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1.
In order to constrain the origin and fluxes of elements carried by rivers of high latitude permafrost-dominated areas, major and trace element concentrations as well as Sr and U isotopic ratios were analyzed in the dissolved load of two Siberian rivers (Kochechum and Nizhnyaya Tunguska) regularly sampled over two hydrological cycles (2005-2007). Large water volumes of both rivers were also collected in spring 2008 in order to perform size separation through dialysis experiments. This study was completed by spatial sampling of the Kochechum watershed carried out during summer and by a detailed analysis of the main hydrological compartments of a small watershed. From element concentration variations along the hydrological cycle, different periods can be marked out, matching hydrological periods. During winter baseflow period (October to May) there is a concentration increase for major soluble cations and anions by an order of magnitude. The spring flood period (end of May-beginning of June) is marked by a sharp concentration decrease for soluble elements whereas dissolved organic carbon and insoluble element concentrations strongly increase.When the spring flood discharge occurs, the significant increase of aluminum and iron concentrations is related to the presence of organo-mineral colloids that mobilize insoluble elements. The study of colloidal REE reveals the occurrence of two colloid sources successively involved over time: spring colloids mainly originate from the uppermost organic-rich part of soils whereas summer colloids rather come from the deep mineral horizons. Furthermore, U and Sr isotopic ratios together with soluble cation budgets in the Kochechum river impose for soluble elements the existence of three distinct fluxes over the year: (a) at the spring flood a surface flux coming from the leaching of shallow organic soil levels and containing a significant colloidal component (b) a subsurface flux predominant during summer and fall mainly controlled by water-rock interactions within mineral soils and (c) a deep groundwater flux predominant during winter which enters large rivers through unfrozen permafrost-paths. Detailed study of the Kochechum watershed suggests that the contribution of this deep flux strongly depends on the depth and continuous nature of the permafrost.  相似文献   

2.
We have conducted a series of laboratory studies to investigate the generation of ferrous iron and reactive oxygen species when solutions of seawater containing natural organic matter (NOM) and ferric iron are exposed to simulated sunlight. Total ferrous iron and hydrogen peroxide were measured at nanomolar concentrations with high temporal resolution using chemiluminescence-based methods. In all cases, ferrous iron concentrations rapidly peaked at several nanomoles per litre after a few minutes, and then declined over time, while hydrogen peroxide concentrations increased in a non-linear manner. Although concentrations of both species depended on the concentration of NOM, hydrogen peroxide concentrations were only minimally affected by the presence of iron. Increasing the NOM concentration while the total iron concentration was maintained constant led to an increase in the maximum ferrous iron concentration, suggesting that superoxide-mediated reduction of iron may be a major pathway for ferrous iron formation. This was supported by measurements of superoxide production from irradiation of NOM in the absence of iron and kinetic calculations, as well as an experiment in which superoxide dismutase was added. Further analysis of the data suggested that dissolved oxygen and photo-produced hydrogen peroxide were the primary oxidants of the Fe(II) formed. Thus we propose that superoxide and ferrous iron may be intricately coupled in the system, and that their generation is determined by the supply of NOM available to harvest light and donate electrons.  相似文献   

3.
为分析铁在含水层介质中的沉积行为,以石英砂为实验材料,研究了铁在石英砂表面的吸附规律,并对接触时间、铁浓度、腐植酸、钙离子等对沉积过程的影响进行了探讨。结果表明:铁在石英砂上的沉积是单分子层沉积,且沉积过程符合准一级动力学模型。低浓度腐殖酸会促进铁在石英砂上的沉积,但受络合作用影响,增加腐植酸浓度会减少铁在石英砂上的沉积。当水中存在阳离子Ca2+和阴离子SO42-时,会促进铁的沉积,NO3-离子的影响较小,而高浓度F-离子会阻碍铁的沉积。  相似文献   

4.
The formation of colloids during the weathering of phyllite was investigated by exposing ground phyllite to Milli-Q water. Secondary mineral colloids of 101–102 nm were detected in significant concentrations. At pH of about 8.5, the solution concentration of these colloids reached up to 10 mg/L (however, acidification to pH 4.0 prevented the formation of the colloids). The mineralogical composition of the secondary mineral colloids is assumed to be a mixture of ferrihydrite, manganese oxyhydroxides, aluminosilicates, amorphous Al(OH)3 and gibbsite with possible additions of iron silicates and␣iron-alumino silicates. The colloids were stable over longer periods of time (at least several weeks), even in the presence of suspended ground rock. Direct formation of iron-containing secondary mineral colloids at the rock–water interface by the weathering of rock material is an alternative to the well-known mechanism of iron colloid formation in the bulk of water bodies by mixing of different waters or by aeration of anoxic waters. This direct mechanism is of relevance for colloid production during the weathering of freshly crushed rock in the unsaturated zone as for instance crushed rock in mine waste rock piles. Colloids produced by this mechanism, too, can influence the transport of contaminants such as actinides because these colloids have a large specific surface area and a high sorption affinity.  相似文献   

5.
 Sediment and its associated pore water were collected from a zoned, freshwater, riparian wetland, located in the Talladega National Forest, northeastern Hale County, Alabama, to study the porewater chemistry and its spatial changes within and between the wetland ecological zones. Obvious changes in pH, Eh and element concentrations were observed between the different wetland ecological zones. Major cations (Ca, Mg, and Na) and trace elements (B, Ba, Sr, and Mn) have very good spatial correlation with Fe and Mn distributions, both in the pore water and the sediment, suggesting that adsorption on, and desorption from, iron and manganese oxyhydroxides are important processes controlling the distributions of these elements in the wetland sediment. However, an equilibrium adsorption model is not able to explain the distribution of trace elements between the pore water and sediment. A redox kinetic model gives similar vertical profiles for iron and the correlated elements as those measured in the field and thus suggests that the relative rates of ferrous iron oxidation and the reductive dissolution of ferric iron in the sediment are important variables determining the distributions of these elements in the wetland pore waters. Received: 31 October 1996 · Accepted: 27 May 1997  相似文献   

6.
On-site size fractionation of about 40 major and trace elements (TE) was performed on waters from boreal small rivers and their estuaries in the Karelia region of North-West Russia around the “Vetreny Belt” mountain range and in Paanajärvi National Park (Northern Karelia). Samples were filtered in the field using a progressively decreasing pore size (5 μm, 2.5 (3) μm, 0.22 (0.45) μm, 100 kDa, 10 and 1 kDa) by means of frontal filtration and ultrafiltration (UF) techniques and employing in-situ dialysis with 10 and 1 kDa membranes followed by ICP-MS analysis. For most samples, dialysis yields a systematically higher (factor of 2-3) proportion of colloidal forms compared to UF. Nevertheless, dialysis is able to provide a fast and artefact-free in-situ separation of colloidal and dissolved components.Similar to previous studies in European subarctic zones, poor correlation of iron concentration with that of organic carbon (OC) in (ultra)filtrates and dialysates reflect the presence of two pools of colloids composed of organic-rich and Fe-rich particles. All major anions and silica are present as dissolved species (or solutes) passing through the 1-kDa membrane. Size-separation ultrafiltration experiments show the existence of larger or smaller pools of colloidal particles different for each of the considered elements.The effect of rock lithology (acidic versus basic) on the colloidal speciation of TE is seen solely in the increase of Fe and some accompanying TE concentrations in catchment areas dominated by basic rocks compared to granitic catchments. Neither the ultrafiltration pattern nor the relative proportions of colloidal versus truly dissolved TE are affected by the lithology of the underlying rocks: within ±10% uncertainty, the two colloidal (10 kDa-0.22 μm and 1-10 kDa) and the truly dissolved (<1 kDa) pools show no difference in percentage of TE distribution between two types of bedrock lithology. The same conclusion is held for organic- and Fe-rich waters. In contrast, landscape context analysis demonstrated slight dominance, for most TE affected by UF, of large-size colloids (10 kDa-0.22 μm) in rivers and streams and small-size colloids and truly dissolved fractions in swamp stagnant surface waters. This supports the existence of two pathways of colloids formation: during the plant litter degradation in wetland zones and at the redox front in river riparian zone.  相似文献   

7.
ABSTRACT

Given that secondary magnetite is common in serpentinites, it is clear that serpentinites are oxidized rocks. Questions remain, however, concerning the distribution of ferric iron among magnetite and serpentine minerals and the role of ferric iron-rich serpentine in the formation of secondary magnetite. Direct determination of ferric iron in serpentine is not possible using an electron microprobe. We show, however, that the stoichiometic effects of ferric iron substitutions are detectable, although not quantifiable, by microprobe. First, we demonstrate that for studies that provide both microprobe analyses of major elements of serpentine and Mössbauer analysis of ferric iron, substitution effects are obvious. Next, it is equally clear that the early veins forming at the onset of olivine hydration (type 1 veins) show no indication of the presence of ferric serpentine, although a small amount of ferric ‘brucite’ may occur. Finally, we show that secondary (type 2) veins, which form as the system becomes open to fluids in equilibrium with plagioclase or pyroxene, contain, in addition to significant alumina, stoichiometric indications of ferric iron substitution. The serpentine in these veins is magnesian, usually with Mg#s around 96–98. Thus, even if a significant proportion of this iron is ferric, it comprises only a small fraction of the total ferric iron budget of the rock. Given that reduced iron is known to be abundant in early-formed brucite and early-formed serpentine and given that brucite, in particular, is absent from evolved serpentine veins, we propose that most magnetite in serpentinites forms as a tertiary product via oxidation of brucite.  相似文献   

8.
The sediment from an acid mine drainage affected reservoir of Guizhou province of China has the iron and arsenic concentration of about 400 and 2.6 g/kg, respectively. Sediment cores were collected, and were used to study the arsenic behavior in the seriously acidified reservoir from the viewpoint of chemical thermodynamics. The limestone neutralization and ferric iron hydrolysis regulated the porewater pH from about 2.9–5.8. The reductive dissolution of As–Fe-rich (hydr)oxides under the mild acidic conditions was the main mechanism for the release of absorbed arsenic into porewater. The maximum concentrations of iron, sulfate and arsenic reached to about 2,800, 9,000 and 1 mg/l, respectively. Arsenic speciation transformation and hydrous ferric oxide (HFO) crystallization enhanced the arsenic mobility in sediment. In addition, the iron sulfide minerals diagenesis could play a role in removing the dissolved arsenic from porewater. The actual distribution of arsenic concentration in porewater was well simulated using the model of surface complexation of arsenic to HFO. Although arsenic concentration in porewater could be above 100 times higher than that of reservoir water, it was not easy to release into the reservoir water through diffusion, because the shallow sediment had relatively strong arsenic adsorption capacity, and new HFO could be generated continuously at the sediment water interface.  相似文献   

9.
The formation of Fe(III) oxyhydroxide colloids by oxidation of Fe(II) and their subsequent aggregation to larger particles were studied in laboratory experiments with natural water from a freshwater lake and a brackish coastal sea. Phosphate was incorporated in the solid phase during the course of hydrolysis of iron. The resulting precipitated amorphous Fe(III) oxyhydroxide phases were of varying composition, depending primarily on the initial dissolved Fe/P molar ratio, but with little influence by salinity or concentration of calcium ions. The lower limiting Fe/P ratio found for the solid phase suggests the formation of a basic Fe(III) phosphate compound with a stoichiometric Fe/P ratio of close to two. This implies that an Fe/P stoichiometry of ≈2 ultimately limits the capacity of precipitating Fe(III) to fix dissolved phosphate at oxic/anoxic boundaries in natural waters. In contrast to phosphorus, the uptake of calcium seemed to be controlled by sorption processes at the surface of the iron-rich particles formed. This uptake was more efficient in freshwater than in brackish water, suggesting that salinity restrains the uptake of calcium by newly formed Fe(III) oxyhydroxides in natural waters. Moreover, salinity enhanced the aggregation rate of the colloids formed. The suspensions were stabilised by the presence of organic matter, although this effect was less pronounced in seawater than in freshwater. Thus, in seawater of 6 to 33 ‰S, the removal of particles was fast (removal half time < 200 h), whereas the colloidal suspensions formed in freshwater were stable (removal half time > 900 h). Overall, oxidation of Fe(II) and removal of Fe(III) oxyhydroxide particles were much faster in seawater than in freshwater. This more rapid turnover results in lower iron availability in coastal seawater than in freshwater, making iron more likely to become a limiting element for chemical scavenging and biologic production.  相似文献   

10.
The banded iron-formation (BIF) of the Hamersley Group, Pilbara Craton, Western Australia, particularly from the well studied Dales Gorge Member, is unique in its lateral stratigraphic and petrological continuity throughout an area exceeding 60,000 km2, enabling reasonable estimates for the annual input of components to the depository. In the model of this paper, varying supply of materials for the medley of mesoband types, particularly of iron and silica in the oxide BIF, can be accommodated by the interaction of two major oceanic supply systems: (1) surface currents and (2) convective upwelling from mid-oceanic ridge (MOR) or hot-spot activity, both modified by varied input of pyrochastic material. (1) The surface currents were saturated in silica and carried minimal iron due to photic precipitation, but were periodically recharged by storm mixing. Precipitation from them gave rise to the banded chert-rich horizons, including the varves, whose regular and finely laminated iron/silica distribution resulted from seasonal meteorological influences. (2) Precipitation from convection driven upwelling of high iron solution from MOR or hot-spot activity periodically overwhelmed the delicate seasonal patterns of (1) to produce the iron-dominated mesobands. A wide range of intermediate mesoband types resulted where the deep water supply was modified by varied MOR activity, or by partial blocking of upwelling waters by surface currents (such as by the present El Niño). During these periods of oxide-dominated BIF, silica was deposited from saturated solution mainly by evaporative concentration, and iron by oxidation due to photolysis and photosynthetically produced oxygen.Superimposed on these supply differences was the varying effect of fine aluminous ash from dominantly northern distal volcanic sources, changing the meteorological and depositional conditions. Occasional input of extremely fi ash during BIF precipitation produced mesoband (cm) scale variations involving increased carbonate-silicate precipitation. Sustained volcanic periods resulted in S-macroband deposition (chert-carbonate-silicate BIF, with shale), gradually returning to the dominant hematite-magnetite-chert BIF as the volcanic input waned. During volcanic periods, the normally high capacity of sunlight to precipitate ferric iron directly by photolytic oxidation of ferrous iron, and by photosynthetic production of oxygen, was modified by turbidity in the atmosphere (aerosols and dust) and in the water (colloids from reactive ash). S Surface-precipitated ferric hydroxyoxide redissolved in the presence of decaying organic matter in the subphotic zone, augmenting the iron content of the zone. Precursor ferrous carbonates and silicates were precipitated when the iron concentration of this sub-photic zone exceeded their respective solubilities. During volcanism, the increased availability of nutrients, particularly phosphorus, to surface waters increased the organic contribution despite lower light values, leading to an almost total absence of ferric iron oxides in the S macrobands (i.e. no magnetite or hematite). Cooling of warm, silica-saturated sea-water during these periods of “olcanic winter” increased the ratio of precipitation of silica to iron, which, however, was still controlled by seasonal conditions. Intermediate concentrations of organic matter, insufficient to totally convert the ferric compounds either during precipitation or diagenesis, resulted in overgrowths of magnetite on hematite, and eventually in the substantial conversion of hematite to magnetite, where higher temperatures were achieved during low-grade regional metamorphism.Changes in sea-level to explain facies changes in BIF are not required in this model, but are not excluded. The preferred conditions are for a very low oxygen to anoxic atmosphere, a much higher level of MOR activity than at present, the presence of photosynthetic plankton, the absence of si silica-secreting organisms, and a deep sea-water temperature higher than 20°C. However, none of these conditions is essential to the model.A narrow carbonate bank is postulated for part of the Fortescue River Valley area during Marra Mamba Iron Formation times (basal Hamersley Group), with BIF precipitation on either side. The reef is postulated to have grown northward becoming a major shallow-water carbonate platform on the Pilbara continent during upper Marra Mamba Iron Formation and Wittenoom Dolomite times, but ceased to play an important role in subsequent periods.  相似文献   

11.
Ferric iron is present in all metamorphic rocks and has the ability to significantly affect their phase relations. However, the influence of ferric iron has commonly been ignored, or at least not been considered quantitatively, mainly because its abundance in rocks and minerals is not determined by routine analytical techniques. Mineral equilibria calculations that explicitly account for ferric iron can be used to examine its effect on the phase relations in rocks and, in principle, allow the estimation of the oxidation state of rocks. This is illustrated with calculated pseudosections in NCKFMASHTO for mafic and pelitic rock compositions. In addition, it is shown that ferric iron has the capacity to significantly increase the stability of the corundum + quartz assemblage, making it possible for this assemblage to exist at crustal P–T conditions in oxidized rocks of appropriate composition.  相似文献   

12.
应用纳米零价铁进行地下水污染治理是近年迅速发展的环境修复新技术,但在实际应用中,纳米零价铁的反应活性受到环境条件的影响,其中自然界中广泛存在的天然有机质就是重要影响因素。通过批实验研究腐殖酸(天然有机质代表物)对纳米零价铁去除水中六价铬的影响,结果表明,腐殖酸的存在能够极大地抑制纳米铁去除六价铬的反应速度和去除效率,原因在于纳米铁对腐殖酸具有一定的吸附作用,从而减少了纳米铁表面的有效活性位点,降低了对六价铬的作用。此外发现,水体中溶解氧的存在有利于纳米铁对六价铬的去除。关于腐殖酸-纳米零价铁-六价铬的相互作用研究,对于进一步揭示修复体系作用机制具有重要的理论和应用价值。  相似文献   

13.
《Applied Geochemistry》2006,21(7):1109-1122
This study investigates a watershed influenced by acid mine drainage emanating from the former Leona Heights Sulfur Mine, located in Oakland, California. The primary factors that temporally controlled the magnitude of iron photoreduction included initial iron concentration, incident ultraviolet radiation, water temperature, biotic oxidation, flow rates, and the Fe(III) species present. Vegetation was not expected to seasonally influence the amount of incoming solar radiation reaching the water surface as the tree canopy contained significant cover during both the April and July monitoring events. Accordingly, it was anticipated that iron photoreduction would be greatest during the summer when both incoming ultraviolet radiation and dissolved iron were at a maximum. This was, however, not the case. A substantial decline in the apparent magnitude of iron photoreduction occurred during the summer/dry season (July) with respect to measurements taken during the spring/wet season (April). The primary reasons for the observed phenomenon were attributed to factors which may seasonally control the physical presence of iron oxidizing bacteria at the site and water temperature, which influences the optimum rate of bacterially mediated iron oxidation.  相似文献   

14.
The chemical status of major and trace elements (TE) in various boreal small rivers and watershed has been investigated along a 1500-km transect of NW Russia. Samples were filtered in the field through a progressively decreasing pore size (5, 0.8 and 0.22 μm; 100, 10, and 1 kD) using a frontal filtration technique. All major and trace elements and organic carbon (OC) were measured in filtrates and ultrafiltrates. Most rivers exhibit high concentration of dissolved iron (0.2–4 mg/l), OC (10–30 mg/l) and significant amounts of trace elements usually considered as immobile in weathering processes (Ti, Zr, Th, Al, Ga, Y, REE, V, Pb). In (ultra)filtrates, Fe and OC are poorly correlated: iron concentration gradually decreases upon filtration from 5 μm to 1 kD whereas the major part of OC is concentrated in the <1–10 kD fraction. This reveals the presence of two pools of colloids composed of organic-rich and Fe-rich particles. According to their behavior during filtration and association with these two types of colloids, three groups of elements can be distinguished: (i) species that are not affected by ultrafiltration and are present in the form of true dissolved inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, Si, B, As, Sb, Mo) or weak organic complexes (Ca, Mg, Sr, Ba), (ii) elements present in the fraction smaller than 1–10 kD prone to form inorganic or organic complexes (Mn, Co, Ni, Zn, Cu, Cd, and, for some rivers, Pb, Cr, Y, HREE, U), and (iii) elements strongly associated with colloidal iron in all ultrafiltrates (P, Al, Ga, REE, Pb, V, Cr, W, Ti, Ge, Zr, Th, U). Based on size fractionation results and taking into account the nominal pore size for membranes, an estimation of the effective surface area of Fe colloids was performed. Although the total amount of available surface sites on iron colloids (i.e., 1–10 μM) is enough to accommodate the nanomolar concentrations of dissolved trace elements, very poor correlation between TE and surface sites concentrations was observed in filtrates and ultrafiltrates. This strongly suggests a preferential transport of TE as coprecipitates with iron oxy(hydr)oxides. These colloids can be formed on redox boundaries by precipitation of Fe(III) from inflowing Fe(II)/TE-rich anoxic ground waters when they meet well-oxygenated surface waters. Dissolved organic matter stabilizes these colloids and prevents their aggregation and coagulation. Estuarine behavior of several trace elements was studied for two small iron- and organic-rich rivers. While Si, Sr, Ba, Rb, and Cs show a clear conservative behavior during mixing of freshwaters with the White sea, Al, Pb and REE are scavenged with iron during coagulation of Fe hydroxide colloids.  相似文献   

15.
纳米零价铁原位修复地下水污染是近年发展起来的新技术,通过改性合成不同种类纳米零价铁可以克服其易团聚易氧化的问题,水体中存在的天然有机质也会对纳米铁的分散性和反应活性产生影响,因此开展原位测试并研究不同种类纳米铁在水中的团聚效应具有重要意义。本文对实验合成的纳米零价铁、羧甲基纤维素包覆纳米零价铁、膨润土负载纳米零价铁以及商用纳米零价铁,基于动态光散射技术(DLS),运用纳米粒度/Zeta电位分析仪,结合透射电子显微镜(TEM)和沉降光谱曲线等手段,对比研究了天然有机质(腐植酸HA)对纳米铁团聚效应的影响。结果表明,羧甲基纤维素包覆或膨润土负载改性提高了纳米零价铁颗粒的分散稳定性,有效抑制了团聚沉降,团聚体粒径分布在1000 nm以下。HA会吸附在纳米铁颗粒表面,从而增加静电排斥力,进一步减缓了团聚效应,尤其是对膨润土负载纳米零价铁的影响最为显著,其团聚体粒径能降至100 nm以下,沉降速率也极大减缓,分散稳定性表现最佳。本研究表明DLS结合TEM表征纳米颗粒是获得更加丰富的微观粒子信息的一种非常重要的手段。  相似文献   

16.
The aqueous geochemistry of Zn, Cu, Cd, Fe, Mn and As is discussed within the context of an anaerobic treatment wetland in Butte, Montana. The water being treated had a circum-neutral pH with high concentrations of trace metals and sulfate. Reducing conditions in the wetland substrate promoted bacterial sulfate reduction (BSR) and precipitation of dissolved metal as sulfide minerals. ZnS was the most common sulfide phase found, and consisted of framboidal clusters of individual spheres with diameters in the submicron range. Some of the ZnS particles passed through the subsurface flow, anaerobic cells in suspended form. The concentration of "dissolved" trace metals (passing through a 0.45 μm filter) was monitored as a function of H2S concentration, and compared to predicted solubilities based on experimental studies of aqueous metal complexation with dissolved sulfide. Whereas the theoretical predictions produce "U-shaped" solubility curves as a function of H2S, the field data show a flat dependence of metal concentration on H2S. Observed metal concentrations for Zn, Cu and Cd were greater than the predicted values, particularly at low H2S concentration, whereas Mn and As were undersaturated with their respective metal sulfides. Results from this study show that water treatment facilities employing BSR have the potential to mobilize arsenic out of mineral substrates at levels that may exceed regulatory criteria. Dissolved iron was close to equilibrium saturation with amorphous FeS at the higher range of sulfide concentrations observed (>0.1 mmol H2S), but was more likely constrained by goethite at lower H2S levels. Inconsistencies between our field results and theoretical predictions may be due to several problems, including: (i) a lack of understanding of the form, valence, and thermodynamic stability of poorly crystalline metal sulfide precipitates; (ii) the possible influence of metal sulfide colloids imparting an erroneously high "dissolved" metal concentration; (iii) inaccurate or incomplete thermodynamic data for aqueous metal complexes at the conditions of the treatment facility; and (iv) difficulties in accurately measuring low concentrations of dissolved sulfide in the field.  相似文献   

17.
The wetland constructed at the Big Five Tunnel in Idaho Springs, Colorado was designed to remove, passively, heavy metals from acid mine drainage. In optimizing the design of such a wetland, an improved understanding of the chemical processes operating there was required, particularly SO42− reduction and sulfide precipitation. For this purpose, field and laboratory data were collected to study the balance of S in the system. Field data collected included water analyses of the mine drainage and wetland effluents and measurements of H2S gas emissions from the wetland. The concentration of sulfide in the wetland effluent ranged from 10−4 to 10−3 mol/l. The average rates of H2S emission from the surface of the substrate were 150 nmol/cm2/d in the summer and 0.17 and 0.35 nmol/cm2/d in the winter. This maximum estimated loss of sulfide was not significant in reducing the amount of sulfide available for precipitation with metals. Sequential extraction experiments for S on wetland substrates showed that acid volatile sulfides (AVS) increased with time in the wetland substrate. A serum bottle experiment was conducted to study the S balance in the Big Five wetland by quantitatively measuring the amount of S in different phases as microbial SO42− reduction progressed. The increase in AVS reasonably balanced the decrease in SO42− concentration in the experiment, suggesting that the decrease in SO42− concentration represented the amount of SO42− reduced and that nearly all of the sulfide produced was precipitated as AVS. Sulfide precipitation was determined to be the primary metal removal process in the wetland system and amorphous FeS is the primary iron sulfide formed in the substrate.  相似文献   

18.
采用国际通用采样方法,在春、夏、秋三季对大夏河甘南段河流湿地6个样点土壤节肢动物群落进行了调查研究,比较分析了土壤节肢动物群落组成、多样性及其季节动态特征.结果表明：共捕获土壤节肢动物8 743只,隶属于3纲9目33科35类,其中,大型土壤节肢动物2 743只,占捕获量的35.52%;中小型土壤节肢动物6 000只,占64.48%;大型土壤节肢动物的优势类群为摇蚊科幼虫和长足虻科幼虫;中小型土壤节肢动物的优势类群为绥螨科、绒螨科、等节跳属和原等跳属. 在不同样点土壤节肢动物类群数和个体数量表现出了明显季节变化,其高低顺序为秋季>夏季>春季;不同样点土壤节肢动物的垂直分布具有明显的表聚特征,即从地表向下,随着土壤深度的增加土壤节肢动物类群数和个体数量逐渐减少.研究结果为进一步开展高原寒区河流湿地土壤节肢动物生态学研究提供了基础资料.  相似文献   

19.
长江源区高寒退化湿地地表蒸散特征研究   总被引：1，自引：0，他引：1  
青藏高原作为“亚洲水塔”,对东亚乃至全球大气水分循环都有非常显著的影响.高寒退化湿地是高原上生态多样性的保证,也是水汽循环和地表径流的重要源地,其地气之间水分交换不但可以反映气候变化,而且也对生态环境保护具有重要意义.以长江源区隆宝滩湿地连续一年、每10分钟一次的观测资料为基础,利用FAO Penman-Monteith方法分析了长江源区高寒退化湿地蒸散量的变化特征及其与环境因子之间的关系.结果表明：1）牧草生长期,潜在蒸散量日、月变化特征显著;实际蒸散量整体表现为冬小、夏大,夏季蒸散贡献最大.2）观测期间,蒸散量远大于降水量,水分亏损严重,局地蒸散对降水的贡献较高.3）土壤温度对蒸散发过程影响显著,尤其是表层5 cm地温与蒸散发相关性较好,土壤湿度变化表明其为蒸散发过程提供了充足的水分.4）全年变化中,气温是影响蒸散的主要因素.晴天中,高寒退化湿地实际蒸散量与辐射具有几乎相同的变化趋势,气温对蒸散量影响较小,蒸散量与相对湿度呈现显著的反相关.  相似文献   

20.
Variations in the physico-chemical speciation of the rare earth elements (REE) have been investigated in a subarctic boreal river during an intense spring flood event using prefiltered (<100 μm) samples, cross-flow (ultra)filtration (CFF), flow field-flow fractionation (FlFFF), and diffusive gradients in thin films (DGT). This combination of techniques has provided new information regarding the release and transport of the REE in river water. The colloidal material can be described in terms of two fractions dominated by carbon and iron, respectively. These two fractions, termed colloidal carrier phases, showed significant temporal changes in concentration and size distribution. Before the spring flood, colloidal carbon concentrations were low, the colloids being dominated by relatively large iron colloids. Colloidal concentrations increased sharply during the spring flood, with smaller carbon colloids dominating. Following the spring flood, colloidal concentrations decreased again, smaller carbon colloids still dominating. The REE are transported mainly in the particulate and colloidal phases. Before the spring flood, the REE composition of all measured fractions was similar to local till. During the spring flood, the REE concentrations in the colloidal and particulate fractions increased. The increase was most marked for the lighter REE, which therefore showed a strong enrichment when normalized to local till. Following the spring flood, the REE concentrations decreased again and reverted to a distribution similar to local till. These changes in the concentration and distributions of carbon iron and REE are interpreted in terms of changing hydrological flow paths in soil and bedrock which occur during the spring flood.  相似文献   

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