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1.
The formation conditions and distribution regularities of oil-gas pools in volcanic rocks in western Huimin Depression have been studied in terms of geolgic,sesmic and well logging information,This paper discusses the types and lithofacies,development and distribution of Tertiary volcanic rocks in the area.The results demonstrate that volcanic activity occurred mainly during the period from the Sha-4 stage to the Guantao episode,i.e.,before the oil-generating period(before the end of the Guantao episode and the Minghuazhen episode).The activity did not destroy oil and gas formation and accumulation,but was favourable for the concentration of organic matter and its conversion to hydrocarbons;besides,volcanic rocks can serve as reservoir rocks and cap rocks,playing a role very similar to that of a syndepositional anticline,The volcanic rocks are distributed near the margins of the oil-generating depression;there are many secondary interstices in the rocks,which are connected with each other.These are the leading conditions for the formation of oil-generating period and their self-sealing or good combination with other cap rocks are important factors for forming volcanic rock-hosted oil and gas pools.The oil-gas pools associated with volcanic rocks in western Huimin are mainly distributed around the deep oil-generating depression,in the central up lift or the high structural levels on the margins of the depression.In particular,the sites where several faults cross are usually locatons where hith-yielding oil-gas pools in volcanic rocks are concentrated.  相似文献   

2.
Types and degree of muturity of organic matters in sedimentary rocks as index for oil generation and evolution can be determined by infrared spectrometry. In normal cases,oil-generating rocks can be preliminarily identified by infrared spectra of solubable bitumen components. However, the spectra of condensed nuclei of aromatic hydrocarbon should be resorted to whenever the composition and structure of organic matters arc comparative complex and their degree ofmuturity are not all the same. Systematic researches of known samples show that a configuration of condensed aromatic hydrccarbon can be proposed on the basis of the index of aromatic hydrocarbon structure and the ratio of methyl and methylene to aromatic nucleus. It is evidenced by preliminary experience that oil- and coal-generating organisms can be distinguished from each other with the help of this configuration.  相似文献   

3.
有机质差热分析在有机地球化学中的应用和解释   总被引：2，自引：0，他引：2  
The present paper primarily deals with DTA data on organic matters in carbonate rocks. In combination with analyzes of organic carbon and bituminous substances as well as infrared absorption spectra, an explanation of the features with respect to oil-generating carbonate roeks has been made. The results are summarized as fellows: (1) If the degree of hydrocarbonization ef organic matters in carbonate rocks is high, DTA exothermic pre-peaks will be expected at lower temperatures. (2) Insoluble organic matters in carbonate rocks, would crack up into soluble organic matters (light hydroearbons) during the meso-catagenetic stage. (3) Evolution of liquid hydrocarbons produced in the preto-eatagenetic stage is recognizable during the meso-eatagenetie stage.  相似文献   

4.
碳酸盐矿物的包裹有机质及其生油意义   总被引：5，自引：3，他引：5  
Fluorescent slice observations have revealed a considerable amount of organic matter enclosed in carbonate minerals, most of it giving off yellow-brown fluorescence and being zonally distributed in calcite and dolomite. The amount of enclosed organic matter released from the enclosure when treated with HCl is two times higher than that of extractable organic mattes in the same rock sample. In comparison to the extractable organic matter, the enclosed organic matter is possessed of some compositional characters of its own. In terms of the distribution of biological markess, it is suggested that the enclosed organic matter may be low in maturity relative to the extractable organic matter in the same source rock.Results of the simulating experiments under high temperatures and pressures show that this kind of organic matter enclosed in carbonate minerals can be converted into oil-generating substances. Therefore, detailed studies of the enclosed organic matter are of much help to the evaluation of oil-generating potentiality of carbonate source rocks.  相似文献   

5.
碳酸盐岩生油岩的有机地球化学、岩石学特征   总被引：13，自引：1，他引：13  
Features of oil-generating carbonate rocks are studied in terms of petrology and organic geochemistry of fluorescent materials in rocks. It is postulated by the authors that the organic carbon content in oil-generatlng carbonate rocks is necessarily lower than that in shales, and the possible cause of this observation is discussed. The quality of oil-ganerating carbonate rocks may be judged by aromatic structure index,amino acid, pigment index, and DTA data on organic matter. However, the application of presently available organic geochemical criteria to non-oil-generating reservoir rocks may always give misleading results. To circumvent this difficulty, it is necessary first to make distinction between primary and secondary organic matter by cxamining the fluorescent materials under a fluorescence microscope. Measurementof radical content of the organic substances and DTA are useful techniques to determine the degree of maturation. The maturation of organic substances proceeds at a lower rate in carbonate rocks than in shales. It is likely, therefore, that some older carbonate strata can also be promising areas for petroleum exploration. Oil-generating carbonate rocks consist mainly of mierite limestones rich in organic matter and are thought to be formed under low-encrgy environment. Consequently, petrological(especially mierolithofacies) studies are very important in evaluating carbonate source rocks.  相似文献   

6.
Two major characters are recognized with respect to the evolution of organic matter during diagenesis of carbonate rocks; (1) expellation of organic matter from carbonate minerals through crystallization, which could reduce the amount of organic matter significantly in the early stage of diagenesis; (2) protection of organic matter by the minerals, especially in the late stage of diagenesis. According to their nature and relations to the protection during diagenesis, three majer forms of disseminated organic matter in carbonate rocks can be distinguished: adsorbed, ctystallization-trapped organic matter and organic inclusions. Owing to the protection by minerals the maturation process of disseminated organic matter proceeds very slowly, and the matority of crystallization-trapped organic matter may play an important role in carbonate source rocks. Most of the organic inclusions are migrated organic matter, such as hydrocarb ons; so organic inclusions may be a good indicator which can be used to study the primary,secondary migration and the concentration of oil and gas in carbonate source rocks and carbonate reservoir strata,  相似文献   

7.
Studies of organic inclusions from the offshore oil and gas fields provide much information about the number of times,temperature,depth,time and phase state of oil-gas migration,as well as about the composition of organic inclusions.On the basis of the type,character,composition and distribution of organic inclusions in the Zhu-Ⅲ Depression at the Pearl River Mouth,information can be developed about the source rocks of oil and gas,and their evolution and migration.  相似文献   

8.
Through the analysis of ocean organisms, the distribution characteristics and enrichment of organic matters in modern marine sediments and ancient marine strata, this paper shows that the main factors influencing the formation of excellent marine source rocks are the paleoclimate, biologic productivity, terrestrial organic matter, oxidation–reduction environment, sedimentation rate, and the type of the basin. In addition to those factors,high biologic productivity or high content of terrestrial organic matter input is a requirement for the enrichment of the organic matter in a marine environment. Reducing environment was favorable for organic matter accumulation and preservation in depositing and early diagenesis stage, which is an important element for the formation of high-quality marine source rocks. Paleoclimate also influences the marine source rocks formation, as humid subtropical and tropical climates are the most favorable regimes for the formation of marine source rocks. Wind transports some vascular plant materials into the marine environment. Furthermore, upwellings driven by steady wind can cause high biologic productivity, thus formingorganic-C-rich mud. Suitable sedimentation rate is beneficial for marine organic matter accumulation. Moreover, the type of the basin also plays an important role in the development of marine source rocks. Silled basins with a positive water balance often act as nutrient traps, thus enhancing both productivity and organic matter preservations, while in open oceans, organic matter enrichment in sediments has just been found in the oxygen minimum layers.  相似文献   

9.
岩石吸附烃及其与油气的关系   总被引：2，自引：0，他引：2  
Some spatio-temporal correlations have been established between the distribution of oil-generating and reservoir strata and the characteristics of hydrocarbons absorbed in the rocks, in the light of analytical data on absorbed hydrocarbons in a carbonate rock district. The practical value of systematic rock-absorbed hydrocarbon measurements as an indicator in petroleum prospecting is thus epparent  相似文献   

10.
Five major froms(lamellar,banded,crack-like,dissceminated and segregated encrustation(of organic matter distribution in sourc rocks have been revealed under scanning electron microscope by using the heavy metal staining technique.The degree of organic impregnation is related to the amount of liquied hydrocarbons in the rocks,and from this relationship a rough estimation of organic matter can be made on the basis of electron microscopic observations.In conjunction with experimental studies it has been found that the distribution forms of organic matter are a function of its maturity in the process of thermal evolution and accordingly some microscopic criteria can be developed for the assessment of source rocks.  相似文献   

11.
The chemistry of organo-clay in somc Tertiary clay-stones from the northern part of the South China Sea was studied. The preliminary results are summarized as follows : (1) Three basic types of organic matter are distinguished in the claystones after treated with different chemical agents: spluble, combined and insoluble (kerogen). It is suggested that the distribution of organic matter and its conversion to petroleum are closely related with the composition and structure of expansive clay minerals in the claystones. Therefore, more detailed studies of these expansive clay minerals may provide new indices for oil-generating potentiality. (2) It is considered from the study of the state of existence of organic matter and. of organo-clay complexes in tile clay-stones that the accumulation and preservation of organic substances may substantially take the form of organo-clay complexes in the process of sedimentation and burial and that the organo-clay complexes may make considerable contributions to the formation of petroleum hydrocarbons during diagenesis. Studies in this aspect are of great significance in developing new theories conccrning petroleum generation and in localizing oil-generating occurrences.  相似文献   

12.
Gld deposits occurring in metamorphosed microcelastic rocks are distributed extensively at home and abroad.Some deposits of this type are of superlarge tonnage.The formation of gold deposits in metamorphosed microclastic rocks involves three stages:the sedimentary stage,the regionally metamorphic stage,and the ore-forming stage.At the first stage,microclastic sedimentary source rocks were developed in a relatively semi-enclosed reducing sea basin and were enriched in carbon,sulfur and gold.At the second stage,the gold adsorbed on organic matter and clay minerals was relesed and poorly concentrated during the destruction of organic matter and the depletion of clay minerals by regional metamorphism with increase temperature and pressure.At the third stage,a tectono-hydrothermal event took place.As a result,gold was leached from metamorphosed microclastic rocks,transported to ore depositional locus and/or mixed with gold of other sources in the course of migration,and finally precipitared as ores.Gold deposits of this type were eventually formed at the third stage,and they also can be classified as the orogenic belt type and the activation zone type.The gold deposits occurring in metamorphosed microcalastic rocks are the products of reworking processes and the influence of magmatism should be taken into consideration in some cases.  相似文献   

13.
The presence of shale oil in the Cretaceous Hengtongshan Formation in the Tonghua Basin, drilled by the well TD-01, has been discussed in this geological investigation for the first time. To evaluate the high-quality source rocks of Cretaceous continental shale oil, the distribution characteristics and the evolution of the ancient environment, samples of shale were systematically analyzed in terms of sedimentary facies, organic geochemistry, and organic carbon isotopic composition. The results demonstrate that a TOC value of 1.5% represents the lower-limit TOC value of the high-quality source rocks. Source rocks have an aggregate thickness of 211 m and contain abundant organic matter, with TOC values of 2.69% on average and a maximum value over 5.44%. The original hydrocarbon-generative potential value(S_1+S_2) is between 0.18 mg/g and 6.13 mg/g, and the Ro is between 0.97% and 1.40%. The thermal maturation of the source rocks is relatively mature to highly mature. The δ13C value range is between -34.75‰ and -26.53‰. The ratio of saturated hydrocarbons to aromatic hydrocarbons is 1.55 to 5.24, with an average of 2.85, which is greater than 1.6. The organic types are mainly type Ⅱ_1, followed by type Ⅰ. The organic carbon source was C_3 plants and hydrophytes. The paleoclimate of the Hengtongshan Formation can be characterized as hot and dry to humid, and these conditions were conducive to the development of high-quality source rocks. A favorable paleoenvironment and abundant organic carbon sources provide a solid hydrocarbon generation base for the formation and accumulation of oil and gas in the shale of the Tonghua Basin.  相似文献   

14.
Organic geochemistry and comparisons of characteristics of the organic matter in wall rocks of the ore-controlling strata and ores of the Lower Jurassic Songling black shale formation and the related Songxi silver-antimony deposit of northeastern Guangdong have been studied in this paper.The results show that the Lower Jurassic Songling shale formation is a suite of biologic-rich and organic-rich ore-bearing marine sedimentary rocks.Micro-components of the organic matter in the Songling black shale formation consists primarily of algae,amorphous marine kerogen,solid bitument,and pyrobitument.The thermal evolution of organic matter is at the over-maturity stage.There is a general positive correlation between total organic carbon(CO)and metallogenetic elements such as Ag and Sb in the black shale formation.Organic matter in the host rocks in the Songxi ore deposit played a role in controlling the silver-antimony depositing environment during the forming process of the black shale ore-bearing formation.In the absence of vitrinite,the relative level of thermal maturity calculated by solid bitument reflectance indicates that the ore-forming temperatute of the Songxi silver-antimony deposit was about 150-170℃,which was considered as an epithermally reworked ore deposit.The roles of organic matter in the formation of the Sonxi ore deposit are a primitive accumulation of the metallogenetic elements(Ag,Sb) in the sea-water cycle system for ore source and a concentration of metals by ion exchange of chelation as well as reductionn of the oxidzed metals.  相似文献   

15.
Terrigenous clastic reservoir rocks are widespread in China,and nearly all the industrial oil and gas accumulations in eastern China occur in the clastic rocks.The study shows that organic inclusions are mostly distributed in the secondary fissures and pores which were ormed in the process of oil-rock interaction,rather than in the cements or secondary enlargements. The organic inclusions are dominantly organic gas-rich or are composed of pure hydrocarbons.Homogenization temperatures range mainly from 120℃ to 130℃，which shows a relatively high maturity of organic matter.Vertical and horizontal temperature changes provide the grounds for the investigation of basin evolution and thermal fluid-kinetics-model.Fluorescence spectral characteristics o the organic inclusions indicate that oils and gases in the area studied probably have experienced two-stage or two-time migration.Micro-fluorescence rescearch is one of the effective approaches to oil/source correlation and oil migration-stage determination.The abundance and occurrence of organic inclusions is one of the indicators of oil and gas abundance and accumulation in rock layers.With the help of other informatio,organic inclusions can provide the basis for the prospective assessment of oil and gas in clastic reservoir rocks.  相似文献   

16.
One of the most important tasks of evaluating natural resources of petroliferous basins is to determine the organic matter abundance of source rocks in the basin.The usual method for assessing the organic carbon content of source rocks is based on laboratory analyses.There is a deviation in calculating organic carbon content due to the heterogeneous distribution of organic matter and the artificial factors when sampling.According to the continuous characteristics of information logging,the conventional logging curves(mainly acoustics and resistivity,etc.) were calibrated with the organic carbon experimental data of cores,cuttings or sidewall cores.The organic carbon content of source rocks of the 4 th(Es 4) and 3 rd(Es 3) members of the Shahejie Formation in western sag in the Liaohe depression was estimated directly by a great amount of continuous data including resistivity and acoustic logging,etc.Comparison between the results from computer processing and lab analysis of logging data shows that the organic carbon contents derived from the computer processing of logging data have the same reliability and accuracy as the lab analysis results.The present data show that this method is suitable to evaluate the source rocks of western sag in the Liaohe depression and has great potential in evaluating natural resources of sedimentary basins in the future.On the basis of logging data of source rocks,experimental data and existing geochemical analyses of the Liaohe Oilfield,the corresponding total organic carbon(TOC) isograms of source rocks were plotted.The source rocks of Es 4 and Es 3 of the Shahejie Formation are thought to be beneficial to hydrocarbon accumulation due to the high TOC.  相似文献   

17.
Sedimentary rock-hosted disseminated gold (SRHDG) deposits in the Youjiang-Nanpanjiang Basin,southwestem Guizhou Province are commonly hosted by the same fold crests that commonly contain a remarkable amount of organic material. The total organic carbon (TOC) contents of the ores and host rocks are usually less than 1%. The reflectance of vitrinite and pyrobitumen in the ores and the host rocks ranges from 1.5% to 4.5%, often in the range of 2% to 3%. In the Lannigou deposit, the reflectance of vitrinite and pyrobitumen in the ores is usually somewhat higher than those within the host rocks, indicating a hydrothermal impact on the organic matter in the altered host rocks. On the contrary, the estimated maximum paleotemperatures of the Getang and Zimudang deposits are higher than the homogenization temperatures of the fluid inclusions in the ores, signifying that the organic matter maturation predated Au mineralization. No correlation between the organic matter contents and Au concentrations were recognized in the ores.However, the most striking observation is that there is a positive correlation between the $2 (a parameter of Rock-Eval analysis), Au and As contents of the ores in the Lannigou deposit. Organic matter maturation and migration is apparent from the TOC vs. HCI diagram. Furthermore, group analysis of the dichloromethane extractable organic component of the ores and host rocks shows that the maturation degree of the organic matter in the ores is slightly higher than that of the host rocks in the Lannigou gold deposit. However, the compositions of their alkanes, steranes and terpenes, which serve as biomarkers, are quite similar; this suggests that the organic matter found in the ores and host rocks has a common marine source. Organic matter probably contributed to the preconcentration of Au in the host rocks. Hydrocarbons in the system,on the other hand, clearly contributed to the emplacement of the gold mineralization through thermal sulfate reduction.Organic matter in the solution might have increased the potential of the hydrothermal solution to transport Au.  相似文献   

18.
According to the drilling results,there are three sets of source rocks of the Cenozoic Group in the Qiongdongnan Basin,including the Yacheng Formation transitional facies mudstone,the Oligocene Lingshui Formation semi-enclosed marine facies mudstone,and the Miocene neritic-bathyal facies mudstone.The hydrocarbon generating conditions of the source rocks in the study area are mainly controlled by sedimentary environment and organic matter input.The abundance of organic matter in the Oligocene source rocks which were formed in a low-energy back shore environment is confined by organic matter input and hydrodynamic condition.The Miocene source rocks formed in the open marine environment lack terrestrial organic matter input,whose organic matter abundance is constrained by the primary production of the ocean and the preservation condition of organic matter.In addition,the redox conditions are also significant to the formation of source rocks in the study area.According to the differences in key factors controlling the development of source rocks in different time periods and structural belts revealed by drilling practice,three development patterns of source rocks have been put forward.The first one is the transitional facies model featuring a great deal of terrestrial organic matter and weakly hydrodynamic conditions which are apt to develop high effective source rocks in the Yacheng Formation.The second one is the semi-enclosed marine facies featuring abundant terrestrial organic matter,weakly hydrodynamic condition and fine preservation condition in the central depression zone,which are apt to form fine-quality source rocks in the Lingshui Formation.The third one is the marine facies model featuring strong hydrodynamics in the shore-shallow area of northern continental shelf and the lack of benthic algae which are against the development of source rocks.It can be predicted that the continental slope is the perfect place to form source rocks where adequate amounts of light favor the photosynthesis of plants,besides the fine preservation and weakly hydrodynamic conditions.In the deep sea area,although accompanied with weakly hydrodynamic conditions and a reduction environment,it is not suitable for the development of source rocks on account of less aquatic organisms causing low primary production.  相似文献   

19.
The comparative study of organic matter in carbonate rocks and argillaceous rocks from the same horizon indicates that the organic thermal maturities of carbonate rocks are much lower than those of argillaceous rocks .Ana extensive analysis of extracted and inclused organic matter from the same sample shows that inclused organic matter is different from extracted organic matter,and the thermal maturity of the former is usually lower than that of the latter in terms of biomarker structural parameters.It seems that carbonate mineras could preserve organic matter and retard organic maturation.The inclused organic matter,abundant in most carbonate rocks,will be released from minerals and transformed into oil and gas during the high-thermal maturity stage.  相似文献   

20.
The present paper deals with the biomarker characteristics of crude oils and source rocks from different environments(fresh,fresh-brackish and salt waters)of nonmarine depositional basins of different ages in China.Their characters are summarized as follows:1)Souce rocks and crude oils derived from fresh-water lacustrine facies have an odd/even predominance of n-alkanes and high pristine/phytane ratios.Oils from the fresh-water lacustrine facies differ from typical marine oils in the relative contents of total steranes and terpanes,the concentrations of hopanes and organic sul-phur compounds and the values of methylphenanthrene indices and C,H,S stable isotopes.2)The source rocks and crude oils derived from saline lacustrine facies possess an even/odd predominance of n-alkanes and high phytane/pristine ratios.There are also some differences between saline lacustrine oils and freshwater lacustrine oils in the concentrations of steranes,tricyclic terpanes and organic sulphur compounds,as well as in the values of methylphenanthrene indices and C,H,S stable isotopes.3)Oils derived from fresh-brackish water lake facies differ from oils from fresh-water lacustrine or samline lacustrine environments in respect of some biomarkers.According to the various distributions of these biomarkers,a number of geochemical parameters can be applied synthetically to differentiating and identifying the nature of original depositional environments of crude oils and source rocks and that of organisms-primary source materials present in those environments.  相似文献   

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