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1.
松辽盆地庆深气田异常氢同位素组成成因研究 总被引：2，自引：0，他引：2
对松辽盆地徐家围子断陷庆深气田天然气组分、碳氢同位素和稀有气体同位素的分析表明,天然气以烷烃气为主,烷烃气碳同位素组成随着碳数增加呈变轻趋势,且δ13C1＆gt;-30‰, R/Ra一般大于1.0,δ13CCO2值介于-16.5‰~-5.1‰之间;氢同位素组成δD1=-205‰~-197‰,平均值为-203‰,δD2=-247‰~-160‰,平均值为-195‰,δD3=-237‰~-126‰,平均值为-163‰,且存在氢同位素组成倒转现象,即δD1＆gt;δD2＆lt;δD3。根据对庆深气田天然气不同地球化学特征分析,认为该气田烷烃气中重烃主要为有机成因,而 CH4有相当无机成因混入。庆深气田烷烃气氢同位素组成具有 CH4变化小,而重烃（δD2,δD3）变化大的特点。根据与朝阳沟地区天然气烷烃气氢同位素组成对比分析,认为 CH4主要表现为无机成因,而重烃气（δD2,δD3）主要为有机成因,且无机成因CH4氢同位素组成重于有机成因CH4。 相似文献
2.
川东北飞仙关组鲕滩天然气地球化学特征与成因 总被引：29，自引：3，他引：26
四川盆地东北部下三叠统飞仙关组鲕滩气藏天然气烃类气体以甲烷为主,含量主要分布在75%～90%之间,C2 含量很少,为0%～0.15%,干燥系数为0.997 0～0.999 8,是典型的干气;非烃气体以H2S和CO2为主,含量分别为4.21%～16.24%和0.97%～10.41%.天然气δ13C1值为-29.0‰～-31.5‰,δ13C2值为-29.4‰～-32.4‰.多参数表明鲕滩气藏天然气是以腐泥型为主的高过成熟天然气.高含H2S的天然气分布区域与含石膏地层分布基本一致,这些H2S为飞仙关组气藏附近的石膏经热化学硫酸盐还原作用(TSR)而生成,CO2是其主要的副产物.在TSR过程中,C2 重烃气体比甲烷更容易与硫酸盐发生反应,也就是C2 重烃气体的消耗速率大于甲烷,从而导致发生TSR反应的天然气C2 含量低、H2S和CO2含量高.天然气δ13C1值与甲烷含量之间具有很好的负相关关系,而与天然气酸性系数[H2S/(H2S CnH2n 2)]具有正相关关系.根据同位素动力学的分馏效应,随着TSR的进行,烃类分子中的12C损耗速率大于13C,残留下来的烃类分子中则更加富集13C,也就是TSR反应使天然气碳同位素变重. 相似文献
3.
苏里格气田是鄂尔多斯盆地上古生界内发现的大型岩性气藏。天然气中甲烷占绝对优势,干燥系数低,为湿气。灭然气的单体碳同位素具有碳数越高,同位素越审的特点,且正构烷烃碳同位素具有δ^13C1〈δ^13C3〈δ^13C2〈δ^13C4的规律。甲烷碳同位素与甲烷含量旱正相关,与乙烷含量为负相关。根据天然气单体碳同值素及其含垣变化,认为苏里格天然气属煤成气。天然气中含少量CO2气,多为有机成因。苏里格气田二叠系气藏的形成与演化可划分为石炭一二叠纪至中侏罗世气源岩沉积埋藏阶段、晚侏岁世至白垩纪天然气形成阶段和第三纪至现今的保存改造阶段。 相似文献
4.
依据10余口探井60多个气样的化学成份和碳同位素组成数据,结合烃源岩和储层沥青分析资料,系统剖析了四川盆地东部宣汉地区普光、毛坝场等构造带天然气地球化学特征,并探讨了其成因及来源。研究结果表明:这些构造带中飞仙关组—长兴组天然气为高含硫化氢的干气,天然气化学成份表现出古油藏原油裂解气的特点。其烃类气体中以甲烷为主(高于99.5%);富含非烃气体,CO2和H2S平均含量分别达5.32%和11.95%。甲烷碳同位素较重(-33‰～-29‰),表征高热演化性质;乙烷δ13C值主要分布在-33‰至-28‰范围,属油型气。这些天然气与川东邻近气田的同层位天然气具有同源性,而与石炭系气藏天然气在化学成份、碳同位素组成上有所不同,意味着有不同的气源。硫化物硫同位素和沥青元素组成证实高含量的H2S是气藏发生TSR作用所致。δ34S值表征层状沉积成因的硬石膏是TSR作用的反应物,而脉状硬石膏则是其残余物。储层的孔隙类型可能与TSR作用强度和H2S含量高低有联系,裂缝型气层中H2S少,孔洞型储层中H2S丰富。乙烷、沥青和各层系烃源岩干酪根碳同位素对比表明研究区飞仙关组—长兴组气藏天然气主要来自二叠系烃源层。 相似文献
5.
通过对松南气田营城组与登楼库组火山岩天然气的组成、碳同位素及惰性气体同位素特征分析,天然气烃类组成以甲烷为主,含极少量重烃,干燥系数均在0.99左右,为干气;天然气中CO2含量高,在-20.74%~-25.75%之间,为高含CO2的天然气藏;天然气甲烷同位素偏重为-18.3‰~-26.5‰,并且有δ13C1δ13C2δ13C3负碳同位素序列,表明有无机成因烃类气体混合的特征,营城组的CO2同位素表明为幔源无机成因气,3He/4He的比值高,介于壳源成因与幔源成因之间,也表明有幔源3He/4He的输入,多种参数表明松南地区天然气的有幔源成因的甲烷,也有煤系地层生成的煤型气,营城组的CO2为幔源成因,为煤幔混合气。通过模拟计算,松南气田深层天然气幔源成因的烃类气体占40.62%~100%。煤系成因来源为0~59.38%,加之20%左右的CO2气体均为无机幔源成因,因此该区天然气主要为无机幔源成因的天然气。 相似文献
6.
煤成甲烷、乙烷碳同位素动力学研究和应用--以鄂尔多斯盆地上古生界煤成气为例 总被引：10，自引：0，他引：10
同位素动力学模型的发展和应用使天然气的研究工作进入了一个动态的研究阶段。迄今为止,大多数研究工作集中在甲烷的碳同位素动力学模拟。而少有地球化学家对乙烷及其他重烃气组分的碳同位素组成的动力学模拟加以重视。本文在甲烷碳同位素动力学模型基础上,编制了限定体系下乙烷的同位素动力学模拟软件。并在热解模拟实验的基础上对鄂尔多斯盆地上古生界煤成气甲烷、乙烷的同位素演化进行了模拟,获得长期累积甲烷、乙烷的同位素值分别为δ^1C1=-33．46‰3、δ^13C2=-23．1‰,与上古生界储层中天然气的组分特征（δ^13C1=-32．95％。、δ^13C2=-23．41‰）基本一致,与下古生界天然气的同位素组成存在着明显的差别,说明上古生界煤与上古生界天然气存在着源—气的对应关系;而对下古生界天然气来说,上古生界煤系不是主要的气源岩。 相似文献
7.
针对三塘湖盆地的主力烃源岩二叠系芦草沟组泥质烃源岩开展封闭体系和半开放体系热模拟实验,前者将干酪根密封在金管中开展实验、后者直接对烃源岩样品进行压机半开放体系热解模拟,对实验中生成气体的组分和稳定碳同位素进行分析。实验结果显示,两种热解方法以无机气体生成为主,包括CO2、H2、H2S 和 N2等,其中 CO2含量最丰富,这与样品干酪根中丰富的氧含量一致。半开放体系模拟实验温度达到480℃时,气态烃的含量达40.64%,其中甲烷含量达到26.10%,封闭体系中随着模拟温度升高烃类气体产物的碳同位素呈现先变轻后变重的趋势,但同位素分馏程度不大, CH4气体的δ13C 值分布在-40.2‰~-46.6‰之间, C2H6分布在-34.3‰~-38.0‰之间, C3H8分布在-33.6‰~-36.0‰之间,而CO2气体δ13C值分布在-32.8‰~-28.8‰之间。三塘湖盆地针对气藏的勘探已经有所发现,但有关气藏的地球化学特征报道较少,该工作中的模拟实验结果可为三塘湖盆地深入的气藏地球化学勘探提供基础数据。 相似文献
8.
对北黄海盆地LV井中、上侏罗统烃源岩及上侏罗统原油（油砂抽提物）进行常规有机地球化学分析和碳同位素测试,分析研究烃源岩和原油的地球化学特征并探讨原油的来源问题。测试结果显示,侏罗系烃源岩达成熟-高熟阶段,有机质类型以Ⅲ型为主。中侏罗统烃源岩有机碳含量较高,但生烃潜能、氯仿沥青“A”及总烃含量低值,属于差的烃源岩。干酪根碳同位素总体偏重（-24.4‰～-23.5‰）,与原油碳同位素特征（-29‰左右）差异显著,排除与原油的母岩关系。上侏罗统烃源岩有机碳含量较中侏罗统低,但生烃潜能、氯仿沥青“A”及总烃含量高值。上侏罗统烃源岩抽提氯仿沥青“A”碳同位素（-26‰～-21.5‰）特征、单体烃碳同位素分布模式及甾萜烷生物标志物特征都与原油相似,综合分析认为原油应该来源于上侏罗统中干酪根类型较好、母质为混源的成熟烃源岩。 相似文献
9.
塔里木盆地和田河气田天然气的特殊来源及非烃组分的成因 总被引：21，自引：1，他引：21
本文主要讨论和田河气田天然气的地球化学特征和来源以及非烃气体的可能成因，和田河气田天然气以烃类气体为主，但含有较高的非烃气体，含量一般为10％－25％，乙烷碳同位素值为－37．8‰－34．9‰，说明形成该天然气的母质属于腐泥型，烃类组分，非烃组分分布以及天然气δ13C1值在和田河气田的东、西部存在明显的差异，和田河气田天然气源自寒武系烃源岩，但表现为具有原油二次裂解气的特殊来源特征，东部的玛4井区天然气以原油裂解气为主，西部的玛3、玛8井区则为干酪根裂解气与原油裂解气的混合气，初步分析N2，CO2和H2S的成因，，认为和田河气田天然气的特殊来源是天然气中非烃气体高含量的重要原因。 相似文献
10.
川中-川南地区须家河组天然气同位素组成特征 总被引：9，自引：0，他引：9
川中-川南地区须家河组天然气烃类组成以甲烷为主,主要分布在80%～96%之间;天然气干燥系数(C1/C1-5)以小于0.95为主,为典型的湿气.天然气同位素组成包括C1-c4碳、氢同位素等.总体特征是碳、氢同位素值主要受成熟度的影响,均表现出较轻的特点, δ13C1,值介于-43‰～-37‰之间,δ13C2值介于-30‰～-24‰之间;δDCH4值介于-190‰～-150‰之间,δDC2H6值介于-150‰～-110‰之间,δD2与δD1的差值大于15‰,明显轻于海相层系的天然气,具有煤型气特征,表明须家河组天然气主要来源于上三叠统煤系烃源岩.天然气甲烷碳同位素值与干燥系数之间有很好的正相关关系,同时,甲、乙烷氢同位素值也呈正相关关系. 相似文献
11.
ZOU Huayao HAO Fang ZHU Yangming GUO Tonglou CAI Xunyu LI Pingping ZHANG Xuefeng 《《地质学报》英文版》2008,82(3)
Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized: low sulfur content, low reflectance (LSLR) solid bitumens in sandstone reservoirs in the Xujiahe Formation and high sulfur content, high reflectance (HSHR) solid bitumens in the carbonate reservoirs in the Lower Triassic Feixianguan and Upper Permian Changxing formations. Solid bitumens in the Upper Triassic Xujiahe Formation correlate well with extracts from the Upper Triassic to Jurassic nonmarine source rocks in isotopic composition of the saturated and aromatic fractions and biomarker distribution. Solid bitumens in the Feixianguan and Changxing formations are distinctly different from extracts from the Cambrian and Silurian rocks but display reasonable correlation with extracts from the Upper Permian source rocks both in isotopic composition of the saturated and aromatic fractions and in biomarker distribution, suggesting that the Permian especially the Upper Permian Longtan Formation was the main source of solid bitumens in the carbonate reservoirs in the Feixianguan and Changxing formations in the Puguang gas field. Chemical and isotopic composition of natural gases indicates that the majority of hydrocarbon gases originated from sapropelic organic matter and was the products of thermal cracking of accumulated oils. This study indicates that source rock dominated by sapropelic organic matter existed in the Upper Permian and had made major contribution to the giant Puguang gas field, which has important implication for petroleum exploration in marine sequences in South China. 相似文献
12.
Source Rocks for the Giant Puguang Gas Field,Sichuan Basin:Implication for Petroleum Exploration in Marine Sequences in South China 总被引：7，自引：1，他引：6
ZOU Huayao HAO Fang ZHU Yangming GUO Tonglou CAI Xunyu LI Pingping ZHANG Xuefeng 《《地质学报》英文版》2008,82(3):477-486
Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized： low sulfur content, low reflectance （LSLR） solid bitumens in sandstone reservoirs in the Xujiahe Formation and high sulfur content, high reflectance （HSHR） solid bitumens in the carbonate reservoirs in the Lower Triassic Feixianguan and Upper Permian Changxing formations. Solid bitumens in the Upper Triassic Xujiahe Formation correlate well with extracts from the Upper Triassic to Jurassic nonmarine source rocks in isotopic composition of the saturated and aromatic fractions and biomarker distribution. Solid bitumens in the Feixianguan and Changxing formations are distinctly different from extracts from the Cambrian and Silurian rocks but display reasonable correlation with extracts from the Upper Permian source rocks both in isotopic composition of the saturated and aromatic fractions and in biomarker distribution, suggesting that the Permian especially the Upper Permian Longtan Formation was the main source of solid bitumens in the carbonate reservoirs in the Feixianguan and Changxing formations in the Puguang gas field. Chemical and isotopic composition of natural gases indicates that the majority of hydrocarbon gases originated from sapropelic organic matter and was the products of thermal cracking of accumulated oils. This study indicates that source rock dominated by sapropelic organic matter existed in the Upper Permian and had made major contribution to the giant Puguang gas field, which has important implication for petroleum exploration in marine sequences in South China. 相似文献
13.
To determine the origin, maturity, formation mechanism and secondary process of marine natural gases in Northeastern Sichuan area, molecular moieties and carbon isotopic data of the Carboniferous and Triassic gases have been analyzed. Typical samples of marine gas precursors including low-maturity kerogen, dispersed liquid hydrocarbons (DLHs) in source rocks, residual kerogen and oil have been examined in a closed system, and several published geochemical diagrams of gas origins have been calibrated by using laboratory data. Results show that both Carboniferous and Triassic gases in the study area have a thermogenic origin. Migration leads to stronger compositional and weak isotopic fractionation, and is path dependent. Carboniferous gases and low-H2S gases are mainly formed by secondary cracking of oil, whereas high-H2S gases are clearly related to the TSR (Thermal Sulfate Reduction) process. Gases in NE Sichuan show a mixture of heavy (13C-enriched) methane in comparison to the lower maturated ethane of Triassic gas samples, suggesting a similar source and maturity for ethane and propane of Carboniferous gases, and a mixture of heavy ethane to the propane for Triassic gases. Based on the data plotted in the diagram of Chung et al. (1988), the residual kerogen from Silurian marine shale and palaeo oil reservoirs are the main source for Carboniferous gases, and that the residual kerogen from Silurian and Permian marine rocks and Permian paleao oil reservoirs constitute the principal source of Triassic gases. 相似文献
14.
WU Xiaoqi LIU Quanyou LIU Guangxiang WANG Ping LI Huaji MENG Qingqiang CHEN Yingbin ZENG Huasheng 《《地质学报》英文版》2017,91(6):2200-2213
The molecular compositions and stable carbon and hydrogen isotopic compositions of natural gas from the Xinchang gas field in the Sichuan Basin were investigated to determine the genetic types. The natural gas is mainly composed of methane (88.99%–98.01%), and the dryness coefficient varies between 0.908 and 0.997. The gas generally displays positive alkane carbon and hydrogen isotopic series. The geochemical characteristics and gas-source correlation indicate that the gases stored in the 5~(th) member of the Upper Triassic Xujiahe Formation are coal-type gases which are derived from source rocks in the stratum itself. The gases reservoired in the 4~(th) member of the Xujiahe Formation and Jurassic strata in the Xinchang gas field are also coal-type gases that are derived from source rocks in the 3~(rd) and 4~(th) members of the Xujiahe Formation. The gases reservoired in the 2~(nd) member of the Upper Triassic Xujiahe Formation are mainly coal-type gases with small amounts of oil-type gas that is derived from source rocks in the stratum itself. This is accompanied by a small amount of contribution brought by source rocks in the Upper Triassic Ma'antang and Xiaotangzi formations. The gases reservoired in the 4~(th) member of the Middle Triassic Leikoupo Formation are oil-type gases and are believed to be derived from the secondary cracking of oil which is most likely to be generated from the Upper Permian source rocks. 相似文献
15.
地球内部物质物性的原位高温高压研究：大体积压机与同步辐射源的结合 总被引：77，自引：2，他引：77
四川盆地是一个大型复合含气为主、含油为辅的叠合盆地。多旋回的沉积演化过程,孕育了多套海相、陆相烃源岩,且不同区域发育不同成因类型的烃源岩。目前下寒武统、志留系、下二叠统、上二叠统和上三叠统五套主要烃源岩均已进入高演化阶段,并以成气为主。由于多阶成烃、混源聚集和后期遭受TSR次生蚀变等成藏过程的复杂性使得天然气组分较干、碳同位素组成复杂,常规方法进行气源对比较困难。文中在对四川盆地沉积演化背景分析的基础上,通过对有效烃源岩发育特征和分布规律的探讨,分区域进行了气藏的分析,特别是对天然气组分、非烃组成(H2S、CO2、N2等)和碳同位素等资料综合研究的基础上,基本确定了各区块各含气层系的主力源岩。认为川东主力产层石炭系、三叠系和二叠系的气源分别为志留系、上二叠统龙潭组和下二叠统;川南气区震旦系灯影组、寒武系、二叠系和三叠系产层的气源分别主要来自下寒武统,上、下二叠系源岩;川西气区侏罗系和三叠系须家河组主产层的气源主要来自三叠系须家河组煤系烃源岩,下二叠统和嘉陵江组产层气源则可能主要来自二叠系;川中主要为产油区,下侏罗统自流井群原油应来自侏罗系源岩,浅部层系气源为上三叠统须家河组的陆相烃源岩,深部气藏则为寒武系烃源岩。由于川东北部烃源岩发育层数最多,且质量都较好,因此川东北部是烃类最富集的地区,也是勘探潜力最大的地区。 相似文献
16.
Geochemistry and origin of sour gas accumulations in the northeastern Sichuan Basin, SW China 总被引：2，自引：0，他引：2
Jian Li Zengye Xie Jinxing Dai Shuichang Zhang Guangyou Zhu Zhaolu Liu 《Organic Geochemistry》2005,36(12):1703-1716
Significant natural gas reserves have recently been discovered in the Lower Triassic oolitic reservoirs from northeastern Sichuan Basin, SW China. In the wake of the December 2003 sour gas well blow-out, this study presents an overview on the petroleum geology and geochemistry of the sour gas accumulations in the study area. Two types of natural gas accumulations were identified in the Lower Triassic oolitic reservoirs, both containing highly mature thermogenic gases, with their hydrocarbon source rocks in Upper Permian strata. Natural gases from the area south of the ancient Kaijiang-Liangping Seaway are generally sweet gases formed as the result of thermal maturation, whereas those discovered from north of the Seaway are products of both thermal maturation and thermochemical sulfate reduction of early accumulated oils in the Feixianguan Formation reservoirs. The proposed origins of the gases are supported by their chemical and stable carbon isotope compositions, as well as the presence or absence of pyrobitumens in the reservoir. The distribution of gas accumulations is controlled predominantly by the combination of lithologic and structural factors. The regional variation in the concentrations of H2S in the gases appears related to the presence and thickness of anhydrite-bearing evaporitic rocks interbedded or intercalated with the oolitic reservoirs. 相似文献
17.
18.
川西前陆盆地天然气成藏过程 总被引：13，自引：0，他引：13
川西前陆盆地具有丰富的天然气资源,发育上三叠统巨厚的煤系烃源岩,以生气为主,并发育多套储盖组合。天然气成因类型主要是煤成气,目前的气田分布主要受古隆起、沟通下部烃源岩和上部储集层的隐伏断层以及储集条件的控制。川西前陆盆地具有多期成藏、燕山期或喜山期聚集、喜山期调整等特点。来自上三叠统煤系源岩的天然气聚集主要在燕山期,形成原生气藏或下生上储型气藏;后经过喜山期的逆冲作用,对浅层储集层进行改造,产生的断裂沟通深部气藏与浅层圈闭,在对深层(主要在上三叠统)原生气藏进行改造的同时形成浅层(侏罗系)次生气藏。 相似文献
19.
从烃源岩特征、天然气组分、油气碳同位素、凝析油全烃和轻烃、储层沥青等方面对营山地区上三叠统和中、下侏罗统油气源特征进行了对比研究,阐明了营山地区上三叠统须家河组和中、下侏罗统油气的地球化学特征、成因和可能来源。研究表明营山地区上三叠统须家河组油气主要来自须家河组自身的煤系烃源岩,天然气以成熟腐殖型母质成因为主,而中、下侏罗统气藏产出的油气主要来自其自身的烃源岩。营山地区构造活动强烈,断层发育,使得部分井区中、下侏罗统产出的天然气特征与下伏产层极为相似,反映了断层对该井区附近的各层段有一定的沟通作用。中、下侏罗统地层在部分井区可能有上三叠统须家河组油气的侵入,须家河组烃源岩对中、下侏罗统油气成藏有一定贡献作用。 相似文献
20.
中国南方古生界-中生界油气藏成藏规律及勘探方向 总被引：17，自引：3，他引：17
中国南方古生界—中生界古油藏主要分布于黔中—雪峰 -江南隆起北侧 (以下古生界及上震旦统灯影组古油藏为主 ,其烃源主要是下寒武统 )及南盘江—十万大山地区上古生界及下三叠统台地及孤立台地边缘 (主要是上古生界及下三叠统自生自储型古油藏 ) ;现存古生界—中生界油气藏主要分布于四川盆地。根据南方多期构造改造及油气演化复杂性的特点 ,将南方古生界—中生界油气藏分成原生、次生及再生烃油气藏 3类。认为南方现存的古生界—中生界原生油气藏很少 ,绝大部分原生油气藏均已破坏成为古油藏 ,四川盆地现存的大多数油气藏是典型的次生油气藏。提出次生气藏有利勘探领域有川东南及大巴山前缘上石炭统—下三叠统、乐山 -龙女寺隆起东南斜坡上震旦统灯影组及下古生界、川西北地区及楚雄盆地北部凹陷上三叠统—下侏罗统煤成气藏 ,再生烃油气藏有利勘探地区有苏北盆地阜宁—盐城—海安—兴化—宝应地区、江汉盆地沉湖地区南部潜江—仙桃—牌州—汊参 1井地区及江西鄱阳盆地南部凹陷。这一认识已经得到苏北盆地盐城凹陷朱家墩气田、川东方斗山背斜带寨沟湾石炭系气田及江汉盆地沉湖地区南部开先台西油藏勘探发现的证实。 相似文献