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1.
湖南平江县仁里超大型伟晶岩型铌钽多金属矿床的发现及其意义 总被引：1，自引：0，他引：1
湖南平江县仁里铌钽多金属矿床是湖南省核工业地质局311大队新发现的高品位超大型伟晶岩型稀有多金属矿床,经过多年的地质勘查,在幕阜山复式花岗岩体西南缘的仁里矿区查明伟晶岩脉140条,发现铌钽矿脉14条。对主要矿脉进行了地表槽探和深部钻探验证,具有北铌钽南锂的特征,铌钽矿体具规模大、矿体形态简单、连续性好,矿化较均匀,品位富、埋藏浅,矿石质量优及资源潜力大等特点。矿区估算(333+334)Ta2O5资源量10791 t,Nb2O5:14057 t,平均品位Ta2O5:0.036%,Nb2O5:0.047%,达到超大型规模。仁里超大型铌钽多金属矿床的发现,突破以往对大岩基难以形成和找到超大型伟晶岩型稀有金属矿床的既往认识,提出幕阜山矿集区定位于构造岩浆隆起带,仁里矿床大型层状构造与燕山期岩浆岩联合控矿、含铌钽矿伟晶岩脉形成于区域后造山构造环境的伸展构造体制的新认识,分析了区域上的找矿方向,丰富和发展了稀有金属成矿理论,为华南地区稀有金属矿产找矿实现了重大突破,使幕阜山地区有望成为我国一个新的重要铌钽等稀有金属资源基地。 相似文献
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内蒙古下护林铅锌银矿床位于额尔古纳地块吉尔布干断裂带南段,系额尔古纳晚元古代变质地体内的铅锌矿区之一。为总结额尔古纳地块铅锌银多金属成矿作用和产出规律,对下护林铅锌银矿床开展详细研究。在总结该矿床地质特征的基础上,对控矿因素及矿化富集规律进行分析总结,进而推断矿床成因,最后还归纳了找矿标志。研究表明,矿体赋存于侏罗纪花岗岩与震旦系额尔古纳河组侵入接触断裂复合构造带中的大理岩一侧,呈脉状断续分布,围岩蚀变发育,主要为矽卡岩化和中低温热液蚀变的硅化、碳酸盐化、黄铁矿化和萤石化,并且硅化越强,铅锌矿体品位越高。花岗岩边部的石英斑岩与额尔古纳河组大理岩断裂接触带构成了成矿结构面,其发育程度控制了矿体规模,是最主要的矿化富集规律,而地层岩性、构造、岩浆岩则是影响成矿结构面发育程度的主要控矿因素。矿床成因类型为中低温热液充填交代型脉状矿床。研究成果可为后续该矿床的勘查及额尔古纳地块同类型矿区的铅锌银多金属矿研究提供参考。 相似文献
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内蒙锡林浩特石灰窑铌钽矿床是我国最近发现的一处大型稀有金属矿床.通过详细分析该矿床地质特征、控矿因素及其成因,主要获得如下认识:1)该矿床矿石属于碱性花岗岩系列;2)矿石中的铌钽矿物主要包括铌锰矿、铌钽铁矿、铌钽锰矿、锡锰钽矿和细晶石;3)该矿床可能是前期花岗岩岩浆结晶和后期热液交代综合作用的产物,热液交代是铌钽铷主要成矿阶段;4)从铌钽铷矿化成因和富集规律可知,金属矿化与钠长石化、云英岩化密切相关,且矿体赋存于蚀变花岗岩中,分布上严格受北东向构造的控制,因此,钠长石化、云英岩化的花岗岩是寻找上述稀有金属的直接找矿标志,同时石灰窑燕山早期花岗岩出露地段很可能是寻找稀有金属矿的有希望地区;5)围绕石灰窑花岗岩主岩体周围寻找晚期侵位的钠长石化花岗岩小岩体的隆起和浅部部位,是寻找钽铌铷矿的基本思路. 相似文献
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通过全岩化学分析、显微镜下鉴定、扫描电镜分析及矿物自动定量分析(AMICS),查明了断峰山铌钽矿床的矿石物质组成和铌钽赋存状态.矿石Nb2O5品位为0.0112％～0.0117％,Ta2O5品位为0.0033％～0.0084％,主要矿物组成为钠长石、石英、白云母、黑云母及高岭石等,矿石中的铌钽矿物主要有钽锰矿(Ta/Nb=2.94,Fe/Mn=0.45)、钽铌锰矿(Ta/Nb=0.51,Fe/Mn=0.56)和铌锰矿(Ta/Nb=0.11,Fe/Mn=0.82)3种.矿石含Nb2O5量为0.0112％～0.0117％,含Ta2O5量为0.0033％～0.0084％,该矿床为花岗伟晶岩类铌钽矿床.铌在铌锰矿、钽铌锰矿和钽锰矿分布率分别为48.76％、37.26％和13.99％.钽在钽锰矿、钽铌锰矿和铌锰矿的分布率分别为62.65％、28.96％和8.39％.铌钽矿物粒度主要分布于16～75μm之间,矿物单体解离度较低,占24.47％. 相似文献
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《大地构造与成矿学》2020,(3)
仁里铌钽矿床是我国东部近年来新发现的超大型高品位花岗伟晶岩型铌钽矿,已探明的Ta2O5资源量10791t,Nb2O5资源量14057 t, Ta2O5平均品位0.036%, Nb2O5平均品位0.047%,矿床仍具有较大的找矿潜力。为了厘定铌钽等稀有金属矿的成矿年龄,研究其成矿物质来源,为下一步勘查及成矿预测指明方向,本次对5号主矿脉钻孔ZK1616中的4件辉钼矿样品进行了Re-Os同位素年龄测试,获得的4件辉钼矿Re-Os平均模式年龄为130.5±1.1 Ma(MSWD=0.17), 4件辉钼矿中Re含量为76.59～106.33μg/g,平均值为96.81μg/g。综合研究表明稀有金属成矿作用发生在中生代早白垩世,成矿年龄为130.5 Ma左右,成矿物质来源于壳幔混合源,以及岩浆演化晚期富F、Cl热液流体对冷家溪群地层稀有金属元素的释出、迁移和叠加。 相似文献
6.
内蒙古赵井沟大型铌钽矿床地质特征及成因 总被引：8，自引：2，他引：6
内蒙古武川县赵井沟矿床是近年来在内蒙古中部地区找到的一处大型铌钽矿床.铌钽氧化物储量为8000余吨(钽氧化物含量大于50％),其中,ω(Nb2O5)和ω(Ta2O5)的平均含量为0.011％和0.012％.铌钽矿化主要在早二叠世碱长花岗岩类侵入杂岩体内,呈浸染状和条带状产出,并且构成似层状、脉状和透镜状矿体.研究表明,碱长花岗岩、碱长花岗细晶岩和碱长花岗伟晶岩锆石U-Pb同位素年龄值分别为(277.14±0.82) Ma、(277.0±2.1) Ma和(276.6±2.1) Ma.鉴于铌钽矿化呈浸染状在含矿侵入杂岩体内产出,推测赵井沟矿床的成矿作用与海西期构造-岩浆活动有关.古大陆块体伸展构造条件下,富钠质钙-碱性岩浆作用为铌钽矿床的形成提供了动力和物质来源,而断裂构造为成矿物质沉淀聚集创造了空间条件.赵井沟矿床属富钠的过铝质花岗岩型铌钽矿床. 相似文献
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回顾江西有色地勘局稀有金属矿产勘查的历史背景,大型-特大型钽、铌、锂、铷、铯矿床的发现及勘查经过和所取得的成果.提出钠长石化花岗岩型稀有金属矿床是今后勘查的主要类型、指出矿化花岗岩体的标志. 相似文献
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苏州善安浜超大型钽矿地质特征及找矿前景 总被引：1，自引：1，他引：0
善安浜地区钽矿找矿的突破,是江苏省地质调查研究院近几年开展国土资源大调查所取得的重大成果.该矿床为碱性长石花岗岩型钽矿床.矿体赋存在隐伏花岗岩体隆起部位的顶部,自上而下分为三个矿体,呈上钽下铌关系产出.矿石类型主要为钠长石花岗岩型,次为少量花岗伟晶岩型.矿石主要有益组分为钽、铌,伴生有益组分为锂、铷、铯、锆、铪.钽、铌主要赋存在铌铁矿-钽铁矿中,铌铁矿-钽铁矿主要嵌布在长石、石英等矿物颗粒间,矿石可选性好.估算的资源量:钽达超大型矿床规模,铌达中型矿床规模.该矿床的发现不仅对苏州西部稀有金属矿地质找矿有重要指导意义,亦为平原区隐伏矿床的找矿研究提供了典型实例. 相似文献
10.
仁里矿田位于扬子陆块与华夏陆块交汇的江南隆起造山带中段、幕阜山岩体西南缘的舌状体区域。稀有金属伟晶岩矿化类型在空间上具分带性,矿田北东部为白云母伟晶岩,西南部为锂辉石白云母伟晶岩。本文对矿田内3条代表性的锂辉石白云母伟晶岩开展了地质和地球化学特征研究。测试结果为:SiO2含量为62.0%~78.0%(平均71.8%);Al2O3为14.8%~18.0%(平均16.1%),Al2O3/(K2O+Na2O+CaO)摩尔比(A/CNK=1.52~13.0)大于1.1,分异指数(DI)89.7~97.5,∑REE=2.07~14.8μg/g,LREE/HREE=6.90~15.9。研究表明:①仁里矿田伟晶岩为过铝质岩浆系统下高分异、富碱、富稀有金属、富铪锆型花岗质伟晶岩,锂铌钽等稀有金属矿化与磷灰石化关系密切。②锂辉石白云母伟晶岩具有良好的分带性,其结晶分异时间晚于白云母伟晶岩,我们推测伟晶岩岩浆的结晶、分异时间越长越有利于Li元素的富集;矿田稀有金属矿化组合呈现Be+Nb+Ta→Be+Nb+Ta+Li→Be+Li的演化规律。③仁里矿田锂矿资源丰富,主要集中在矿田西南部,有望在进一步增加矿田钽铌资源量的基础上,提交一处高品位的大型锂矿床;在锂矿找矿工作中,尤其注意伟晶岩中的贫Nb、Ta锂辉石白云母伟晶岩地段。 相似文献
11.
《International Geology Review》2012,54(8):936-955
ABSTRACTThe Ordovician plutons in the Erguna Block, NE China, can be classified into two groups: Early Ordovician diorites with zircon U–Pb ages ranging from 486 to 485 Ma and Middle Ordovician gabbros and granites with zircon U–Pb ages ranging from 466 to 463 Ma. The diorites are calc-alkaline in nature and are characterized by weak to moderate enrichments of large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to high field strength elements (HFSE) and heavy rare earth elements (HREE). The gabbros and granites have high total alkali contents, and all samples are enriched in LREE and LILE and depleted in HFSE such as Nb, Ta, and Ti. Isotopically, Early Ordovician diorites display values that are less radiogenic [εHf(t) = + 9.9–+16.8] compared to those of Middle Ordovician gabbros [εHf(t) = ? 3.0–+5.0]. Middle Ordovician granites have positive εHf(t) values of +1.4 to +4.3 and two-stage Hf model ages (TDM2) of 1167 to 1356 Ma. These data indicate that the diorites may have been generated by the partial melting of a recently metasomatized mantle source, whereas the gabbros and granites may have been formed by the partial melting of enriched lithospheric mantle and Mesoproterozoic crust, respectively. Our results, combined with other regional results, suggest that Early Ordovician magmatism was likely associated with the northward subduction of the Heihe–Xilinhot oceanic plate beneath the Erguna–Xing’an Block, whereas the Middle Ordovician gabbros and granites were most likely formed in an extensional setting controlled by the rollback of this subducted oceanic plate. 相似文献
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大兴安岭北部漠河盆地广泛发育漠河组,其形成时代、物源区特征及大地构造背景等对研究盆地的形成与演化具有重要意义。本文在漠河盆地西缘恩和哈达地区漠河组内发现了2层凝灰岩夹层。采用LA-ICP-MS U-Pb测年方法进行了锆石U-Pb年代学研究,分别获得(158±1)Ma、(157±2)Ma的年龄,表明漠河组形成于晚侏罗世早期。砂岩岩石地球化学分析结果显示,漠河组砂岩SiO_2含量高(70.20%～76.13%),SiO_2/Al_2O_3值为4.99～5.87,K_2O/Na_2O值为0.59～1.62;在稀土元素球粒陨石标准化图解上,曲线与活动大陆边缘的稀土元素曲线吻合较好;样品富集高场强元素(Th、Hf)和大离子亲石元素(Rb、K),亏损高场强元素(Nb、Ta、Ti、P)和大离子亲石元素(Ba、Sr),微量元素蛛网图曲线与活动大陆边缘相似。地球化学物源分析图解和大地构造背景判别表明:漠河组砂岩的母岩主要来源于石英质沉积岩和酸性火山岩的混合区。砂岩碎屑锆石LA-ICP-MS U-Pb测年结果显示,碎屑锆石年龄与盆地南缘前寒武系基底和各期花岗岩类岩石的时代一致。综合研究认为,漠河组沉积物主要来自盆地南缘额尔古纳、兴安等地块,物源区既有古老陆壳物质,也有年轻的火成岩,大地构造背景以活动大陆边缘为主。 相似文献
14.
I. A. Andreeva 《Petrology》2016,24(5):462-476
Melt inclusions were studied by various methods, including electron and ion microprobe analysis, to determine the compositions of melts and mechanisms of formation of rare-metal peralkaline granites of the Khaldzan Buregtey massif in Mongolia. Primary crystalline and coexisting melt inclusions were found in quartz from the rare-metal granites of intrusive phase V. Among the crystalline inclusions, we identified potassium feldspar, albite, tuhualite, titanite, fluorite, and diverse rare-metal phases, including minerals of zirconium (zircon and gittinsite), niobium (pyrochlore), and rare earth elements (parisite). The observed crystalline inclusions reproduce almost the whole suite of major and accessory minerals of the rare-metal granites, which supports the possibility of their crystallization from a magmatic melt. Melt inclusions in quartz from these rocks are completely crystallized. Their daughter mineral assemblage includes quartz, microcline, aegirine, arfvedsonite, polylithionite, a zirconosilicate, pyrochlore, and a rare-earth fluorocarbonate. The melt inclusions were homogenized in an internally heated gas vessel at a temperature of 850°C and a pressure of 3 kbar. After the experiments, many inclusions were homogeneous and consisted of silicate glass. In addition to silicate glass, some inclusions contained tiny quench zircon crystals confined to the boundary of inclusions, which indicates that the melts were saturated in zircon. In a few inclusions, glass coexisted with a CO2 phase. This allowed us to estimate the content of CO2 in the inclusion as 1.5 wt %. The composition of glasses from the homogeneous melt inclusions is similar to the composition of the rare-metal granites, in particular, with respect to SiO2 (68–74 wt %), TiO2 (0.5–0.9 wt %), FeO (2.2–4.6 wt %), MgO (0.02 wt %), and Na2O + K2O (up to 8.5 wt %). On the other hand, the glasses of melt inclusions appeared to be strongly depleted compared with the rocks in CaO (0.22 and 4 wt %, respectively) and Al2O3 (5.5–7.0 and 9.6 wt %, respectively). The agpaitic index is 1.1–1.7. The melts contain up to 3 wt % H2O and 2–4 wt % F. The trace element analysis of glasses from homogenized melt inclusions in quartz showed that the rare-metal granites were formed from extensively evolved rare-metal alkaline melts with high contents of Zr, Nb, Th, U, Ta, Hf, Rb, Pb, Y, and REE, which reflects the metallogenic signature of the Khaldzan Buregtey deposit. The development of unique rare metal Zr–Nb–REE mineralization in these rocks is related to the prolonged crystallization differentiation of melts and assimilation of enclosing carbonate rocks. 相似文献
15.
We report new geological, mineralogical, geochemical and geochronological data about the Katugin Ta-Nb-Y-Zr (REE) deposit, which is located in the Kalar Ridge of Eastern Siberia (the southern part of the Siberian Craton). All these data support a magmatic origin of the Katugin rare-metal deposit rather than the previously proposed metasomatic fault-related origin. Our research has proved the genetic relation between ores of the Katugin deposit and granites of the Katugin complex. We have studied granites of the eastern segment of the Eastern Katugin massif, including arfvedsonite, aegirine-arfvedsonite and aegirine granites. These granites belong to the peralkaline type. They are characterized by high alkali content (up to 11.8 wt% Na2O + K2O), extremely high iron content (FeO1/(FeO1 + MgO) = 0.96–1.00), very high content of most incompatible elements – Rb, Y, Zr, Hf, Ta, Nb, Th, U, REEs (except for Eu) and F, and low concentrations of CaO, MgO, P2O5, Ba, and Sr. They demonstrate negative and CHUR-close εNd(t) values of 0.0…−1.9. We suggest that basaltic magmas of OIB type (possibly with some the crustal contamination) represent a dominant part of the granitic source. Moreover, the fluorine-enriched fluid phases could provide an additional source of the fluorine. We conclude that most of the mineralization of the Katugin ore deposit occurred during the magmatic stage of the alkaline granitic source melt. The results of detailed mineralogical studies suggest three major types of ores in the Katugin deposit: Zr mineralization, Ta-Nb-REE mineralization and aluminum fluoride mineralization. Most of the ore minerals crystallized from the silicate melt during the magmatic stage. The accessory cryolites in granites crystallized from the magmatic silicate melt enriched in fluorine. However, cryolites in large veins and lens-like bodies crystallized in the latest stage from the fluorine enriched melt. The zircons from the ores in the aegirine-arfvedsonite granite have been dated at 2055 ± 7 Ma. This age is close to the previously published 2066 ± 6 Ma zircon age of the aegirine-arfvedsonite granites, suggesting that the formation of the Katugin rare-metal deposit is genetically related to the formation of peralkaline granites. We conclude that Katugin rare-metal granites are anorogenic. They can be related to a Paleoproterozoic (∼2.05 Ga) mantle plume. As there is no evidence of the 2.05 Ga mantle plume in other areas of southern Siberia, we suggest that the Katugin mineralization occurred on the distant allochtonous terrane, which has been accreted to Siberian Craton later. 相似文献
16.
《International Geology Review》2012,54(15):1842-1863
ABSTRACTThe late Mesozoic magmatic record within the Erguna Block is critical to evaluate the tectonic history and geodynamic evolution of the Great Xing’an Range, NE China. Here, we provide geochronological and geochemical data on Late Jurassic–Early Cretaceous plutonic-volcanic rocks in the northern Erguna Block and discuss their origin within a regional tectonic framework. Late Mesozoic magmatism in the Erguna Block can be divided into two major periods: Late Jurassic (162–150 Ma) and Early Cretaceous (140–125 Ma). Late Jurassic quartz monzonite and dacite show adakite characteristics such as high Al2O3, high Sr, and steeply fractionated REE patterns. Contemporary granitoids and rhyolites are also characterized by strong enrichment of light rare earth elements (LREE) and significant depletion in heavy rare earth elements (HREE), but with more pronounced negative Eu anomalies. Early Cretaceous trachytes and monzoporphyries exhibit moderate LREE enrichment and relatively flat HREE distributions. Coeval granites and rhyolites have transitional signatures between A-type and fractionated I-type felsic rocks. Both Late Jurassic and Early Cretaceous rocks have distinctive negative Nb, Ta, and Ti anomalies, and positive zircon εHf(t) values, suggesting that these magmas were derived from partial melting of Meso-Neoproterozoic accreted lower crust, although melting occurred at a variety of crustal levels. The transition from adakite to non-adakite magmatism reflects continued crustal thinning from Late Jurassic to Early Cretaceous. Our data, together with recently reported isotopic data for plutonic and volcanic rocks, as well as geochemical data, in NE China, suggest that Late Jurassic–Early Cretaceous magmatism in the Erguna Block was possibly induced by post-collisional extension after closure of the Mongol-Okhotsk Ocean. 相似文献
17.
贵州省松桃县道坨超大型锰矿床的发现及其成因探讨 总被引：5，自引：0，他引：5
贵州省松桃县道坨锰矿床是新发现的一个超大型全隐伏锰碳酸盐矿床。文章阐述了该矿床的发现概况及基本的地质和地球化学特征,并应用锰矿石和含锰黑色页岩的元素和碳同位素地球化学特征对菱锰矿的形成机制提出了制约。道坨超大型锰矿床的发现是填图及对区域地质资料综合分析的结果。该矿床具有品位高、厚度大、呈层性好及展布广等特点。其锰矿石的主量元素特征为Al2O3、TiO2、Fe2O3含量较低,P2O5中等程度富集,MnO、MgO含量相对较高,Fe/Mn比值低。在微量元素方面,锰矿石显示出较为明显的Co富集,含锰黑色页岩则显示出较为明显的Co、Mo富集;在稀土元素方面,锰矿石具有较高的稀土元素总量,轻微的"帽式"稀土元素PAAS标准化配分模式及明显的Ce正异常,含锰黑色页岩的稀土元素总量与PAAS接近,其稀土元素PAAS标准化配分模式较为平坦,无Ce异常。碳同位素测试结果显示出菱锰矿富集碳的轻同位素,表明在菱锰矿形成过程中存在有机碳的参与。文章表明,道坨锰矿床内的锰是以氧化物或氢氧化物的形式沉淀,菱锰矿是在缺氧且富含有机物质的成岩环境中转化而成。 相似文献
18.
西昆仑北带喀依孜斑岩型钼矿床地质地球化学特征及年代学研究 总被引：3，自引：1，他引：2
喀依孜钼矿床是近年来西昆仑地区新发现的具规模的斑岩型矿床。钼矿化赋存在花岗闪长岩体边部,由南、北两个矿化带组成,矿石呈浸染状,矿石矿物由辉钼矿及少量黄铁矿和黄铜矿组成。矿石Mo品位0.04%～1.53%,局部达10%～15%。围岩蚀变有钾化、黄铁绢英岩化和青磐岩化等斑岩型矿床蚀变组合。含矿岩体为花岗闪长岩,岩石地球化学具高SiO2、Al2O3,富K2O、Na2O,低CaO、TiO2等特点,属于高钾钙碱性系列,微量元素富集大离子亲石元素(LILE),亏损高场强元素(HFSE)和重稀土元素,显示Nb和Ta的负异常,与俯冲带岩浆地球化学特征类似,岩石成因可能与俯冲作用有关。含矿岩体锆石LA-ICPMS定年获得250.7±4.7Ma(MSWD=1.6),3件辉钼矿Re-Os模式年龄分别为254.4±1.9Ma、257.0±3.4Ma、258.5±2.0Ma,成岩成矿发生在晚二叠世末-早三叠世初。综合区域演化特征,本文认为喀依孜斑岩型钼矿床成因与古特斯洋向塔里木板块俯冲有关,形成于塔里木大陆边缘弧环境。 相似文献
19.
湖南尖峰岭矿床是一个典型的花岗岩型Li、Nb和Ta稀有金属矿床,为研究花岗岩成矿作用以及指导湘南地区稀有金属找矿工作,采用XRF、ICP-MS和ISE法分析了与成矿有关的黑云母花岗岩、钠长石花岗岩及云英岩的中主量、微量元素和挥发分。结果表明:钠长石花岗岩和云英岩中的SiO_2(70.6%~84.85%)和挥发分F(2.43%~3.74%)质量分数高,富Al_2O_3(9.36%~22.99%),且A/CNK1.0,为过铝质岩石,全碱(w(Na_2O+K_2O)=1.51%~7.52%)和w(CaO)(0.1%~3.44%)变化大,w(Fe_2O_3)、w(MgO)、w(TiO_2)、w(MnO)、w(P_2O_5)较低;稀土元素组成具显著的Eu负异常和"M"型四分组效应,强烈富集Rb、Th、U、Nb、Ta元素,亏损Ba、Sr、Ti元素。花岗岩地球化学特征显示在演化过程中经历了高程度分异演化作用和岩浆不混溶作用,其挥发分F对稀有元素有明显的富集作用,并制约着熔体/流体体系的地球化学行为及其成矿效应。钠长石花岗岩和云英岩的稀有金属富集成矿受到岩浆不混溶作用、水岩反应、风化淋滤作用的共同控制。 相似文献
20.
陕西华阳川铀稀有多金属矿床伴生大量的稀土资源,其矿石类型独特、组分复杂,系统的稀土矿物学工作将揭示矿石主要稀土矿物类型、稀土元素赋存状态,进而对矿床开发中稀土元素综合利用及选冶技术提供重要参考。本文在岩相学基础上,利用电子探针、扫描电镜对陕西华阳川铀稀有多金属矿床矿石中的稀土独立矿物与含稀土矿物进行系统研究,在矿石中发现了褐帘石（La2O3 6.49%～7.61%,Ce2O3 11.50%～14.00%）、磷铈镧矿（La2O3 16.30%～21.21%,Ce2O3 32.06%～39.18%）、磷钇矿（La2O3 2.29%～3.58%,Ce2O3 1.89%～2.37%,Y2O3 39.77%～42.80%）、氟碳铈镧矿（La2O3 12.86%～14.20%,Ce2O3 36.67%～39.90%）、褐钇铌矿（La2O3 1.19%～2.11%,Ce2O3 1.29%～2.30%,Y2O3 22.67%～25.88%）等5种稀土独立矿物;同时发现磷灰石、贝塔石、榍石等矿物中稀土元素含量较高。研究表明,该矿床稀土元素以独立矿物（褐帘石、磷铈镧矿、磷钇矿、氟碳铈镧矿、褐钇铌矿）与类质同象（磷灰石、贝塔石、榍石等矿物）两种形式存在,稀土资源以La、Ce轻稀土元素为主,并富含重稀土元素Y。 相似文献