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1.
The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), α-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials.  相似文献   

2.
Melilite and wollastonite from the Colle Fabbri stock contain silicate melt and silicate-carbonate inclusions. The homogenization temperatures of silicate inclusions are within the magmatic temperature range of mantle ultrabasic melts: about 1,320?±?15 °С. Their composition is melilititic and evolves to the composition of leucite tephrite and phonolite. The composition of silicate-carbonate inclusions are high SiO2, Ca-rich, enriched in alkalies and are similar to that of inclusions of carbonatite melts in the minerals of melilitolites of other intrusive ultramafic complexes. They are also similar to the compositions of metasomatized travertine covering the melilitolite stock. The presence of primary silicate and silicate-carbonate inclusions evidences that the melilitite magma from which melilitolites of Colle Fabbri crystallized was associated with carbonatite liquid. This liquid was highly fluidized, mobile and aggressive. Actively interacting with overlying travertine, the liquid enriched them with alkalies, aluminosilicates and incompatible elements, which resulted in the equalization of their compositions. Heterogeneous compositional dominions were formed at the contact between melilitolite and wall pelites. In the minerals of these contact facies high-Si melt inclusions of varying composition have been observed. Their occurrence is related to the local assimilation by the high-temperature melilitite magma of pelitic country rocks. The content of incompatible elements in melilitite melts and melilitolites is higher than the mantle norm and they have peculiar indicator ratios, spectra, Eu/Eu* ratio, which suggest a peculiar mantle source.  相似文献   

3.
Mineral assemblages and chemical compositions of minerals foundin impure dolomitic marbles embedded in gneisses and migmatitesof the E. Greenland Caledonian fold belt (Scoresby Sund) suggestthat the marbles were metamorphosed near 630 °C at 5 kbpressure. The analysis of complex textural and mineralogicalrelations among minerals such as dolomite, calcite, forsterite,pargasite, chlorite, spinel, diopside and phlogopite led tothe conclusion that the major mineralogical features of therocks were probably caused by sodium metasomatism at constanttemperature and pressure. The effect of the inferred sodiummetasomatism may be summarized by three schematic reactionsall involving modal changes of excess dolomite, calcite, forsterite,chlorite and spinel: (a) nucleation and growth of pargasite,(b) resorption of phlogopite, and (c) growth of pargasite fromphlogopite.  相似文献   

4.
In order to prepare iron phosphate by waste sludge, we report a method for effective utilization of the sludge obtained from the electrocoagulation treatment of source-separated urine. The sludge was dissolved with hydrochloric acid and pretreated with H2O2 and Na3PO4; finally, NaOH was added to precipitate iron phosphate from the solution. Thermal treatment of the precipitate at 750 °C in air yielded crystalline quartz-like anhydrous FePO4. The precipitate was characterized by a number of thermal techniques such as thermogravimetry/differential thermal analysis, scanning electron microscopy, and X-ray powder diffraction.  相似文献   

5.
The Gejiu tin field in southern China consists of six major deposits and many minor ones containing more than 120 million tons (pre-mining resource) at 1% Sn and significant amounts of Cu, Ag, Zn, and Pb. It is one of the largest tin fields of primary deposits in the world. Mineralization is the result of the intrusion of granitic plutons into Permian and Triassic sedimentary rocks, which are dominantly limestone, dolomitic limestone, and dolomite. Five (mostly peraluminous) granitic intrusives (64-115 Ma) are present in the area. The largest orebodies are spatially and temporally related to the Laoka (principally), Beipaotai, and Marsong granites. Tin mineralization is mainly within greisens developed at the outermost zone of a skarn zonal sequence and are mineralogically dominated by fluorite, quartz, and micas.

The deposits are the result of volatile-rich ore solutions that evolved late in the plutonic crystallization history. The solutions produced metamorphic skarns as well as ore skarns, both of which later became “greisenized” skarns. Gejiu is the largest example of what has been, up to now, a style of mineralization reported only in minor amounts.  相似文献   

6.
Radiocarbon dates on pedogenic CaCO3, accumulated at various depths in a stabilised dune at Budha Pushkar, Rajasthan, show inversion with respect to ‘stratigraphy’. Occurrence of younger carbonates overlain by older ones at various levels, is interpreted in terms of a shift in climatic conditions causing pedogenic carbonates to be leached to greater depths. Based on this model, several wetter regions during the last 6000 years have been identified. The most significant shift from a dry to a wet phase seems to have taken place between 5000 and 4500 years ago. Conclusions drawn from this study is in agreement with that based on pollen data and extends this method as a potential palaeoclimatic indicator.  相似文献   

7.
Geotechnical investigations have been carried out for many years in order to identify the depth, extent and the properties of the glacial deposits of Northern England. This valuable source of data exists in various forms because of the differences in the design of the investigations, the codes of practice relevant at the time of investigations, and contractors practice. An electronic store of these data would be a valuable asset not only to future development but to help in scientific studies of glacial till. This paper presents an overview of NETDATA (Northern England Till DATA), a relational database which is designed to store that data in a consistent format, allowing flexibility for further use. A preliminary analysis of the data has resulted in a characteristic data set for the tills.  相似文献   

8.
ＴｈｅｈｙｐｏｔｈｅｓｉｓｏｆｔｒａｎｓｆｏｒｍａｔｉｏｎｏｆｂａｓａｌｔｔｏｅｃｌｏｇｉｔｅａｔｔｈｅｃｏｎｔｉｎｅｎｔａｌＭｏｈｏｄｉｓｃｏｎｔｉｎｕｉｔｙｉｎ 196 0ｓｅｖｅｒｂｒｏｕｇｈｔｂｒｏａｄｉｎｔｅｒｅｓｔｓｔｏｇｅｏｓｃｉｅｎｃｅｃｏｍｍｕｎｉｔｙ (ＲｉｎｇｗｏｏｄａｎｄＧｒｅｅｎ ,1996 ;ＧｒｅｅｎａｎｄＲｉｎｇｗｏｏｄ ,1972 ;ＩｔｏａｎｄＫｅｎｎｅｄｙ ,1971;ＫｕｓｈｉｒｏａｎｄＡｏｋｉ,196 8) .Ｔｈｉｒｔｙｙｅａｒｓｌａｔｅｒ ,ｗｉｔｈｔｈｅｄｉｓｃｏｖ ｅｒｉｅｓｏｆｃｏｅｓ…  相似文献   

9.
利用拉曼光谱对几件九连墩楚墓出土青铜器的腐蚀产物进行了测试。结果表明,九连墩楚墓出土的青铜器上主要的锈蚀产物为孔雀石[CuCO_3·Cu(OH)_2],存在部分蓝铜矿[2CuCO_3·Cu(OH)_2]和少许副氯铜矿[Cu_2(OH)_3Cl];此批青铜器锈蚀情况比较复杂,锈蚀种类比较丰富。在此基础上,探讨了科学保护此批青铜器的方法。  相似文献   

10.
Brine chemical data obtained from oil wells in Cretaceous oilfields in the Southeastern Basin of Mexico show a complex evolution, with the following main hydrochemical processes: (1) mixing of highly evaporated brines, past the point of halite precipitation with seawater; (2) water/rock interactions between brines and carbonated rocks (dolostones).  相似文献   

11.
机械工业第六设计研究院原隶属于机械工业部,为事业单位,2000年10月转制后隶属于中国机械装备(集团)公司,为企业单位。该院现有在职员工459人,外聘人员300人,离退休人员356人,其中,中国工程院院士1人,中国工程设计大师2人,教授级高级工程师50人,高级工程师近260人,工程师300多人。该院是工业和民用建筑设计双甲级单位,并具有甲级工程总承包和工程监理资质。建院五十多年来,该院先后完成了5000余项大中型工业和民用建筑项目的设计和咨询,为我国国民经济建设和发展做出了卓越贡献。  相似文献   

12.
两类榴辉岩的石榴石变形特征差异——来自TEM研究的证据   总被引：9，自引：4，他引：9  
大陆碰撞造山带中超高压榴辉岩从变形程度上通常可以分为面理化榴辉岩和块状榴辉岩两类。本文利用透射电子显微镜对中国大陆科学钻探主孔岩心中面理化榴辉岩和块状榴辉岩的石榴石变形特征进行了比较研究。结果表明:(1)面理化榴辉岩中石榴石的位错密度比块状榴辉岩中石榴石的位错密度高大约3个数量级,位错密度达1.2×1010/cm2。并且有水分子团与高密度位错共存,表明主导石榴石发生强烈塑性变形的机制为水弱化的位错滑移。(2)块状榴辉岩中石榴石的位错密度低,没有观察到水分子团,虽然在局部发现有位错网,但总体上仍呈刚性。(3)两类榴辉岩的石榴石中占主导地位的位错滑移系都是1/2<111>{110},其次为<100>{010}。本文对变形石榴石晶体中水的赋存状态、水弱化机制及变形石榴石形态优选方位与晶格优选方位不协调问题进行了讨论:(1)水在石榴石晶体中有三种可能赋存状态:第一种是吸附于位错管道中的极化水分子;第二种是通过晶体表面以及位错管道扩散进入晶格的间隙水分子;第三种是以4OH-替代SiO44-形式的结构水。(2)石榴石水弱化机制有两种可能:一种是水弱化促进的位错滑移机制,在面理化榴辉岩石榴石的塑性变形中起主导作用;另一种是水弱化促进的扩散和颗粒边界滑移机制,在面理化榴辉岩石榴石的塑性变形中只起次要作用。(3)变形石榴石不产生明显的LPO是由其晶体结构本身特征所决定的,并不能排除其主导变形机制仍然是位错滑移的可能性。  相似文献   

13.
This review provides an introduction to presolar grains - preserved stardust from the interstellar molecular cloud from which our solar system formed - found in primitive meteorites. We describe the search for the presolar components, the currently known presolar mineral populations, and the chemical and isotopic characteristics of the grains and dust-forming stars to identify the grains’ most probable stellar sources.  相似文献   

14.
Discovery of the remains of belemnites referred to the Hibolithes sp. from the Jurassic–Cretaceous Pedawan Formation in Sarawak, on the island of Borneo(Malaysia) comprises four fragments of belemnite rostra. The specimens are characterized by multiple fractures and vein filling. Two fragments measuring about 130 mm are relatively intact, with only part of the alveolar region missing; a third piece represents the middle part of a rostrum, and the fourth specimen is too fragmentary to be assigned to any specific part of the rostrum. Based on specimen characteristics, a Tithonian–Hauterivian age is plausible. The sedimentary succession that yielded the belemnite material comprises thick shale that reflects the Te division of Bouma sequence. The occurrence of a Hibolithes taxon in the uppermost Jurassic to lowermost Cretaceous Pedawan Formation sediments in Borneo reflects a near to global palaeobiogeographic distribution of this genus.  相似文献   

15.
Specimens of fossil wood preserved lignified in Pliocene brown coal and identified as Pinus armandii Francher come from an opencast coalmine at Longling in western Yunnan Province, China. Phytochemical investigation of the fossil wood isolated using liquid column chromatography seven compounds （1-7） including a new fluorene derivative named 11,11-dimethyl-11H-benzo[b]fluorene. A further 28 volatiles were detected by gas chromatography-mass spectrometry （GC-MS）. Spectroscopic investigation methods, including MS and 1D and 2D-NMR techniques elucidated the structure of the seven compounds. Two types of natural products, isopimara and stilbene commonly occuring in extant and Pliocene fossil P. armandii indicate phytochemical fidelity during burial under certain circumstances in sediments. Discovery of stilbenes that can inhibit the activities of wood-destroying fungi in the Pliocene P. armandii prompts the assumption that the chemical preservation of this Pliocene fossil wood of P. armandii in brown coal might contribute to the presence of inner natural inhibitors against wood-destroying fungi.  相似文献   

16.
Specimens of fossil wood preserved lignified in Pliocene brown coal and identified as Pinus armandii Francher come from an opencust coalmine at Longling in western Yunnan Province,China. Phytochemical investigation of the fossil wood isolated using liquid column chromatography seven compounds(1-7)including a new fluorene derivative named 11,11-dimethyl-11H-benzo[b]fluorene.A further 28 volatiles were detected by gas chromatography-mass spectrometry(GC-MS).Spectroscopic investigation methods,including MS and 1D and 2D-NMR techniques elucidated the structure of the seven compounds.Two types of natural products,isopimara and stilbene commonly occuring in extant and Plincene fossil P.armandii indicate phytochemical fidelity during burial under certain circumstances in sediments.Discovery of stilbenes that can inhibit the activities of wood-destroying fungi in the Pliocene P.armandii prompts the assumption that the chemical preservation of this Pliocene fossil wood of P.armandii in brown coal might contribute to the presence of inner natural inhibitors against wood-destroying fungi.  相似文献   

17.
Giles M. Foody 《GeoJournal》1995,36(4):361-370
Remotely sensed data are an attractive source of land cover information. In many applications the required information relates to the extent or coverage of land cover class(es) in a region, which is generally derived from a count of the pixels allocated to the class(es) of interest in a classification. A highly accurate classification is not required for the derivation of accurate estimates of class coverage, provided the classification is accompanied by appropriate information on its quality. For instance, the information on classification quality contained in the classification confusion matrix can be used to significantly increase the accuracy of the estimates of land coverage. This is illustrated with reference to a case study focused on the estimation of despoiled land coverage in administratively defined local district in industrial South Wales from Landsat TM data. The accuracy of the investigation was assessed relative to a map of despoiled land cover for this region produced by conventional methods. From an image classification of moderate accuracy, the classification accuracy ranged form 57–83% between the districts investigated, a pixel count provided estimated of despoiled land coverage that were only poorly correlated to the mapped coverage;r = 0.27. Using the information on the pattern of error in the class allocation contained in the classification confusion matrix the estimation accuracy was increased significantly, with a correlation ofr = 0.81 observed between the remote sensing based estimate and the mapped land coverage. Furthermore, the r.m.s. error in despoiled land coverage estimation was reduced by approximately half, to less than 1% district area, when the classification was used in conjunction with information on the pattern of classification error.  相似文献   

18.
阿尔泰基性麻粒岩的发现：来自矿物学的证据   总被引：5，自引：10，他引：5  
新疆北部阿尔泰造山带富蕴乌恰沟一带首次发现代表中、下地壳深变质作用的基性麻粒岩详细的野外和室内研究表明阿尔泰基性麻粒岩主要由粗粒和细粒的麻粒岩组成(SiO2含量为47．83～53．57％)。两者的矿物组合相近，为斜方辉石 单斜辉石 斜长石 角闪石 黑云母。角闪石和黑云母成分富镁，可能与岩石的成分富镁有关、基性麻粒岩的岩石地球化学成分显示其富Mg/(Mg Fe^2 )和亏损U，Th，K及Rb，而且其原岩为钙碱性玄武岩，是岛弧构造环境下形成的产物。矿物化学特征表明斜方辉石中Mg／(Mg Fe^2 )介于0．65～0．71之间，为紫苏辉石，具高MgO FeO，低Al2O3和Ca／(Ca Mg Fe)，而单斜辉石具低TiO2和Al2O3的特点，说明它们皆为变质成因。部分角闪石和褐色黑云母富钛，指示它们为高温下形成的产物。这些特征证实了上述岩石为基性麻粒岩。角闪石和黑云母氟和氯含量较低以及水速度较高，暗示其流体成分氟和氯在变质作用过程中不起主导作用。根据麻粒岩中矿物共生组合、期次和矿物温压计估算，麻粒岩形成的峰期和退变质温压条件分别为750～780℃，0．6～0．7GPa和590～620℃，0．23～0．37GPa，前者属高温中压条件，阿尔泰地区基性麻粒岩的发现为进一步研究阿尔泰地区深部下地壳的组成和结构以及深化阿尔泰地区、新疆北部甚至中亚地区大陆动力学过程和机制都具有重要意义。  相似文献   

19.
利用Griggs型 5GPa高压仪器 ,在柯石英稳定域围压条件下 ( >3GPa)完成大别山超高压榴辉岩流变学实验 ,建立了榴辉岩流变状态本构方程 (流动律 ) : ε=Aexp( -Q/RT)σn ,应力指数 (n)为 3 .4 ,活化能 (Q)为 4 80kJ/mol,结构常数 (A)为 10 3.3.实验结果表明 :( 1)作为两相矿物组成的榴辉岩 ,其流变学强度在很大程度上取决于强相矿物 (石榴石 )和弱相矿物 (绿辉石 )含量比例 ;( 2 )天然榴辉岩塑性变形机制是以位错蠕变为主 ;( 3 )根据实验成果比较榴辉岩和上地幔方辉橄榄岩流变学强度相当 ,两者耦合在大陆深俯冲 10 0km左右深度发生拆沉作用可能性很小 ,与上地幔上隆 (upwelling)作用有关的造山期后伸展作用对超高压岩石折返更具有重要意义 .  相似文献   

20.
The cored sediments sampled by R/V Marion Dufrense in the active margin off southwestern Taiwan on the east side of the Manila Trench are mostly muds consisting mainly of quartz, feldspar, illite, chlorite ＋ kaolinite with a trace amount of montmorillonite. The cored sediments have higher Fe, Ti, Cr, Cs, Li, Ni, and V but lower Ca, Na, Mn, Hf, Nb, Sr, Ta, U and Zr contents when compared with the upper continental crust（UCC, Taylor and McLennan, 1985）. The Eu/Eu＊ ratios of the sediments averaging 0.69 indicate that the recycling effect on the Eu anomaly may be minor and the contribution of mafic source rock was unimportant, which can also be depicted in the La-Th-Sc plot（Cullers, 1994） showing a ＂mixed origin＂ close to the felsic end member. The chemistry of the cored sediment can be explained by a mixing model designed by Ho and Chen（1996） with four end members i.e., greywacke, shale, quartzite and limestone, which are widely distributed in the Cenozoic formations of southern Taiwan with greywacke as the dominant contributor followed by shale.  相似文献   

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