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1.
碳酸盐倒退溶解模式的化学热力学基础——与H_2S有关的溶解介质及其与CO_2的对比 总被引：1，自引：1，他引：0
以化学热力学中的吉布斯自由能增量为基础,计算了与H2S(g)/ H2S(aq) /HS-/ H+/S2-系统有关反应在不同温度下的平衡常数,同时根据方解石和白云石在酸性条件下的溶解过程,获得了这两种碳酸盐矿物溶解过程中地层中流体pH值与PCO2、地层压力和埋藏深度的关系。在此基础上,对比了从地表到深埋藏的温度和压力条件下,与CO2和H2S有关的酸性介质对流体\[H+\]贡献的差异性,以及对于碳酸盐溶解作用的差异性。计算结果表明:1）无论以CO2还是以H2S作为溶解介质,温度增加和（或）PCO2增加,都会造成方解石和白云石溶解所需要的\[H+\]增加,在深埋藏相对高温和高压条件下,高PCO2条件会使得碳酸盐矿物的溶解更加困难,如果\[H+\]受到缓冲,CO2的增加不仅不能造成碳酸盐矿物的溶解,反而会造成碳酸盐矿物的沉淀;2）无论在何种酸性介质中,碳酸盐矿物的倒退溶解模式在化学上都是成立的,低温的成岩环境,深部地层中高温流体的向上运移、构造抬升所造成的温度降低（-ΔT）都会提高H2S和（或）CO2流体（也包括其它酸性介质）对碳酸盐矿物溶解能力;3）在地表和近地表条件下（几百米深度范围内）,在同时存在CO2和H2S的环境中,CO2对应酸的电离提供的\[H+\]略多于H2S对应酸的电离,与CO2有关的酸性流体对碳酸盐矿物溶解相对重要,而在深埋藏条件下、尤其是深度大于4 000 m的深埋藏地层中,H2S对应酸的电离提供的\[H+\]显著大于CO2,其对碳酸盐矿物的溶解更为重要,在存在硫酸盐还原作用的深埋藏地层中,碳酸盐的深部溶解作用会更为发育,这可能是川东北地区深埋藏条件下次生孔隙发育的重要原因之一。 相似文献
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CO2—咸水—方解石相互作用实验 总被引：1，自引：0，他引：1
为揭示咸水环境中CO2与方解石相互作用的特点,选取方解石作为研究对象,设计在不同温压条件下(85℃,5.0MPa;135℃,5.7MPa;185℃,8.8MPa)进行了3组CO2-咸水-方解石的系列实验研究,重点探讨了方解石溶解现象的成因和温度对于方解石溶解程度的影响。实验前后岩样扫描电镜观察、反应液离子变化分析表明,实验后,3组实验中的方解石均表现出溶蚀坑、溶蚀带和溶蚀晶锥的溶解现象;方解石的溶解度在85℃时最低,185℃次之,135℃最高。研究结果表明,在含CO2的咸水中,方解石的溶解现象有溶蚀坑、溶蚀带和溶蚀晶锥,各自的分布规律及规模与温度有关。在含CO2的咸水中,方解石也具有各向异性的溶解特点。使方解石产生最大溶解度的温度峰值可能出现在135～185℃之间。超过这一温度,温度的升高会使方解石的溶解度下降。实验再现了方解石在咸水环境中的溶解、沉淀过程,对于CO2地质封存示范工程具有非常重要的意义。 相似文献
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《矿物岩石地球化学通报》2015,(4)
砂岩储层中溶蚀次生孔隙的形成与碎屑岩骨架颗粒在地质流体中的矿物的溶解度密切相关。本文从温度、压力、p H值、有机酸等方面描述了石英、长石、碳酸盐矿物的溶解度特征,指出矿物溶解度和溶解组分的平衡分布主要依赖于地层温度和孔隙流体的p H值,而地层温度和p H值则通过改变地层水中络合物的形式与含量、CO2-3、HCO-3与CO2的相对含量控制着矿物溶解度。受控于温度、压力、p H值的储层流体作用于矿物,可导致不同矿物溶蚀次生孔隙形成机理具有明显的差异。在未来的研究中,应注重根据实际储层的温度、压力、流体等地质环境条件,结合储层岩石中的矿物组成进行实验模拟和数值模拟,以建立矿物溶解度与次生孔隙特征之间的定量关系。 相似文献
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塔中地区志留系柯坪塔格组顶部不整合面附近沥青砂岩中发育大量因石英及次生加大边的溶蚀贡献的次生孔隙,根据薄片(铸体)观察、SEM观察显示石英溶蚀主要有3种赋存状态,其中对储层有建设性作用的溶蚀主要有石英硅质颗粒边缘的溶蚀及次生加大边的溶蚀两种,而对储层建设性作用不大的溶蚀为碳酸盐对石英及硅质的交代作用,这些SiO2的溶蚀路径可分为碱性环境和酸性环境下的SiO2溶解,统计表明碱性环境下的SiO2溶蚀普遍发育,但程度较低,而在酸性环境中溶解时对有机酸的种类、数量、流体性质、溶解环境中的流体能力以及地层温度的要求更为苛刻。本次研究中的酸性流体介质条件下的石英溶解即为古油藏破坏过程中受微生物降解烃类释放出大量的草酸起主要作用,因其降低了石英颗粒表面溶解反应的活化能,并在地层水中碱金属离子的"盐效应"作用下,大大提高了SiO2的溶解速率,溶解产物扩散到地层水中被带走,从而造成强烈的石英溶蚀现象,研究同时表明溶蚀程度强烈但具有很强的局限性。SiO2的溶蚀(解)作用能够提供一定量的油气富集空间,改善储层的物性,对在埋藏较深、时代较老的志留系海相致密碎屑岩储层中发育孔隙度较高的优质储层具有重要意义。 相似文献
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四川盆地东北部三叠系飞仙关组硫酸盐还原作用对碳酸盐成岩作用的影响 总被引：15，自引：0，他引：15
四川盆地东北部三叠系飞仙关组存在广泛的硫酸盐还原作用,同时地层中也存在锶含量异常高的成岩流体。研究表明:热化学硫酸盐还原作用（TSR）和（或）细菌硫酸盐还原作用（BSR）造成的SO42-离子的消耗对成岩孔隙流体中SrSO4溶解度的改变是三叠系中高Sr成岩流体的形成机制之一,该机制使得孔隙流体从白云石化作用和碳酸盐矿物的新生变形作用中获得的Sr在流体中以高浓度的Sr2+形式存在,并使之在流体中极度富集,这也是四川盆地东北部三叠系中大型和超大型天青石矿床的形成机制之一。H2S和CO2是硫酸盐还原作用的重要产物,不同温度条件下溶于水中的H2S和CO2,与不溶于水的气体分子之间的平衡反应H2S（aq）H2S(g)和CO2(aq)CO2(g)的平衡常数和吉布斯自由能增量计算表明,当温度从25℃升高至220℃时,两个反应的平衡常数分别大致从10增至240和从20增至500,两个反应的平衡常数都始终大于1,说明H2S和CO2更趋向于以气体形式存在,同时温度越高,系统中以气体形式存在的H2S和CO2会越多,溶解于水中的H2S和CO2会越少,因而在深埋藏的高温条件下,H2S和CO2对碳酸盐矿物的溶解能力可能相对很小。相对低温的成岩环境、高温流体的向上和侧向运移、构造抬升、富氧流体与含有H2S流体的混合以及金属硫化物的沉淀是提高含H2S和（或）CO2流体对碳酸盐矿物溶解能力的五个途径。因此,与较早成岩阶段相对浅埋藏环境的碳酸盐溶解作用有关的H2S和CO2流体可能与细菌硫酸盐还原作用（BSR）关系更为密切;断层或其它流体运移通道是高温含有H2S和CO2流体向上运移的基础条件,具有原生孔隙度和渗透率的礁、滩相高能沉积物也是流体发生侧向运移的先决条件;大幅度的构造抬升造成的地层温度降低是提高含H2S和（或）CO2地层流体对碳酸盐矿物溶解能力的重要因素,地壳抬升至近地表造成的古喀斯特作用也可以为H2S的氧化提供良好的地质环境。在有关的勘探中应注意:在断层等流体运移通道造成高温含H2S和CO2流体向上运移的条件下,与之有关的构造低点应该是主要的勘探目标;在燕山运动导致的地层抬升并导致深部热流体降温的条件下,与之有关的构造高点应该是主要的勘探目标,应分别对待。 相似文献
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鄂尔多斯盆地奥陶系不同组构碳酸盐岩埋藏溶蚀实验 总被引：1，自引：0，他引：1
鄂尔多斯盆地奥陶系碳酸盐岩储层受埋藏溶蚀作用控制明显,而地层深部复杂的水-岩反应造成埋藏溶蚀研究难度较大,并进而影响了储层的评价与预测。分别利用CO2溶液和乙酸溶液为流体介质进行溶蚀模拟实验,探讨埋藏条件下温度、压力、流体等因素对不同矿物及组构碳酸盐岩溶蚀作用的影响。结果表明:1）随着温度与压力升高,碳酸盐岩样品在乙酸溶液中的溶解速率均相应提高,在CO2溶液中的溶解速率则先增加后减小,且在110℃~130℃区间内溶蚀速率最大;深埋藏环境下,各岩类溶蚀速率差异减小,并趋于一致;2）岩石矿物成分和组构,原岩初始孔隙度的大小及其连通关系,以及晶体的产状对成岩后期的埋藏溶蚀作用也具有重要的影响。不溶组分含量低、颗粒/灰泥比高、矿物成分复杂的碳酸盐岩由于组构选择性溶蚀作用而更易被溶蚀;碳酸盐岩的溶蚀速率随方解石含量的增加而增加,但深埋藏环境下,矿物成分含量差异对溶蚀速率的影响作用减弱;硬石膏与白云岩相伴生时,可优先溶蚀形成膏模孔,并促进白云石的溶解,改善储层效果。不同岩性,总体上灰岩较白云岩及过渡岩类更易发生埋藏溶蚀作用。结合研究区实际地质条件分析,砂屑灰岩、膏质白云岩等埋藏溶蚀强度较大,通过对原岩早期组构选择性溶蚀形成孔隙的继承和调整,叠加埋藏期岩溶作用后,可形成规模优质储层。 相似文献
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湖泊沉积物不同粒级组分的元素含量特征及其环境指示意义①——以内蒙古黄旗海为例 总被引：1，自引：0，他引：1
黄旗海湖泊柱状沉积物的全样、77~20 μm、<20 μm粒级的钛(Ti)、锰(Mn)、锶(Sr)、銣(Rb)、钡(Ba)、锆(Zr)等元素含量分析表明,元素在湖泊沉积物各粒级组分的丰度存在较大差异:Ti、Zr倾向于在粗颗粒中富集,Mn、Sr、Rb倾向于在细颗粒中富集,Ba的富集粒级不明显。Ti、Zr与Mn、Rb的颗粒粒级富集倾向可能是其硅酸盐矿物颗粒碎化过程的结果,而Sr则与湖泊自生碳酸盐有关。元素比值Zrc/（Rbc+Bac）、Zrc/Rbc与Ti、Zr的粒度效应Tic/Tif、Zrc/Zrf指示了沉积物重、轻矿物的相对比率,是流域侵蚀强度与湖泊涨缩的信息指示;Ba、Rb与Sr在细粒级的含量之比Baf/Srf、Rbf/Srf指示了硅酸盐与碳酸盐矿物的相对含量,是流域风化、侵蚀搬运强度与湖泊过程（包括物理/化学/生物）等混合信息指示,没有明确的环境指向性。 相似文献
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彭州地区是＂5.12＂地震灾区,其震后的水文地球化学特征还未有相关研究,本文利用以热力学为基础的水文地球化学平衡理论与方法对彭州通济地区震后浅层地下水化学特征及其形成进行了分析,为研究地震对浅层地下水的影响提供基础信息。分析表明：研究区水化学场受到地形地貌的控制,水化学类型以HCO3--Ca型为主;HCO3-、Ca2＋普遍含量较高,CO2分压控制碳酸盐的溶解度及水中的pH值;其浅层地下水相对于石英处于过饱和状态,相对于非晶质SiO2处于未饱和状态,CO2气体参与硅酸盐矿物水解,产生可溶SiO2;矿物溶解及与水中化学组分平衡的非硅铝酸盐矿物主要为方解石,硅铝酸盐矿物主要为长石,其次是高岭石、蒙脱石。水化学平衡理论与方法可以较好的用于研究地下水所处的水文地球化学环境以及判断SiO2的来源和矿物溶解过程。 相似文献
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为了更深入地了解微生物与大气可吸入矿物细颗粒的作用机理,实验以方解石(PM2.5)为研究对象,采用反相高效液相色谱(RP-HPLC)对硅酸盐细菌、金黄色葡萄球菌和大肠杆菌胞外有机酸主要组分进行定性定量分析,考察了细菌胞外有机酸对方解石的溶蚀效应。实验结果表明,3种常见细菌的胞外有机酸主要组分有草酸、乳酸、柠檬酸和琥珀酸;不同有机酸对方解石的溶蚀效应不同,但均能不同程度地促进Ca离子的释放;草酸、乳酸和琥珀酸对方解石发生作用后,表现为颗粒失重,而柠檬酸对方解石发生作用后,导致其发生重结晶行为,能改变方解石的表面形貌,使残余固体呈纤维状;在草酸和柠檬酸作用下,残余固体表现出了对有机酸基团(如C=O、C—C或C—H)的吸附,特别是柠檬酸在1 600~500 cm-1区域。 相似文献
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Fayalite, hypersthene, basalt, and obsidian were dissolved in buffered solutions (25°C; pH 4.5 and 5.5) under air, N2 or O2 atmospheres, in order to follow the kinetics of dissolution. Each dissolved more rapidly at lower pH values, dissolving most rapidly in the initial few days, followed by slower dissolution for periods up to six months. Dissolution was more rapid when air was excluded. In oxygen atmospheres an Fe(OH)3 precipitate armors mineral surfaces, thus inhibiting further dissolution, and further affects the solution by scavenging dissolved silica and cations. Dissolution reactions include initial exchange between cations and H+, incongruent dissolution of silicate structures, oxidation of Fe2+ in solution, precipitation of Fe(OH)3, and scavenging of dissolved silica and cations by Fe(OH)3. Dissolution kinetics may explain weathering of mafic rocks and minerals at the Earth's surface, the formation of Fe-oxide coatings on mineral grains, weathering of submarine mafic rocks and intrastratal solution of mafic minerals in buried sandstones. Early Precambrian weathering would have been more rapid before the appearance of large amounts of oxygen in the atmosphere, and continental denudation rates may have been higher than at present because of this effect and the predominance of mafic igneous rocks at an early stage of continent formation and growth. 相似文献
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蚯蚓肠道内小分子有机酸与摄入的土壤矿物相互作用,加速矿物溶解。摄入的土壤在蚯蚓肠道内平均停留时间约为12 h,不足以使土壤矿物产生显著的溶解特征,因此这一过程难以在蚯蚓体内进行评估。本研究通过体外实验控制pH值和有机酸浓度,模拟蚯蚓肠道中有机酸对土壤中常见矿物的溶解反应,探讨了方解石和钾长石在蚯蚓肠道环境中的初始溶解动力学。研究发现,矿物在混合有机酸中的溶解速率比在纯水中高一个数量级,说明有机配体和质子促进了矿物溶解。溶解速率及粒度分析表明,方解石(CaCO3)溶解速率不受溶解过程中粒度变化的影响,而钾长石(KAlSi3O8)粒度在溶解期间未出现显著变化。在此基础上,采用初始速率法模拟了钾长石的初始溶解动力学,计算得出的溶解速率表明钾长石在溶解初期主要为表面K~+的释放。使用缩核模型(shrink core model)和Hixson-Crowell模型对方解石溶解过程进行动力学解析,发现方解石的溶解主要受溶液中反应物内扩散的速率影响。这定量描述了两种矿物在有机酸溶液和纯水中的溶解差异。现有研究表明,有机配体和质子协同促... 相似文献
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基于热模拟实验的富有机质泥页岩成岩作用及演化特征 总被引：1，自引：0，他引：1
富有机质泥页岩蕴含丰富的油气资源,但成岩研究基础薄弱,已成为制约页岩油气勘探开发进程的重要因素。通过开展成岩热模拟实验,结合扫描电镜观察、流体成分测试及有机酸测试等实验测试手段,全面描述实验过程中所发生的水-岩化学反应,试图揭示泥页岩成岩过程及成岩演化规律。研究结果显示,有机质热演化过程中存在一个较宽的有机酸生成窗口,对孔隙流体性质具有重要影响;长石和方解石存在接力溶蚀现象,长石溶蚀高峰过后紧接着出现方解石溶蚀高峰,但方解石溶蚀窗较窄,此后出现方解石重新沉淀结晶;黏土矿物转化及长石的溶蚀过程中会产生大量自生微晶石英,成链状或簇状胶结泥页岩骨架。泥页岩地层作为一个相对封闭体系,各类成岩作用之间相互关联,相互影响,构成错综复杂的成岩体系,进一步增加其成岩作用研究难度。 相似文献
14.
《矿物学报》2013,(Z1)
In this paper, the dissolution characteristics of Xining dustfall in citric acid solution was studied to evaluate the physical chemical change in acid conditions. pH along with conductivity was tested with time. FTIR, SEM and ICP analysis were applied to analyze the residuum and filtrate after 2 days’ dissolution experiment. It was shown in the pH/conductivity variation, solution’s pH rise sharply in the front 4 hours, then decrease slowly. After 4 hours, both the pH and conductivity become stable. Based on combined analysis of XRD and FTIR spectrum of dustfall before and after dissolution, that calcite and dolomite in dustfall are dissolved completely in the 0.05M citric acid solution in two days. Besides, amount of metal cations were extracted from the dustfall during the dissolution, including Ca2+,K+,Mg2+,Fe3+,Al3+,Si. In general, after the dissolution of dustall in citric acid, some minerals are dissolved and amount of metal elements are extracted. Carbonate minerals almost dissolved completely, also the structure of silicate minerals changed as the extraction of elements. 相似文献
15.
Geochemistry of soil, soil water, and soil gas was characterized in representative soil profiles of three Michigan watersheds. Because of differences in source regions, parent materials in the Upper Peninsula of Michigan (the Tahquamenon watershed) contain only silicates, while those in the Lower Peninsula (the Cheboygan and the Huron watersheds) have significant mixtures of silicate and carbonate minerals. These differences in soil mineralogy and climate conditions permit us to examine controls on carbonate and silicate mineral weathering rates and to better define the importance of silicate versus carbonate dissolution in the early stage of soil-water cation acquisition.Soil waters of the Tahquamenon watershed are the most dilute; solutes reflect amphibole and plagioclase dissolution along with significant contributions from atmospheric precipitation sources. Soil waters in the Cheboygan and the Huron watersheds begin their evolution as relatively dilute solutions dominated by silicate weathering in shallow carbonate-free soil horizons. Here, silicate dissolution is rapid and reaction rates dominantly are controlled by mineral abundances. In the deeper soil horizons, silicate dissolution slows down and soil-water chemistry is dominated by calcite and dolomite weathering, where solutions reach equilibrium with carbonate minerals within the soil profile. Thus, carbonate weathering intensities are dominantly controlled by annual precipitation, temperature and soil pCO2. Results of a conceptual model support these field observations, implying that dolomite and calcite are dissolving at a similar rate, and further dissolution of more soluble dolomite after calcite equilibrium produces higher dissolved inorganic carbon concentrations and a Mg2+/Ca2+ ratio of 0.4.Mass balance calculations show that overall, silicate minerals and atmospheric inputs generally contribute <10% of Ca2+ and Mg2+ in natural waters. Dolomite dissolution appears to be a major process, rivaling calcite dissolution as a control on divalent cation and inorganic carbon contents of soil waters. Furthermore, the fraction of Mg2+ derived from silicate mineral weathering is much smaller than most of the values previously estimated from riverine chemistry. 相似文献
16.
Abstract. Sandstones with high reservoir quality occur in the Paleogene and Upper Cretaceous coal measures off Sanriku and Sohma in the Pacific coast of northeast Honshu. The sandstone porosity was generally produced by the dissolution of calcite cement and clastic grains such as feldspar and glassy volcanics. The most probable cause of dissolution is the organic acids generated from the maturation of coal and coaly matter in the deeply subsiding source area prior to thermogenic hydrocarbon generation. The pore fluid including organic acids dissolved calcite and clastic silicates to form a small amount of laumontite and kaolinite at around 60C. The acidic and not neutralized pore fluid was responsible for the formation of kaoli-nite. On the other hand, laumontite was formed when the acidic pore fluid was neutralized and then made alkaline after the reaction with minerals such as plagioclase, glassy volcanics and calcite cement. Therefore, laumontite and kaolinite generally occur separately. Laumontite is 0.6–4.6 % by volume, whereas kaolinite is 0.6–9.8 % and the sandstone porosity remains from 10 to 22 %. This type of laumontization after the secondary pore formation might not give a severe damage to the reservoir property of the Paleogene and Upper Cretaceous coal measures in the Pacific coast of northeast Honshu and indicates further exploration possibility. 相似文献
17.
碳酸盐矿物是火山岩储层内重要的矿物成分,长岭断陷火山岩储层内的自生碳酸盐矿物主要是方解石.本文通过对营城组储层内方解石矿物的碳氧同位素特征分析,探讨储层内碳酸盐矿物成因.研究表明,长岭断陷火山岩储层内方解石δ13 CV-PDB值范围为-12.7‰～0.4‰,δ18OV-SMOw值范围为3.8‰～12‰,具有高δ18O值.与方解石平衡的CO2碳同位素计算值范围较宽,为-16.0‰～2.2‰,表明其形成物质的多源性.在δ18 O-δ13C图解中显示,形成碳酸盐矿物的CO2来源于幔源-岩浆无机成因的CO2和有机质演化过程中产生的CO2,以无机成因CO2源为主.这些无机成因CO2、有机成因CO2和沉积有机质热演化产生的有机酸溶于流体,形成酸性流体.火山岩储层中碳酸盐矿物的形成实质就是这种酸性流体与储层围岩反应的结果. 相似文献
18.
In general, aragonite exists as a metastable carbonate mineral under near-surface conditions, and is commonly transformed into calcite under the subsurface and during diagenesis. It is thus seldom found in sedimentary rocks, but aragonite is common in the Paleogene lacustrine shales in the Jiyang Depression in eastern China. Dissolution experiments were conducted on the Paleogene aragonite-enriched and calcite-enriched shales at different temperatures, pressures and acetic acid concentrations, and in different types of solution. The results show that aragonite is insoluble in the in situ formation water but dissolved more readily under acetic acid conditions than calcite with the degree of dissolution increasing with increasing temperature, pressure and acetic acid concentrations. During the shallow burial diagenesis of the Paleogene sediment sequence in the Jiyang Depression, aragonite was relatively stable and was not dissolved by the connate pore water in the shales. Increasing burial (temperature) and maturity of the organic matter produced large amounts of organic acids that accelerated the dissolution of aragonite. In the late stage, as the organic matter became over-matured, the pore water changed from acidic to alkaline, and calcite precipitated from the carbonate-rich solution. Therefore, the conditions provided by organic acids enabled the conversion of aragonite to calcite during sedimentary diagenesis in the Paleogene lacustrine shales in the Jiyang Depression. This transformation corresponded to the thermal evolution of the organic matter within the shale sequence. 相似文献
19.
砂岩中重矿物在埋藏成岩环境中会发生溶蚀甚至形成新的重矿物胶结物。利用重矿物特征进行物源分析是鄂尔多斯盆地上三叠统延长组物源分析的最重要方法之一,但石榴子石、榍石和绿帘石这3种重矿物在成岩作用期间发生了明显的后生变化。研究表明,延长卡中石榴子石发生溶蚀形成粒内溶孔和刻面石榴子石,部分被方解石、绿泥石或硅质交代;见自生榍石晶体及榍石次生加大,且榍石的生长具有多期次性;见自生绿帘石晶体及绿帘石次生加大,部分绿帘石被绿泥石或硅质交代;相对稳定性强的石榴子石部分被溶蚀,而相对稳定性弱的碎屑状榍石、绿帘石并未见到溶蚀现象,这与以往研究中对于重矿物稳定性的认识是不一致的,希望能引起未来研究者的重视。 相似文献
20.
Yuyu Wan Shanghai Du Guangyu Lin Fengjun Zhang Tianfu Xu 《Environmental Earth Sciences》2017,76(1):43
This study focused on typical injection layers of deep saline aquifers in the Shiqianfeng Formation used in the Carbon Capture and Sequestration Demonstration Projects in the Ordos Basin, Northwest China. The study employed experiments and numerical simulations to investigate the mechanism of CO2 mineral sequestration in these deep saline aquifers. The experimental results showed that the dissolved minerals are plagioclase, hematite, illite–smectite mixed layer clay and illite, whereas the precipitated minerals are quartz (at 55, and 70 °C) and kaolinite (at 70 °C). There are rare carbonate mineral precipitations at the experimental time scale, while the precipitation of quartz as a product of the dissolution of silicate minerals and some intermediate minerals rich in K and Mg that transform to clay minerals, reveals the possibility of carbonate precipitation at the longer time scale. These results are consistent with some results previously reported in the literature. We calibrated the kinetic parameters of mineral dissolution and precipitation by these experimental results and then simulated the CO2 mineral sequestration under deep saline aquifer conditions. The simulation results showed that the dissolved minerals are albite, anorthite and minor hematite, whereas the precipitated minerals are calcite, kaolinite and smectite at 55 and 70 °C. The geochemical reaction of illite is more complex. At 55 °C, illite is dissolved at the relatively lag time and transformed to dawsonite; at 70 °C, illite is precipitated in the early reaction period and then transformed to kaolinite. Based on this research, sequestrated CO2 minerals, which are mainly related to the temperature of deep saline aquifers in Shiqianfeng Fm., are calcite and dawsonite at lower temperature, and calcite at higher temperature. The simulation results also establish that calcite could precipitate over a time scale of thousands of years, and the higher the temperature the sooner such a process would occur due to increased reaction rates. These characteristics are conducive, not only to the earlier occurrence of mineral sequestration, but also increase the sequestration capacity of the same mineral components. For a sequestration period of 10,000 years, we determined that the mineral sequestration capacity is 0.786 kg/m3 at 55 °C, and 2.180 kg/m3 at 70 °C. Furthermore, the occurrence of mineral sequestration indirectly increases the solubility of CO2 in the early reaction period, but this decreases with the increase in temperature. 相似文献