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1.
Marine Isotope Stage (MIS) 11 palaeoclimate has so far been documented in marine and ice sheet isotopic records. However, excepting some lacustrine pollen records, very little is known about palaeoclimatic conditions in continental areas. This study uses geochemical records in calcareous tufa deposits from rivers as a basis for reconstructing temperate palaeoclimatic conditions. Tufa deposits are now proven to record high‐quality palaeoclimatic information in recent to Holocene deposits. Work on older interglacial tufas is just starting and in this paper we present the first comprehensive results from a MIS 11 tufa. The tufa comes from the Seine Valley (La Celle, northern France). Geochemical data in the tufa calcite are interpreted to record primarily air temperature (δ18O) and humidity (δ13C and Mg/Ca and Sr/Ca). The combined data identify a warm and wet climatic optimum followed by two temperature decreases associated with oscillations in humidity. These marked climatic variations recorded through the La Celle profile are strongly coherent with the palaeoenvironmental reconstructions from malacological data. The abrupt climatic and environmental events recorded could be related to short‐term degradation of vegetation cover in Europe, which is itself controlled by global palaeoclimatic events. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

2.
《Quaternary Science Reviews》2004,23(7-8):947-958
High-resolution chronologies in continental carbonate deposits such as tufas are required for detailed palaeoclimatic and environmental studies. This work set out to establish if high-resolution U-series dating of detritus-rich Holocene tufas is routinely possible. The study centres on a paludal Holocene tufa from southern England that already has an existing Holocene chronology, based on 14C and supported by biostratigraphy, against which to compare U-series dates. The results show that significant detrital contamination combined with low initial U concentrations, and short time for ingrowth of radiogenic 230Th make high-resolution U-series dating of Holocene tufa very difficult. Moreover, a single (230Th/232Th)initial value to correct for the presence of detrital 230Th is not appropriate at the study site, a finding that may apply to most Holocene tufas. Total sample dissolution of coeval samples demonstrates considerable variability in the isotopic composition of the detritus. The total sample dissolution data are too scattered to constrain chronologies at the required resolution and may indicate the incorporation of a 230Th-rich component in the detritus.  相似文献   

3.
Combined stable isotope (δ18O and δ13C) and trace element (Mg, Sr) geochemistry from bulk tufa calcite and ostracod shell calcite from an early Holocene British tufa reveal clear records of Holocene palaeoclimatic change. Variation in δ18O is caused principally by change in the isotopic composition of Holocene rainfall (recharge), itself caused mainly by change in air temperature. The δ13C variability through much of the deposit reflects increasing influence of soil‐zone CO2, owing to progressive woodland soil development. Bulk tufa Mg/Ca and Sr/Ca are controlled by their concentrations in the spring water. Importantly, Mg/Ca ratios are not related to δ18O values and thus show no temperature dependence. First‐order sympathetic relationships between δ13C values and Mg/Ca and Sr/Ca are controlled by aquifer processes (residence times, CO2 degassing and calcite dissolution/reprecipitation) and probably record intensity of palaeorainfall (recharge) effects. Stable isotope records from ostracod shells show evidence of vital effects relative to bulk tufa data. The ostracod isotopic records are markedly ‘spiky’ because the ostracods record ‘snapshots’ of relatively short duration (years), whereas the bulk tufa samples record averages of longer time periods, probably decades. The δ18O record appears to show early Holocene warming, a thermal maximum at ca. 8900 cal. yr BP and the global 8200 yr BP cold event. Combined δ13C, Mg/Ca and Sr/Ca data suggest that early Holocene warming was accompanied by decreasing rainfall intensity. The Mg/Ca data suggest that the 8200 yr BP cold event was also dry. Warmer and wetter conditions were re‐established after the 8200 yr BP cold event until the top of the preserved tufa sequence at ca. 7100 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

4.
Freshwater carbonates (tufas) develop today from the Arctic to the tropics, many being localized about springs and upper water courses. Some Quaternary tufas, especially in the Mediterranean region, extend over tens of square kilometres and exceed 30 m in thickness. Radiometric dating of Holocene deposits shows that many have accumulated at an average rate of 1 mm year?1. However, local precipitation may be much faster and some Holocene deposits may even have outpaced their tropical marine carbonate counterparts. Recently, the study of active sites has attempted to quantify the precipitation mechanisms which lead to tufa deposition. However, field observation and sampling procedures suffer from the inherent disadvantages of uncontrolled fluctuations in environmental conditions during the study programme. These disadvantages compromise any interpretations, particularly where controls on spar versus micrite precipitation are concerned. Many of these problems have been overcome in the current study by the construction and operation of laboratory mesocosm flumes which simulate the natural conditions (e.g. pH, flow rate, ambient temperature and daylight) in which freshwater carbonate (tufa) is deposited. Three mesocosms were supplied with natural river water from tufa precipitating streams and two mesocosms were supplied with UV‐treated (sterile) river water from the same source. One of the untreated flume mesocosms was linked with a calcium reactor, which replaced calcium ions removed during the precipitation process in order to maintain tufa growth over extended experimental runs. Low‐magnesium calcite precipitates (both rhombic sparite grown from long‐crystallite dendrites and short‐crystallite dendrite triad precursors) and micrite peloids (grown from spherulitic precursors) were precipitated in intimate association with biofilm (extracellular polymeric substances) within the four mesocosms supplied with natural river water. Virtually, no tufa‐like precipitate was obtained from the flumes supplied with UV‐treated river water. A second extended run flume experiment was also carried out for comparison purposes using a calcium hydroxide solution in deionized water. Collectively, these experiments provide convincing evidence confirming that the presence of a microbial biofilm strongly influences the precipitation of carbonates in riverine freshwater settings. In particular, experimental results show that micro‐peloidal micrite and short‐crystallite calcite dendrites are only produced in the presence of microbial extracellular polymeric substances.  相似文献   

5.
The effect of changing palaeoclimate and palaeoenvironment on human evolution during the Pleistocene is debated, but hampered by few East African records directly associated with archaeological sites prior to the Last Glacial Maximum. Middle to Late Pleistocene deposits on the shoreline of eastern Lake Victoria preserve abundant vertebrate fossils and Middle Stone Age arte‐facts associated with riverine tufas at the base of the deposits, which are ideal for palaeoenvironmental reconstructions. New data from tufas identified on Rusinga Island and on the mainland near Karungu, Kenya are provided from outcrop, thin sections, mineralogical, stable isotopic and U‐series dating analyses. Tufa is identified in four sites: Nyamita (94·0 ± 3·3 and 111·4 ± 4·2 ka); Kisaaka, Aringo (455 ± 45 ka); and Obware. The age ranges of these tufa deposits demonstrate that spring‐fed rivers were a recurrent, variably preserved feature on the Pleistocene landscape for ca 360 kyr. Poor sorting of clastic facies from all sites indicates flashy, ephemeral discharge, but these facies are commonly associated with barrage tufas, paludal environments with δ13C values of ca 10‰ indicative of C3 plants and fossil Hippopotamus, all of which indicate a perennial water source. Other tufa deposits from Nyamita, Obware and Aringo have a mixed C3/C4 signature consistent with a semi‐arid C4 grassland surrounding these spring‐fed rivers. The δ18O values of tufa from Nyamita are on average ca 1‰ more negative than calcite precipitated from modern rainfall in the region, suggesting greater contribution of depleted monsoonal input, similar to the Last Glacial Maximum. Microdebitage and surface‐collected artefacts indicate that early modern humans were utilizing these spring‐fed rivers. The presence of spring?fed rivers would have afforded animals a reliable water source, sustaining a diverse plant and animal community in an otherwise arid environment.  相似文献   

6.
Three Holocene tufas from Gran Canaria volcanic island were studied with the aim of deciphering their sedimentary evolution through space and time. Las Temisas tufa (south-eastern arid part of the island) is dominantly composed of oncoids, intraclasts, phytoclasts, coated stems, minor thin stromatolites, and a high amount of siliciclastics. It was deposited in a fluvial system with variable flow velocities and palustrine conditions areas, which alternated with high energy events. Azuaje tufa (northern humid part of the island) is composed of coated stems, stromatolites, oncoids and phytoclasts, with relatively low amounts of siliciclastics, suggesting slow-flowing and palustrine conditions and a relatively low incidence of (high energy) floodings. Los Berrazales tufa (north-west of Gran Ganaria, the most humid one), is mainly composed of coated stems and crystalline crusts, formed in a laminar flow regime. Dominant clastic sedimentation in Las Temisas and high calcite growth rates in Los Berrazales led to a poor development of stromatolites in comparison with Azuaje. Las Temisas and Azuaje deposits have similar upward evolution with decreasing trend in siliciclastics and increasing trend in carbonates. However, Las Temisas has higher siliciclastic and lower phytoclastic contents suggesting a less vegetated area and more arid climate than in the other deposits. Additionally, tufas record local events common in volcanic terrains. Azuaje presents three units bounded by erosive discontinuities, which reveal significant erosion by enhanced runoff that could be caused by loss of vegetation due to wildfires related to volcanic eruptions at headwaters. Las Temisas record a possible interruption in sedimentation represented by aligned boulders due to rockfalls from the hillsides. These deposits formed from waters with similar chemistry providing to the carbonates their similar signals in δ13C–δ18O stable isotopes and 87Sr/86Sr ratios like that of the volcanic rocks. This work shows how, in volcanic areas, tufas are unique archives of the climate, vegetation and volcanic-related processes, because all imprint the sedimentary regime of tufa deposition.  相似文献   

7.
Pedley  Hill  Denton  & Brasington 《Sedimentology》2000,47(3):721-737
Unlithified and partly lithified carbonate sequences are ideally suited to the application of ground‐penetrating radar (GPR), augmented by percussion augering and shallow seismic techniques, all tied to present‐day topography using global positioning system (GPS) methods. This methodology provides the first clear information on the distribution and geometry of lithofacies within buried tufa complexes. The approach has been applied to a thick succession of Holocene tufas filling a gorge site along a 3·5‐km length of the River Lathkill, north Derbyshire. Earlier studies have demonstrated the presence of up to 16 m of tufas and sapropels associated with two transverse tufa dams (barrages). These strata have been accumulating throughout the Holocene, although tufa developments at present are of minor extent. Internal tufa morphologies are recorded by GPR as ‘bright’, laterally continuous reflections for lithified, concretionary and lithoclast‐rich horizons. The ‘brightest’ reflectors occur within well‐cemented barrages and delineate core areas and prograding buttress zones. In contrast, unlithified lime muds and sapropels produce low‐contrast reflections. Lithostratigraphic control and depth calibration of the GPR profiles was provided by percussion augering at selected sites. Six distinct lithofacies and four secondary barrages are identified in the study. Constructional and destructional events can be identified and correlated within the GPR profile network, and the internal growth morphologies of the barrages are apparent. GPR profiles also clearly define the evolution of the facies geometries. Three phases of tufa development can be recognized within the GPR data and greatly extend our understanding of Holocene tufa‐forming processes in valley sites: (a) Early Holocene barrage build‐ups but with limited paludal deposition; (b) Middle Holocene ponding and sapropel accumulation under ‘warm’ conditions; and (c) Late Holocene barrage termination and valley levelling, probably coincidental with anthropogenic activity. This type of multidisciplinary approach should be considered as an essential prerequisite to all biostratigraphic and geochemical studies of Holocene freshwater carbonate sites.  相似文献   

8.
We present a continuous ∼14-yr-long (1985 to 1999) high-resolution record of trace element (Mg, Sr, Ba, U) and stable isotope (δ13C, δ18O) variations in a modern freshwater tufa from northwestern Queensland, Australia. By utilizing the temperature dependence of the δ18O signal, an accurate chronology was developed for the sampled profile, which allowed a comparison of the chemical records with hydrological and meteorological observations. As a consequence, it was possible to constrain the relevant geochemical processes relating climate variables, such as temperature and precipitation, to their chemical proxies in the tufa record. Temperatures calculated from the Mg concentrations of the tufa samples provide close approximations of average annual water temperature variations. Furthermore, we demonstrate that temporal changes in (Mg/Ca)water can be estimated using an empirically derived equation relating (Mg/Ca)water to the (Sr/Ba) ratio measured in the tufa samples. By means of this relationship, it is theoretically possible to determine the (Mg/Ca) ratio of paleowaters, and hence to derive reliable estimates of former water temperatures from the Mg concentrations of fossil tufas from the study area. Sympathetic variations in Sr, Ba, and δ13C along the sampled profile record changes in water chemistry, which are most probably caused by variable amounts of calcite precipitation within the vadose zone of the karst aquifer. This process is thought to be markedly subdued whenever the amount of wet-season precipitation exceeds a given threshold. Accordingly, distinct minima in Sr, Ba, and δ13C are interpreted to reflect years with above-average rainfall. The pronounced seasonal and annual variability of the U concentration along the profile is thought to primarily record changes in the U flux from the soil to the water table. We suggest that during intensive rain events U is transported to the phreatic zone by complexing organic colloids, giving rise to conspicuous U maxima in the tufa after above-average wet seasons. This study demonstrates the potential of freshwater tufas to provide valuable information on seasonal temperature and rainfall variations. If tufa deposits turn out to be reasonably resistant to secondary processes, combined investigation of speleothems and tufas from the same area could become a promising approach in future research. While speleothems offer continuous records of long-term paleoenvironmental changes, tufas could provide high-resolution time windows into selected periods of the past.  相似文献   

9.
Tufas, which are freshwater carbonates, are potential archives of terrestrial paleoclimate. Time series of stable isotopic compositions commonly show regular seasonal patterns controlled by temperature-dependent processes, and some perturbation intrinsic to the locality. We examined three tufa-depositing sites in southwestern Japan with similar temperate climates, to understand the origin of local characteristics in the isotopic records. Seasonal change in the oxygen isotope is principally reflected by temperature-dependent fractionation between water and calcite but was perturbed after heavy rainfalls overwhelming the stability of the δ18O value of the groundwater at one site. Isotopic mass balance indicates an undersaturated and relatively small aquifer at this locality. Water δ18O values at the other two sites were stable, reflecting a regular seasonal change in the δ18O value of tufa. Perturbation of the δ13C values in tufa is largely due to CO2 degassing from the stream, which significantly increases the δ13C values of dissolved inorganic carbon (DIC). At a site with remarkably high pCO2 in springwater and a sensitive response of flow rate to rainfall, the amount of CO2 degassing changed distinctly with flow rate. In contrast, the other two sites having low pCO2 springwater reflect a regular seasonal pattern of δ13C in DIC and tufa specimens.  相似文献   

10.
Continental carbonates of Quaternary age in southern Italy commonly exhibit the facies of calcareous tufa, often reported as related to shallow aquifers fed by meteoric waters and to organic processes. A close spatial relationship exists between the mappable tufa deposits and major Quaternary extensional faults. With respect to the Ca‐Mg‐HCO3 composition of limestone aquifers’ springs, tufa‐depositing springs exhibit higher salinity and alkalinity, are slightly warmer, have lower pH and are enriched in SO4 and CO2. Their δ13C values are systematically positive and compatible with a deep‐seated carbon source. A clear input of soil‐derived organic carbon is indicated only for small, non‐mappable tufas deposited by perched springs. The dataset indicates that the large tufa deposits owe their origin to a supplementary source of CO2 advected by degassing through active faults, as a necessary prerequisite for inducing a rise of total dissolved salts and alkalinity. Meteoric waters that have come from a shallow aquifer are able to precipitate only limited amount of carbonates.  相似文献   

11.
The Urrea de Jalón tufa deposits constitute the 20‐ to 50‐m‐thick caprock (0·3 km2) of an isolated mesa. They disconformably overlie horizontal strata of the Tertiary Ebro Basin (NE Spain), which contains a thick succession of lacustrine gypsum and marls, followed by limestones, marls and, locally, fluvial sandstones and mudstones. The tufa deposits show a complex, large‐scale framework of basin‐like structures with centripetal dips that decrease progressively from the base to the top of the tufa succession, and beds that thicken towards the centre of the structure (cumulative wedge‐out systems). These geometries reveal that the tufa deposits were affected by differential synsedimentary subsidence. Distinct onlapping depressions reflect time migration of the subsiding areas. The studied carbonates are composed mostly of low‐Mg calcite, with minor quartz. Some samples have anomalously high contents of Fe, Mn and Ba that may exceed 1% (goethite, haematite and barite are present). Carbonate facies are: (a) macrophyte encrustation deposits; (b) bryophyte build‐ups; (c) oncolite and coated grain rudstones; (d) non‐concentric stromatolite‐like structures; (e) massive or bioturbated biomicrites; and (f) green and grey marls. Facies a and c show a great variety of microbial‐related forms. These facies can be arranged in dm‐ to 2‐m‐thick vertical associations representing: (i) fluvial–paludal sequences with bryophyte growths; (ii) pond‐influenced fluvial sequences; and (iii) lacustrine–palustrine sequences. The Urrea de Jalón tufa deposits formed in a fluvio‐lacustrine environment that received little alluvial sediment supply. Isotope compositions (δ13C and δ18O) reveal meteoric signatures and accord with such a hydrologically open system of fresh waters. The Fe, Mn and Ba contents suggest an additional supply of mineralized waters that could be related to springs. These would have been discharge points in the Ebro Depression of a regional aquifer of the Iberian Ranges. Rising groundwater caused the solution of the underlying evaporites and the synsedimentary subsidence of the tufa deposits.  相似文献   

12.
This paper investigates the stable isotopic composition from late Pleistocene–Holocene (~ 13 to ~ 10.5 cal ka BP) shells of the land snail Helix figulina, from Franchthi Cave (Greece). It explores the palaeoclimatic and palaeoenvironmental implications of the isotope palaeoecology of archaeological shells at the time of human occupation of the cave. Modern shells from around the cave were also analysed and their isotopic signatures compared with those of the archaeological shells. The carbon isotope composition of modern shells depicts the consumption of C3 vegetation. Shell oxygen isotopic values are consistent with other Mediterranean snail shells from coastal areas. Combining empirical linear regression and an evaporative model, the δ18Os suggest that modern snails in the study area are active during periods of higher relative humidity and lower rainfall δ18O, probably at night. Late glacial and early Holocene δ18Os show lower values compared to modern ones. Early Holocene δ18Os values likely track enhanced moisture and isotopic changes in the precipitation source. By contrast, lower late glacial δ18O could reflect lower temperatures and δ18Op, compared to the present day. Shell carbon isotope values indicate the presence of C3 vegetation as main source of carbon to late glacial and early Holocene snails.  相似文献   

13.
Outcrop‐scale geometries and bed relationships of ambient temperature freshwater carbonates are poorly understood because many described tufas have been dismantled by erosion and present only part of a particular depositional model. At the field scale, four end‐member models encompass the tufa continuum: (1) perched springline; (2) paludal; (3) fluvial; and (4) lacustrine tufas. Individual bed types can occur with variable dominance within several of these models, but one or more beds are characteristically dominant only within a single tufa model, so it can be differentiated from relatively isolated outcrop fragments. Two models (perched springline tufas and paludal tufas) are known in outline only in the literature despite being present within the Quaternary deposits of most karstic regions. Perched springline tufas generally form lobate, fan‐shaped mound morphologies on hillslopes and develop from single or multiple spring resurgences. Mature deposits show a subhorizontal top and a steep face on the downflow side. The steep outer zones of tufa mounds may be developed into cascades with moss curtains or can be dominated by shallow rimstone pools according to face angle. Tufa deposits lying downslope of the mounds are usually detrital in nature, especially if some dismantling of the mound has occurred. The relatively thin subhorizontal lobe‐top deposits commonly contain organic‐rich deposits. Paludal tufas develop predominantly in waterlogged valley bottom situations, where line‐sourced waters emerge from valley side and bottom aquifers. Lime mud precipitation predominates in these sites. Mud is deposited as subhorizontal laminites that thin towards the valley axis and downstream of resurgences. Tufa spring‐mounds may form where lesser volumes of water are involved. Individual tussocks (phytoherm cushions) of grasses and rushes are the most diagnostic feature of the model, but sapropels and peats may be intercalated. Diagenesis in both models is rapid. Lithification of individual beds is virtually instantaneous and always occurs before the decay of the associated living vegetation. The resulting highly porous and permeable fabrics remain fresh in Holocene tufas, but aggrading neomorphism and partial spar infill of vegetation moulds is common in older deposits. Dissolution in many perched springline tufas is small scale. Many large cavities are primary, but with later coatings of speleothems. Early removal of organics from paludal tufas is responsible for autobrecciation and differential compaction.  相似文献   

14.
对山西娘子关绵河不同阶地上沉积的泉钙华进行了高精度的230Th定年和碳氧稳定同位素组成测定。结果发现,绵河II级阶地沉积的娘子关泉钙华的最老年龄在407～466ka,远老于早前通过钙华中的石英砂热发光法(TL)获得的年龄,即绵河II级阶地上的娘子关泉钙华是在中更新世MIS12/11阶段形成的,而非原来认为的是晚更新世的产物。由此推测,绵河III级阶地娘子关泉钙华形成的年代更早,可能是中更新世的MIS14/13阶段。230Th测年获得的绵河I级阶地顶部的钙华形成于5ka前,即是在全新世中期以前形成的。结合钙华规模及其碳氧稳定同位素组成分析进一步发现,上述绵河三级阶地上的娘子关泉钙华均主要是湿热气候下的产物。然而,自II级阶地钙华形成至今,气候总体上在向干冷方向发展,泉域植被则呈现退化的趋势。  相似文献   

15.
Purbeckian (lowermost Cretaceous) peritidal carbonates are characterized by open marine, lagoonal, intertidal and lacustrine facies arranged in Milankovitch-type shallowing upward sequences. Shallowing upward sequences typically consist of 2–6 individual beds. The sequences may be (i) complete, (ii) incomplete or (ii) pedogenetically overprinted, reflecting the duration of subaerial exposure and/or the extent of erosion and pedogenetic modification at the cycle tops. The stable isotopic composition of the peritidal micrites reveals homogenous δ18O values attributed to diagenetic stabilization in a meteoric, water-buffered system. Carbon isotopes show three distinctly different carbon isotope patterns dependent on the completeness of the shallowing upward sequences. Complete shallowing upward sequences consist of 4–6 individual carbonate beds. The carbon isotope values show a facies-dependent pattern: open marine carbonate muds record enriched δ13C values of +0·28‰ while lagoonal (−0·82‰), intertidal (−2·46‰) and lacustrine micrites (−2·96‰) are increasingly depleted. This distinct pattern is explained by carbonate mud deposition in environments of differing salinity and marine influence. Incomplete sequences (2–5 carbonate beds) are characterized by depleted δ13C values below subaerial exposure surfaces that become progressively enriched in 13C with increasing depth. Pedogenetically overprinted sequences (1–3 carbonate beds) show strong 13C depletion throughout the sequence with little variation in the carbon isotopic composition. The depleted values (−4·5‰) of the pedogenetically altered micrites suggest that modification during subaerial exposure was associated with equilibration with meteoric solutions enriched in isotopically light soil gas CO2. The duration of subaerial exposure is the most crucial factor determining the extent of pedogenetic alterations, the completeness of the shallowing upward sequences and the carbon isotope pattern. The recorded patterns clearly illustrate that micrites have a good potential for the preservation of their primary carbon isotopic composition if the duration of subaerial exposure is rather brief. Otherwise, the recorded carbon isotope patterns may support sequence stratigraphic analysis by providing a refinement of the time-stratigraphic interpretation.  相似文献   

16.
Stable carbon isotope analysis of terrestrial plant leaves preserved in Quaternary lake sediments has the potential to provide high‐resolution reconstructions of past climatic conditions. Preferably, δ13C measurements should be made on a single leaf component, e.g. cellulose, but this approach is often precluded by limited leaf availability. Previous work suggests that reliable palaeoclimatic information also may be derived from δ13C measurements on whole‐leaf tissue, given a similar degree of leaf decomposition between samples. Leaf δ13C data for 12 Scandinavian species of dwarf‐shrubs, shrubs and trees, and a comparison of δ13C data on recent and late Holocene Salix herbacea leaves, revealed that the δ13C signal registered by holocellulose is largely reflected by measurements on whole‐leaf tissue. Holocellulose was found to be consistently enriched in 13C, although this δ13C offset was smaller for subfossil leaves. This supports the use of δ13C measurements on whole‐leaf tissue for climate reconstruction, at least for leaves preserved in soft, late Holocene sediments with minimal diagenetic effects. Leaf carbon and nitrogen data on fresh leaves of the same 12 Scandinavian species, and corresponding data on late Holocene Salix herbacea leaves, suggest that the leaf C:N ratio is a suitable indicator of the degree of leaf decomposition. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

17.
The PU‐2 stalagmite from Ursilor Cave provides the first dated Romanian isotope record for the Holocene. The overall growth rate of the speleothem was 3.5 cm kyr?1, corresponding to a temporal resolution of 142 y between each isotope analysis. The ‘Hendy’ tests indicate that isotopic equilibrium conditions occurred during the formation of PU‐2, and hence that it is suitable for palaeoclimatic studies. The relationship between δ18O and temperature was found to be positive. This can be interpreted either as rain‐out with distance from the west‐northwest ocean source of evaporation or shifts in air mass source with changing North Atlantic Oscillation indices. Applying five U–Th thermal ionisation mass spectrometric (TIMS) dates to a 17.5 cm isotope profile (δ18O and δ13C) along the stalagmite growth axis enabled a tentative interpretation of the palaeoclimate signal over the past 7.1 kyr. Spikes of depleted isotopic δ18O values are centred near ca. 7, ca. 5.2 and ca. 4 ka, reflecting cool conditions. The record shows two warm intervals between ca. 3.8 and ca. 3.2 ka (the maximum warmth) and from ca. 2 to ca. 1.4 ka, when the δ18O values were less negative than present. The ‘Holocene Climate Optimum’ spanning the time interval from ca. 6.8 to ca. 4.4 ka is not well expressed in the PU‐2 stalagmite. Individual spikes of lighter δ13C are interpreted as indicative of periods of heavy rainfall, at ca. 7, ca. 5.5, and ca. 3.5 ka. The overall trend to lighter δ13C in the PU‐2 stalagmite may reflect a gradual decrease in water–rock interaction. The results demonstrate that the effect of North Atlantic oceanic changes extended to the investigated area. Nevertheless, some differences in temporal correlation and intensity of stable isotopic response to these climatic events have been found, but the exact nature of these differences and the underlying mechanism is yet to be determined. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

18.
《Applied Geochemistry》1999,14(1):119-131
The major source of methane (CH4) in subsurface sediments on the property of a former hazardous waste treatment facility was determined using isotopic analyses measured on CH4 and associated groundwater. The site, located on an earthen pier built into a shallow wetland lake, has had a history of waste disposal practices and is surrounded by landfills and other waste management facilities. Concentrations of CH4 up to 70% were found in the headspace gases of several piezometers screened at 3 different depths (ranging from 8 to 17 m) in lacustrine and glacial till deposits. Possible sources of the CH4 included a nearby landfill, organic wastes from previous impoundments and microbial gas derived from natural organic matter in the sediments.Isotopic analyses included δ13C, δD, 14C, and 3H on select CH4 samples and δD and δ18O on groundwater samples. Methane from the deepest glacial till and intermediate lacustrine deposits had δ13C values from −79 to −82‰, typical of natural “drift gas” generated by microbial CO2-reduction. The CH4 from the shallow lacustrine deposits had δ13C values from −63 to −76‰, interpreted as a mixture between CH4 generated by microbial fermentation and the CO2-reduction processes within the subsurface sediments. The δD values of all the CH4 samples were quite negative ranging from −272 to −299‰. Groundwater sampled from the deeper zones also showed quite negative δD values that explained the light δD observed for the CH4. Radiocarbon analyses of the CH4 showed decreasing 14C activity with depth, from a high of 58 pMC in the shallow sediments to 2 pMC in the deeper glacial till. The isotopic data indicated the majority of CH4 detected in the till deposits of this site was microbial CH4 generated from naturally buried organic matter within the subsurface sediments. However, the isotopic data of CH4 from the shallow piezometers was more variable and the possibility of some mixing with oxidized landfill CH4 could not be completely ruled out.  相似文献   

19.
Three types of recent carbonate precipitates from the River Krka, Croatia, were analysed: (1) bulk tufa from four main cascades in a 34 km long section of the river flow through the Krka National Park; (2) a laminar stromatolite‐like incrustation formed in the tunnel of a hydroelectric power plant close to the lowest cascade; and (3) recent precipitates collected on artificial substrates during winter, spring and summer periods. Stable isotope compositions of carbon (δ13C) and oxygen (δ18O) in the carbonate and organic carbon (δ13Corg) were determined and compared with δ18O of water and δ13C of dissolved inorganic carbon (DIC). The source of DIC, which provides C for tufa precipitation, was determined from the slope of the line ([DIC]/[DIC0]?1) vs. (δ13C‐DIC × ([DIC]/[DIC0])) ( Sayles & Curry, 1988 ). The δ13C value of added DIC was ?13·6‰, corresponding to the dissolution of CO2 with δ13C between ?19·5 and ?23·0‰ Vienna Pee Dee Belemnite (VPDB). The observed difference between the measured and calculated equilibrium temperature of precipitation of bulk tufa barriers indicates that the higher the water temperature, the larger the error in the estimated temperature of precipitation. This implies that the climatic signals may be valid only in tufas precipitated at lower and relatively stable temperatures. The laminar crust comprising a continuous record of the last 40 years of precipitation shows a consistent trend of increasing δ13C and decreasing δ18O. The lack of covariation between δ13C and δ18O indicates that precipitation of calcite was not kinetically controlled for either of the elements. δ13C and δ18O of precipitates collected on different artificial substrates show that surface characteristics both of substrates and colonizing biota play an important role in C and O isotope fractionation during carbonate precipitation.  相似文献   

20.
A multi-tracer approach has been carried out in the Sbeïtla multilayer aquifer system, central Tunisia, to investigate the geochemical evolution, the origin of groundwaters and their circulation patterns. It involves statistical data analysis coupled with the definition of the hydrochemical and isotopic features of the different groundwaters. Principal Components Analysis (PCA) of geochemical data used in conjunction with bivariate diagrams of major and trace elements indicate that groundwater mineralization is mainly controlled by water-rock interaction and anthropogenic processes in relation to return flow of irrigation waters. The PCA of isotopic data and bivariate conventional diagrams of stable and radiogenic isotopes i.e. δ18O vs. δ2H and δ18O vs. 14C provide valuable information about the origin and the circulation patterns of the different groundwater groups. They permit classifying groundwaters into three groups. The first group is characterized by low 3H concentrations, low 14C activities and depleted stable isotope contents. It corresponds to an old end-member in relation with palaeoclimatic recharge which occurred during the Late Pleistocene and the Early Holocene humid periods. The second group is distinguished by high to moderate 3H concentrations, high 14C activities and enriched heavy isotope signatures. It corresponds to a modern end-member originating from a mixture of post-nuclear and present-day recharge in relation to return flow of irrigation waters. The third group is characterized by an average composition of stable and radiogenic isotope signatures. It provides evidence for the mixing between the upward moving palaeoclimatic end-member and the downward moving present-day end-member.  相似文献   

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