共查询到20条相似文献，搜索用时 165 毫秒
1.
石英玻璃原料矿的流体包裹体特征 总被引：4，自引：0，他引：4
研究不同产地石英玻璃原料矿中包裹体的显微形貌、均一温度及红外光谱特征，矿物加工成高纯石英粉后，在氢气保护高温电炉中溶制成石英玻璃。分析原料矿包裹体特征与石英玻璃气泡、羟基质量的联系，结果表明：高温下不爆破的流体包裹体是形成石英玻璃气泡的主要因素，包裹体中的水发子溶解于SiO2熔体中形成石英玻璃的残余羟基。 相似文献
2.
石英胶结物是砂岩中重要的胶结物类型。用纳米离子探针(CAMECA Nano SIMS 50L)对石英胶结物中Al、Ca和Mg等重要微量元素进行原位分析,可为成岩作用研究提供重要基础依据。然而,由于缺乏相应的标准物质,一直不能对石英胶结物中Al、Ca和Mg进行研究。针对不均一的石英颗粒样品,文中采用细磨、混合、高温熔融(2000℃,6个小时)与快速冷却等措施,制作均一化的石英玻璃。经纳米离子探针验证,该石英玻璃中Al、Ca和Mg在亚微米尺度上是均一的,已能满足成岩作用研究的需要。随后,用电感耦合等离子体发射光谱和激光剥蚀电感耦合等离子体质谱测定了石英玻璃中Al、Ca和Mg的含量。相对灵敏度因子分析显示,这些测试结果是协调、合理的。该均一化的石英玻璃可作为亚微米尺度Al、Ca和Mg原位分析的标准物质。 相似文献
3.
激光熔蚀微量氧同位素分析方法及其地质应用 总被引：2，自引：1，他引：1
研究小尺度或微区的同位素组成变化已成为地球化学分析技术发展的重要方向之一。在研制CO2激光熔蚀氧同位素制样装置的基础上,通过该装置与MAT253质谱计联机实现了硅酸盐和氧化物矿物的氧同位素在线分析。所测样品包括NBS28石英标样、石英玻璃,以及天然的石榴子石、锆石、橄榄石等一些难熔矿物。该装置分析的颗粒样品氧同位素分析精度为±022‰,最低样品量为8μmol的O2;石英玻璃原位分析的氧同位素分析精度为±035‰,最低样品量为7μmol的O2。这种装置和分析方法具备速度快,熔样温度高的特点,尤其适于难熔矿物。该装置可采用脉冲激光实现石英玻璃的微区原位分析,可应用于单个矿物生成环带的氧同位素研究。 相似文献
4.
高纯度石英的酸浸实验研究 总被引：14，自引：4，他引：14
针对脉石英矿中含有大量云母及长石等伴生矿的特点，通过调整溶液浓度及温度等手段，强化矿物的酸浸效果。根据石英与杂质矿物在酸浸过程中的差异，探索消除石英中杂质矿物的方法。研究表明石英原料粉在温度为120℃、HF酸与水的比为0．4～0．5的溶液中酸浸适当时间后，其纯度可达到中高档石英玻璃的技术要求。 相似文献
5.
6.
分析岩石矿物中的气体化学组成,可为岩石圈地幔的不同地球化学过程、地球内部氧化还原环境以及水在深部地球中的循环等研究提供重要的信息与约束条件。对岩矿样品加热使气体脱出是一种常用的实验手段,使用单石英玻璃管作为样品管,石英玻璃结构中不规则的空隙使得气体在高温下易发生扩散与渗透;由钼、钽坩埚组成的双真空炉管一般用于稀有气体同位素组成分析,较少用于气体化学组成分析,且该装置结构复杂,不易组装拆解,也易被损坏。针对以上问题,本文研制了石英玻璃与金属零件组成的双真空盛样炉管,该炉管具有体积小、易于组装、拆解和移动等特点。在相同的实验条件下与单石英玻璃管进行对照实验。根据实验结果,尤其是H_2浓度的测量结果表明:不论哪种类型的样品在500℃和950℃加热脱气时,应用本文研制的双真空盛样炉管,测量的H_2浓度均高于同等实验条件下应用单石英玻璃管测量的H_2浓度,该双真空炉管的气密性优于单石英玻璃管,有利于获得样品中更加真实的气体化学组成。 相似文献
7.
8.
9.
10.
《矿物岩石》2016,(1)
为了解国产单晶硅生长用石英坩埚的技术现状,为石英坩埚的研究与应用提供科学依据,采用多种现代检测方法,对四川某企业生产的石英坩埚及其高纯石英原料的化学成分、物相和结构特征进行测试分析,结果表明:单晶硅生长用石英坩埚是一种以高纯石英为原料加工制备的石英玻璃功能材料;石英坩埚的透明情况和分层结构均由内部的气泡引起,透明层中气泡较少,直径?=10μm~100μm,不透明层中复合气泡密集且明显大于透明层,直径?=50μm~300μm。该企业所生产的石英坩埚出现双层、透明单层、不透明单层等3种不同横断面结构,但它们的微量杂质元素含量相似(总量为101×10~(-6)~188×10~(-6))、物相相同(非晶态的石英玻璃),其质量还未达到国家质量标准,一个重要原因是所用的高纯石英原料13种微量杂质元素总量为55×10~(-6),属4N中端产品,与美国尤尼明4N8标准级高端产品还存在很大差距。 相似文献
11.
In high-grade (granulite facies) quartzofeldspathic rocks the progressive development of a fabric records contrasting deformation
behaviour of quartz and feldspar. Feldspar has undergone deformation mainly by recrystallization-accommodated dislocation
creep and produced smaller recrystallized grains progressively in the course of deformation. Quartz has not deformed solely
by dislocation creep but also by a diffusion-controlled mechanism. Dislocation climb is important in the dislocation creep
of quartz. In contrast to feldspar, quartz grains have not recrystallized into smaller grains at any stage of deformation.
Rather, they have transformed initially to short monocrystalline ribbons and ultimately to long polycrystalline ribbons. This
textural change of quartz is a continuous process and has taken place in the course of bulk textural change of the rocks during
the deformation. 相似文献
12.
The raw sands from Hohenbocka (Germany) containing iron essentially in pyrite form is used for glass grade sands processing by dump leaching for several weeks followed by attrition and two-stage classification. The analysis of the sands by means of X-Ray Fluorescence Analysis (RFA) showed an average of about 420 ppm Fe. The objective of this investigation was to reduce the processing time and the total iron content below 105 ppm in the sand product for special glass applications. Due to the presence of sulfide and oxide iron at different ratios in raw sands, a combination of chemical and physical methods was investigated. Leaching was carried out at different acid concentrations, followed by surface cleaning by neutral and alkaline attrition, and gravity separation. Additionally, the effect of continuous addition of H2O2 during leaching to remove iron from sands was investigated. Only two days of leaching was required at the initial acid concentration to 25 g/L. After attrition and tabling of leached sands, a product with 84 ppm of iron was achieved. The continuous removal of dissolved metals by adsorption with active carbon could make it possible to reuse the regenerated sulphuric acid for leaching. With recirculation, the quantity of fresh sulphuric acid required was 0.4 kg/t of quartz sand. 相似文献
13.
油气聚集对石英矿物成岩演化的影响 总被引：4，自引：0，他引：4
油气在砂岩储层中的聚集会对石英矿物的胶结作用产生影响。对黄骅坳陷三马探区的石英矿物的包裹体分析以及对开放孔隙中原油抽提物和包裹体中原油的生物标志物进行分析,含油级别较低的油层与水层具有相似的均一化温度分布范围,但富含油层中流体包裹体均一化温度高值分布范围比低级别油层和水层低,包裹体中的烃类组成与开放孔隙中的主要存在成熟度上的不同。分析认为石油的充注不会使石英矿物的胶结作用立刻停止,石英的次生加大作用仍在继续,但胶结作用受到一定的抑制,当石油充注到一定程度后,胶结作用将会停止,后期进入储层的成熟度较高的原油可能未被捕获。 相似文献
14.
辽宁四道沟热液金矿床中石英的稀土元素的特征及意义 总被引：30，自引：10，他引：20
本文用ＩＣＰ－ＭＳ测定了辽宁四道沟金矿矿脉中石英及其中流体包裹体中的稀土元素含量,发现石英的稀土元素配分模式类似于其中流体包裹体的稀土元素配分模式,推断石英中的稀土元素主要赋存于注流体包裹体中,流体包裹体中的稀土元素了石英的稀土元素配分模式,原生包裹中的流体是和石英同源的,其稀土元素指示的是石英形成过程中流体的信息。而次生包裹体中的流体是石英形成后的流体活动产物,其稀土元素指示的是后期流体活动的信 相似文献
15.
A natural example of crystal-plastic deformation enhancing the incorporation of water into quartz 总被引：2，自引：0，他引：2
Water content of quartz in and around a greenschist facies mylonitic shear zone located in the western Adirondacks was analyzed by micro-FTIR spectroscopy. The shear zone is within a pegmatitic dike, which cuts across a granitic gneiss. The thickness of the shear zone varies along strike from 15 cm wide and encompassing all of the pegmatite dike at its northern most exposure to 5 cm wide approximately 10 m south, along strike. Microstructures, including quartz ribbons and recrystallized grains, indicate quartz and feldspar within the mylonite underwent dislocation creep. Infrared spectral analysis was carried out using a Nicolet micro-FTIR on mylonitic quartz ribbons, pegmatitic quartz and gneissic quartz. A small aperture size (56 μm by 50 μm) for the IR beam allowed optically clear regions of the quartz grains to be analyzed without any contribution from grain boundaries. The smallest dimension of the quartz ribbons is 0.3 mm, whereas the pegmatitic quartz has a grain size of 3 to 5 cm. Results show mylonitic quartz ribbons contain the most water (320 H:106 Si average, range of 50 to 1120 H:106 Si); pegmatite quartz contains much less water (30 H:106 Si average, range of 20–40 H:106 Si) and the gneissic quartz contained an intermediate amount (200 H:106 Si average, range of 20 to 870 H:106 Si). These data indicate that water was preferentially incorporated into the deformed quartz ribbons. 相似文献
16.
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been applied to determine the elemental composition of the surface layer, as well as of the first interior layer, of quartz grains from the mine tailings from Kristineberg (northern Sweden) in order to determine concentration gradients between these two layers. The quartz grains were collected from the oxidized and unoxidized zones within the tailings. The aim of this study is to assess the role of quartz surfaces as sites for the attenuation of solutes from the mine-tailings porewater. Concentrations of Cu, Ag, Sb, Pb and Bi are highest near the surface of each grain and decrease towards the interior. The surface concentration of Cu, Zn and Pb is more pronounced within the unoxidized than within the oxidized zone of the tailings. Cu exhibits a distinct concentration peak at the surface of the quartz grains below the pre-remediation oxidation front. For Zn and Ce the trend of high surface concentration is less pronounced than for Cu or Pb. Silver, Bi and As are preferably adsorbed within the uppermost layers of the oxidized zone where the pH is as high as 6.2. The conversion of intensity signals of the elements to concentration values in ppm was done by using external standards (NIST silicate glass). 相似文献
17.
This study presents an evaluation of Norwegian kyanite quartzites from Gullsteinberget, Knøsberget, Kjeksberget, Sormbrua, Tverrådalen, Juovva?orrú and Nasafjellet as potential deposits of high-purity quartz (HPQ) for use as raw material for special applications in high-technology industries. Fine-grained quartz, which forms 70 to 85 vol.% of these rocks, generally contains less than 50 μg g?1 (total sum) of the structurally incorporated trace elements B, Li, Al, Ge, Ti, Fe, Mn, K and P. The concentrations are in the same range as those found in HPQ products, which are being mined and produced in Norway and elsewhere. Quartz analyses were performed using laser ablation–inductively coupled plasma mass spectrometry. Complimentary whole-rock analyses and cathodoluminescence studies of quartz were carried out to reveal processes, which have led to the low trace-element concentrations in quartz. This discovery, together with a better knowledge of the processes leading to the formation of HPQ in kyanite quartzites, could lead to the recognition of a new global type of HPQ resource applicable for industrial use. However, the processing technology necessary to separate HPQ from kyanite quartzite economically has not been developed so far. 相似文献
18.
Geology and geochemistry of giant quartz veins from the Bundelkhand Craton,central India and their implications 总被引：1，自引：0，他引：1
J. K. Pati S. C. Patel K. L. Pruseth V. P. Malviya M. Arima S. Raju P. Pati K. Prakash 《Journal of Earth System Science》2007,116(6):497-510
Giant quartz veins (GQVs; earlier referred to as ‘quartz reefs’) occurring in the Archean Bundelkhand Craton (29,000 km2) represent a gigantic Precambrian (∼2.15 Ga) silica-rich fluid activity in the central Indian shield. These veins form a
striking curvilinear feature with positive relief having a preferred orientation NE-SW to NNE-SSW in the Bundelkhand Craton.
Their outcrop widths vary from ≤1 to 70m and pervasively extend over tens of kilometers along the strike over the entire craton.
Numerous younger thin quartz veins with somewhat similar orientation cut across the giant quartz veins. They show imprints
of strong brittle to ductile-brittle deformation, and in places are associated with base metal and gold incidences, and pyrophyllite-diaspore
mineralization. The geochemistry of giant quartz veins were studied. Apart from presenting new data on the geology and geochemistry
of these veins, an attempt has been made to resolve the long standing debate on their origin, in favour of an emplacement
due to tectonically controlled polyphase hydrothermal fluid activity. 相似文献
19.
研究表明,文峪金矿床无矿、贫金与矿体石英脉其热爆裂特征在起爆温度、爆裂温度范围、热爆曲线形态主爆峰值等方面均存在明为差异,可作为石英脉含矿性评价的重要标志。根据石英热爆裂参数,对５０５及５３０脉局部地段开展了填图研究。圈定了具不同类爆裂特征的石英分布范围,据此平价了其深部成矿远景,其结果对同类金矿床预测评价工作具有重要的方法学意义。 相似文献
20.
对石英原料的加工分选提纯,是获得高纯石英原料的主要途径,而有关对石英晶体中有害杂质的分选提纯,国内对这方面的工作较少。根据水晶、石英的ICP分析结果,对水晶石英晶体中的有害杂质元素主要种类、分布特征、在晶体中的赋存状态及提纯方法,分别进行了讨论。 相似文献