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1.
Abstract

The King Island Scheelite Mine lies in the contact aureole of a granodiorite stock. Its open cut and numerous drill cores expose a contact metamorphosed and metasomatized series of finely interbedded argillaceous and calcareous sediments, with interleaved flows of picrite-basalt and basic pyroclastics, the scheelite ore being limited to two limestone horizons. The range and gradation in composition of the original rocks has resulted in an unusual variety of meta-morphic rocks, including forsterite-phlogopite-spinel-tremolite hornfels, anthophyllite-cordierite hornfels, biotite hornfels, actinolite hornfels, a variety of calc-flinta, and marbles. The original sedimentation gave rise to a rapid alternation of limestone and shale, many times repeated, and during metamorphism these rocks reacted with each other to produce narrow bands of calc-flinta.

Subsequent pyrometasomatism selectively converted the greater part of the marble beds to scheelite-bearing andradite skarn, leaving the various hornfels and calc-flinta very little affected. The replacement of the marble was a volume for volume process, and the conversion of 1,000,000 tons of marble to average grade ore involved the introduction of about 350,000 tons of SiO2, 250,000 tons of Fe2O3, 55,000 tons AI2O3, 30,000 tons of H2O and 82,500 tons of CaO.

The temperature of the contact metamorphism attained over 500° C, and the rocks cooled to about 400° C. before the pyrometasomatism occurred. The rocks giving rise to the various hornfels underwent varying degrees of contraction during metamorphism, whereas the limestones probably expanded during metamorphism, and became more permeable to solutions.  相似文献   

2.
《International Geology Review》2012,54(11):1020-1039
The Shizhuyuan deposit is the largest among the economically important polymetallic tungsten deposits in China. The deposit occurs within the thermal aureole of Yanshanian felsic intrusions that were emplaced into Devonian carbonates and marls. The mineralization can be divided into three phases that are genetically associated with three episodes of granitic emplacement-pseudoporphyritic biotite granite, equigranular biotite granite, and granite porphyry. During the emplacement of pseudoporphyritic biotite granite, thermal metamorphism and subsequent skarnization developed around the stock. The pure limestone was transformed to marble, whereas marls and argillite interlayers were changed to a series of metamorphic rocks such as grossular-diopside hornfels, wollastonite hornfels, diopside hornfels, wollastonite-vesuvianite hornfels, muscovite-K-feldspar-anorthite hornfels, and prehnitevermiculite hornfels. Because of the subsequent strong skarn development, most hornfelses later were transformed into skarns. The skarns distributed around the granite stock are mainly calcic. They are massive in structure, and are composed mainly of garnet, pyroxene, vesuvianite, and wollastonite, with interstitial fluorite, scheelite, and bismuthinite. Although there is no cassiterite in the early skarns, their tin contents average 0.1%. The distribution and compositional and mineralogical relationships of skarn minerals suggest that they formed as a result of progressive reactions of a hydrothermal solution with a limestone of generally constant composition, and that the dominant process was progressive removal of Ca and addition of other constituents to the rocks.

Following the primary skarn formation, some of the assemblages were retrograded to new assemblages such as fluorite-magnetite-salite rock, magnetite-fluorite-amphibole rock, and magnetite-fluorite-chlorite rock. The retrograde alteration of the skarns is characterized by a progressive addition of fluorine, alkali components, silica, tin, tungsten, and bismuth. A zonation from garnet-pyroxene skarn or garnet skarn, through fluorite-magnetite-salite rock, to magnetite-fluorite-chlorite rock frequently can be recognized in the deposit. All retrograde-altered rocks contain scheelite, cassiterite, molybdenite, and bismuthinite.

During the emplacement of equigranular biotite granite, skarn veins several tens of centimeters wide were developed; they contain large crystals of garnet and vesuvianite, and interstitial scheelite, wolframite, cassiterite, and molybdenite. This second stage of mineralization occurs predominantly as coarse and fine stockwork greisens, which were superimposed on the massive skarns and surrounding marble. Such W-Sn-Mo-Bi-bearing greisens can be divided into topaz greisen, protolithionite greisen, muscovite greisen, and margarite greisen. Besides calcic skarn veins and greisens, manganese skarn veinlets also were developed; they consist of rhodonite, spessartine-almandine solid solution, spessartine, and helvite. The distribution of greisens is responsible for a metal zonation—i.e., W-Sn-Mo-Bi and Sn-Be-Cu-F zones from the contact boundary between the granite stock and skarns outward in the deposit. A third stage of mineralization is represented by lead-zinc veins, which also are accompanied by manganese skarns consisting of spessartine, rhodonite, manganese-rich pyroxene, helvite, tephroite, fluorite, tourmaline, and manganese-rich phlogopite.  相似文献   

3.
The skarn‐type tungsten deposit of the Date‐Nagai mine is genetically related to the granodiorite batholith of the Iidateyama body. Skarn is developed along the contact between pelitic hornfels and marble that remains as a small roof pendant body directly above the granodiorite batholith. Zonal arrangement of minerals is observed in skarn. The zonation consists of wollastonite, garnet, garnet‐epidote, and vesuvianite‐garnet zones, from marble to hornfels. Sheelite is included in garnet, garnet‐epidote, and vesuvianite‐garnet zones. The oxygen isotope values of skarn minerals were obtained as δ18O = 4.2–7.7‰ for garnet, 5.9–6.9‰ for vesuvianite, ?0.3–3.4‰ for scheelite, 6.0–10.9‰ for quartz, and 8.2‰ for muscovite. The temperature of skarn‐formation was calculated from oxygen isotopic values of scheelite‐quartz pairs to be 288°C. Calculated oxygen isotope values of fluid responsible for skarn minerals were 6.1–9.5‰ for garnet, 1.2–4.8‰ for scheelite, ?1.3‐3.6‰ for quartz, and 4.5‰ for muscovite. Garnet precipitated from the fluids of different δ18O values from scheelite, quartz, and muscovite. These δ18O values suggest that the origin of fluid responsible for garnet was magmatic water, while evidence for the presence of a meteoric component in the fluids responsible for middle to later stages minerals was confirmed.  相似文献   

4.
Analysis of magmatic and sedimentary rocks of several large igneous provinces has demonstrated that the release of gas during plutonic-metamorphic processes may be linked to global climate change and mass extinctions. Aguablanca, one of the largest Cu–Ni–PGE deposits in Europe, formed during the Variscan orogeny when a mafic magma intruded limestones and shales, creating a contact aureole composed of marble, skarn and hornfels. Our petrological and geochemical investigation of the aureole provides evidence that a combination of the two processes led to the formation of the ore deposit: The assimilation of terrigenous sediments supplied S to the magma while the assimilation of carbonates changed the oxygen fugacity and decreased the solubility of sulfur in the magma. The metamorphic assemblages in the contact aureole are directly related to heterogeneity of the protolith and particularly to the original proportions of calcite and clay. We modeled carbon dioxide degassing during contact metamorphism and showed that pure limestone is relatively unproductive because of its high reaction temperature. The presence of clay, however, leads to the formation of calc-silicates and significantly enhances CO2 degassing. Our estimations suggest that degassing of the Aguablanca contact aureole released about 74.8 Mt of CO2, a relatively low volume that we attribute to the composition of the host rock, mainly a pure limestone. A far larger volume of carbon dioxide was emitted by the contact metamorphism of dolostones in the contact aureole of Panzhihua (part of Emeishan large igneous province, SW China). We propose that the level of emission of carbon dioxide depends strongly on the nature of the protolith and has to be considered when predicting environmental impact during the emplacement of large igneous provinces.  相似文献   

5.
Devonian evaporites and associated sedimentary rocks in the Norilsk region were contact metamorphosed during emplacement of mafic sills that form part of the end-Permian (~252 Ma) Siberian Traps. We present mineralogical, geochemical and Sr–Nd isotopic data on sedimentary rocks unaffected by metamorphism, and meta-sedimentary rocks from selected contact aureoles at Norilsk, to examine the mechanisms responsible for magma-evaporite interaction and its relation to the end-Permian environmental crisis. The sedimentary rocks include massive anhydrite, rock salt, dolostone, calcareous siltstones and shale, and the meta-sedimentary rocks comprise calcareous hornfels, siliceous hornfels and minor meta-anhydrite and meta-sandstone. Contact metamorphism took place at low pressure and at maximum temperatures corresponding to the phlogopite-diopside stability field. Calcareous hornfels have high CaO, MgO, CΟ2, SΟ3, low SiO2 and initial Sr isotopic ratios of 0.7079–0.7092, features indicative of calcareous siltstone protoliths. Siliceous hornfels, in contrast, have high SiO2, Al2O3, Na2O, low in other major element oxides and initial Sr isotopic ratios of 0.7083–0.7152, consistent with pelitic or shaley protoliths. Loss of CO2 in a subset of calcareous hornfels can be explained by decarbonation reactions during metamorphism, but release of SO2 from evaporites cannot be accounted for by a similar mechanism. Occurrences of wollastonite and a variety of hydrous minerals in the calcareous hornfels are consistent with equilibration with hydrous fluid, which was capable of leaching large quantities of anhydrite in the presence of dissolved NaCl. In this way, substantial sediment-derived sulfur could have been mobilized, incorporated into the magmatic system and released to the atmosphere. The release of CO2 and SO2 from Siberian evaporites added to the variety of toxic gases generated during metamorphism of organic matter, coal and rock salt, contributing to the end-Permian environmental crisis.  相似文献   

6.
湖南柿竹园矽卡岩-云英岩型W-Sn-Mo-Bi矿床地质和成矿作用   总被引：7，自引：2，他引：7  
柿竹园钨多金属矿床由三个阶段不同成矿作用复合叠加而形成。它们分别与似斑状黑云母花岗岩、等粒黑云母花岗岩和花岗斑岩脉有着成因联系。第一阶段矿化包括含矿块状外质矽卡岩和含矿退化蚀变岩；第二阶段为云英岩矿化，在空间上叠加于块状矽卡岩及外部的大理岩；第三阶段为与锰质矽卡岩相伴生的铅锌银矿化。本文详细地描述了前两阶段矿化的地质和成矿地球化学特征，并探讨了其成矿过程。在此基础上，建立了柿竹园矿床的多阶段成矿模  相似文献   

7.
The Shivar pluton, a large granodiorite–monzonite intrusion in NW Iran, was intruded into Cretaceous sedimentary rocks during the Oligo‐Miocene. Its thermal aureole contains a variety of pelitic, basic and calc‐silicate hornfelses. Mineral parageneses in the pelitic and calc‐silicate hornfelses are studied here and mineralogical zones are determined. The maximum pressure of contact metamorphism is estimated to have been about 2.2 kbar on the basis of mineral parageneses in the pelitic rocks, indicating that the intrusion was emplaced no deeper than 8 km in the crust. Crystal size distribution (CSD) studies in the calc‐silicate hornfelses indicate that the degree of overstepping was high near the igneous contact. Secondary solid phases (SSP) inhibited growth of calcite grains in the calc‐silicate rocks and impure marbles. Garnet had a greater inhibitory effect as a SSP than tremolite or clinopyroxene. The time required for coarsening of calcite is calculated for two samples collected at different distances from the igneous contact. The time required for calcite coarsening is about 33 000 years for the sample 800 m from the contact and about 226 000 years for the sample 120 m from the contact. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

8.
西藏墨竹工卡县甲玛铜多金属矿床勘查模型   总被引：31，自引：14，他引：17  
甲玛铜多金属矿床是西藏藏中有色金属开发基地的重要矿床.文章重点研究了该矿床的成矿地质条件、找矿标志、地球化学勘查模型、地球物理勘查模型、矿体空间结构等.研究表明:赋矿地层为林布宗组(K1 l)砂板岩、角岩和多底沟组(J3d)大理岩、灰岩,角岩控制了钼(铜)矿体的分布,角岩与大理岩之间的层间构造是矽卡岩型矿体的赋存部位....  相似文献   

9.
云南文山官房钨矿床团山矿段围岩蚀变与矿化规律研究   总被引：1，自引：0，他引：1  
云南省文山县官房白钨矿床属于中—大型矽卡岩型白钨矿床。矿区内围岩蚀变强烈,蚀变分带明显,依据蚀变岩岩相学及岩石化学测试结果,并结合钻孔编录资料,将团山矿段围岩蚀变划分为3个蚀变带,自花岗岩体向外依次为金云母-绿帘石化带→透辉石-透闪石化带→镁橄榄石化带。通过对各蚀变带中岩石组分迁移量分析认为:在团山矿段热液蚀变及白钨矿化过程中,来自花岗质岩浆热液的A l2O3、S iO2、TFe、K2O、Na2O迁入,灰岩(白云质灰岩)中MgO、CaO迁出,团山矿段白钨矿化主要发生在透辉石-透闪石化带中,矿体产状与透辉石-透闪石带产状基本一致,橄榄石化带中钨矿化相对较弱,金云母-绿帘石化带中仅可见零星钨矿化。这一研究成果将对文山官房钨矿床成矿规律研究以及矿区进一步找矿提供重要的理论依据。  相似文献   

10.
A Devonian granite complex intrudes Precambrian and Silurian siltstones and sandstones as well as (?) Cambrian volcanics and dunite.

Metamorphism of the Precambrian sediments is slight, and an andalusite‐bearing, pelitic hornfels is the only characteristic assemblage. The (?) Cambrian volcanics give rise to a variety of assemblages; (1) lime‐ and ferromagnesia‐rich (hypersthene — cummingtonite — labradorite; diopside — hornblende — labradorite); (2) magnesia‐rich (cordierite — hypersthene; cordierite — anthophyllite); (3) ultrabasic (olivine and/or pleonaste). Biotite (or phlogopite) is an almost invariable component, and garnet may also be present in these groups.

No significant metamorphism of the dunite is evident; minor development of veins and segregrations of aragonite, magnetite, phlogopite, brucite, chalcedony and antigorite may result from low‐grade hydrothermal activity Metamorphic assemblages in calcareous Silurian siltstones contain garnet, diopside, calcite and epidote.

A characteristic feature of the contact metamorphic aureole is the occurrence of diopside‐rich bodies in granite, volcanic hornfels, quartzite and dunite host rocks.  相似文献   

11.
The Huntly Gabbro is one of a suite of large, Ordovician, syn-orogenic,mid-crustal, layered, mafic intrusions, emplaced into Proterozoicmetaclastic rocks of NE Scotland soon after the thermal peakof static, high-T, low-P regional metamorphism. This gabbroand its associated contact metamorphic rocks illustrate a varietyof processes operating during contact anatexis and subsequentmelt segregation and extraction. These processes may closelymirror those occurring at much larger scales in the deep crustduring high-grade regional metamorphism and the generation ofgranitic magmas. The emplacement of the Huntly mafic magma resultedin high-grade contact metamorphism and, locally, anatexis ofmetapelites, leading to the formation of migmatites. The migmatitesand country-rock schists were studied to establish the physicalconditions of metamorphism and anatexis, the nature of the meltingreactions, the compositions of the melts produced, and the extentto which melting was a closed- or open-system process. The country-rockschists immediately to the south of the Huntly Complex containmineral assemblages characteristic of the regional andalusitezone. Thermobarometry of an andalusite schist yields regionalmetamorphic conditions of 537 ± 42°C and 0·27± 0·12 GPa, consistent with previously publishedP–T estimates. The contact metamorphic rocks include sillimanitehornfelses, metatexites and diatexites. The metatexites consistof cordierite–K-feldspar hornfels melanosomes and K-feldspar-richgarnetiferous leucosomes. The diatexites consist of schollenof fine-grained granoblastic hornfels and metatexite suspendedin igneous-textured matrix rocks composed of abundant sub/euhedralgarnet, cordierite, plagioclase and, locally, orthopyroxene,with minor interstitial biotite, K-feldspar and quartz. Thehornfels melanosomes and schollen retained their structuralintegrity during partial melting, but the matrix rocks did not.In the highest-grade diatexites, the assemblage Grt + Opx +Crd + Hc + Pl characterizes both the hornfels schollen and thesub/euhedral minerals of the matrix rocks. Application of phaseequilibria to Opx-bearing rocks yields estimated peak-metamorphicconditions of 900 ± 50°C, 0·45 ± 0·1GPa and aH2O < 0·3. The pressure estimate impliesan emplacement depth of  相似文献   

12.
The Xuebaoding crystal deposit, located in northern Longmenshan, Sichuan Province, China, is well known for producing coarse‐grained crystals of scheelite, beryl, cassiterite, fluorite and other minerals. The orebody occurs between the Pankou and Pukouling granites, and a typical ore vein is divided into three parts: muscovite and beryl within granite (Part I); beryl, cassiterite and muscovite in the host transition from granite to marble (Part II); and the main mineralization part, an assemblage of beryl, cassiterite, scheelite, fluorite, apatite and needle‐like tourmaline within marble (Part III). No evidence of crosscutting or overlapping of these ore veins by others suggests that the orebody was formed by single fluid activity. The contents of Be, W, Sn, Li, Cs, Rb, B, and F in the Pankou and Pukouling granites are similar to those of the granites that host Nanling W–Sn deposits. The calculated isotopic compositions of beryl, scheelite and cassiterite (δD, ?69.3‰ to ?107.2‰ and δ18OH2O, 8.2‰ to 15.0‰) indicate that the ore‐forming fluids were mainly composed of magmatic water with minor meteoric water and CO2 derived from decarbonation of marble. Primary fluid inclusions are CO2? CH4+ H2O ± CO2 (vapor), with or without clathrates and halites. We estimate the fluid trapping condition at T = 220 to 360°C and P > 0.9 kbar. Fluid inclusions are rich in H2O, F‐ and Cl‐. Evidence for fluid‐phase immiscibility during mineralization includes variable L/V ratios in the inclusions and inclusions containing different phase proportions. Fluid immiscibility may have been induced by the pressure released by extension joints, thereby facilitating the mineralization found in Part III. Based on the geochemical data, geological occurrence, and fluid inclusion studies, we hypothesize that the coarse‐grained crystals were formed by: (i) the high content of ore elements and volatile elements such as F in ore‐forming fluids; (ii) occurrence of fluid immiscibility and Ca‐bearing minerals after wall rock transition from granite to marble making the ore elements deposit completely; (iii) pure host marble as host rock without impure elements such as Fe; and (iv) sufficient space in ore veins to allow growth.  相似文献   

13.
江秀敏  罗照华  陈必河  王章棋  张倩 《岩石学报》2014,30(11):3455-3466
致矿侵入体的识别是成矿学研究和资源勘查的关键环节之一,对于许多矿床类型来说也是一个难点.本文以新疆阿尔夏提矽卡岩型铁铜矿床为例,阐述了通过建立五种联系及其地质学、岩石学、矿物学、地球化学和成矿学标志的识别方法,进而提出推木尔特岩基为含矿流体屏蔽层的认识.推木尔特岩基与矽卡岩矿体具有紧密的空间联系,容易被误认为是致矿侵入体.然而,其成岩时间早于成矿时间,仅导致围岩的大理岩化和角岩化,因而不是成矿物质的来源.相反,矿区内分布的闪长质小岩体和各类岩墙不仅与矿体和矽卡岩存在紧密的空间联系,而且岩石中普遍见有造矿矿物与造岩矿物的共结关系,岩体(墙)本身及其围岩也经受了强烈的流体改造,是含矿流体的通道和真正的致矿侵入体.  相似文献   

14.
《International Geology Review》2012,54(11):1229-1240
Intrusion-bordering migmatites comprise a substantial, high-grade metamorphic part of the Alvand aureole near Hamadan, western Iran. Abundant Al-rich metasedimentary rocks and various granites occur in this region. Migmatites consist of Bt?+?Sill?+?Grt?+?Crd?+?Sp ± Opx melanosomes and Grt?+?Pl?+?Kfs?+?Qtz leucosomes. These assemblages reflect upper pyroxene hornfels to lower sanidinite facies physical conditions. The appearance of orthopyroxene in these rocks marks the pressure–temperature transition from the pyroxene hornfels to the sanidinite facies. Field relations, mineral parageneses, and pressure–temperature estimates suggest that intrusion of granitic magma and concomitant partial melting of metasedimentary wallrock units were the main processes involved in the migmatization. Peak metamorphism took place at 650–750°C and ～2–4 kbar; such high-temperature/low-pressure metamorphism was caused mainly by advective heat derived from the emplacement of plutons. Regional metamorphism, granitic magmatism, and contact metamorphism reflected arc construction and collision during subduction of a Neotethyan seaway and subsequent Late Cretaceous–early Tertiary oblique collision of Afro-Arabia (Gondwana) with the Iranian microcontinent.  相似文献   

15.
The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO2‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv., 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO2‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H2O, with some CO2 and very little CH4, N2, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ18OH2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ18OH2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ18OH2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ34S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO2 or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO2 from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.  相似文献   

16.
The rate of mineral transformations in rocks near magmatic intrusions may be estimated using mathematical modeling for study of the duration of metamorphism and geological and mineralogical data. At the contacts of the Anakit trappean massif on the Nizhnyaya Tunguska River, where the temperature reached 900°C, the rate of growth of a wollastonite rim at the boundary between the limestone and the siliceous nodule was ～3 × 10–10 cm/s. The zone of “spotted” hornfels with a width of 300?400 m was formed during metamorphism of chlorite–sericite–epidote–albite–quartz schist near the Kharlov gabbro massif in the foothills of the Altai Mountains. The movement rate of the metamorphic front during the formation of rock may be estimated as ～2 × 10–8 cm/s. It is suggested that the rate of metamorphism is controlled by the temperature and rock composition. As a whole, the rates of metamorphism of rocks near magmatic intrusive bodies exceed the rates of regional metamorphism. Upon accumulation of the actual data, this may be applied for diagnostics of the types of metamorphism.  相似文献   

17.
安徽贵池铜山矽卡岩型铜矿床蚀变矿化分带特征及其成因   总被引：6，自引：1，他引：5  
铜山矽卡岩型铜矿床产于长江中下游铁铜成矿带中的安庆—贵池矿集区。研究区矽卡岩化与矿化发生于碳酸盐岩地层与花岗闪长斑岩间的接触带中,蚀变及矿化具有水平与垂向分带特征。水平方向上,靠近岩体的矽卡岩中石榴子石含量较高,远离岩体的矽卡岩中透辉石含量较高;靠近大理岩带发育钙铁辉石矽卡岩,远离大理岩带的灰岩硅化较强。垂向上,从上到下依次为角岩带、钙质矽卡岩带和镁质矽卡岩带。矿物成分研究表明,靠近岩体处氧化性较强,石榴子石的钙铁榴石端员含量高;铜多富集于含石英脉的岩体、距岩体略远的矽卡岩、角岩或大理岩中,而锌多富集于硅化灰岩及远离岩体的矽卡岩中。研究表明,该矿床中蚀变矿化经历了进变期和退变期,包括接触热变质阶段、进化交代阶段和早退化蚀变阶段、晚退化蚀变阶段。其中,大规模的黄铜矿化主要发生于早退化蚀变阶段,且在岩浆演化晚期进一步富集于斑岩石英脉中。  相似文献   

18.
西藏甲玛铜多金属矿床为冈底斯成矿带的超大型矿床之一,其矽卡岩型主矿体受林布宗组砂板岩、角岩(硅铝质岩石)和多底沟组大理岩(钙质岩石)的岩性界面所控制。基于岩、矿心地质编录,开展矽卡岩岩石、矿物分带及矽卡岩地球化学、矿物化学研究,探讨硅钙岩性界面对矽卡岩及多金属矿体形成的影响。从顶板至底板由石榴子石矽卡岩、硅灰石石榴子石矽卡岩至硅灰石矽卡岩表现出Si O2、Ca O逐渐增加和Al2O3、Fe2O3+Fe O逐渐减少的趋势,石榴子石矽卡岩、硅灰石矽卡岩的稀土元素和微量元素特征对顶板、底板岩石表现出明显的继承性。靠近顶板的矽卡岩中石榴子石属于钙铝-钙铁过渡系列,由石榴石核部向外环带具有Al含量减少、Fe含量增加的特点;靠近底板矽卡岩相对于靠近顶板具有钙铁榴石比例增加、钙铝榴石比例减少特征,由核部向外围未见明显的环带成分演变特征。矽卡岩是流体与硅铝质、钙质岩石水岩反应的产物,沿硅钙界面流体减压沸腾、地下水混合作用和界面内垂向的流体地球化学障是主要的致矿机制。硅、铝质岩石化学性质、物理性质差异是界面控矿的主要因素,硅钙面复合张性构造带、岩浆热事件增加界面渗透率差异有利于矿体规模的增加和品位提高。  相似文献   

19.
High‐P/low‐T metamorphic rocks of the Hammondvale metamorphic suite (HMS) are exposed in an area of 10 km2 on the NW margin of the Caledonian (Avalon) terrane in southern New Brunswick, Canada. The HMS is in faulted contact on the SE with c. 560–550 Ma volcanic and sedimentary rocks and co‐magmatic plutonic units of the Caledonian terrane. The HMS consists of albite‐ and garnet‐porphyroblastic mica schist, with minor marble, calc‐silicate rocks and quartzite. Pressure and temperature estimates from metamorphic assemblages in the mica schist and calc‐silicate rocks using TWQ indicate that peak pressure conditions were 12.4 kbar at 430 °C. Peak temperature conditions were 580 °C at 9.0 kbar. 40Ar/39Ar muscovite ages from three samples range up to 618–615 Ma, a minimum age for high‐P/low‐T metamorphism in this unit. These ages indicate that the HMS is related to the c. 625–600 Ma subduction‐generated volcanic and plutonic units exposed to the SE in the Caledonian terrane. The ages are also similar to those obtained from detrital muscovite in a Neoproterozoic‐Cambrian sedimentary sequence in the Caledonian terrane, suggesting that the HMS was exposed by latest Neoproterozoic time and supplied detritus to the sedimentary units. The HMS is interpreted to represent a fragment of an accretionary complex, similar to the Sanbagawa Belt in Japan. It confirms the presence of a major cryptic suture between the Avalon terrane sensu stricto and the now‐adjacent Brookville terrane.  相似文献   

20.
新疆雅满苏铁矿床赋存于下石炭统雅满苏组中,矿区发育火山岩、碳酸盐岩及矽卡岩,因此,研究碳酸盐岩与矽卡岩及成矿的关系对厘定矿床成因类型和指导找矿勘查具有重要的理论和实际意义。文章在野外地质剖面测制和调查研究的基础上,对矿区及外围碳酸盐岩进行了岩相学、主量元素、稀土元素及微量元素分析,探讨了矿区碳酸盐岩的地质、地球化学特征。研究结果表明,雅满苏铁矿区的碳酸盐岩含有浅海相生物化石、鲕粒结构及内碎屑构造,与火山岩互层产出,指示沉积作用及火山喷发活动发生于浅海环境;矿区碳酸盐岩岩石类型包括微晶灰岩、细晶灰岩、大理岩、含凝灰质大理岩、糜棱岩化碳酸盐岩和方解石构造片岩,它们的主量元素含量差别不大,说明在变质变形和成矿作用过程中没有主量元素组分的明显带入带出;稀土、微量元素含量除方解石构造片岩稍有降低外,其余岩性均变化不大,也表明变质变形和成矿作用过程中没有外来物质的明显加入,包括成矿物质;与矿体毗邻的碳酸盐岩为方解石构造片岩,没有发生矽卡岩化,表明该碳酸盐岩在构造及成矿作用过程中只发生了构造片理化和热液重结晶,没有发生接触交代。因此,雅满苏铁矿床不是狭义的矽卡岩(接触交代)型铁矿床,而是海相火山岩型铁矿床。研究区的矽卡岩并非是接触交代的产物,而应是火山热液交代含碳酸盐的火山岩而成。是否有下部地层中的碳酸盐岩提供成岩成矿物质还需要进一步研究。  相似文献   

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