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渝东南秀山石堤铅锌矿S、Pb同位素地球化学特征与成矿物质来源探讨 总被引：1，自引：0，他引：1
石堤铅锌矿位于重庆市秀山县境内,紧邻湖南花垣铅锌矿,矿体赋存于中寒武统平井组碳酸盐岩中。本文对该矿床矿石进行了系统的硫、铅同位素研究,探讨了成矿物质来源。研究表明,石堤铅锌矿矿石中硫化物δ34S值变化范围为10.8‰~15.6‰,平均13.52‰,主要为海相硫酸盐的还原产物,硫酸盐的还原机制为热化学还原作用。矿石铅206Pb/204Pb为18.319~18.422,207Pb/204Pb为15.740~15.784,208Pb/204Pb为38.355~38.511,铅同位素组成较为均一,显示正常铅的组成特征,在Zartman铅同位素图解中,主要位于上地壳演化线之上,在Δβ-Δγ图解中,总体落入上地壳与地幔混合的俯冲带铅和上地壳铅的过渡范围内,因此认为石堤铅锌矿床成矿物质主要来源于上地壳物质,下寒武统牛蹄塘组黑色页岩可能是石堤铅锌矿床成矿物质的重要来源。 相似文献
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青海三江北段莫海拉亨铅锌矿床地质特征及铅同位素组成的地质意义 总被引：2，自引：0，他引：2
莫海拉亨铅锌矿地处三江北段成矿带北缘的结多弧后前陆盆地,含矿层位主要为下石炭统杂多群碳酸盐组,赋矿地层及北西西向断裂为重要的控矿因素,矿石矿物主要为方铅矿、闪锌矿、褐铁矿等。对研究区铅同位素研究显示,铅石矿μ多为9.27～9.77,μ平均值小于9.58,ω平均值为39.99,铅同位素组成具有正常铅演化特征;铅石矿206Pb/204Pb一般为18.51～18.92,208Pb/204Pb平均为38.64,具稳定同位素组成的特性;在Zartman铅同位素构造模式图中,铅成矿物质具有壳幔演化的特征。由上所述,莫海拉亨铅锌矿主要赋存于厚-巨厚层状碳酸盐岩中,且成矿与岩浆活动无直接关系,反映研究区Pb来源于上地壳含矿建造,赋矿地层或次级断裂构造交汇部位是成矿或找矿的有利部位。 相似文献
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通过对矿床矿石铅同位素组成的分析,并与矿区岩浆岩脉和围岩地层中的岩石铅同位素组成进行对比,借以示踪矿床成矿物质来源。研究表明,矿石铅与矿区岩石铅(灰岩和脉岩)的铅同位素组成具有较相近和较窄的变化范围,暗示铅可能属同一铅源。在铅同位素构造模式图及不同成因类型矿石铅的Δγ-Δβ成因分类图解中,显示出造山带铅、地壳与地幔混合的俯冲带岩浆作用铅特征,说明铅不是单一来源的正常铅,而是混合型多来源的异常铅。成矿物质是多来源的,赋矿地层和岩浆岩共同提供了铅源及成矿物质,但以岩浆为主,地层为辅,地幔铅参与了成矿。 相似文献
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《地质科技情报》2017,(2)
银山银铅锌多金属矿是近几年来在该区域发现的中型以上的银铅锌多金属矿床,为地层-构造-岩浆综合控制型矿床。运用矿区的黄铁矿矿石S、Pb同位素示踪的方法探讨了矿床成矿物质来源。矿区黄铁矿和方铅矿的硫同位素组成δ34S值为-1.5‰~27.9‰,且硫同位素分布直方图中显示3种来源特征,指示成矿物质来源可能为海水、地层或岩浆。Pb同位素组成μ(~(238)U/~(204)Pb)值特征、Zartman构造模式、Δγ-Δβ成因分类研究表明,矿区矿石铅为幔-壳混源,指示物源主要来自于中生代岩浆热液,而非海底热液沉积物。综合表明银山银铅锌多金属矿床是中生代岩浆热液型矿床。 相似文献
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滇西地区下地壳铅同位素的组成及其意义 总被引：1，自引：0，他引：1
滇西地区新生代碱性侵入岩中广泛分布的麻粒岩包体可以代表该地区的下地壳岩石,为了确定滇西下地壳岩石的铅同位素组成,我们系统采集了该区碱性岩中的麻粒岩包体,挑选出其中的长石、石榴子石等造岩矿物,测定了其铅同位素组成,在Zartman等的铅构造演化模式图上,剔除个别异常的铅同位素组成,圈出投影于下地壳铅同位素演化趋势线上及附近的铅同位素分布范围,由此确定了该区下地壳的铅同位素组成的区域,并进一步结合作者先前确定的该区上地壳及上地幔铅同位素组成,构建了该区三维岩石圈铅同位素组成,并将这一结果用于滇西金顶超大型铅锌矿床的成矿物质来源的研究中,发现颇受争议的金顶铅锌矿床中的铅并非来自上地幔,而相当于下地壳来源的铅与兰坪盆地沉积岩铅二者的混合铅。 相似文献
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甲生盘铅锌硫矿床位于华北地台北缘狼山—渣尔泰山成矿带内,赋矿地层为中元古代渣尔泰山群的一套黑色岩系。铅同位素测试结果表明,甲生盘矿床铅同位素组成分为两组:A组以低放射性成因铅为特征,其同位素组成206Pb/204Pb为15.889~16.257,207Pb/204Pb为15.158~15.455,208Pb/204Pb为35.112~36.271;B组以相对高放射性成因铅为特征,其同位素组成206Pb/204Pb为17.871~18.990,207Pb/204Pb为15.509~15.672,208Pb/204Pb为37.525~38.770。矿石硫化物明显分为早期沉积的层纹状、浸染状细粒硫化物和后期脉状产出的粗粒硫化物,均含有A、B两组铅特征,前者以A组特征为主,后者以B组特征为主。根据铅构造模式图解及μ值等铅同位素参数综合分析:A组铅来自上地壳中的造山带,并且有幔源铅的补偿,成矿物质来自于古老的基底地层;B组铅主要来源于上地壳,部分受矿体北翼花岗岩侵入体的影响,成矿物质主要来自赋矿围岩;矿床铅具有多来源混合铅结构特征。 相似文献
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金顶锌铅矿作为世界级的超大型矿床一直以来受到国内外学者的广泛关注,但对于其成矿类型及成矿物质来源存在较大争议。矿石铅同位素组成是探讨矿床成因,特别是成矿金属来源的重要手段。然而,由于实验技术和采样的原因,前人所报道的数据相差甚远,这也是矿床成因争论的主要原因。本文应用飞秒激光剥蚀多接收器等离子体质谱法首次获得金顶铅锌矿中方铅矿及闪锌矿原位铅同位素组成,结果显示铅同位素组成相对均一,~(206)Pb/~(204)Pb=18.480~18.032(平均值为18.436),~(207)Pb/~(204)Pb=15.688~15.588(平均值为15.668),208Pb/~(204)Pb=38.056~38.778(平均值为38.689),全部测点的μ值介于9.55~9.63之间,平均为9.60。矿石铅同位素组成在铅构造模式图上位于上地壳演化线与造山带演化线之间,表明其成矿物质具有壳源特征,其壳源特征亦得到其他地球化学证据(S、C、H、O、Sr、He同位素)的支持。结合前人研究及野外地质现象,认为这一铅锌矿床应属于MVT铅锌矿,为典型的后生矿床且与岩浆活动无关。对比兰坪盆地沉积岩及岩浆岩的铅同位素组成特征,可以推断其成矿物质来源主要为兰坪盆地沉积地层及其基底。 相似文献
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安徽铜陵焦冲金-硫矿床S、Pb同位素组成
及其指示意义 总被引：2，自引：1，他引：1
安徽铜陵焦冲金硫矿床位于长江中下游铜陵矿集区内,矿（化）体主要赋存于二叠系下统栖霞组（P1q）中。在分析该矿床成矿地质条件的基础上,系统研究了矿石S、Pb同位素组成特征,探讨了矿床成矿物质来源。矿石硫化物的S同位素组成变化范围较窄,成矿热液δ34SΣS在4.0‰左右,反映其来源与岩浆硫密切相关。矿石Pb同位素组成变化范围较大,经同位素组成特征及特征参数法判断矿石Pb为异常Pb。通过Zartman铅构造坏境演化图解和Δγ-Δβ成因分类图解,确定矿床物质来源与岩浆作用密切相关,其源于上地壳物质与地幔的混合。通过成矿物质来源的研究,期望为铜陵地区寻找与花岗闪长斑岩有关的矿床提供帮助。 相似文献
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区域成矿带铅稳定同位素地球化学研究是区域地球化学分区、示踪成岩成矿物质来源、阐明矿床成因的有效途径。本文以中国特有的大地构造背景为基础,以新生代上地幔铅同位素组成的地球化学场为依据,示踪了中国大型、超大型斑岩型铜矿床及铜镍硫化物型矿床的成岩成矿物质来源。结果显示:①斑岩型铜矿床及铜镍硫化物型矿床成矿母岩继承了所属陆块的上地幔铅同位素组成特征;②两类矿床的含矿岩体和矿石矿物铅同位素组成十分一致,示踪两者同源;壳熔花岗岩和围岩地层的铅同位素组成与矿石铅同位素组成迥异;③位于各陆块的斑岩型铜矿床及铜镍硫化物型矿床的成矿母岩和矿石铅同位素组成除继承了各陆块上地幔不同的铅同位素组成特征外,还示踪了壳幔层圈间耦合性的"块体效应",同时,上地幔铅同位素组成可能还具"延迟效应"。 相似文献
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华南扬子地块是我国古热水沉积成矿作用最为发育的地区之一,其热水沉积特性最早引起我国学者的关注。华南下寒武统黑色岩系中赋存多个与热水沉积成矿作用相关的大型、超大型重晶石矿床与N i-Mo-U-V多金属富集层。进一步研究分布在华南扬子地块黑色岩系中的金属、非金属矿床成因及其地球化学特征,对认识华南乃至全球晚震旦—早寒武世生物与环境演化有着十分重要的意义。本文对华南下寒武统镍-钼富集层矿石进行电子探针研究,识别出黄铜矿、黝铜矿等铜的独立矿物;闪锌矿等锌的独立矿物;方铅矿、白铅矿等铅的独立矿物。研究表明,在镍-钼矿石中这些矿物的发现为镍-钼矿层是热水沉积作用产物提供了直接的矿物学证据。 相似文献
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Shao-Yong Jiang Yong-Quan Chen Hong-Fei Ling Jing-Hong Yang Hong-Zhen Feng Pei Ni 《Mineralium Deposita》2006,41(5):453-467
The Lower Cambrian black shale sequence of the Niutitang Formation in the Yangtze Platform, South China, hosts an extreme metal-enriched sulfide ore bed that shows >10,000 times enrichment in Mo, Ni, Se, Re, Os, As, Hg, and Sb and >1,000 times enrichment in Ag, Au, Pt, and Pd, when compared to average upper continental crust. We report in this paper trace- and rare-earth-element concentrations and Pb–Pb isotope dating for the Ni–Mo–PGE–Au sulfide ores and their host black shales. Both the sulfide ores and their host black shales show similar trace-element distribution patterns with pronounced depletion in Th, Nb, Hf, Zr, and Ti, and extreme enrichment in U, Ni, Mo, and V compared to average upper crust. The high-field-strength elements, such as Zr, Hf, Nb, Ta, Sc, Th, rare-earth elements, Rb, and Ga, show significant inter-element correlations and may have been derived mainly from terrigenous sources. The redox sensitive elements, such as V, Ni, Mo, U, and Mn; base metals, such as Cu, Zn, and Pb; and Sr and Ba may have been derived from mixing of seawater and venting hydrothermal sources. The chondrite-normalized REE patterns, positive Eu and Y anomalies, and high Y/Ho ratios for the Ni–Mo–PGE–Au sulfide ores are also suggestive for their submarine hydrothermal-exhalative origin. A stepwise acid-leaching Pb–Pb isotope analytical technique has been employed for the Niutitang black shales and the Ni–Mo–PGE–Au sulfide ores, and two Pb–Pb isochron ages have been obtained for the black shales (531±24 Ma) and for the Ni–Mo–PGE–Au sulfide ores (521±54 Ma), respectively, which are identical and overlap within uncertainty, and are in good agreement with previously obtained ages for presumed age-equivalent strata.Editorial handling: R. Coveney Jr. 相似文献
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贵州天柱大河边重晶石矿床硫同位素研究 总被引：4，自引：0，他引：4
对贵州天柱大河边重晶石矿床硫同位素组成进行了系统研究,该矿床重晶石的硫同位素组成为36.7‰-41．6‰,具有比同期海水硫酸盐高得多的硫同位素组成特征,且在834S分布直方图上呈塔式,表明形成该矿床的硫来源单一,主要来自于海水中硫酸盐并经历了较强的生物细菌分馏作用,且矿床形成环境为半封闭一封闭的台地泻湖环境。 相似文献
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Major minerals (sulfates, sulfides, quartz) are distributed in different parts of submarine hydrothermal ore deposits. For instance, the abundance of barite increases stratigraphically upwards in the massive orebodies of the Kuroko deposits (black and yellow ores), while quartz is abundant in the lower parts (siliceous ore). The different distribution of barite and quartz in the Kuroko deposits can not be accounted for by thermochemical equilibrium calculations based on the precipitation due to mixing of ascending hydrothermal solutions with ambient cold seawater. In the present study, a coupled fluid flow‐precipitation kinetics model was used to calculate the amounts of quartz, barite, and anhydrite precipitated from a hydrothermal solution mixed with seawater, assuming reasonable values for temperature, precipitation rate, fluid flow velocity, mineral surface area/fluid mass ratio (A/M), and initial concentrations of hydrothermal solution and seawater before mixing occurred. The results indicate that barite precipitates more efficiently than quartz from discharging fluids with relatively higher flow velocity, lower temperatures and under the condition of lower A/M ratios on the seafloor (black ore), whereas quartz precipitates more effectively from solutions with lower flow velocity, higher temperatures and higher A/M ratios beneath the seafloor (siliceous ore) and in the orebody (barite ore, ferruginous chert ore). Anhydrite precipitates in shallow sub‐seafloor environments with lower precipitation rates and higher A/M ratios than barite and higher precipitation rates and lower A/M ratios than quartz. These results explain the observed occurrences of barite, anhydrite, and quartz in the Kuroko deposits. Namely, barite is abundant in black ore and barite ore which formed above the seafloor, anhydrite formed in high‐permeability tuff breccias, and quartz formed in low permeability dacite intrusive bodies in the sub‐seafloor environment. 相似文献
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大河边重晶石矿床是一个世界级的超大型重晶石矿床。最近在该区重晶石矿床下部的震旦系陡山沱组碳酸盐岩(白云岩)和碎屑岩中,新发现一套规模较大、层位产出稳定的铅锌矿化。铅锌矿体和重晶石矿床具有"上部为重晶矿,下部为铅锌硫化物矿床"的矿化特征。铅锌矿段矿石矿物主要为闪锌矿、黄铁矿及方铅矿,含少量白铁矿、黄铜矿及磁黄铁矿;脉石矿物主要为石英和重晶石,少量白云石、热液磷灰石、炭沥青及钡冰长石。成矿流体特征类似于形成沉积喷流型铅锌矿床的流体特征。铅锌矿化中的硫源自局限海盆内早寒武世海水经硫酸盐还原作用提供。此种类似于喷流沉积型铅锌矿床在南华裂谷盆地一带矿化层位稳定、分布范围较广泛,体现早寒武世时在裂谷盆地内存在一次大规模的热液事件。天柱大河边铅锌矿床的发现具有重要的资源意义及区内该种矿床的勘查意义。 相似文献
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The paper reports the results of Pb isotope study of several gold deposits of the Russia’s largest metallogenic province of Northern Transbaikalia. Potential sources of the ore material are considered by the example of new and previously published Pb–Pb data on nine deposits and occurrences of different scales. The comparison of Pb–Pb isotope-geochemical characteristics of ores, Paleozoic granitoids, as well as metamorphic pyrite from barren metasedimentary sequences shows that the Neoproterozoic terrigenous–carbonate rocks of the Baikal–Patom fold belt (BPB) served as the main source of lead and other components in the mineral-forming systems of the deposits. Significant variations of Pb isotope ratios typical in general of the considered deposits of the BPB reflect the initial isotopic heterogeneity of Pb source. This heterogeneity is caused by mixing of two geochemical types of continental crust during sedimentation: old (Early Precambrian) crust of the Siberian craton with long-term geochemical evolution and newly formed Late Precambrian crust. Pb–Pb data serve in support of the hydrothermal–metamorphogenic hypothesis of the formation of gold deposits of the BPB. 相似文献
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湘西震旦—寒武纪交替时期古海洋环境的恢复 总被引：6，自引：0，他引：6
前寒武纪至寒武纪的交替时期是地质史和生命史的重要转折。中国南方地区广泛发育了上震旦统、下寒武统的黑色岩系。文中运用沉积学和沉积地球化学的理论和方法对湘西黑色岩系的岩石类型、矿物组成、元素地球化学特征、干酪根的结构以及碳同位素的组成等方面进行了研究 ,讨论了黑色岩系的形成条件 ,恢复了震旦纪 /寒武纪地史转折期的古环境。研究认为 ,湘西地区在晚震旦世和早寒武世地史转折期的生物爆发和高有机质的产率是形成缺氧环境的重要因素之一。 相似文献
19.
Bingsong Yu Hailiang Dong Elisabeth Widom Jianqiang Chen Changsong Lin 《Journal of Asian Earth Sciences》2009,34(3):418-436
Black shales and thin-bedded cherts in the basal Cambrian are widespread worldwide and they carry important information on the formation of sedimentary basins and on the tectonic history. We studied the geochemical signatures of the early Cambrian black shales and bedded cherts from the Northern Tarim Basin, China, with the objectives of understanding the depositional setting of these rocks and inferring the tectonic history in the region. Twenty two black shales, ten cherts, and two nodular phosphorites were collected from two outcrops at Xiaoerbulake and Sugaitebulake in the Northern Tarim Basin, spanning vertical sections of 8.8 and 7.5 m, respectively. A suite of techniques, including field investigations, X-ray diffraction, electron microscopy, trace element, rare earth element (REE), and isotope geochemistry, were employed to characterize the geochemical signatures of these rocks. Field evidence indicates that the black shales and bedded cherts are over- and underlain by dolomites, suggesting a shallow marine depositional environment. Mineralogical and trace element data suggest that the Tarim black shales and cherts were deposited in a suboxic continental shelf environment, and hydrothermal activity may have extracted certain trace elements from mafic continental crust and concentrated them in the sedimentary basin. REE characteristics for the cherts are very similar to those that are known to be deposited in pelagic ocean floor settings, suggesting that the hydrothermal fluids may be derived from the infant southern Tianshan Ocean in the north of the Tarim Basin. Os isotope signatures at the time of deposition (187Os/188Osi = 1.1–2.7) are typical of crustal signatures, and the radiogenic Os isotope signatures rule out the mantle as a possible source of Os and other metals. A positive correlation between 187Os/188Os and εNd is consistent with upper crust-derived basin sediments that contain a variable contribution of hydrothermal fluids possibly derived from ancient mafic continental crust. These trace element, REE, and isotope systematics collectively suggest that incorporation of hydrothermal fluids derived from ancient, mafic continental crust combined with deposition in relatively reducing conditions may have controlled the chemical and isotopic compositions of these rocks. We infer that the hydrothermal fluid was carried to the continental shelf by upwelling during the initial stages of formation of the southern Tianshan Ocean, where the fluid interacted with thinned, mafic crustal basement lithologies and was subsequently incorporated into the black shales and bedded cherts in the Northern Tarim Basin. This study provides important geochemical evidence for the creation of the Tianshan Ocean, which is a result of break-up of the Rodinia Supercontinent during the early Cambrian. 相似文献
20.
东天山康古尔金矿床成矿物源的同位素地球化学特征 总被引：5，自引：0，他引：5
康古尔金矿床属晚古生代火山岩区剪切带蚀变岩型金矿。同位素地球化学研究表明,矿石中铅为正常铅,热液系统硫同位素组成为陨石硫型,矿石中碳、钕同位素组成具深源特征,同时矿石与火山岩围岩中的Ｓｉ、Ｓｒ、Ｓ、Ｐｂ等同位素组成相近,说明成矿物质主要来自矿体围岩———火山岩,晚期有少量来自矿区附近的侵入岩。铅、锶同位素组成反映成矿过程中也有少量壳源物质的加入。 相似文献