature ranging from 175 oC to 295oC, which represents the metallogenic temperature of the S2-stage. The salinities of these inclusions are in the range of 1.5% to 16%. The fluid inclusions in the C-stage belong to types I, II and III, having homogenization temperatures at 120–210oC, and salinities ranging from 0.9% to 14.5%. These observations indicate that the ore-forming fluids evolved from high-temperature to lowtemperature, from high-salinity to low-salinity, from homogenization to immiscible separation. Results of Laser Raman Spectroscopy show that high density of CO2 and CH4 were found as gas compositions in the inclusions. CO2, worked as the pH buffer of ore-forming fluids, together with reduction of organic gases(i.e. CH4, etc), affected the transport and sediment of the minerals. The fluid system alternated between open and close systems, namely, between lithostatic pressure and hydrostatic pressure systems. The calculated metallogenic pressures are in the range of 30 to 87 Mpa corresponding to 3 km mineralization depth. Under the influence of tectonic movements, immiscible separation occurred in the original ore-forming fluids, which were derived from the previous highsalinity, high-temperature magmatic fluids. The separation of CO2 changed the physicochemical properties and composition of the original fluids, and then diluted by mixing with extraneous fluids such as meteoric water and groundwater, and metallogenic materials in the fluids such as lead, zinc and gold were precipitated.  相似文献   

13.
九曲金矿位于招远—平度成矿带内,地处胶东金矿集中区的西北部。矿区内出露的岩浆岩为黑云母二长花岗岩、浅色细粒花岗岩及似斑状花岗闪长岩,矿体受断裂构造控制,属石英脉型金矿床。矿化分为四个阶段:石英-黄铁矿阶段、黄铁矿-石英阶段、石英-多金属硫化物阶段及碳酸盐阶段。流体包裹体研究表明,矿体中含金石英脉发育含CO2三相包裹体(Ⅰ型)、气液两相包裹体(Ⅱ型)和纯CO2包裹体(Ⅲ型)3种类型。成矿流体具有由早阶段到晚阶段,温度从中高温(301℃~365℃)到中低温(200℃~256℃)逐渐降低,CO2从富到贫逐渐减少,整体上具有低盐度(3.53%~10.74%Na Cleqv)和低密度(0.55~0.96 g·cm-3)的特点,成矿压力为75~129 MPa,成矿深度为7.04~9.46 km,成分以CO2、H2O为主。δD=-51×10-3~-64.2×10-3,δ18O水=0.9×10-3~7.1×10-3。笔者认为成矿流体以地幔流体为主,后期有大气降水参与;δ34S变化范围为6.4×10-3~7.4×10-3,显示成矿物质为深源含矿岩浆,上涌过程中与赋矿围岩发生重熔。矿床属幔源流体参与成矿的中温热液脉型金矿床。  相似文献   

14.
《China Geology》2022,5(4):696-721
The Dayin’gezhuang gold deposit is located in the central part of the Zhaoping Fault metallogenic belt in the Jiaodong gold province —the world ’s third-largest gold metallogenic area. It is a typical successful case of prospecting at a depth of 500‒2000 m in recent years, with cumulative proven gold resources exceeding 180 t. The main orebodies (No. 1 and No. 2 orebody) generally have a pitch direction of NNE and a plunge direction of NEE. As the ore-controlling fault, the Zhaoping Fault is a shovel-shaped stepped fault, with its dip angle presenting stepped high-to-low transitions at the elevation of −2000‒0 m. The gold mineralization enrichment area is mainly distributed in the step parts where the fault plane changes from steeply to gently, forming a stepped metallogenic pattern from shallow to deep. It can be concluded from previous studies that the gold mineralization of the Dayin’gezhuang gold deposit occurred at about 120 Ma. The ore-forming fluids were H2O-CO2-NaCl-type hydrothermal solutions with a medium-low temperature and medium-low salinity. The H-O isotopic characteristics indicate that the fluids in the early ore-forming stage were possibly magmatic water or mantle water and that meteoric water gradually entered the ore-forming fluids in the late ore-forming stage. The S and Pb isotopes indicate that the ore-forming materials mainly originate from the lower crust and contain a small quantity of mantle-derived components. The comprehensive analysis shows that the Dayin ’gezhuang gold deposit was formed by thermal uplifting-extensional tectonism. The strong crust-mantle interactions, large-scale magmatism, and the material exchange arising from the transformation from adakitic granites to arc granites and from the ancient lower crust to the juvenile lower crust during the Early Cretaceous provided abundant fluids and material sources for mineralization. Moreover, the detachment faults formed by the rapid magmatic uplift and the extensional tectonism created favorable temperature and pressure conditions and space for fluid accumulation and gold precipitation and mineralization.©2022 China Geology Editorial Office.  相似文献   

15.
邓格庄金矿地处华北克拉通胶东半岛东部苏鲁超高压带内,黄金储量已超过50t,是胶东牟平-乳山成矿带第二大石英脉型金矿床。矿体产于昆嵛山岩体和荆山群变质岩接触带附近的昆嵛山岩体中,金矿体受控于金牛山断裂带西侧的次级断裂。矿石中的硫-铅-氢-氧同位素值表明成矿流体主要来源于岩浆,具有以地壳为主兼具地幔混合特征,通过深渊断裂发生迁移,在成矿晚期遭受天水混染。围岩昆嵛山二长花岗岩高精度的锆石U-Pb年龄为155. 8Ma,成矿前期蚀变岩中蚀变矿物钾长石和绢云母~(40)Ar-~(39)Ar精确测年结果分别为123Ma和104Ma。结合近年来前人的研究资料,我们建立了胶东金矿集区中生代岩浆岩演化序列,将其划分为160~150Ma、130~110Ma、110~100Ma三个阶段,并给出了大规模爆发式成矿的年龄峰值(120±10Ma)。认为邓格庄金矿既非以变质流体为特征的典型造山型金矿,也非浅成低温热液型金矿,而是伴随华北克拉通岩石圈减薄、软流圈物质上涌、地壳拉张而使壳幔混合流体在浅部以大纵深脉状集中成矿为基本特征的中温岩浆热液型金矿。  相似文献   

16.
西秦岭凤太矿集区丝毛岭金矿床地质地球化学特征   总被引:1,自引:0,他引:1  
西秦岭凤太矿集区丝毛岭金矿床位于八卦庙造山型金矿床西侧5km左右,是一个新探明的剪切带型金矿。其成矿作用过程可分为早期石英-绢云母-硫化物阶段、中期多金属-硫化物阶段和晚期碳酸盐阶段。对早、中期的石英流体包裹体测试结果表明,丝毛岭金矿床成矿流体以富CO2、中温、低盐度为特征,总体上属于中温低盐度CO2-H2O体系,流体包裹体类型的多样性是流体不混溶性的产物。从早阶段到主成矿阶段成矿流体的温度、压力和盐度均有降低,硫逸度增高,有利于金的沉淀富集。H、O、S、C同位素研究结果,以及与八卦庙金矿床的对比分析表明,二者的成矿流体具有相似性和同源性,都是以深部来源为主的多源流体。由于丝毛岭金矿床产出的层位高于八卦庙金矿床,其成矿环境相对开放。  相似文献   

17.
Six epizonal gold deposits in the 30-km-long Yangshan gold belt, Gansu Province are estimated to contain more than 300 t of gold at an average grade of 4.76 g/t and thus define one of China's largest gold resources. Detailed paragenetic studies have recognized five stages of sulfide mineral precipitation in the deposits of the belt. Syngenetic/diagenetic pyrite (Py0) has a framboidal or colloform texture and is disseminated in the metasedimentary host rocks. Early hydrothermal pyrite (Py1) in quartz veins is disseminated in metasedimentary rocks and dikes and also occurs as semi-massive pyrite aggregates or bedding-parallel pyrite bands in phyllite. The main ore stage pyrite (Py2) commonly overgrows Py1 and is typically associated with main ore stage arsenopyrite (Apy2). Late ore stage pyrite (Py3), arsenopyrite (Apy3), and stibnite occur in quartz ± calcite veins or are disseminated in country rocks. Post-ore stage pyrite (Py4) occurs in quartz ± calcite veins that cut all earlier formed mineralization. Electron probe microanalyses and laser ablation-inductively coupled plasma mass spectrometry analyses reveal that different generations of sulfides have characteristic of major and trace element patterns, which can be used as a proxy for the distinct hydrothermal events. Syngenetic/diagenetic pyrite has high concentrations of As, Au, Bi, Co, Cu, Mn, Ni, Pb, Sb, and Zn. The Py0 also retains a sedimentary Co/Ni ratio, which is distinct from hydrothermal ore-related pyrite. Early hydrothermal Py1 has high contents of Ag, As, Au, Bi, Cu, Fe, Sb, and V, and it reflects elevated levels of these elements in the earliest mineralizing metamorphic fluids. The main ore stage Py2 has a very high content of As (median value of 2.96 wt%) and Au (median value of 47.5 ppm) and slightly elevated Cu, but relatively low values for other trace elements. Arsenic in the main ore stage Py2 occurs in solid solution. Late ore stage Py3, formed coevally with stibnite, contains relatively high As (median value of 1.44 wt%), Au, Fe, Mn, Mo, Sb, and Zn and low Bi, Co, Ni, and Pb. The main ore stage Apy2, compared to late ore stage arsenopyrite, is relatively enriched in As, whereas the later Apy3 has high concentrations of S, Fe, and Sb, which is consistent with element patterns in associated main and late ore stage pyrite generations. Compared with pyrite from other stages, the post-ore stage Py4 has relatively low concentrations of Fe and S, whereas As remains elevated (2.05~3.20 wt%), which could be interpreted by the substitution of As? for S in the pyrite structure. These results suggest that syngenetic/diagenetic pyrite is the main metal source for the Yangshan gold deposits where such pyrite was metamorphosed at depth below presently exposed levels. The ore-forming elements were concentrated into the hydrothermal fluids during metamorphic devolatilization, and subsequently, during extensive fluid–rock interaction at shallower levels, these elements were precipitated via widespread sulfidation during the main ore stage.  相似文献   

18.
陈博  侯泉林  冯宏业  郭虎  许英霞 《岩石学报》2019,35(7):2086-2104
阿沙哇义金矿位于中国新疆南天山造山带,属于著名的中亚南天山锑-汞-金成矿带的东延部分。该矿床严格受断裂所控制,以浸染状黄铁矿化、毒砂化为特征。矿化可分为三个阶段:早期无矿或贫矿石英阶段,中期石英多金属硫化物阶段,晚期石英-碳酸盐阶段。其中,中期是主要成矿阶段。成矿流体气相成分以H_2O为主,摩尔含量为75%~93%,其次为CO_2,摩尔含量为6%~25%,其余为CH_4、C_2H_6、H_2S、N_2和Ar;液相成分阳离子以Na~+为主,含少量K~+、Ca~(2+)离子,阴离子以Cl~-为主,SO~(2-)次之;矿石的Au含量与其流体的CO_2含量呈反相关,与K~+含量呈正相关。硫化物成分分析结果表明:(1)围岩地层和矿石中的黄铁矿和毒砂是重要的载金矿物,黄铁矿Au含量为0~0. 09%,平均值0. 03%;毒砂Au含量为0~0. 28%,平均值0. 07%;(2)黄铁矿和毒砂Au含量与其自形程度没有明显的相关性;(3)环带状黄铁矿较均质结构黄铁矿具有更高的Au含量;(4)岩体中的黄铁矿几乎不含Au。在成矿构造环境、成矿流体特征及演化、金矿富集机制、成矿温压条件等方面,该矿床与世界上大多数造山型金矿显示出一致性,成矿类型应属于剥蚀程度较浅的造山型金矿。断层阀作用控制的断层愈合-破裂导致的流体不混溶作用是本区金富集、沉淀的最重要机制,但流体混合机制对金的富集沉淀也发挥了作用。黄铁矿、毒砂发育及较多的含炭物质三者共存是本区寻找富矿的关键标志。  相似文献   

19.
The Zhuanshanzi gold deposit lies in the eastern section of the Xingmeng orogenic belt and the northern section of the Chifeng‐Chaoyang gold belt. The gold veins are strictly controlled by a NW‐oriented shear fault zone. Quartz veins and altered tectonic rock‐type gold veins are the main vein types. The deposits can be divided into four mineralization stages, and the second and third metallogenic stages are the main metallogenic stages. In this paper, based on the detailed field geological surveys, an analysis of the orebody and ore characteristics, microtemperature measurement of fluid inclusions, the Laser Raman spectrum of the inclusions, determination of C? H? O? S? Pb isotopic geochemical characteristics, and so on were carried out to explore the origin of the ore‐forming fluids, ore‐forming materials, and the genesis of the deposits. The results show that the fluid inclusions can be divided into four types: type I – gas–liquid two‐phase inclusions; type II – gas‐rich inclusions; type III– liquid inclusions; and type IV – CO2‐containing three‐phase inclusions. However, they are dominated by type Ib – gas liquid inclusions and type IV – three‐phase inclusions containing CO2. The gas compositions are mainly H2O and CO2, indicating that the metallogenic system is a CO2? H2O? NaCl system. The homogenization temperature of the ore‐forming fluid evolved from a middle temperature to a low temperature, and the temperature of the fluid was further reduced due to meteoric water mixing during the late stage, as well as a lack of CO2 components, and eventually evolved into a simple NaCl? H2O hydrothermal system. C? H? O? S? Pb isotope research proved that the ore‐forming fluids are mainly magmatic water during the early stage, with abundant meteoric water mixed in during the late stage. Ore‐forming materials originated mostly from hypomagma and were possibly influenced by the surrounding rocks, suggesting that the ore‐forming materials were mainly magmatic hydrothermal deposits, with a small amount of crustal component. The fluid immiscibility and the CO2 and CH4 gases in the fluids played an active and important role in the precipitation and enrichment of Au during different metallogenic stages. The deposit is considered a magmatic hydrothermal deposit of middle–low temperature.  相似文献   

20.
The Paleoproterozoic terranes (Birimian) of West Africa are well known to host numerous economic gold mineralizations. The Angovia gold mineralization is located in a brecciated and mylonitic zone within the Birimian greenstones. The sulfide–gold mineralization is mainly represented by gold associated with pyrite and chalcopyrite. A fluid inclusion study undertaken on mineralized quartz veins revealed the presence of aqueous-carbonic (CO2–H2O) fluids, the association of carbonic (CO2) and early aqueous fluids, followed by later aqueous (H2O-salt) and finally nitrogen-rich fluids. Entrapment of the initial homogeneous aqueous-carbonic fluids prior to fluid immiscibility depicts the evolution of the P–T conditions during the exhumation of the terranes after the peak of green-schist metamorphism. The CO2 rich-fluid occurs especially in gold-bearing quartz, and are considered as the main evidence of the ore-forming process in the gold-bearing quartz veins. It is considered as a product of immiscibility of the CO2–H2O parent. The volatile fraction of carbonic and aqueous-carbonic fluid inclusions is dominated by CO2, containing minor amounts of N2, even smaller amounts of CH4 and sporadically, H2S. The aqueous-carbonic fluids have moderate salinity (3–10 wt.% eq. NaCl). Late aqueous and N2 – (CH4–CO2) fluids are considered as later, unrelated to the main ore stage, and were trapped during the cooling of the hydrothermal system from 300 to 200 °C.The immiscibility has been favored by a strong pressure drop, the main trapping P–T conditions being 320–370 °C and 105–135 MPa. The mineralizing process is likely related to the immiscibility event, which was probably favored by the release of the fluid pressure after fracturing along the main shear zones. The ore process is likely to have occurred along the main shear zones or related secondary structures affected by cycling of the fluid pressure and quartz sealing–fracturing processes. The superimposed process can also explain the relative complexity of the quartz textures and fluid inclusion microfractures, and the rather wide range in the density of both parent fluid and CO2-dominated fluid.  相似文献   

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