共查询到20条相似文献，搜索用时 328 毫秒
1.
碱性岩中磷灰石、榍石和锆石的稀土元素地球化学特征 总被引：3，自引：0，他引：3
碱性岩的副矿物磷灰石和榍石是岩体中稀土元素的主要载体矿物。它们的稀土分布模式与母岩相同，向右陡倾斜，磷灰石的Eu负异常明显，榍石具Ce正异常，锆石呈大体对称“V”形模式，Eu负异常最大。与花崩岩中同一矿物对比，上述矿物都体现了幔源碱性岩浆轻稀土富集，Eu亏损小的特点。磷灰石、榍石和锆石相应富集了母岩中的轻、中、重稀土元素，稀土元素的这种置换行为主要是矿物晶体化学性质控制的。 相似文献
2.
广东仁居石英闪长岩为燕山期钙碱性长英质岩浆岩,稀土总量为332~338μg/g。石英闪长岩中副矿物榍石的平均稀土总量约为10309μg/g,以其3.29%含量提供全岩52.7%的稀土,因此榍石在风化过程中的行为是离子吸附型稀土矿床中稀土富集成矿的关键。岩相学研究表明,仁居石英闪长岩风化过程中矿物风化顺序为:氟碳钙铈矿→(榍石→磷灰石)/(黑云母/角闪石→斜长石)→钾长石→磁铁矿→石英→锆石。由于榍石和磷灰石的抗风化能力与黑云母和斜长石相近,它们在半风化–全风化层发生溶解,所释放出的稀土元素易于被黏土矿物吸附,因此榍石和磷灰石分解是风化壳中离子吸附态稀土元素的主要来源。稀土元素主要富集于风化壳的全风化层上部5~15 m,稀土总量为504~813μg/g。由于原岩中稀土主要赋存于榍石之中,因此风化壳的稀土配分很大程度上继承了榍石的轻稀土富集特征。研究表明,热带–亚热带地区风化壳基岩中原生矿物的风化顺序和主要富稀土副矿物的抗风化能力是制约离子吸附型稀土矿床中稀土富集成矿的关键因素。 相似文献
3.
4.
吉黑东部花岗岩类中副矿物锆石、磷灰石、榍石的初步研究 总被引：2，自引：0，他引：2
吉黑东部花岗岩中副矿物种类繁多,特别是锆石、磷灰石、榍石广泛分布.它们在不同成因类型花岗岩中有些标型特征彼此有别,如锆石的颜色、晶形和群型特征,磷灰石的两种晶形REE分布模式及SrI值和榍石的不同世代、成因等,这些均有助于查明不同成因花岗岩的形成条件.因此,可以利用锆石、磷灰石、榍石的标型特征作为判别和划分花岗岩成因的辅助标志. 相似文献
5.
金红石-榍石转变过程中元素地球化学行为——以雅鲁藏布江缝合带角闪岩为例 总被引：2，自引：1，他引：1
金红石边缘形成榍石冠状边结构在变质中-基性岩中普遍存在,是金红石与退变质流体携带的SiO_2与CaO作用的结果,反应形成的榍石微量元素特征受到金红石和流体的共同影响。雅鲁藏布江缝合带中角闪岩LZ06-04在抬升过程经历近等温降压退变质作用,石榴子石分解导致同一样品中含石榴子石部分与不含石榴子石部分的退变质流体成分的差异。两种流体分别与金红石反应,对应形成的榍石具有相似的Nb、Ta含量和Nb/Ta比值特征,但截然不同的REE特征。榍石的Nb、Ta来源于金红石,残余金红石与含水流体再平衡Nb、Ta的分配系数增大,且D_(Nb)~(Rt/Fluid)≥D_(Ta)~(Rt/Fluid);虽然Nb和Ta在含水流体中都表现为不活动元素,但相对于Nb,Ta在含水流体中活动性较高。榍石的Zr-Hf体系特征受到锆石、石榴子石等矿物的综合影响,并且Zr-Hf在含水流体中表现出比Nb-Ta更高的活动性。榍石的REE特征受流体中REE特征、榍石与流体配分系数以及共生矿物的影响。在岩浆或变质体系,榍石形成过程中,REE富集矿物(如石榴子石、锆石、褐帘石、独居石、磷灰石等)形成或分解将影响榍石的REE分布特征或形成REE环带结构。含水流体中金红石退变质形成榍石反应的进行受流体中TiO_2、CaO和SiO_2活度的影响。因此榍石常见于钙碱性岩浆岩、富Ca基性变质岩和矽卡岩中。流体中CaO活度的变化影响榍石的形成,进而影响Ti、Nb、Ta在流体中的运移能力。俯冲板片产生流体在交代上覆富Ca地幔楔物质过程中形成榍石残留同样可以造成部分熔融体具有亏损HFSE特征。 相似文献
6.
粤北大宝山次英安斑岩中副矿物榍石的初步研究 总被引：2，自引：0，他引：2
榍石是花岗岩,尤其是钙碱性花岗岩中常见的副矿物之一。利用背散射图像和电子探针成分分析对粤北大宝山矿区岩心样品(次英安斑岩)中的榍石进行了系统的矿物学研究。结果表明,研究区榍石可分为岩浆榍石和次生(热液)榍石两类,其中岩浆榍石为自形至半自形,颗粒较大,具环带结构,平均w(Al2O3)=1.24%,w(TiO2)=38.10%,w(F)=0.40%;次生(热液)榍石与绿泥石等蚀变矿物共生,多呈它形,平均w(Al2O3)=2.44%,w(TiO2)=36.02%,w(F)=1.00%。榍石的不同世代、成因、副矿物组合特征等可以揭示花岗岩的形成条件、演化历史,且对判别花岗岩的成因类型具有重要意义。 相似文献
7.
8.
拉萨地块南缘记录了新特提斯洋俯冲到印度-欧亚大陆碰撞及碰撞后的岩浆作用,其中晚白垩世的岩浆作用对研究印度-欧亚大陆碰撞前成岩成矿作用具有重要的意义。本文以拉萨地块南缘100Ma的角闪辉长岩和68Ma花岗斑岩的锆石、磷灰石、榍石为研究对象,利用背散射、阴极发光(CL)、电子探针(EPMA)和LA-ICP-MS原位微区分析等方法,查明锆石、磷灰石、榍石的主、微量元素特征,进一步反演岩石源区性质、结晶历史及结晶条件,并对岩体含矿性进行评价,有助于探讨冈底斯成矿带晚白垩世岩浆成因机制和成矿潜力。研究结果表明,角闪辉长岩锆石初始饱和温度为598～626℃,锆石Ti结晶温度为645～758℃,磷灰石饱和温度为690～819℃,榍石Zr温度为602～778℃;磷灰石具有中等-弱的负铕异常(δEu=0. 67)、富集LREE,早期高温阶段锆石的结晶主要受到磷灰石结晶影响,随着温度降低,受到少量榍石结晶的影响;角闪辉长岩中的锆石在低的Hf、温度较高时却具有较高的Th、U含量显示岩浆源区受到更多俯冲板片出溶流体的影响,磷灰石具有较高的(La/Sm)N值以及Sr含量低于主岩,显示岩浆源区均一、熔体富Cl特征。花岗斑岩的锆石初始饱和温度为704～736℃,锆石Ti温度为630～799℃,磷灰石饱和温度为846～891℃,结合锆石的Ce/Sm、Yb/Gd以及磷灰石较大的负铕异常(δEu=0. 29),显示花岗斑岩中的锆石从高温到低温阶段都受到磷灰石和榍石的共同结晶影响,磷灰石的结晶受到斜长石影响;花岗斑岩中大部分锆石Ti结晶温度高于其初始饱和温度,磷灰石Sr-Ap/Sr-WR为0. 78～1. 45,具有较高的F/Cl(32. 87～67. 60)、低的(La/Sm)N,指示花岗斑岩岩浆源区不均一,受到多期岩浆熔体的脉冲式灌入并加入了更多镁铁质的岩浆熔体,其熔体具有低的Cl。此外,花岗斑岩锆石具有较高的Ce~(4+)/Ce~(3+)、磷灰石具有较高的SO_3、熔体中更富S,指示花岗斑岩具有高的氧逸度和成矿潜力。本文研究结果表明结合锆石、磷灰石和榍石微量元素特征可有效指示岩浆岩的源区组成、结晶历史、结晶条件以及成矿潜力,为岩石学的研究提供了一个新的思路。 相似文献
9.
10.
安徽庐枞盆地罗河铁矿床中榍石LA-ICP-MS U-Pb定年及其意义 总被引：1，自引：1，他引：0
罗河铁矿床位于长江中下游铁铜金成矿带庐枞矿集区,已探明资源量约10亿吨,是成矿带内最大的铁矿床。矿床主成矿阶段广泛发育热液成因榍石,以榍石-硬石膏-磷灰石组合为特征,在矿床-800~-900m和-1500~-1600m两个不同深度稳定发育,为确定成矿时代和成矿流体演化提供了良好的研究对象。本次工作对罗河铁矿床深部和浅部两层矿体中热液榍石开展了年代学及地球化学研究,结果表明榍石中存在(Al,Fe)~(3+)+(F,OH)~-=Ti~(4+)+O~(2-)置换反应,并富含Zr、Nb和REE等元素。榍石中Zr含量估算矿床成矿温度约700℃,指示玢岩型矿床比矽卡岩型铁矿床具有更高的成矿温度,高温条件有利于Ti元素的迁移。榍石的稀土元素配分图均呈现出明显右倾,并具较高的稀土元素总量以及明显的负Eu异常特征,轻稀土富集表明其结晶早于磷灰石和绿帘石等矿物,形成于高温热液环境,不同深度榍石的Eu异常变化表明成矿流体的氧逸度从深部到浅部有所升高。热液榍石原位微区LA-ICPMS U-Pb定年结果表明,上、下两层榍石形成时代分别为130.0±0.9Ma和129.1±0.8Ma~129.7±0.8Ma,表明罗河铁矿床两层矿体是同一成矿系统的在不同深度的产物。矿床成矿时代与区内隐伏闪长岩体成岩时代一致,结合矿床地质特征研究,本文认为闪长玢岩是矿床的成矿母岩。罗河铁矿床属于燕山晚期岩浆热液活动的产物,形成于区域早白垩世岩石圈减薄的环境。 相似文献
11.
The accessory minerals apatite and sphene are the main carriers of REE in alkaline rocks.Their chondrite-normalized REE patterns decline sharply to the right as those of the host rocks,In the patterns an obvious negative Eu anomaly and a positive Ce anomaly can be seen in apatite and sphene,respectively.Zircon from alkaline rocks is different in REE pattern,I,e,. a nearly symmetric“V“-shaped pattern with a maximum negative Eu anomaly.Compared with the equivalents from granites,apatite,sphene and zircon from alkaline rocks are all characterized by higher (La/Yb)N ratio and less Eu depletion,As to the relative contents of REE in minerals,apatite,sphene and zircon are enriched in LREE,MREE and HREE respectively,depending on their crystallochemical properties. 相似文献
12.
南岭地区高度演化花岗岩类的稀土元素模型 总被引：1，自引：0，他引：1
本文应用现有的理论模型和矿物／熔体分配系数讨论南岭地区高度演化花岗岩类的ＲＥＥ模型，包括重稀土富集型和稀土亏损型。在花岗岗岩浆分异演化过程中，副矿物（尤其是稀土矿物）的晶出种类，顺序和物理化学条件是控制ＲＥＥ强烈分馏的关键因素。ＲＥＥ分布型式不能简单地作为鉴别岩石成因的标志。 相似文献
13.
Rare earth element partition between sphene,apatite and other coexisting minerals of the Kangerdlugssuaq intrusion,E. Greenland 总被引：1，自引：0，他引：1
P. Henderson 《Contributions to Mineralogy and Petrology》1980,72(1):81-85
Cumulus apatite, sphene, feldspar, amphibole and biotite from the pulaskite of the Kangerdlugssuaq alkaline intrusion have been analysed for rare earth elements (REE) by instrumental neutron activation analysis. The apatite is particularly rich in REE, contains 3.6% Ce and shows a steep, light REE-enriched, chondrite-normalised pattern. The other minerals have light REE enrichment but with sphene showing a peak at Ce on a chondrite-normalised plot. REE partition coefficient values show that the light REE are preferentially accommodated by apatite relative to sphene. The differences in these coefficients result from differences in the co-ordination of the REE in the two minerals. 相似文献
14.
The Mlindi ring complex in southern Malawi, dated at 495 Ma, is intrusive in the Proterozoic migmatite basement composed mainly of hornblende- and biotite-bearing paragneiss and dolomitic marble. Three main lithologic facies have been distinguished: (1) syenite, which crops out in the outer part of the complex as an oval-shaped ring dike (7 km×9 km) and as a rim of massive bodies cutting the mafic rocks of the central part, (2) two types of diopside-biotite gabbro (syenogabbro and gabbronorite), and (3) a banded phlogopite pyroxenite cumulate intruded by the diopside-biotite gabbro. Major- and trace-element geochemistry shows these rocks to form a continuous suite from pyroxenite to syenite with two potassium trends: a highpotassium trend comprising pyroxenite and syenogabbro in which ultrapotassic rocks (K2O/Na2O > 3) are developed, and a low-potassium trend with gabbronorite and sodic syenite. The major-element geochemistry of the phlogopite pyroxenite is similar to that of the kamafugitic series volcanic rocks containing micaceous pyroxenite inclusions. The pyroxenite is poorer in compatible elements (e.g. Ni=100–200 ppm, Cr=40–1200 ppm, Cu=5–200 ppm and Co=50 ppm) than other mafic cumulates or lamproite and lamprophyre, which suggests that the Mlindi rocks crystallized from an already differentiated magma. On the other hand, the pyroxenite has a very high content of incompatible elements (e.g. Th or REE) due to abundant apatite; consequently their REE patterns are commonly similar to that of apatite. The A12O3 (2%) and TiO2 (<0.4%) contents of diopside are very low, whereas the biotite (or phlogopite) is rich in TiO2 (3–4%). Compositional changes, especially Fe-Mg substitution, in these minerals were small during differentiation. 相似文献
15.
The variant rock types of an Alkaline-Carbonatite Complex (ACC) comprising alkali pyroxenite, nepheline syenite, phoscorite, carbonatite, syenitic fenite and glimmerite along with REE and Nb-mineralization are found at different centres along WNW-ESE trending South Purulia Shear Zone (SPSZ) in parts of Singhbhum Crustal Province. The ACC occurs as intrusions within the Mesoproterozoic Singhbhum Group of rocks. Alkali pyroxenite comprises of aegirine augite, magnesiotaramite, magnesiokatophorite as major constituents. Pyrochlore and eucolite are ubiquitous in nepheline syenite. Phoscorite contains fluorapatite, dahllite, collophane, magnetite, hematite, goethite, phlogopite, calcite, sphene, monazite, pyrochlore, chlorite and quartz. Coarse fluorapatite shows overgrowth of secondary apatite (dahllite). Secondary apatite is derived from primary fluorapatite by solution and reprecipitation. The primary fluorapatite released REE to crystallize monazite grains girdling around primary apatite. Carbonatite is composed dominantly of Srcalcite along with dolomite, tetraferriphlogopite, phlogopitic biotite, aegirine augite, richterite, fluorapatite, altered magnetite, sphene and monazite. The minerals comprising of the carbonatite indicate middle stage of carbonatite development. Fenite is mineralogically syenite. Glimmerite contains 50–60% tetraferriphlogopite. An alkali trend in the evolution of amphiboles (magnesiotaramite-magnesiokatophorite-richterite) and chinopyroxenes (aegirine augite, aegirine) during the crystallization of the suite of rocks is noted. Monazite is the source of REE in phoscorite and carbonatite. Fluorapatite has low contents of REE, PbO, ThO2 and UO2. Pyrochlore reflects Nb-mineralization in nepheline syenite and it is enriched in Na2O, CaO, TiO2, PbO and UO2. Pyrochlore containing UO2 (6.605%) and PbO (0.914%) in nepheline syenite has been chemically dated at 948 ± 24 Ma by EPMA. 相似文献
16.
Implication of Apatite and Anhydrite for Formation of an Iron‐Oxide‐Apatite (IOA) Rare Earth Element Prospect,Benjamin River,Canada 
下载免费PDF全文
下载免费PDF全文 The Benjamin River apatite prospect in northern New Brunswick, Canada, is hosted by the Late Silurian Dickie Brook plutonic complex, which is made up of intrusive units represented by monzogranite, diorite and gabbro. The IOA ores, composed mainly of apatite, augite, and magnetite at Benjamin River form pegmatitic pods and lenses in the host igneous rocks, the largest of which is 100 m long and 10–20 m wide in the diorite and gabbro units. In this study, 28 IOA ore and rock samples were collected from the diorite and gabbro units. Mineralogical observations show that the apatite–augite–magnetite ores are variable in the amounts of apatite, augite, and magnetite and are associated with minor amounts of epidote‐group minerals (allanite, REE‐rich epidote and epidte) and trace amounts of albite, titanite, ilmenite, titanomagnetite, pyrite, chlorite, calcite, and quartz. Apatite and augite grains contain small anhydrite inclusions. This suggests that the magma that crystallized apatite and augite had high oxygen fugacity. In back scattered electron (BSE) images, apatite grains in the ores have two zones of different appearance: (i) primary REE‐rich zone; and (ii) porous REE‐poor zone. The porous REE‐poor zones mainly appear in rims and/or inside of the apatite grains, in addition to the presence of apatite grains which totally consist of a porous REE‐poor apatite. This porous REE‐poor apatite is characterized by low REE (<0.84 wt%), Si (<0.28 wt%), and Cl (<0.17 wt%) contents. Epidote‐group minerals mainly occur in grain boundary between the porous REE‐poor apatite and augite. These indicate that REE leached from primary REE‐rich apatite crystallized as allanite and REE‐rich epidote. Magnetite in the ores often occurs as veinlets that cut apatite grains or as anhedral grains that replace a part of augite. These textures suggest that magnetite crystallized in the late stage. Pyrite veins occur in the ores, including a large amount of quartz and calcite veins. Pyrite veins mainly occur with quartz veins in augite. These textures indicate pyrite veins are the latest phase. Apatite–augite–magnetite ore, gabbro–quartz diorite and feldspar dike collected from the Benjamin River prospect contain dirty pure albite (Ab98Or2–Ab100) under the microscope. The feldspar dikes mainly consist of dirty pure albite. Occurrences of the dirty pure albite suggest remarkable albitization (sodic alteration) of original plagioclase (An25.3–An60 in Pilote et al., 2012) associating with intrusion of monzogranite into gabbro and diorite. SO42? bearing magma crystallized primary REE‐rich apatite, augite and anhydrite reacted with Fe in the sodic fluids, which result in oxidation of Fe2+ and release of S2? into the sodic fluids. REE, Ca and Fe from primary REE‐rich apatite, augite and plagioclase altered by the sodic fluids were released into the fluids. Then Fe3+ in the sodic fluids precipitated as Fe oxides and epidote‐group minerals in apatite–augite–magnetite ores. Finally, residual S2? in sodic fluids crystallized as latest pyrite veins. In conclusion, mineralization in Benjamin River IOA prospect are divided into four stages: (1) oxidized magmatic stage that crystallized apatite, augite and anhydrite; (2) sodic metasomatic stage accompanying alteration of magmatic minerals; (3) oxidized fluid stage (magnetite–epidote group minerals mineralization); and (4) reduced fluid stage (pyrite mineralization). 相似文献
17.
岚皋金云角闪辉石岩类捕虏体：地幔交代作用的证据 总被引：6，自引：2，他引：6
产于陕西岚皋地区碱质基性－超基性潜火山杂岩中的金云角闪辉石岩类捕虏体，主要由透辉石、富钛韭闪石、金云母、磷灰石、榍石、及钛铁矿组成。捕虏体发育三联晶、碎裂边、肯克变形等固相线下变形变质结构，矿物学特征表明，透辉石、富钛韭闪石、金云母为地幔来源，是地幔交代作用的产物；与正常地幔尖晶石二辉橄榄岩相比，捕虏体富ＴｉＯ２、Ｆｅ２Ｏ３、ＣａＯ、Ｎａ２Ｏ、Ｋ２Ｏ，贫ＭｇＯ，其稀土元素具富集特征，尤其富集ＬＲＥＥ；微量元素分配型式显示了富亲石不相容元素的特征。岩相学、矿物学及岩石化学特征表明：该类捕虏体为交代地幔捕虏体，它代表了北大巴山早古生代裂谷作用时期的异常地幔，是地幔交代作用的产物。交代营力可能源于地幔热缕的上升，交代过程推测为深处小范围的流体交代及随后硅酸岩熔体的“弥散”性交代 相似文献
18.
Rare earth element distributions among minerals in a granodiorite and their petrogenetic implications 总被引：2，自引：0，他引：2
A study of the distribution of lanthanide rare earths in a granodiorite from the eastern Peninsular Ranges batholith, southern California, reveals that a large fraction of the REE in this rock resides in the accessory phases sphene and allanite. The minerals plagioclase, alkali feldspar, biotite, epidote and apatite each contribute approximately 1% or less of each REE to the whole rock, with the exception of Eu for which plagioclase contributes 7%. Sphene and allanite together contain 80% to 95% of each REE. Each of these phases is zoned in REE concentration with substantial decreases from core to margin. Textural observations argue for relatively early saturation and precipitation of sphene and allanite in the magma. REE zoning trends in sphene and allanite, and unexpectedly low REE concentrations in largely later crystallizing minerals such as feldspar, indicate that the precipitation of sphene and allanite significantly reduced REE concentrations in residual melts. These results illustrate the potential that sphene and allanite have for controlling the behavior of REE in granitic magmas.Available information collectively suggest that the sampled granodiorite existed as a complete melt, that the REE contained in the assemblage of phases were derived by direct crystallization from the melt, and that the melt behaved essentially as a closed system once crystallization of the phases now present began. Close correspondences between the major and trace element chemistries of the granodiorite and phenocryst-poor lavas from similar tectonic settings support these conclusions. The REE pattern of the granodiorite melt appears to have originated at depth and is characteristic of its source regions and derivation mechanism. The high liquidus temperature of a granodiorite melt (~ 1000°C) indicates the importance of mantle-derived components within the sources of batholithic magmas in the Peninsular Ranges. 相似文献
19.
20.
Phlogopite-Amphibole-Pyroxenite Xenoliths in Langao,Shaanxi Province,China:evidence for Mantle Metasomatism 总被引：1，自引：0，他引：1
Phlogopite-amphibole-pyroxenite xenoliths contained in the alkali basic-ultrabasic subvolcanic complex in Langao, Shaanxi
Province, are composed of diopside, Ti-rich pargasite, phlogopite apatite, sphene and ilmenite, which have subsolidus metamorphism-deformation
textures such as triple-points, cataclastic boundaries and kink-bands. Mineral chemical characteristics show that the diposide,
Ti-rich paragasite and phlogopite are derived from the mantle and are the products of mantle metasomatism. Compared with normal
mantle-derived spinel-lherzolites, the xenoliths are enriched in TiO2, Fe2O3, CaO, Na2O and K2O, with apparent depletion in MgO. Chondrite-normalized REE patterns and primordial-mantle normalized trace elements data
show that they are enriched in REE (especially LREE) and incompatible trace elements. The petrographic, mineralogical and
petrochemical characteristics indicate that the xenoliths are metasomatized mantle xenoliths, which offers the evidence for
mantle metasomatism and represents the anomalous mantle beneath the Early Paleozoic rift in northern Daba Mountains. The agents
of mantle metasomatism are probably derived from the rising of mantle hot plumes. The processes of metasomatism varied from
limited-range fluid metasomatism in deep mantle (>90 km) to pervasive metasomatism of silicate melt.
This project was financially supported by the National Natural Science Foundation of China (No. 49402035). 相似文献