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为研究山东蒙阴金伯利岩型金刚石晶体中氮片晶的分布特征,采用红外光谱仪对116粒宝石级金刚石晶体样品中的氮片晶进行分析,并采用微分干涉显微镜观察氮片晶在金刚石表面所具有的物理化学性质及其表面微细结构。结果表明,80.2%的金刚石样品中具有氮片晶;在个别浅褐色、八面体金刚石样品{111}面上观察到平行于[100]晶带方向的长条状蚀像,这些蚀像相互平行,大小不等。显微红外光谱对具长条状蚀像的金刚石样品{111}面的测试结果表明,该类晶体均具有较强的氮片晶的吸收峰（1359~1375cm-1）。综合浅褐色、八面体金刚石样品的红外光谱及其表面微形貌特征,推测长条状蚀像是由氮片晶的出露点受优先选择性腐蚀而致。 相似文献
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小秦岭金矿含金石英脉中黄铁矿晶体的表面微形貌研究 总被引：1，自引：0，他引：1
利用微分干涉显微镜、扫描电镜、透射电镜等对小秦岭金矿含金石英脉中黄铁矿晶体的表面微形貌进行了研究。黄铁矿晶体的{210}面上发育自由生长层，表明{210}面是F面，其生长机理受二维成核层生长所制约。除简单的五角十二面体外，其他形态黄铁矿晶体的{210}面上也发育有自由生长层。{210}面上的正条纹有些是由{100}面上生长层的边缘台阶在{210}面上叠堆形成，另一些正条纹则是{210}面上生长层边缘台阶堆叠的产物。透射电镜和电子衍射花样研究表明，负条纹黄铁矿晶体是由30～50nm大小的核团经自动定向附生作用形成，每个核团不是单晶体，而是由许多早先在溶液中形成的小微晶聚合而成。这些特征表明负条纹黄铁矿晶体是在溶液过饱和度极高和温度梯度小的理想环境中形成，它的形成与杂质无关。PBC理论和唐纳-哈克定律能较好地解释自然界中黄铁矿晶体{100}面上普遍发育自由生长层、而{210}面上自由生长层极为罕见的原因。除日本释迦内矿区黑矿之上的浮岩凝灰岩中产生出负条纹黄铁矿晶体外，在石英脉型金矿床中也有负条纹黄铁矿晶体产出。 相似文献
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天然金刚石同生位错的同步辐射X射线貌相研究 总被引：2，自引：0，他引：2
利用同步辐射白光透射貌相术研究了辽南天然金刚石的晶体缺陷。采用作者提出的计算晶体缺陷空间取向的方法计算了金刚石中位错的取向。晶体中所有位错均起源于晶核，并且柏氏矢量都平行于[1^-01]。多数位错并非位于{111}面内。位错所在晶面属于[1^-01]晶带，并且多数与{211}或{110}面近于平行。位错线平直，部分有拐折。所有位错均为混合位错。位错走向与生长面近于垂直，多数与＜111＞夹角较小。所有位错均为同生位错，形成后未发生滑移。晶核在形成期曾受到较大应力作用造成较大的晶格畸变。晶体内部未出现生长带，反映晶体成长过程中环境未发生大的变化。形成晶体的碳质来源不均一，反映了中元古代华北陆台下地壳岩浆成分的不均一性。 相似文献
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利用透射电子显微镜(TEM)系统观测了黄铁矿片、板状晶体的微结构,发现在水热条件下生成的黄铁矿片、板状晶体具有正方形、矩形等多种形貌。其中,正方形较多,矩形次之,另可见到一些其他不规则形状。黄铁矿片、板状晶生长完好,未见缺陷。经测定多数四边形片状黄铁矿的两组边分别平行(010)和(100),其生长晶面为(001);个别四边形片状黄铁矿的两组边分别平行(010)和(101),其生长晶面为(101),矩形片状黄铁矿长轴生长方向为001。在水热条件下黄铁矿以多形貌出现,黄铁矿的片、板状晶体多数是沿(001)面生长的结果,(001)为黄铁矿片、板状晶体的主要二维生长面,并沿001方向扩展,构成了二维晶体。 相似文献
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板状绿柱石产于花岗岩云英岩化边部或晶洞壁的白云母-钠长石-绿柱石-水晶的矿物组合中,钠长石呈自形晶,绿柱石的洁净度与透明度相对较差。晶体测量表明,晶体的单形晶面发育依次为c{0001}→s{11 2-1}→p{10 1-1}→m{10 1-0}→v{21 3-1}、n{45 9-4}、a{11 2-0}。微分干涉显微镜(DIC)及扫描电镜(SEM)研究表明:各单形晶面上生长纹(微形貌)反映面网结构的对称性,c{0001}单形晶面上的六边形溶蚀坑(50～170μm)是由平行晶体C轴的各单形晶面生长层从晶体中心向外叠堆组成,层生长机理制约晶体生长全过程,平行双面(c)的生长层较薄(5～8μm)且较稳定,六方双锥(s)生长层较厚且圆滑,六方柱(m)生长层由晶体中心往外其厚度由厚逐渐变薄(12～20μm),台间隔由窄变宽。晶体溶蚀是从面网密度最大的c{0001}开始,溶蚀面积依平行双面(c)、六方双锥(s)单形晶面由大变小,六方柱(a)、复六方双锥(v、n)单形晶面因面网密度小而未受到溶蚀。据矿物共生组合、流体包裹体均一法测量与拉曼光谱(LRS)分析表明板状绿柱石是在中–高温(303℃)、过饱和度较大、成矿介质的钠长石化发育且热动力环境相对稳定的条件下形成,气液包裹体主要由H2O、CO2及微量CH4、N2组成,CO2及微量CH4、N2可能与碳酸盐围岩有关。 相似文献
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粤北乐家湾锑矿床中辉锑矿特征 总被引：1，自引：0，他引：1
乐家湾锑矿床中辉锑矿在成分上表现出阴离子亏损,亏损量为0.067—0.080;晶胞参数α_0与形成温度呈很好的负相关;反射率Rg=37.81—48.11％、Rm=33.63—38.98％、Rp=25.97—30.39％,其非均质性在长波段变化较强;实测和理论计算的比重值近标准值上限;自然热发光出现两类发光峰,Ⅰ类位于163—200℃,另一类位220—227℃;δ~(34)S在-1.2—+1.0‰之间;晶体测量表明晶体均具有{010},{110}、(210}及{111}单形,未出现{okl}和{hol}单形,在其生长过程中,锥面单形数目逐渐减小且晶面指数由高到低变化。 相似文献
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Different diagenetic transformations and their relative chronological sequence are studied in the meteoric diagenetic zone from the Upper Oligocene limestone at the North of the Aquitaine Basin (France), by combining high-resolution cathodoluminescence spectroscopy and electron-microprobe analyses. More than 128 spot analyses by electron microprobe and 60 analyses by cathodoluminescence spectroscopy are done on different meteoric cements firstly identified by classic optical microscopy. Three cement types are identified according to the relative intensity of the bands of their respective cathodoluminescence spectra (350, 380, 430, 500, and 620 nm). From these investigations, we could identify for each meteoric cement different phases of crystalline growth and crystalline dissolution. As a result, a better and more realistic meteoric diagenetic model is proposed. It illustrates the cyclic transformations from vadose zone (unsaturated) to meteoric zone (saturated). To cite this article: R. Chapoulie et al., C. R. Geoscience 337 (2005). 相似文献
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早期形成的碳酸盐结核在埋藏期间会经历多种碳酸盐矿物相沉淀的复杂胶结作用,岩石学研究是探究结核成因的关键。通过野外剖面观察、岩石学观察和阴极发光技术,分析了鄂尔多斯盆地渭北地区上三叠统延长组长7油层组泥页岩中各种形状的方解石和白云石结核中自生碳酸盐矿物的特征。这些结核为成岩早期的产物,构成结核的自生碳酸盐矿物特征显著:(1)球粒方解石结核中,方解石呈纤维状或刃片状,球粒间充填晶粒方解石或因压实呈贴面结合,纤维状方解石发桔红色和暗红色2种光,刃片状方解石发暗红色光;(2)粉晶方解石结核中,方解石呈他形粒状,含有机质包裹体或纤维状晶形残余,晶间含沥青和纤维状方解石残余,主要发暗红色光;(3)白云石结核有泥晶和粉晶2种晶体类型,粉晶白云石结核含较多泥质,泥质条带或有机质条带处常见纤柱状白云石;(4)沿裂缝充填的方解石和白云石常呈纤维状或纤柱状结构,发暗红色光或不发光。研究区长7油层组碳酸盐结核中的方解石和白云石具有不同的成因类型和复杂的胶结作用:球粒方解石和泥晶白云石代表了结核开始形成时的胶结作用,可以准确地反映结核的成因;粉晶方解石、粉晶白云石反映了交代成因;裂缝中纤维状、纤柱状方解石和白云石集合体则为结核经历了较强压实作用之后充填裂缝而成。 相似文献
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Three main sets of deformation bands are identified in the Lower Pleistocene carbonate grainstones of Favignana Island (Italy). A bedding-parallel set is interpreted to contain compaction bands, based on the lack of evidence for shear. The other two sets are oriented at a high-angle to bedding, forming a conjugate pair comprised of compactive strike-slip shear bands. In this study, we focus on the compactive shear bands documenting their development, as well as analyzing their dimensional parameters and scaling relationships.Single compactive shear bands are thin, tabular zones with porosity less than the surrounding host rocks, and have thicknesses and displacements on the order of a few mm. The growth process for these structures involves localizing further deformation within zones of closely-spaced compactive shear bands and, possibly, along continuous slip surfaces within fault rocks overprinting older zones of bands. During growth, single bands, zones of bands and faults can interact and link, producing larger structures. The transitions from one growth step to another, which are controlled by changes in the deformation behavior (i.e. banding vs. faulting), are recorded by different values of the dimensional parameters for the structures (i.e. length, thickness and displacement). These transitions are also reflected by the ratios and distributions of the dimensional parameters. Considering the lesser porosity values of the structures with respect to the host rock, the results of this contribution could be helpful for mapping, assessing, and simulating carbonate grainstone reservoirs with similar structures. 相似文献
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《Sedimentary Geology》2006,183(3-4):261-268
Xenotime and zircon in heavy mineral separates of siliciclastic sediments can easily be distinguished by means of cathodoluminescence (CL). All shades of bright blue, yellow and grey to white colours have been reported for zircon while only bottle green to greenish yellow colours have been found in xenotime in heavy mineral separates of Lower Buntsandstein samples as well as in two samples from crystalline rocks from Bahia (Brazil) and the Karpaty Mts. (Slovakia). The CL-spectra of both minerals are commonly dominated by narrow emission bands of rare earth elements, especially Dy3+. The two different crystal lattices induce differences in the intensity ratios of the emission lines that are thought to be the reason for the different CL-colours. Additionally, intrinsic broad bands that may occur in the CL-spectra of zircon are missing in the xenotime spectra. The possibility to distinguish minerals with similar optical properties underlines the large potential of cathodoluminescence in sedimentary petrology. 相似文献
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Tine?Derez Tom?Van Der?Donck Oliver?Plümper Philippe?Muchez Gill?Pennock Martyn?R.?Drury Manuel?Sintubin
Fine extinction bands (FEBs) (also known as deformation lamellae) visible with polarized light microscopy in quartz consist of a range of nanostructures, inferring different formation processes. Previous transmission electron microscopy studies have shown that most FEB nanostructures in naturally deformed quartz are elongated subgrains formed by recovery of dislocation slip bands. Here we show that three types of FEB nanostructure occur in naturally deformed vein quartz from the low-grade metamorphic High-Ardenne slate belt (Belgium). Prismatic oriented FEBs are defined by bands of dislocation walls. Dauphiné twin boundaries present along the FEB boundaries probably formed after FEB formation. In an example of two sub-rhombohedral oriented FEBs, developed as two sets in one grain, the finer FEB set consists of elongated subgrains, similar to FEBs described in previous transmission electron microscopy studies. The second wider FEB set consists of bands with different dislocation density and fluid-inclusion content. The wider FEB set is interpreted as bands with different plastic strain associated with the primary growth banding of the vein quartz grain. The nanometre-scale fluid inclusions are interpreted to have formed from structurally bounded hydroxyl groups that moreover facilitated formation of the elongate subgrains. Larger fluid inclusions aligned along FEBs are explained by fluid-inclusion redistribution along dislocation cores. The prismatic FEB nanostructure and the relation between FEBs and growth bands have not been recognized before, although related structures have been reported in experimentally deformed quartz. 相似文献
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玛瑙是一种隐晶质硅质岩石,主要由玉髓以及少量蛋白石、斜硅石和微晶石英等组成.其在世界各地分布广泛,质地坚硬细腻、色彩鲜艳多样、纹理交错、造型千姿百态,是一种平凡而美丽的宝石.本文结合国内外最新研究进展,对玛瑙矿物的结构、水含量和成因机制进行了综合评述.玛瑙以纹带构造为特征,其内部纹带花纹和化学组成呈韵律性变化,并在不同观察尺度表征出来.因此,玛瑙也被定义为条带状玉髓.然而,多数玛瑙实际上是由纤维状玉髓、同心环带状玉髓、水平条带状玉髓、微晶石英和自形石英晶体等组成,它们的相对含量与玛瑙的产地和形成过程密切相关.X射线衍射和电子背散射衍射(EBSD)测量数据揭示,玛瑙中的硅质矿物多发生定向生长,其中微晶石英a轴倾向于垂直韵律环带,c轴则近似平行韵律环带.傅立叶变换红外光谱(FTIR)测量表明,玛瑙含有少量分子水和羟基水,并且总水含量随着硅质矿物结晶度提高而降低.至今实验室仍然无法合成玛瑙,还不清楚玛瑙纹带构造的形成机制和过程.一种代表性假设认为,玛瑙中的纹带源于硅质热液沉淀作用或者硅胶原位结晶作用.但是,最近研究发现玛瑙纹带中共生矿物的结晶度、晶体取向和含水量具有系统差异,揭示其形成过程可能与成岩序列密切相关.将实验岩石学与定量显微结构观察以及多种矿物微区分析测试手段有机结合,深入研究玛瑙环带内部微量元素、水含量和晶体取向数据,获得其系统性变化特征及其内部联系,可以为玛瑙成因机制和形成过程研究提供重要数据支撑和关键性的约束条件. 相似文献
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敦煌复合造山带前寒武纪地质体的组成和演化 总被引：3，自引：3，他引：0
敦煌复合造山带位于塔里木克拉通东端,是连接塔里木克拉通和华北克拉通的重要纽带。近年来,敦煌基础地质研究取得了重大进展。本文简要回顾了敦煌基础地质研究历史和现状,系统归纳了区内前寒武纪地质单元时空分布特征及前寒武纪构造-热事件序列,初步讨论了前寒武纪大陆地壳形成和演化规律、前寒武纪结晶基底亲缘性及构造演化过程,提出:(1)敦煌造山带前寒武纪结晶基底形成于ca.3.1~1.6Ga,构造-热事件主要划分为新太古代(ca.2.7~2.6Ga和2.6~2.5Ga)、古元古代晚期(ca.2.0~1.8Ga)和中元古代早期(1.8~1.6Ga)三个阶段;(2)新太古代早期(ca.2.7~2.6Ga)和新太古代晚期(2.6~2.5Ga)是敦煌造山带大陆地壳形成的主要阶段;古元古代晚期(ca.2.0~1.8Ga)和中元古代早期(1.8~1.6Ga)主要是古老大陆地壳物质再循环阶段,也有少量新生陆壳物质的形成;(3)敦煌造山带前寒武纪结晶基底最初拼合事件可能发生在新太古代末期(~2.5Ga),之后经历了古元古代晚期(ca.2.0~1.8Ga)汇聚、碰撞造山过程,直到中元古代早期(1.8~1.6Ga),造山活动结束,前寒武纪结晶基底最终固结,进入稳定发展阶段;(4)前寒武纪结晶基底最终稳定固结之后,即～1.6Ga之后,敦煌前寒武纪结晶基底可能进入长达12亿年的静寂期,一直处于稳定状态,目前没有发现相关的岩浆-变质-沉积记录(类似于地盾状态),直至古生代志留纪开始活化(～440Ma),卷入古亚洲洋南缘俯冲、碰撞造山过程并被强烈改造。 相似文献
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Hartmut Schneider 《Contributions to Mineralogy and Petrology》1972,37(1):75-85
Mechanical deformation features in shocked biotites from crystalline rocks of the Ries crater are: kink bands, planar elements, and plastic lattice deformations as determined by X-ray investigations.Kink bands can be observed in micas of various pressure histories (stages 0, I, II and less frequently stage III of shock metamorphism). Kink bands in shocked micas are less symmetrical than kinks of static origin. Asymmetry increases with increasing dynamic pressures. Moreover, kink band width is sensitive against changing peak pressures. Distribution of kinked and undistorted micas within a rock permits to fix the shock front direction. Shock-induced kinks in micas are produced by various gliding processes in the cleavage plane (001).Planar elements seldom occur in biotites of shock stages II and III and have never been described in endogenic rocks. Up to now orientations of planar elements parallel to (111), (1¯11), (112) and (11¯2) have been determined. Planar elements are interpreted as planes of plastic lattice gliding. {[110]} is supposed to be the main gliding direction. In the same pressure region other plastic lattice deformations have been determined. They are orientated parallel to (001), (100) and (¯132) or (201) which results from single crystal X-ray investigations and may represent planes of plastic lattice gliding. The dependency of formation of gliding planes and gliding directions on increasing dynamic pressures will be discussed. 相似文献
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浅层包气带水汽昼夜运移规律及其数值模拟研究 总被引：3，自引：0，他引：3
西北干旱、半干旱地区,浅层包气带水分通量主要由水汽组成,而水汽在运移过程中产生的能量转换和质量迁移是地表质能平衡计算不可缺少的重要源汇项。在野外进行一个沙坑实验,发现土壤水在中午(12:00—15:00)达到最大值(10cm深度,5.9~6.1cm3/cm3;30cm深度,11.9~13.1cm3/cm3),而在凌晨(02:00—05:00)出现最小值(10cm深度,4.4~4.5cm3/cm3;30cm深度,10.4~10.8cm3/cm3)。为进一步验证该实验条件下的土壤水运移及分布规律,考虑了土壤水、汽、热耦合运移的HYDRUS-1D模型被用来对实验过程进行模拟,模拟结果与实测结果吻合较好。为描述土壤水分昼夜运移模式,笔者将土壤水耦合运移的时间信息和空间信息进行同步分析;并根据土壤水运移的不同驱动力,分别对温度梯度、基质势梯度作用下的液态水及汽态水通量进行了分析。 相似文献
20.
塔河油田溶洞巨晶方解石充填物的微量元素、碳、氧、锶同位素地球化学和流体包裹体的对比研究表明,不同井位巨晶方解石可能来源于不同的流体体系。T417井和S76井鹰山组、T904井一间房组及TS1井丘里塔格组溶洞巨晶方解石样品具有富U、高V/Cr特征,且均一温度主要分布于148.9～169.9 ℃,相对围岩所经历最高温度约20 ℃,反映为还原性的热液流体体系,该流体具有高 87Sr/86Sr及低 δ18O 的特征。T904井良里塔格组巨晶方解石具有贫U、低V/Cr及均一温度较低的特征（75～81 ℃）,反映为富氧低温流体体系,结合样品的高 87Sr/86Sr及低 δ18O特征,可以推测该低温流体可能为大气水来源。热液流体与大气淡水的运移受断层、裂缝和不整合面等因素控制,从而使得不同井位、层位的巨晶方解石沉淀时具有不同的流体成分与温度特征。
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