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1.
捕虏体麻粒岩是了解下地壳形成和演化的重要样品.汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物.电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni Co Cu)/Fe(原子比)远小于0.2;(Fe Cu Co Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境.各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系.磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳. 相似文献
2.
捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相，主要类型有：①孤立产出的球状出溶硫化物；②矿物颗粒之间或颗粒内的粗晶硫化物；③次生硫化物包裹体群；④裂隙充填硫化物。电子探针分析表明，硫化物的矿物成分均为贫镍磁黄铁矿，（Ni＋Co＋Cu）／Fe（原子比）远小于0．2；（Fe＋Cu＋Co＋Ni）／S（原子比）比地幔岩的磁黄铁矿小，多小于0．875，反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量，其平均值分别为0．19％～0.22％（Au）、0．01％～0．02％（Ag），反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关，说明微量重金属元素与S具有同源的关系，由于地幔去气伴随S而进入下地壳。 相似文献
3.
福建牛头山新近纪碱性玄武岩中地幔岩包体内硫化物研究 总被引：3，自引：0，他引：3
福建牛头山一带新近纪碱性玄武岩中含有尖晶石二辉橄榄岩包体。这些地幔岩包体内普遍存在有硫化物。硫化物按产状和成因分为两类:1)分布于寄主矿物内部,未与裂隙相连,是地幔岩浆作用的产物;2)分布于颗粒内或颗粒边部,在裂隙上或与裂隙相连,是地幔流体交代作用的产物。电子探针分析表明,15个硫化物测点中,除2个黄铜矿、1个硫铜铁矿外,其余为不同Ni/Fe(mol比)比值的铁镍硫化物:6个测点为富镍镍黄铁矿,其Ni/Fe=0.98～2.79,(Fe+Ni)/S=1.03～1.08;2个为针镍矿,其Ni/Fe=5.5,(Fe+Ni)/S=1.01;4个测点为富镍磁黄铁矿,其Ni/Fe=0.29～0.49,(Fe+Ni)/S=0.79～0.94。4粒单一硫化物矿物的成份是不均一的,多数表现为自中心到边部Ni含量和Ni/Fe值呈增加趋势,而Fe和Cu含量呈减少趋势。本研究还发现单一硫化物中由中心到边部金与镍大致有相同的变化趋势。 相似文献
4.
烧锅营子金矿床的黄铁矿形成于早、中、晚3期,是主要的矿石矿物和载金矿物,其中以中期黄铁矿为最主要的载金者.黄铁矿的化学成分为:TFe43.34%~45.52%,S46.58%~48.86%,与标准黄铁矿相比显示亏铁、亏硫特点.黄铁矿内含丰富的微量元素,有Au、Ag、As、Sb、Bi、Cu、Zn、Pb、Co、Ni、W、Mo、Se等.其中Au、Ag、Cu、Pb、Zn、Bi含量较高,而As、Sb低,Se极低.其Au/Ag(多大于0.5)、(Cu+Pb+Zn)/(Co+Ni+As)(4.26)、Co/Ni(>> 1)比值表明其属中温岩浆热液矿床. 相似文献
5.
攀西红格钒钛磁铁矿矿田白草矿区发育富钴硫化物矿物,关于其成因和形成环境方面的研究较为薄弱。本文采用矿物学、矿物化学、地球化学等方法对其进行系统研究。矿石中主要富钴硫化物为磁黄铁矿（Po）、黄铁矿（Py）、镍黄铁矿（Pn）、硫钴镍矿（Se）。磁黄铁矿Co、Ni平均质量分数分别为0.21%、0.42%,Co/Ni平均值为1.10;黄铁矿Co、Ni平均质量分数分别为0.18%、0.29%,Co/Ni平均值为0.77;镍黄铁矿Co、Ni平均质量分数分别为2.67%、34.30%,Ni/Fe平均值为1.08、S/Fe平均值为1.91、M/S#平均值为1.13;硫钴镍矿Co、Ni平均质量分数分别为24.30%、22.90%,Co/Ni平均值为1.06。根据Po-Py矿物温度计,白草矿区富钴硫化物结晶温度在267~490℃之间,表明其形成于中高温的条件。通过与地幔包体镍黄铁矿S/Fe、M/S#特征值的对比,结合磁黄铁矿具有陨硫铁（Tr）同质多象晶体的特征,认为白草矿区硫化物具有地幔源的特征,说明成矿物质来源于地幔。白草矿区钴地球化学特征研究表明,在硫化物熔体分离过程中,钴迁移至单硫化物固溶体形成Po-Py固溶体,再由Po-Py固溶体中迁移至Pn、Se,形成了Se、Pn、Po-Py、Ccp（黄铜矿）中Co质量分数依次递减的现象。 相似文献
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7.
《矿物学报》2019,(6)
甘肃寨上金矿是我国重要的卡林型金矿床,发育多种特征的黄铁矿、毒砂、黝铜矿、黄铜矿等金属硫化物。黄铁矿贯穿整个地质过程,对其进行研究可深入理解成矿作用。观察发现,黄铁矿可分为3个世代。第1世代黄铁矿为莓球状黄铁矿(Py1A)和多孔海绵状黄铁矿(Py1B)2类;第2世代中粗粒自形黄铁矿(Py2);第3世代粗粒黄铁矿(Py3)。Py1A呈莓球状,直径介于10～50μm,w(Co)/w(Ni)小于1,w(S+As)/w(Fe)大于2,部分黄铁矿因受到热液改造,莓球中w(Co)/w(Ni)大于1,w(S+As)/w(Fe)小于2;Py1B呈多孔海绵状,w(Co)/w(Ni)大于1,w(S+As)/w(Fe)小于2。Py2呈中粗粒五角十二面体,w(Co)/w(Ni)介于1.41～3.78,w(S+As)/w(Fe)由内向外逐渐升高,介于1.93～2.02,w(Au)/w(As)介于0.023～0.108。Py3呈粗粒立方体晶,周围发育石英压力影,w(Co)/w(Ni)介于1.36～1.39,w(S+As)/w(Fe)介于1.98～2.00。结合地质背景分析认为,黄铁矿微晶直接聚集形成Py1A(莓球状),或在松散状态下经胶结作用形成Py1B(多孔海绵状),并遭受热液叠加改造。Py2(中粗粒五角十二面体)由含矿热液环绕多孔海绵状核部直接结晶形成,Py3(粗粒自形立方体)由晚期热液结晶形成,并同时遭受构造变形活动。该区黄铁矿的特征对于判别地质环境有标型意义。 相似文献
8.
川西龙门山地区元古代VMS铜矿床:硫化物微量元素和硫同位素证据 总被引：3，自引：0，他引：3
川西龙门山地区元古宙变质火山碎屑岩系中发育一系列块状黄铁矿型铜矿床,含矿围岩形成于岛弧构造环境.矿石中黄铁矿占金属矿物总质量分数的90%左右,黄铜矿质量分数为0.8%~3.0%,闪锌矿为1%~4%.矿石主要元素为Fe、S、Zn、Cu、Mn等,其次为Ag、Au、Pb、Se、Cd、Ga、Ti、V、Co等元素,全区各矿层矿石中δ(34S)分布范围为 -1.5‰~+15.9‰,平均为 +7.6‰,N(32S)/N(34S)值为22,据此推断成矿物质应来自地壳深部,与洋壳俯冲作用有关.主要金属硫化物及其微量元素和硫同位素组成特征表明矿床类型为火山成因块状硫化物矿床,即VMS矿床. 相似文献
9.
《矿物学报》2016,(1)
西藏多龙矿集区铁格隆南铜(金-银)矿床是西藏第一例得到确认的浅成低温热液矿床。矿床中黄铁矿发育广泛且特征明显,矿区钻孔浅部内的黄铁矿发育环带状结构,这在其他类型铜矿床中较少见。本文通过系统的野外钻孔地质编录、镜下鉴定和电子探针分析等对矿区广泛发育的黄铁矿进行了矿物学特征、微量元素及特有的环带状结构进行了系统的研究,并解释环带状黄铁矿的成因及其地质意义。结果表明:铁格隆南矿床内黄铁矿的环带为生长不连续形成的。环带状黄铁矿的环带从核部到边缘,其Co/Ni比值,Au、Cu和Se等元素含量呈现出一定的韵律变化,形成外部环带时流体的温度依次增高且均高于矿物内部环带形成时的温度,并且外部环带形成时流体内Au、Cu和Se元素的含量高于内部环带形成时流体内含量。环带状黄铁矿内的Au是以Au+替换Fe2+的形式进入黄铁矿晶格,而Cu一部分以Cu2+置换Fe2+形成Cu S2形式存在,一部分以含铜硫化物包体的形式存在。矿区环带状黄铁矿多数发育在矿体浅部,接近铜矿化强烈的位置,且该位置Au、Ag和Cu元素的品位均较高。因此,环带状黄铁矿可以作为铁格隆南矿区Au、Ag和Cu元素开始富集的指示标志。 相似文献
10.
在胶东莱州吴一村地区完成的3266.06 m深钻,是目前焦家金成矿带最深见矿钻孔,研究钻孔揭露的深部矿石中金矿物及黄铁矿微量元素特征,对探讨深部成矿作用演化具有重要意义。笔者采取深钻中2420~3206 m垂深的岩（矿）芯样品进行了详细的岩相学和矿相学研究,结合扫描电镜和电子探针微区分析,研究了矿石中金矿物的赋存状态和成分。对不同成矿阶段形成的黄铁矿进行了LA-ICPMS微量元素分析。研究结果表明,深部矿石中载金矿物主要为黄铁矿,其次为石英、黄铜矿、方铅矿,可见金主要以自然金和银金矿的形式存在,以晶隙金和裂隙金为主,其次为包体金。与浅部金矿床比较,深部金的成色较高。黄铁矿分为6种类型,第Ⅰ成矿阶段形成富Co型黄铁矿Py1,第Ⅱ成矿阶段形成富Ni型黄铁矿Py2a和Py2b,第Ⅲ成矿阶段形成富Au、As型黄铁矿Py3a和富Au、Ag、Pb、Bi型黄铁矿Py3b,第Ⅳ成矿阶段形成贫微量元素黄铁矿Py4。其中,Py1和Py2a发生强烈破碎,裂隙表面对热液中的Au络合物产生吸附作用,对金沉淀富集起重要作用。黄铁矿中Co、Ni、As等微量元素主要以类质同象形式赋存,而Au、Ag、Cu、Pb、Zn、Bi等主要以纳米级、微米级矿物包体形式赋存。Pb+Bi、Cu+Pb+Zn、Te+Bi与Au+Ag呈明显正相关,而Au与As相关性较差。黄铁矿中Co、Ni含量较低,而Au+Ag+As或Au+Ag+Pb+Bi+Cu含量较高指示成矿有利。另外,黄铁矿中Co、Ni含量较高,并且破碎强烈,成矿相关元素含量较高也指示成矿有利。 相似文献
11.
Mantle xenoliths are common in the Cenozoic basalts of the Changbaishan District,Jilin Province,China.Sulfide assemblages in mantle minerals can be divided into three types:isolated sulfide grains,sulfide-meh inclusions and filling sulfides in fractures.Sulfide-meh inclusions occur as single-phase sulfides,sulfide-silicate melt,and CO_2-sulfide-silicate melt inclusions. Isolated sulfide grains are mainly composed of pyrrhotite,but cubanite was found occasionally.Sulfide-meh inclusions are mainly composed of pontlandite and MSS,with small amounts of chalcopyrite and talnakhite.The calculated distribution coefficient K_(D3)for lherzolite are similar to that of mean experimental value.The bulk sulfides in lherzolite were in equilibrium with the enclosing minerals, indicating immiscible sulfide melts captured in partial melting of upper mantle.Sulfide in fractures has higher Ni/Fe and(Fe Ni)/S than those of sulfide melt inclusions.They might represent later metasomatizing fluids in the mantle.Ni/Fe and(Fe Ni)/S increase from isolated grains,sulfide inclusions to sulfides in fractures.These changes were not only affected by temperature and pressure,hut by geochemistry of Ni,Fe and Cu,and sulfur fugacity as well. 相似文献
12.
Yu. A. Poltavets V. N. Sazonov Z. I. Poltavets G. S. Nechkin 《Geochemistry International》2006,44(2):143-163
Relationships between noble-metal and oxide-sulfide mineralization during the origin of the Volkovsky gabbroic pluton are discussed on the basis of geochemical data and thermodynamic calculations. The basaltic magma initially enriched in noble metals (NM) relative to their average contents in mafic rocks, except for Pt, is considered to be a source of Pd, Pt, Au, and Ag in the gabbroic rocks of the Volkovsky pluton. The ores were formed with a progressive gain of NM in the minerals during the fractionation of the basaltic magma. The active segregation of NM in the form of individual minerals (palladium tellurides and native gold) hosted in titanomagnetite and copper sulfide ore occurred during the final stage of gabbro crystallization, when the residual fluid-bearing melt acquired high concentrations of Cu, Fe, Ti, and V, along with volatile P and S. Copper sulfides—bornite and chalcopyrite—are the major minerals concentrating NM; they contain as much as 22.65–25.20 ppm Pd and 0.74–1.56 ppm Pt; 4.39–8.0 ppm Au, and 127.2–142.6 ppm Ag, respectively. The copper ore and associated NM mineralization were formed at a relatively low sulfur fugacity, which was a few orders of magnitude (attaining 5 log units) lower than that of the pyrite-pyrrhotite equilibrium. The low sulfur fugacity and the close chemical affinity of Pd and Pt to Te precluded the formation of pyrrhotite, pyrite, and PGE disulfides. The major ore minerals and NM mineralization were formed within a wide temperature range (800–570°C), under nearly equilibrium conditions. Foreign elements (Ni, Co, and Fe) affected the thermodynamic stability of Pd and Pt compounds owing to the difference in their affinity to Te and to elements of the sulfur group (S, Se, and As). The replacement of Pd with Ni and Co and, to a lesser extent, with Pt and the replacement of Te with S, As, and Se diminish the stability field of palladium telluride. Comparison of Pd tellurides from copper sulfide ores at the Volkovsky and Baronsky deposits showed the enrichment of the former in Au, Sb, and Bi, while the latter are enriched in Pt, Ni, and Ag. The enrichment of Pd tellurides at the Baronsky deposit in Ni is correlated with the analogous enrichment of the host gabbroic rocks. 相似文献
13.
江苏六合新生代玄武岩中地幔捕虏体的硫化物相研究 总被引：13，自引：3，他引：10
江苏六合一带碱性玄武岩中的出露有以尖晶石二辉橄榄岩为主的地幔捕虏体,这些地幔矿物中普遍有硫化物相出现：（１）被寄主矿物捕获的早期硫化物颗粒。（２）产于矿物晶粒边界或次生裂隙充填物,（３）硫化物包裹体,包括单相硫的包裹体、硫化物－玻璃两相熔体包裹体和ＣＯ／２－硫化物－玻璃（含硅酸盐子矿物）的多相包裹体,电子探针分析表明,硫化物包裹体比例隙中硫化物具有更高的相对Ｆｅ和Ｓ含量,较低的Ｎｉ含量。硫化物包裹 相似文献
14.
Djerfisherite, a Cl-bearing potassium sulfide (K6Na(Fe,Ni,Cu)24S26Cl), is a widespread accessory mineral in kimberlite-hosted mantle xenoliths. Nevertheless, the origin of this sulfide in nodules remains disputable. It is usually attributed to the replacement of primary Fe–Ni–Cu sulfides when xenoliths interact with a K-and Cl-enriched hypothetical melt/fluid. The paper is devoted to a detailed study of the composition and morphology of djerfisherite from a representative collection (22 samples) of the deepest mantle xenoliths—sheared garnet peridotite, taken from the Udachnaya-East kimberlite pipe (Yakutia). Four types of djerfisherite were distinguished in the mantle rocks on the basis of morphology, spatial distribution, and relationships with the rock-forming and accessory minerals in the nodules. Type 1 was found in the rims of polysulfide inclusions in the rock-forming minerals of the xenoliths; there, it was younger than the primary sulfide assemblage pyrrhotite + pentlandite ± chalcopyrite. Type 2 formed rims around large polysulfide segregations (pyrrhotite+ pentlandite) in the xenolith interstices. Type 3 formed individual grains in the xenolith interstices together with other sulfides, silicates, oxides, phosphates, and carbonates. Type 4 was present as a daughter phase in the secondary melt inclusions which occurred in healed cracks in the rock-forming minerals of the xenoliths. Along with djerfisherite, the inclusions contained silicates, oxides, phosphates, carbonates, alkaline sulfates, chlorides, and sulfides. The results indicate that djerfisherite from the xenoliths is consanguine with kimberlite. Djerfisherite both in the sheared-peridotite xenoliths from the Udachnaya-East pipe and in different xenoliths from other kimberlite pipes worldwide formed owing to the interaction between the nodules and kimberlitic melts. Djerfisherite forming individual grains in the melt inclusions and xenolith interstices crystallized directly from the infiltrating kimberlitic melt. Djerfisherite bounding the primary Fe–Ni ± Cu sulfides formed by their replacement as a result of a reaction with the kimberlitic melt. 相似文献
15.
Cora C. Wohlgemuth-Ueberwasser Raúl O. C. Fonseca Chris Ballhaus Jasper Berndt 《Mineralium Deposita》2013,48(1):115-127
Typical magmatic sulfides are dominated by pyrrhotite and pentlandite with minor chalcopyrite, and the bulk atomic Cu/Fe ratio of these sulfides is typically less than unity. However, there are rare magmatic sulfide occurrences that are dominated by Cu-rich sulfides (e.g., bornite, digenite, and chalcopyrite, sometimes coexisting with metallic Cu) with atomic Cu/Fe as high as 5. Typically, these types of sulfide assemblages occur in the upper parts of moderately to highly fractionated layered mafic–ultramafic intrusions, a well-known example being the Pd/Au reef in the Upper Middle Zone of the Skaergaard intrusion. Processes proposed to explain why these sulfides are so unusually rich in Cu include fractional crystallization of Fe/(Ni) monosulfide and infiltration of postmagmatic Cu-rich fluids. In this contribution, we explore and experimentally evaluate a third possibility: that Cu-rich magmatic sulfides may be the result of magmatic oxidation. FeS-dominated Ni/Cu-bearing sulfides were equilibrated at variable oxygen fugacities in both open and closed system. Our results show that the Cu/Fe ratio of the sulfide melt increases as a function of oxygen fugacity due to the preferential conversion of FeS into FeO and FeO1.5, and the resistance of Cu2S to being converted into an oxide component even at oxygen fugacities characteristic of the sulfide/sulfate transition (above FMQ?+?1). This phenomenon will lead to an increase in the metal/S ratio of a sulfide liquid and will also depress its liquidus temperature. As such, any modeling of the sulfide liquid line of descent in magmatic sulfide complexes needs to address this issue. 相似文献
16.
The bulk composition, mineralogy and mineral chemistry of base-metal sulfides have been investigated in the Fe-Ni-(Cu) ore deposits of the Ivrea-Verbano basic complex.The sulfide ores mostly display textural evidence of having been primarily deposited as an immiscible melt. Bulk compositions of the ores indicate that considerably low Ni/Fe and Ni/Co ratios are found in deposits developed close to metasedimentary country rocks, possibly as a result of mixing with sedimentary sulfur.Phase relations of primary sulfides indicate that early crystallization of the ore was dominated by a monosulfide solid solution (Mss) with a pyrrhotite composition, from which pentlandite and chalcopyrite were formed through subsolidus exsolution. Pentlandite from contaminated ores is typically enriched in Co. Troilite and hexagonal intermediate pyrrhotite intergrowths frequently occur due to low-temperature equilibration of metal-rich pyrrhotites, suggesting a low S fugacity of the original sulfide melt.The sulfides may be locally mobilized and redeposited along shear zones within the same host rock, giving rise to fairly massive ores having a typical cemented-breccia texture. Bulk composition and assemblages suggest that mobilization occurred at various temperatures during the cooling history of the ore, when sulfides were still in the molten state or at a lower temperature under the influence of abundant deuteric fluids. In this last case, growth of pyrite is seen as being possibly due to sulfurization and/or oxidation. 相似文献
17.
Small bodies of pyrrhotite, chalcopyrite, minor pentlandite, and magnetite occur at the peripheries of podiform bodies of chromite in ultramafic ophiolitic rocks at Tsangli, Eretria, central Greece. Banding of magnetite and sulfide within the bodies is reminiscent of magmatic banding. A magmatic origin has been proposed for similar sulfide masses in the Troodos ophiolite (Panayiotou, 1980). The compositions of the host rocks, chromite, and of the sulfides have been investigated. On average, the sulfide mineralization, recalculated to metal content in 100% sulfide, contains 0.55% Ni, 5.15% Cu, 0.29% Co, 9 ppb Pd, 179 ppb Pt, 16 ppb Rh, 112 ppb Ru, 31 ppb Ir, 58 ppb Os, and 212 ppb Au. These metal contents, particularly the high Cu/(Cu+Ni) ratio of 0.78 and the Pt/(Pd+Pt) ratio of 0.95, are inconsistent with the sulfides having reached equilibrium with their Ni rich host rocks at magmatic temperatures and accordingly it is concluded that they are not of magmatic origin. The average 34S value of the sulfide bodies is +2 while that of a sample of pyrite from country-rock schist is –15.6. These values are inconclusive as to the origin of the sulfur. It is suggested that the sulfides have been precipitated by hydrothermal fluids, possibly those responsible for the serpentinization of the host rocks. The source of the metals may have been the host rocks themselves. 相似文献
18.
粤北大宝山铜多金属矿床一直存在燕山期岩浆热液成因和海西期火山喷流成因之争,争议的焦点在于块状、似层状硫化物矿体的成因。本文在全面开展矿区地质调查和钻探查证的基础上,对块状、似层状和脉状硫化物矿石中的黄铁矿和磁黄铁矿开展EPMA和LA-ICP-MS原位分析。测试结果表明,不同产状黄铁矿的平均分子式相似,分别为FeS_(1.98)、FeS_(1.99)和FeS_(1.98),似层状和脉状硫化物中磁黄铁矿的平均化学式为Fe_(0.886)S和Fe_(0.874)S,属形成温度相对较低单斜磁黄铁矿。与花岗岩岩浆热液标型黄铁矿相比,不同产状的黄铁矿和磁黄铁矿中Co、Ni、Mn、Se和Ge等元素以类质同象形式赋存,它们含量较低但稳定,Cu、Pb、Zn、Ag、Bi和Tl及Ga主要以微细矿物子晶形式存在,其含量丰富,但变化明显。从块状、似层状到脉状硫化物矿体,黄铁矿和磁黄铁矿中Co、Zn和Se的含量及Co/Ni值降低,而Cu、Pb、Ag、Bi等元素的含量明显升高。结合矿区次英安斑岩的产状和含矿性特征表明,大宝山矿床块状、似层状和脉状硫化物矿体都是次英安斑岩深部岩浆房产出的含矿流体在不同赋矿环境中的产物。 相似文献
19.
G. A. Palyanova Yu. L. Mikhlin N. S. Karmanov K. A. Kokh Yu. V. Seryotkin 《Doklady Earth Sciences》2017,474(2):636-640
The forms of Au and Ag occurrence in the crystallization products of melts in the Fe–S–Ag–Au system depending on the proportions of Fe/S and Ag/Au have been studied at (Fe + S)/(Ag + Au) = 0.1. It is shown that the S-rich systems with S/Fe = 2 contain Au–Ag sulfides and Au–Ag alloys. The systems depleted in S with S/Fe = 1 contain only Au–Ag alloys. The results of XPS provide evidence for the sulfide and metallic components of Au and Ag among the crystallization products of melts in the system studied at S/Fe = 2 and a metallic component with S/Fe = 1. According to the data of electron microprobe analysis, the content of “invisible” forms of noble metals in pyrite and pyrrhotite is < 0.024 wt % for Au and <0.030 wt % for Ag; the contents of “invisible” Au and Ag in troilites are 0.040 ± 0.013 wt % Au and 0.079 ± 0.016 wt % Ag. 相似文献