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1.
位于法国比利牛斯山的Trimouns矿床是世界上最大的滑石-绿泥石矿床之一。对该矿床形成的条件及滑石和绿泥石矿石的含量已较清楚。它是由不同类型的岩石通过热液交代蚀变而形成的，主要包括白云岩蚀变为滑石为主的矿石和硅铝质岩石(云母片岩和伟晶岩)蚀变为绿泥石为主的矿石。滑石矿石显示片理化结构(滑石片岩)或压实块状结构(块滑石)。由伟晶岩蚀变而来的绿泥石矿石为呈绿色的球状矿体，而由云母片岩蚀变而来的绿泥石矿石呈块状或片理状、颜色为灰绿色和深灰色。本文对欧洲这个独一无二的滑石和绿泥石矿床的地质特征和成因进行了总结和讨论。流体包裹体研究表明成矿流体为高盐度(20to30％eq．wt％NaCl)、中温(320℃)、压为为2．5kbars。磷钇矿和独居石的U—Ph定年结果表明，成矿年代为112—97Ma，成矿作用可能持续了16Ma以上。  相似文献   

2.
The Guelb Moghrein Fe oxide–Cu–Au–Co (IOCG) deposit is located in the northern part of the Mauritanides chain at the western edge of the West African Craton. It is commonly held that the orogenic belt has experienced a polyphase tectonothermal evolution, including two Panafrican and one Variscan event. Dating of two distinct morphological types of hydrothermal monazite and xenotime from Guelb Moghrein yielded in situ U–Pb ages of 2492 ± 9 and 1742 ± 12 Myr respectively. Such ages have not been reported previously from the region which is conspicuous by the widespread occurrence of banded iron formations, more akin to Proterozoic or Archean than to Paleozoic settings. The supracrustal rocks are thought, therefore, to represent a greenstone terrane that was mineralized by hydrothermal fluids during the late Archean and reactivated by middle Proterozoic fluid flow. Final emplacement at the current position on the West African Craton was at ～300 Ma during Gondwana–Laurentia collision.  相似文献   

3.
The Olympic iron oxide–copper–gold province in South Australia contains numerous deposits and prospects, including the Olympic Dam Cu–U–Au–Ag deposit and the Acropolis prospect. The Acropolis prospect comprises massive, coarse-grained magnetite–apatite veins partly replaced by a hematite-stable assemblage. The apatite grains in the veins contain zones with abundant inclusions of other minerals (including monazite and xenotime) and low trace-element concentrations relative to the inclusion-free zones. The inclusion-rich apatite zones are interpreted to be formed from the recrystallisation of the inclusion-free apatite and remobilisation of U, Th and rare earth element (REE) from apatite into monazite and xenotime. Apatite, monazite and xenotime are all established U–Th–Pb geochronometers and offer the potential to constrain the alteration history of the Acropolis prospect. The LA-ICPMS U–Pb age of inclusion-free apatite is within error of the age of the host volcanic units (ca 1.59 Ga). Inclusion-rich apatite yields both near-concordant analyses that are within error of the inclusion-free apatite as well as highly disturbed (discordant) analyses. The most concordant analyses of monazite (Th–Pb) inclusions and xenotime (U–Pb) inclusions and rim grains indicate an alteration event occurred at ca 1.37 Ga and possibly also at ca 500 Ma. The disparity in age of the inclusion-rich apatite and the REE-phosphate inclusions (and rim grains) is suggested to be owing to the apatite being initially recrystallised at ca 1.59 Ga and modified again by a later event that also formed (or coarsened) most of the inclusions. Partial resetting of the majority of the monazite inclusions as well as the presence of significant amounts of common Pb has complicated the interpretation of the monazite results. In contrast, xenotime is a more robust geochronometer in this setting. The ages of the two post-1.59 Ga events that appear to have affected the Acropolis prospect do not correspond to any events known to have occurred in the Gawler Craton. The earlier (ca 1.37 Ga) age instead corresponds best with metamorphic–magmatic–hydrothermal activity in Laurentia, consistent with the proximity of Laurentia and the Gawler Craton inferred from palaeogeographic reconstructions. The later (ca 500 Ma) event corresponds to the Delamerian Orogeny and has been shown by prior studies to have also affected the Olympic Dam deposit.  相似文献   

4.
The rare metal minerals of mineralized altered granites within the Ghadir and El-Sella shear zones, are represented by betafite, U-minerals (uraninite and uranophane), zircon, monazite, xenotime, and rutile in the Ghadir shear zone. While they are columbite-tantalite minerals as ferrocolumbite, pyrochlore, and fergusonite, Th-minerals (cheralite, uranothorite, and huttonite monazite), Hf-zircon, monazite and xenotime in the El-Sella shear zone. Hf-zircon in the El-Sella and Ghadir shear zones (increasing from the core to the rim) contains high inclusions of U-Th, and REE minerals such as cheralite, uranothorite, huttonite monazite and xenotime especially in the El Sella shear zone. The rare-metal minerals, identified from peralkminous granites of the shear zones are associated with muscovite, quartz, chlorite, fluorite, magnetite, and biotite that are restricted to the two shear zones. Uraninite (low Th content) occurring in the Ghadir shear zone indicates the hydrothermal origin, but there are thorite, uranothorite, cheralite, and Hf-zircon in the El Sella shear zone, also indicating the hyrothermal proccess after magmatic origin. Compositional variations of Ta/(Ta+Nb) and Mn/(Mn+Fe) in columbite from 0.07-0.42 and 0.04-0.33, respectively, and Hf contents in zircon are so high as to be 12%, especially in the rim in the El Sella shear zone. This feature re-flects the extreme degree of magmatic fractionation. Four samples from the altered granites of the Ghadir shear zone also are very low in TiO2 (0.04 wt%-0.17 wt%), Sr [(82-121)×10-6], and Ba [(36-380)×10-6], but high in Fe2O3T (0.46 wt%-0.68 wt%), CaO (0.64 wt%-1.23 wt%), alkalis (8.59 wt%-8.88 wt%), Rb [(11-203)×10-6], Zr [(98-121)×10-6], Nb [(9-276)×10-6], Ta [(2-139)×10-6], U [(14-63)×10-6], Th [(16-105)×10-6], Pb [(13-32)×10-6], Zn [(7-8)×10-6], Y [(15-138)×10-6], Hf [(3-9)×10-6], and ∑REE [(81-395)×10-6, especially LREE [(70-322)×10-6]. They are very high in Zr/Hf (15.07-85.96) and Nb/Ta (7.17-21.48), and low in Rb/Sr (2.56-3.36) and Th/U (0.096-3.36). Four samples of the altered granites from the El Sella shear zone are very low in TiO2 (0.23 wt%-0.38 wt%), Sr [(47-933)×10-6], and Ba [(82-175)×10-6] , with high Fe2O3T (1.96 wt%-2.87 wt%), CaO (0.43 wt%-0.6 wt%), alkalis (4.46 wt%-10.7 wt%), Rb [(109-313)×10-6], Zr [(178-1871)×10-6], Nb [(11-404)×10-6], U [(56-182)×10-6], Th [(7-188)×10-6], Ta [(0.5-57)×10-6], Pb [(12-28)×10-6], Zn [(1-13)×10-6], Y [(62-156)×10-6], Hf [(3-124)×10-6], and ∑REE [(101-184)×10-6], especially HREE [(7-139)×10-6]. This is consistent with the very fractionated, fluorine-bearing granitic rocks that were altered and sheared in the El Sella shear zone. Zr/Hf (14.23-39.79) and Nb/Ta (1.98-7.01) are very high, and Rb/Sr (0.14-1.7) and Th/U (0.25-2.5) are low in the Ghadir shear zone. Field evidence, textural relations, and the composi-tion of ore minerals suggest that the main mineralizing event was magmatic (615+/-7 Ma, and 644+/-7 Ma CHIME monazite), especially in the El Sella shear zone, with later hydrothermal alteration and local remobilization of the high-field-strength elements.  相似文献   

5.
SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime 207Pb/206Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.  相似文献   

6.
花岗岩型铀矿中铀的来源问题，长期以来是铀矿床学研究的热点问题之一。大多数学者认为其成矿物质主要来源于花岗岩本身的含铀副矿物，然而对于含铀副矿物热液蚀变行为研究较少。鹿井铀矿田位于诸广山复式岩体的中部，是华南最主要花岗岩型铀矿田之一，碎裂蚀变岩型铀矿化在该矿田内占主导地位。小山铀矿床位于鹿井矿田中部，是近些年新发现的碎裂蚀变岩型矿床。本文以钻孔ZK1- 1为研究对象，对热液蚀变带开展了精细矿物学研究。研究表明：蚀变带中发育有晶质铀矿、铀石—钍石、独居石、磷钇矿、锆石、磷灰石、金红石等含铀副矿物。晶质铀矿、铀石—钍石中铀含量高，热液蚀变条件不稳定，铀容易释放；独居石蚀变为直氟碳钙铈矿和磷钇矿蚀变为次生磷灰石过程中容易释放出铀；锆石因结构稳定，铀难以释放；磷灰石、金红石中铀含量较低，供铀能力差。综合分析认为花岗岩中晶质铀矿、铀石—钍石是主要铀源矿物，独居石、磷钇矿为次要铀源矿物。  相似文献   

7.
Monazite petrogenesis in the Nelson contact aureole is the result of allanite breakdown close to, but downgrade and therefore independent of, major phase isograds involving cordierite, andalusite and staurolite. The development of garnet downgrade of the staurolite and andalusite isograds does not appear to affect the onset of the allanite-to-monazite reaction but does affect the textural development of monazite. In lower pressure, garnet-absent rocks, allanite breakdown results in localized monazite growth as pseudomorphous clusters. In higher pressure, garnet-bearing rocks, allanite breakdown produces randomly distributed, lone grains of monazite with no textural relationship to the original reaction site. Fluids liberated from hydrous phases (chlorite, muscovite) during garnet formation may have acted as a flux to distribute light rare earth elements more widely within the rock upon allanite breakdown, preventing the localized formation of monazite pseudomorphs. Despite these textural differences, both types of monazite have very similar chemistry and an indistinguishable age by electron microprobe chemical dating (157 ± 6.4 Ma). This age range is within error of isotopic ages determined by others for the Nelson Batholith. Garnet from the garnet, staurolite and andalusite zones shows euhedral Y zoning typified by a high-Y core, low-Y collar and moderate-Y annulus, the latter ascribed to allanite breakdown during garnet growth in the garnet zone. The cause of the transition from high-Y core to low-Y collar, traditionally interpreted to be due to xenotime consumption, is unclear because of the ubiquitous presence of xenotime. Accessory phase geothermometry involving monazite, xenotime and garnet returns inconsistent results, suggesting calibration problems or a lack of equilibration between phases.  相似文献   

8.
Monazite is accepted widely as an important U-Pb geochronometer in metamorphic terranes because it potentially preserves prograde crystallization ages. However, recent studies have shown that the U-Pb isotopic system in monazite can be influenced by a variety of processes that partially obscure the early growth history. In this paper, we attempt to interpret complex monazite and xenotime U-Pb data from three Paleoproterozoic granite dikes exposed in the Grand Canyon. Single-crystal monazite analyses from an unfoliated granite dike spread out along concordia from the crystallization age of the dike (defined by U-Pb zircon data to be 1685 ± 1 Ma) to 1659 ± 2 Ma, a span of 26 million years. Back-scattered electron (BSE) imaging reveals that magmatic domains within most crystals from this sample are truncated by secondary domains associated with prominent embayments at the grain margin. Fragments of a single crystal yield contrasting, concordant dates and fragments from the edges and tips of crystals yield the youngest dates. Based on these observations we suggest that the secondary domains formed at least 26 million years after the crystal formed. Monazite and xenotime dates from the second sample, a sheared dike that cross-cuts the previous dike, spread out along concordia over 16 million years and range up to 2.4% normally discordant. Again, BSE imaging reveals secondary domains that truncate both magmatic zoning and xenocrystic cores. Fragments sliced from specific domains of a previously imaged monazite crystal demonstrate that the secondary domain is 13 million years younger than the core domain. Textures revealed in BSE images suggest that the secondary domains formed by fluid-mineral interaction. Normal discordance appears to result from both radiation damage accumulated at temperatures below 300 °C and water-mineral interaction. Monazite data from the third sample exhibit dispersion in both the 207Pb/206Pb dates (1677–1690 Ma) and discordance (+ 1.6% to − 3.1%). Reverse discordance in these monazites cannot be explained by incomplete dissolution or excess (thorogenic) 206Pb. Sliced fragments from several crystals reveal dramatic intragrain U-Pb disequilibrium that does not correlate with either Th or U concentration or position within the crystal. We suggest that reverse discordance resulted from mechanisms that involve exchange or fractionation of elemental U or elemental Pb, and that neither the U-Pb dates nor the 207Pb/206Pb dates are reliable indicators of the rock's crystallization age. Given the large number of processes proposed in the recent literature to explain monazite U-Pb systematics from rocks of all ages, our results can be viewed as another cautionary note for single-crystal and multi-crystal monazite geochronometry. However, we suggest that because individual crystals can preserve a temporal record of primary and secondary monazite growth, micro-sampling of individual monazite crystals may provide precise absolute ages on a variety of processes that operate during the prograde, peak and/or retrograde history of metamorphic terranes. Received: 9 June 1996 / Accepted: 18 October 1996  相似文献   

9.
U–Pb sensitive high resolution ion microprobe mass spectrometer (SHRIMP) ages of zircon, monazite and xenotime crystals from felsic intrusive rocks from the Rio Itapicuru greenstone belt show two development stages between 2,152 and 2,130 Ma, and between 2,130 and 2,080 Ma. The older intrusions yielded ages of 2,152±6 Ma in monazite crystals and 2,155±9 Ma in zircon crystals derived from the Trilhado granodiorite, and ages of 2,130±7 Ma and 2,128±8 Ma in zircon crystals derived from the Teofilândia tonalite. The emplacement age of the syntectonic Ambrósio dome as indicated by a 2,080±2-Ma xenotime age for a granite dyke probably marks the end of the felsic magmatism. This age shows good agreement with the Ar–Ar plateau age of 2,080±5 Ma obtained in hornblendes from an amphibolite and with a U–Pb SHRIMP age of 2,076±10 Ma in detrital zircon crystals from a quartzite, interpreted as the age of the peak of the metamorphism. The predominance of inherited zircons in the syntectonic Ambrósio dome suggests that the basement of the supracrustal rocks was composed of Archaean continental crust with components of 2,937±16, 3,111±13 and 3,162±13 Ma. Ar–Ar plateau ages of 2,050±4 Ma and 2,054±2 Ma on hydrothermal muscovite samples from the Fazenda Brasileiro gold deposit are interpreted as minimum ages for gold mineralisation and close to the true age of gold deposition. The Ar–Ar data indicate that the mineralisation must have occurred less than 30 million years after the peak of the metamorphism, or episodically between 2,080 Ma and 2,050 Ma, during uplift and exhumation of the orogen.Electronic supplementary material Supplementary material is available for this article at  相似文献   

10.
Late stages of the Svecofennian orogeny in SW Finland were related to a tranpressional stress field and dextral movements along crustal scale shear zones under decreasing temperature and pressure conditions. In the Kemiö area, a minimum estimate for the time span of movements along one of these shear zones is obtained from the ages of 1840 to 1830 Myr-old microcline granite sheets, related to early ductile deformation, and by dating structurally late rare-mineral granite pegmatites, related to brittle deformation. One pegmatite was emplaced when the rheological conditions in the gabbro changed from ductile to semi-ductile and brittle. It has U-Pb ferrotapiolite ages ranging between 1807.0 ± 2.9 Myr (2 ) and 1803.1 + 2.9/ -2.0 Myr (2 ). Another pegmatite emplaced under brittle conditions has an U-Pb ferrotapiolite age of 1802.9 ± 1.3 Myr (2 ). These pegmatites were emplaced preferentially in gabbroic rocks, that showed brittle to semi-ductile deformation at a time when their more felsic host-rocks still showed ductile deformation. The age range bracketed by the microcline granite sheets and the structurally late pegmatites indicates that ductile deformation related to the transpressional Late Svecofennian tectonic regime in southwestern Finland, persisted for at least 30–40 Myr.  相似文献   

11.
The basement of central Madagascar displays two contrasted structural patterns. The first one (D1) is characterized by north-striking foliations that are gently dipping to the west and carry W- to WSW-plunging lineations, whereas the second one (D2) is characterized by steeper foliations that are striking to the NNE and lineations that are either subhorizontal or gently plunging to the SSW. The younger pattern is related to late-Panafrican tectonics along the major Angavo shear zone that is about 1000 km in length and 40 km in width with apparently little offset. Deformation in the Angavo zone induced interference folding on both sides. The D2 event is characterized by low pressures (ca 400 MPa) and high temperatures (up to 790 °C) responsible for prograde granulite facies conditions, that resulted from heat transfer due to magma and fluid advection in the Angavo shear zone. The D2 event is pinned at 550 ± 11 Ma by a new monazite age from a reoriented Andringitrean granite near Ankaramena. A new suite of amphibole and biotite Ar–Ar geochronological data enables to retrace the thermochronogical evolution inside and outside the Angavo shear zone. Combined with new structural results from the western interference zone, these ages yield a better understanding of the late-Panafrican history of central Madagascar. No diachronism is observed along the strike of the Angavo shear zone. Conversely, amphibole and especially biotite ages decrease from West to East, i.e. towards the shear zone. These new ages range from 511 to 469 Ma. A 1-D conductive model constrains the thermal effect in relation with the Angavo shear zone to be restricted to a lateral distance of ca 60 km (in map view) for a maximum heating duration of 20 Myr. This is in agreement with the Ar–Ar data and with the width of the observed interference zone. Following this episode of deformation and heat transfer, the estimated cooling rates of the Angavo shear zone range from to 15 to 6 °C/Myr, respectively before and after 515 Ma. A post-collision intracontinental setting is suggested for the Angavo shear zone, which is regarded as a remote effect of the Kuunga Orogeny between India and Antarctica.  相似文献   

12.
Zircon, monazite and xenotime crystallized over a temperature interval of several hundred degrees at the magmatic to hydrothermal transition of the Sn and W mineralized Mole Granite. Magmatic zircon and monazite, thought to have crystallized from hydrous silicate melt, were dated by conventional U–Pb techniques at an age of 247.6 ± 0.4 and 247.7 ± 0.5 Ma, respectively. Xenotime occurring in hydrothermal quartz is found to be significantly younger at 246.2 ± 0.5 Ma and is interpreted to represent hydrothermal growth. From associated fluid inclusions it is concluded that it precipitated from a hydrothermal brine ≤ 600 °C, which is below the accepted closure temperature for U–Pb in this mineral. These data are compatible with a two-stage crystallization process: precipitation of zircon and monazite as magmatic liquidus phases in deep crustal magma followed by complete crystallization and intimately associated Sn–W mineralization after intrusion of the shallow, sill-like body of the Mole Granite. Later hydrothermal formation of monazite in a biotite–fluorite–topaz reaction rim around a mineralized vein was dated at 244.4 ± 1.4 Ma, which distinctly postdates the Mole Granite and is possibly related to a younger hidden intrusion and its hydrothermal fluid system.

Obtaining precise age data for magmatic and hydrothermal minerals of the Mole Granite is hampered by uncertainties introduced by different corrections required for multiple highly radiogenic minerals crystallising from evolved hydrous granites, including 230Th disequilibrium due to Th/U fractionation during monazite and possibly xenotime crystallization, variable Th/U ratios of the fluids from which xenotime was precipitating, elevated contents of common lead, and post-crystallization lead loss in zircon, enhanced by the fluid-saturated environment. The data imply that monazite can also survive as a liquidus phase in protracted magmatic systems over periods of 106 years. The outlined model is in agreement with prominent chemical core-rim variation of the zircon.  相似文献   


13.
EPMA U-Th-Pbtotal dating in U- and Th bearing minerals (e.g., monazite, zircon, and xenotime) is a low-cost and reliable technique used for retrieving age information from detrital, diagenetic and low to high-T metamorphic, as well as magmatic rocks. Although, the accuracy on measured ages obtained using EPMA is considered to be poor compared to isotopic ages, the superior spatial resolution, ability to integrate textural and age information by in-situ measurement, lack of sample damage and easier and cheaper data generation in EPMA make chemical dating a very valuable tool to decipher diverse petrological processes.This contribution presents an improved analytical protocol to obtain precise estimates of U, Th and Pb concentrations in xenotime. Results were tested on monazite standard (Moacyr pegmatite, Brazil; TIMS age: 487 ± 1 Ma) as the reference material. The proposed analytical protocol has been successfully applied to achieve an analytical uncertainty of less than 10% in U, Th and Pb measurements in xenotime. The protocol was further used to resolve polygenetic xenotime ages (ca. 1.82, 1.28 and 0.93 Ga) in metapelite samples from the Mangalwar Complex, Northwestern India. Monazites in the same samples were also analyzed and found to preserve the two younger ages (i.e., ca. 1.28 and 1.0 Ga). The obtained ages from the xenotime and monazite very well corroborate with the earlier published ages from the area validating the proposed analytical protocol.  相似文献   

14.
The distribution of REE minerals in metasedimentary rocks was investigated to gain insight into the stability of allanite, monazite and xenotime in metapelites. Samples were collected in the central Swiss Alps, along a well‐established metamorphic field gradient that record conditions from very low grade metamorphism (250 °C) to the lower amphibolite facies (～600 °C). In the Alpine metapelites investigated, mass balance calculations show that LREE are mainly transferred between monazite and allanite during the course of prograde metamorphism. At very low grade metamorphism, detrital monazite grains (mostly Variscan in age) have two distinct populations in terms of LREE and MREE compositions. Newly formed monazite crystallized during low‐grade metamorphism (<440 °C); these are enriched in La, but depleted in Th and Y, compared with inherited grains. Upon the appearance of chloritoid (～440–450 °C, thermometry based on chlorite–choritoid and carbonaceous material), monazite is consumed, and MREE and LREE are taken up preferentially in two distinct zones of allanite distinguishable by EMPA and X‐ray mapping. Prior to garnet growth, allanite acquires two growth zones of clinozoisite: a first one rich in HREE + Y and a second one containing low REE contents. Following garnet growth, close to the chloritoid–out zone boundary (～556–580 °C, based on phase equilibrium calculations), allanite and its rims are partially to totally replaced by monazite and xenotime, both associated with plagioclase (± biotite ± staurolite ± kyanite ± quartz). In these samples, epidote relics are located in the matrix or as inclusions in garnet, and these preserve their characteristic chemical and textural growth zoning, indicating that they did not experience re‐equilibration following their prograde formation. Hence, the partial breakdown of allanite to monazite offers the attractive possibility to obtain in situ ages, representing two distinct crystallization stages. In addition, the complex REE + Y and Th zoning pattern of allanite and monazite are essential monitors of crystallization conditions at relatively low metamorphic grade.  相似文献   

15.
In situ U-Pb dating of monazite and xenotime in sedimentary rocks from the mid-Archean Soanesville Group in the Pilbara Craton, yields ages for provenance, diagenesis and multiple low-grade metamorphic events. Detrital monazite and xenotime grains give dates >3250 Ma, whereas diagenetic xenotime provides a new minimum age of 3190 ± 10 Ma for deposition of the basal Soanesville Group, previously constrained between ∼3235 Ma and ∼2955 Ma. Metamorphic monazite provides evidence for three episodes of growth: at 2.88, 2.16 and 1.65 Ga. Element mapping of monazite for La, Sm, Y and Th reveals distinct cores and rims in some crystals that were used to guide the placement of analytical spots during in situ U-Pb dating by sensitive high-resolution ion microprobe (SHRIMP). Specifically, La and Sm distributions closely correlate with different generations of monazite. The presence of two generations in single monazite crystals highlights the need for characterizing mineral chemistry prior to geochronology. It also shows the importance of using in situ dating techniques rather than methods that rely on the analysis of entire, potentially multi-aged, crystals. The ages recorded by metamorphic monazite span more than one billion years and are interpreted to record cryptic tectonothermal events within the craton. The 2.88 Ga age coincides with a phase of regional deformation, metamorphism and gold mineralization along a major crustal lineament, whereas the most common monazite age population (at 2.16 Ga) corresponds with the migration of a foreland fold-and-thrust belt across the craton. The youngest age (1.65 Ga) coincides with an episode of tectonic reworking in the Capricorn Orogen along the southern Pilbara margin. The prolonged history of monazite growth may, in part, relate to channelized fluid flow during reactivation of long-lived N- to NE-trending crustal structures that transect the craton. Despite repeated episodes of metamorphism, the isotopic system in each generation of monazite remained unperturbed, yielding precise dates. The ability of monazite to record three separate events, and in some instances two events in a single crystal, distinguishes it from most other low-temperature mineral chronometers, which are readily reset during metamorphic overprinting. Low-temperature monazite geochronology can provide a detailed isotopic history of cryptic thermal events and reveal the temporal and spatial patterns of far-field fluid flow related to tectonic processes. The previously unrecognized history of crustal fluid flow in the Pilbara Craton has implications for chemical, mineralogical and isotopic studies seeking to understand conditions on the early Earth.  相似文献   

16.
After a decade of studies and development, it is now accepted that reliable U–Th–total Pb isochron ages can be calculated for monazite using an electron microprobe at μm scale, either directly on thin sections or on separated grains mounted in polished section. The potential for determining U–Th–Pb chemical ages from other U- and Th-enriched phases has been investigated compared to chemical monazite-dating results for which individual spot-age precisions of 20 to 100 Ma can be achieved from individual spot analyses. Using isochron plots for monazite, the age homogeneity of a given population of data can be assessed and, depending upon the number of analyses (n  50), a precision of 5 to 10 Ma can be obtained. The U content in xenotime widely varies from less than 0.1 wt.% up to 3 wt.%, but Th rarely exceeds 1 wt.%. As a consequence, the amount of radiogenic Pb produced during a given period remains significantly lower for xenotime than for monazite, leading to a lower precision (± 20 Ma) on the mean ages. Xenotime, however, appears to remain as a closed system, but common Pb must be carefully checked. Furthermore, the electron-microprobe technique (EPMA) allows controlling any age discrepancy on xenotime grains as small as 10–20 μm that cannot be dated by other isotopic methods. Such xenotime ages can be useful when studying the monazite–xenotime equilibrium. The electron microprobe is not the most reliable method for dating zircon since U and Th concentrations are generally low and common Pb is not negligible. Nevertheless, the spatial resolution of EPMA coupled with isotope methods allows conclusive in situ studies about radiogenic Pb mobility and metamictization. Thorite does not seem suitable for dating with either isotope methods or EPMA because of continuous radiogenic Pb loss. Conversely, the oxide phases, thorianite and baddeleyite are robust minerals with closed systems. They are rather rare and seem to incorporate negligible common Pb, making EPMA a method of choice for dating them. For thorianite, the precision on the mean age can be similar as that obtained for monazite, or even better, while the precision for baddeleyite cannot be significantly better than 20 to 50 Ma due to the limited amount of U ( 0.1%) and the lack of Th.  相似文献   

17.
Two granitoid intrusions within the Bu Khang extensional complex in central Vietnam have been dated by U–Pb and Rb–Sr geochronology. A monazite U–Pb age of 26.0 ± 0.2 (2σ) Myr was obtained for the Bu Khang pluton and 23.7 + 1.6/–1.7 Myr for monazite, allanite and zircon from the Dai Loc intrusion. These ages date crystallization of magmas previously assigned Precambrian to Devonian. Rb–Sr analyses of K-feldspar and biotite fractions from the samples yield ages of 19.8 ± 0.6 (2σ) Myr and 19.6 ± 0.5 Myr, respectively. The thermal history recorded by the different geochronometers implies an average exhumation rate of ∼2 mm yr−1 corresponding to ∼9 km of unroofing. Magmatism was either (i) induced passively by lithospheric thinning driven by changes in regional tectonic stresses, or (ii) triggered actively by an ascending plume. Tertiary exhumation and magmatism documented elsewhere in Indochina (e.g. Ailao Shan-Red River and Wang Chao shear zones) favours a regional tectonic cause for extension and granitoid magmatism in the Bu Khang complex. On the other hand, the presence of an upwelling thermal anomaly since at least 35 Ma, causing mantle melting below Indochina, is supported by shear-wave velocity variations in the mantle, and source geochemistry of both the Bu Khang plutons and the Red River belt intrusions. In either case, Tertiary exhumation of the Bu Khang complex can account for previously undocumented NE–SW-directed extension, which is required in northern Vietnam to account for structural changes related to the opening of the South China Sea.  相似文献   

18.
The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives 207Pb/206Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined 207Pb/206Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin  相似文献   

19.
The formation conditions and age of the Sukhoi Log gold deposit are considered on the basis of new isotopic-geochemical data. The U-Pb isotopic study of zircon and monazite from high-grade ore and host black slates at the Sukhoi Log deposit was carried out with SIMS technique using a SHRIMP II instrument. Two generations of monazite are distinguished on the basis of optical and scanning electron microscopy, cathodoluminescence, and micro X-ray spectroscopy. Monazite I is characterized by black opaque porphyroblasts with microinclusions of minerals pertaining to metamorphic slates and structural attributes of pre- and synkinematic formation. Monazite II occurs only within the ore zone as transparent crystals practically free of inclusions and as rims around monazite I. The REE contents are widely variable in both generations. Porphyroblastic monazite I differs in low U and Th (0.01–0.7 wt % ThO2) contents, whereas transparent monazite II contains up to 4 wt % ThO2. The average weighted U-Pb isotopic age of monazite I is 650 ± 8.1 Ma (MSWD = 1.6; n = 9) and marks the time of metamorphism or catagenesis. The U-Pb age estimates of synore monazite II cover the interval of 486 ± 18 to 439 ± 17 Ma. Zircons of several populations from 0.5 to 2.6 Ga in age are contained in the ore. Most detrital zircon grains have porous outer rims composed of zircon and less frequent xenotime with numerous inclusions of minerals derived from slates. The peaks of 206Pb/238U ages in the most abundant zircon populations fall on 570 and 630 Ma and correspond to the age of newly formed metamorphic mineral phases. The discordant isotopic ages indicate that the U-ThPb isotopic system of ancient detrital zircons was disturbed 470–440 Ma ago in agreement with isotopic age of monazite II and the Rb-Sr whole -rock isochron age of black slates (447 ± 6 Ma). The new data confirm the superimposed character of the gold-quartz-sulfide mineralization at the deposit. Black shales of the Khomolkho Formation of the Bodaibo Synclinorium were affected by metamorphism over a long period; the peaks of metamorphism and catagenesis are dated at 570 and 650–630 Ma. The high-temperature ore formation was probably related to a hidden granitic pluton emplaced 450–440 Ma ago, that is, 200 Ma later than the events of greenschist metamorphism. Hercynian granitoid magmatism (320–270 Ma) did not exert a substantial effect on the U-Th-Pb isotopic system in accessory minerals from the ore and could not have been a major source of ore-forming fluids.  相似文献   

20.
Altered and mineralised rocks at Peak Hill, are confined to a 300–500 m wide, north-south striking, steeply dipping, shear zone that is flanked by the Mingelo Volcanics along its western side, and Cotton Formation siltstones along its eastern side. This shear zone is defined by extensive zones of cataclasite and strongly foliated micaceous schists in marked contrast to the largely undeformed nature of the adjacent rocks. Advanced argillic assemblages (quartz-kaolinite-pyrite ± alunite ± illite) occur throughout the core of the Peak Hill deposit. Propylitic assemblages, including albite, quartz, interlayered chlorite-smectite, illite and ankerite, and a narrow discontinuous zone of argillic (quartz-illite-pyrite) alteration are developed in the Mingelo Volcanics along the western side of the deposit. Propylitic, argillic and advanced argillic assemblages are overprinted by an internally zoned phase of phyllosilicate alteration that grades inwards from a peripheral sericite-clay-chlorite assemblage, through phyllic assemblages (muscovite/illite-pyrite ± paragonite) to a pyrophyllite-pyrite ± diaspore ± andalusite altered core. Au-Cu mineralisation is hosted by barite-pyrite veins that cut the advanced argillic assemblage, but pre-date the phyllosilicate-dominated alteration. Native Au (lacking Ag), calaverite, Te-rich tennantite-tetrahedrite (goldfieldite), chalcopyrite, covellite and chalcocite occur in the barite-pyrite veins. No ore-bearing minerals were detected in any of the alteration assemblages. The total gold content of the Peak Hill deposit is currently 720 K ounces and this includes 100 K ounces of unmined reserves. Within the shear zone phyllosilicate minerals are developed in strain shadows and partly define the stretching lineation associated with dip-slip movement. The zonation within the phyllosilicate assemblages mimics the geometry of bends in the shear zone and minor internal structures. These textures indicate that the phyllosilicate alteration developed synchronous with movement on the shear zone. Earlier advanced argillic alteration and mineralisation are developed in rocks derived from both sides of the shear zone. Hydrothermal activity associated with the earlier advanced argillic alteration was therefore either synchronous with juxtaposition of these distinct rock units, or occurred during a later phase of movement on the shear zone. Cross-cutting fibrous textures in the auriferous barite-pyrite veins indicate that repeated fracturing of the advanced argillic altered rocks accompanied development of successive generations of auriferous veins. Concentrations of auriferous veins are localised in steeply plunging shoots that are oriented parallel to the stretching lineation in the shear zone. These features all indicate movement on the host shear zone accompanied each phase of hydrothermal activity in the Peak Hill deposit. The location, alteration zonation and distribution of mineralised veins within the deposit are intimately controlled by deformation on the host shear zone synchronous with hydrothermal activity. The development of high-sulphidation hydrothermal systems synchronous with deformation along brittle-ductile shear zones is a predictable consequence of intrusive activity during deformation in areas characterised by a high geothermal gradient. The close relationship between tectonism and hydrothermal activity indicates that these deposits are likely to be located in the vicinity of regional-scale shear zones. Deposits are likely to be aligned parallel to the regional-scale structural “grain” and restricted to areas of conspicuous deformation as is the case at Peak Hill (and Temora, NSW). Aluminous alteration zones concentrated in the vicinity of regional-scale structures in the Carolina Slate Belt may be a further example of this style of hydrothermal activity. Received: 30 September 1996 / Accepted: 28 August 1997  相似文献   

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