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1.
Developments in the spark source mass spectrographic technique of trace element analysis have improved the precision of the method by about a factor of three. The main improvements have stemmed from corrections for interferences and corrections to the internal standard. The magnitude of interference corrections for the REE depends on the relative rather than the absolute abundances, being negligible for flat REE patterns and large for heavy REE depleted patterns. Precise determination of the photoplate intensity-density relationship is also considered to be important.Our data for BCR-1 fell within ± 3% of the “best estimate” of the “true” values. A set of relative sensitivity values for 31 elements show a factor of 25 between the most sensitive element (Rb) and the least sensitive (Ir). The relative element sensitivities depend on elemental boiling point, ionisation potential, and nuclide mass. 相似文献
2.
Naresh C. Samtani John M. Kulicki 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2020,14(3):231-243
ABSTRACT In the bridge design specifications of the American Association of State Highway and Transportation Officials (AASHTO) using the Load and Resistance Factor Design (LRFD) method, the loads and resulting force effects are given two-letter designations, e.g. “SE” for “force effects due to settlement”. The SE load factor is used to develop factored values of the induced force effects such as moments and shears in a bridge structure due to foundation movements. In 2018 AASHTO committees voted to adopt calibrated values of the SE load factors that account for the uncertainty in predicted foundation movements from different analytical methods. However, additional uncertainty can occur in the differential settlements. This paper explores the additional uncertainty in differential settlements of bridge foundations and retaining walls using the datasets for two analytical methods that were used by AASHTO to develop the SE load factors for foundation settlement. Normalised probability exceedance charts (NPECs), that integrate the concept of reliability index and data correlation, have been developed and their application in bridge and wall design process is discussed for a variety of scenarios. Guidance is provided for the practical implementation of differential settlement in bridge analysis through an example problem. 相似文献
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5.
《Geoforum》2016
This paper chronicles the rhetorical mechanisms that fostered a potentially radical re-thinking of water rights and property in a most unlikely place: the libertarian Western U.S., and mobilized by the least likely of actors: state officials. There is growing interest, in geography and beyond, in the question of what constitutes the “properly political” in contexts where dissent is actively forestalled by those with power. Much has been written about the “properly political” as the disruption of the established order by previously excluded actors. Comparatively less research, however, has focused on the “conditions of possibility” that might exist within ostensibly “post-political” governing arenas. This paper deepens our understanding of this by examining a participatory water planning group in Montana, which was convened by the state to develop recommendations for a new state water plan. The group was inspired by an alternative drought-management model called “shared giving.” Imbued with principles of “collectivism” and “equality,” the model was strategically (and necessarily) promoted through the discursive shell of the existing prior appropriation system. This was accomplished not by an oppositional force of marginalized actors, but state officials that are rarely, if ever, deemed “disruptive,” and through tactics that are best characterized as post-political. We interpret this case as reflecting a hybrid governing assemblage that highlights both post-political closure and transformative possibilities simultaneously, and conclude by suggesting that the post-political concept, itself, risks foreclosing on conditions whereby fruitful outcomes might become possible from within established governing frameworks otherwise written-off as post-political. 相似文献
6.
This paper presents new major and trace element data from 150 garnet xenocrysts from the V. Grib kimberlite pipe located in the central part of the Arkhangelsk diamondiferous province (ADP). Based on the concentrations of Cr2O3, CaO, TiO2 and rare earth elements (REE) the garnets were divided into seven groups: (1) lherzolitic “depleted” garnets (“Lz 1”), (2) lherzolitic garnets with normal REE patterns (“Lz 2”), (3) lherzolitic garnets with weakly sinusoidal REE patterns (“Lz 3”), (4) lherzolitic garnets with strongly sinusoidal REE patterns (“Lz 4”), (5) harzburgitic garnets with sinusoidal REE patterns (“Hz”), (6) wehrlitic garnets with weakly sinusoidal REE patterns (“W”), (7) garnets of megacryst paragenesis with normal REE patterns (“Meg”). Detailed mineralogical and geochemical garnet studies and modeling results suggest several stages of mantle metasomatism influenced by carbonatite and silicate melts. Carbonatitic metasomatism at the first stage resulted in refertilization of the lithospheric mantle, which is evidenced by a nearly vertical CaO-Cr2O3 trend from harzburgitic (“Hz”) to lherzolitic (“Lz 4”) garnet composition. Harzburgitic garnets (“Hz”) have probably been formed by interactions between carbonatite melts and exsolved garnets in high-degree melt extraction residues. At the second stage of metasomatism, garnets with weakly sinusoidal REE patterns (“Lz 3”, “W”) were affected by a silicate melt possessing a REE composition similar to that of ADP alkaline mica-poor picrites. At the last stage, the garnets interacted with basaltic melts, which resulted in the decrease CaO-Cr2O3 trend of “Lz 2” garnet composition. Cr-poor garnets of megacryst paragenesis (“Meg”) could crystallize directly from the silicate melt which has a REE composition close to that of ADP alkaline mica-poor picrites. P-T estimates of the garnet xenocrysts indicate that the interval of ～60–110 km of the lithospheric mantle beneath the V. Grib pipe was predominantly affected by the silicate melts, whereas the lithospheric mantle deeper than 150 km was influenced by the carbonatite melts. 相似文献
7.
In 1876 Blytt proposed a post-glacial climatic classification, maintaining that the then temperature fluctuated 1- 2℃ higher or lower than that today. Lamb (1969) held that in Europe " the axis of the subtropical high pressure belt was generally displaced north by about 10° latitudes" during the Hypsithermal and that the temperature was three to six times higher than that in the postglacial period.In China, there appear relict beachrocks (living fossils) in tropical tidal zones from the Bohai Bay (40° N) to coastal areas in South China. Many relict tropical marine fossils were discovered, such as Ostrea gigas in Tianjin (which is larger than that found today in Hainan), Placuna placenta in Zhejiang and Spondylus sp. in Fujian. In Hebei, Henan and Zhejiang provinces and Guilin of Guangxi, such tropical fossil animals as Elephas maximus and Rhinoceros sp, were discovered, and in Hebei and Jiangsu provinces such fresh water fossils as Unio douglasiae were found. Their living species are still seen in So 相似文献
8.
To clarify unanswered questions of site formation, geology and the archaeology of the Berelekh geoarchaeological complex, a special survey was undertaken in 2009 of the area surrounding the site. Several geological units have been revealed. By establishing the spatial and temporal relationship of these deposits—as well as their age—we have reconstructed the formation history of the Berelekh bone bed. The mammoth bone deposit belongs to a paleochannel. Radiocarbon dating of mammoth remains at Berelekh demonstrates rapid accumulation during the Bølling warming. Human involvement in its formation is, at best, questionable, since there is no real overlap between the radiocarbon dates associated with past human activity, and those of the mammoth bone bed. This study confirms that humans used mammoth bone remains after the bone bed was deposited. Culturally, the Berelekh “site” does not have any relationship to the so‐called “Dyuktai culture.” Instead, the Berelekh archaeological finds (side notched stone pendants) show certain similarities to non‐microblade terminal Pleistocene assemblages found from Yenisei to Kamchatka. Additionally, the Berelekh complex presents a clear analogy with lithics found in Eastern Beringia. Teardrop‐shaped incomplete bifaces found in the assemblage are comparable to the Chindadn points of Alaska. The nature of this “Chindadn connection” is intriguing but it is the only visible cultural link between Western and Eastern Beringia. 相似文献
9.
Snježana Blažeković Smojić Jasmin Smajlović Georg Koch Jeronim Bulić Mladen Trutin Ernest Oreški Anđa Alajbeg Vladimir Veseli 《Organic Geochemistry》2009,40(8):833-845
Laminated limestone and calcareous shale outcrop samples from the Late Jurassic “Leme?” facies (Croatia) were investigated to characterize their organic facies and palynofacies and their hydrocarbon generative potential. The results indicate that the organic rich sediments of “Leme?” facies were deposited within a relatively shallow marine environment at low redox potential, characterized as an oxygen depleted depositional setting with stratified bottom waters of the carbonate platform (Adriatic Carbonate Platform). The organic rich samples contain a high portion of lipid rich amorphous kerogen of algal/phytoplankton origin, enriched by bacterial biomass. Most of the analyzed samples have total organic carbon contents (TOC) greater than 3%, Rock-Eval S2 >20 mg HC/g rock, yielding Hydrogen Index (HI) values ranging from 509–602 mg HC/g TOC. According to these results, the analyzed samples have very good to excellent oil generative potential. Relatively high sulfur content suggests that the kerogen is best described as Type II-S. Biomarker maturity parameters, as well as the fluorescence of the isolated kerogen, show that the organic matter is at early to peak oil thermal maturity. The observed level of thermal maturity indicates that these samples were once buried to depths of ～5.5–5.8 km before being uplifted in the late Tertiary. The surface outcrops of the “Leme?” facies suggest that these strata have significant source potential and are the likely source of oil in the Croatian External Dinarides. 相似文献
10.
Except for the fringing reef, the limestones of Christmas Island in the Indian Ocean are of Late Eocene (Tertiary “b") and Early Miocene (Tertiary “e” to “f") age. The Upper Eocene limestone is an algal limestone containing Discocyclina, Nummulites, and Heterostegina. The Lower Miocene limestone is an algal limestone containing in its lower part species of Lepidocyclina (Eulepidina) followed by Miogypsinoides dehaarti. Miogypsinoides dehaarti extends into the zone of Flosculinella bontangensis. No rocks younger than Burdigalian were identified other than on the fringing reef which contains an assemblage of Pliocene‐Pleistocene Foraminifera. 相似文献
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C.L. Melcher 《Geochimica et cosmochimica acta》1982,46(10):1999-2000
The usefulness of an “effective” trap depth to approximate the group of closely spaced trap depths responsible for the low temperature thermoluminescence in meteorites is evaluated on the basis of its success when used with the TL equivalent dose method to determine terrestrial ages of Antarctic meteorites. The ages determined in this way agree in every instance with terrestrial age determinations based on 14C, 26Al, 36Cl, and 53Mn. The application of an “effective” trap depth in this TL dating technique in no way implies that the TL signal actually arises from a single trap depth. 相似文献
12.
Mevlut Uyan 《Environmental Earth Sciences》2014,71(4):1629-1639
Landfill site selection is a critical issue in the urban planning process because of its enormous impact on the economy, ecology, and the environmental health of the region. Landfill site selection process aims to locate the areas that will minimize hazards to the environment and public health. Multi-criteria evaluation methods are often used for different site selection studies. The purpose of this study was to determine suitable landfill site selection by using the geographical information system and the analytic hierarchy process in the study area. The final index model was grouped into four categories as “low suitable”, “moderate”, “suitable” and “best suitable” with an equal interval classification method. As a result, 12.69 % of the study area was low suitable, 7.27 % was moderately suitable, 13.79 % was suitable, and 15.52 % was the best suitable for landfilling; 50.72 % of the study area is not suitable for a landfilling. 相似文献
13.
60 geochemical laboratories from the world over, contributing in all 3687 bits of chemical data on 60 elements, haue willingly participated in the study of SOIL-5 as a reference material. The preparation of SOIL-5 in 45 kg and homogeneity teats are described; in addition, all the data compiled are presented. In evaluating the compiled data, the use of four concurrent tests for outlier-rejection at the same level of significance, has been applied. After proper statistical treatment, “recommended values” could be established for 31 elements, most of them trace elements and “information values” for 29 elements. 23 of the recommended values could be given with a “relatively high” degree confidence whereas the other 18 recommended Values with a “reasonable” degree of confidence. An attempt is made to compare the analytical methods employed; the existence of possible sy3tematic differences is pointed ont. 相似文献
14.
Håakon Austrheim 《Geochimica et cosmochimica acta》1983,47(3):655-658
Cameronet al. (1981) proposed a “Free Line Model” for calculating formation ages for rock systems that have undergone local scale homogenization by 87Sr migration. This model is valid only if the variation in the ratio is independent of the variation in Sr-content within the rock system. If Sr increases linearly with increasing the calculated age will be too high. If Sr decreases linearly with increasing , the calculated age will be systematically too low. If the rate of change in Sr with increasing varies systematically through a rock system the “isochron” will be curved and the calculated ages will be younger or older than the real age, depending on the position of samples in relation to the curvature of the “isochron.” This problem with the “Free Line Model” is inherited in both the “Bulk Earth Model 1” and the “Bulk Earth Model 2.” 相似文献
15.
Byung-Su Lee 《《地质学报》英文版》2014,88(1):35-45
Abundant conodont elements have been recovered from the Hwajeol Formation, to allow five zones to be erected: Proconodontus, Eoconodontus notchpeakensis, Cambrooistodus minutus, Cordylodus proavus, and Fryxellodontus inornatus-Monocostodus sevierensis-Semiacontiodus lavadamensis zones, in ascending order. More confident biozones are recognized in the Sesong Slate and lower Hwajeol Formation in the Makgol section, a part of the southern limb of the Baekunsan syncline, Taebaeksan Basin, Korea, especially focusing on the conodont biostratigraphic boundary of two units, and the subdivision potential of the previous "Proconodontus Zone", lowermost biozone of the Hwajeol Formation. Similarly, only a few conodont elements recovered from upper 14.5 m interval, namely the Furongian portion of the Sesong Slate, in the Makgol section did not allow erection of a biozone. Nevertheless, this part of the unit plus the basal 2.5 m interval of the Hwajeol Formation is characterized by the occurrence of Prooneotodus rotundatus(Druce and Jones), Teridontus nakamurai(Nogami), Phakelodus elongatus(An) and Phakelodus tenuis Müller. This interval marks the early Furongian "Prooneotodus rotundatus Zone". The rest of the measured section yielded relatively abundant conodonts, so three conodont biozones are proposed, based on the successive appearance of key species: Proconodontus tenuiserratus, Proconodontus posterocostatus, and Proconodontus muelleri zones, in ascending order, and thus allowing subdivision of the previous "Proconodontus Zone". The four conodont biozones are correlated with the relevant biozones of North and South China, and North America. 相似文献
16.
We present here a pilot study to examine trophic level effects and migration patterns at the middle Shang Dynasty site of Xiaoshuangqiao in Henan Province using δD results combined with δ13C and δ15N values. A total of 33 specimens (17 humans, 7 cattle, 5 pigs, 3 sheep, 1 dog) of bone collagen were isotopically analyzed for δ13C, δ15N, and dD values. A strong positive correlation (R2 = 0.94) between mean δ15N and δD values of herbivores (cattle and sheep), omnivores (pig), carnivores (dog) and humans was observed. The δD results were found to increase by ~10‰ to 20‰ from herbivores to omnivores to carnivorous, evidence that collagen δD results are a useful indicator for the study of trophic levels and dietary patterns at archaeological sites. The δD results were also used to examine the origins of two different groups of individuals buried at Xiaoshuangqiao. Individuals buried in sacrificial pits of district V had mean δD values (?47.0 ± 2.9‰, n = 11) that were significantly (p = 0.049) elevated compared to the people buried in the stratigraphy of district IX (?51.3 ± 3.3‰, n = 3), indicating that they were ingesting water from different locations. In addition, the D values of the people buried in the stratigraphy were similar to the pigs (?54.5 ± 4.2‰, n = 5) at Xiaoshuangqiao, suggesting that they were most probably of the local population, and that the individuals buried in the sacrificial pits were most possibly from the coast and prisoners of the Dongyi (“东夷”) people. Thus, δD results have the potential to examine human origins and migration patterns and should be increasingly used in conjunction with δ13C and δ15N values at archaeological sites. 相似文献
17.
A suite of 11 gem-quality, optically completely clear garnet crystals with a broad variety of compositions in the space of the end members pyrope–almandine–spessartine–grossular–andradite–goldmanite were analyzed for trace amounts of “water” by nuclear reaction analysis, NRA, based on the reaction 1H(15N, αγ)12C, and by single-crystal absorption spectroscopy in the νOH vibrational range using microscope-FTIR-spectroscopic methods. The aim was to establish a calibration of the highly sensitive IR method with high areal resolution for “water” determination in garnets, by studying garnets of a wide compositional range, and to check for compositional dependencies of the integral molar absorptivities of the “water” component, ?int[1molH2O?1cm?2], in the nominally “water”-free garnets. The results of NRA show a broad variation of water contents in the range (14 ± 3) to (950 ± 80) wt ppmH2O, the values being low and very high for the garnet solid solutions (PyrAlm)SS and close-to-end-member GrossSS, respectively. There were no indications of inhomogeneities in the OH distribution, except possibly for one of the garnets (grossular, variety hessonite, from Tanzania). The quantitative evaluation of the complex νOH spectra, which showed similar shape only for members of the (PyrAlm)SS, yielded integral absorption coefficients, αint (cm?2), which allowed the calculation of integral molar absorptivities, ?int, using the “water” values of NRA. The ?int values obtained varied in a wide range but with no obvious correlation with the composition of the garnet except for the extremely high values, in the 104 range, of the two specimen with compositions close to end-member grossular. In all other garnets, ?int was in the 103 range with an average of ?int=3630±1580[1molH2O?1cm?2]. Therefore, this value is proposed for the use in routine “water” determinations of compositionally different garnets by the micro-IR method, except for garnets near to end-member grossular. 相似文献
18.
Benthic foraminifera, preserved in the Late Cretaceous organic carbon-rich sediments of Gamba, southern Tibet, provide high-resolution proxies for sea-level changes and dissolved oxygen fluctuations of southeastern Tethys. The fossils were statistically analyzed and divided into three faunas of "Cenomanian fauna", "Turonian fauna", and "Coniacian fauna". A middle neritic-upper bathal environment (50-250m) was estimated considering the ratios of planktonic and epifaunal benthic foraminifera (P/(P+E)), the morphological analysis according to the studies of recent foraminifera and the abundant distributions of depth-related species such as Alabamina creta, Laevidentalina sp., Praebulimina spp., Pleurostomella cf. naranjoensis, Pyrulina sp., Quinqueloculina spp., Haplophragmoides spp., etc. The result shows an almost parallel trend with the global transgressive and regressive cycles, but the former fluctuates more frequently at upper Cenomanian, which probably indicates tectonic instability of the continental margin. According to the benthic foraminiferal richness (BFN), Shannon-Weiner diversity (H(s)), as well as benthic foraminiferal oxygen index (BFOI), five periods of oxygen depleted conditions (dysoxic-anoxic) have been recognized. They correspond to the OAE2, the lower Turonian, the upper Turonian, the Turonian-Caniacian boundary event and the probably OAE3. In addition, the oxygen fluctuations in Gamba might be controlled directly by sea-level changes, while the paleoproductivity and oxygen conditions interacted with each other under oxygen deficiency environments. 相似文献
19.
James Anderson 《Geoforum》1980,11(2):171-178
Geography has been traditionally concerned with “Nature”, “Place” and “Space”, and yet has failed to make profound contributions to their study and analysis because the discipline lacks a consistent theory of society and its relationships with “Nature”. This paper examines some of the reasons for this deficiency and proposes that Historical Materialism provides the best framework for resolving this problem. 相似文献
20.
This study uses illite crystallinity,chlorite crystallinity,illite polytypes,the b_0 cell-dimension of K-white mica,clay mineral assemblages and mineral geothermo-geobarometers to investigate the overprint of diagenesis and metamorphism on the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang in northeastern Hunan Province,China.Illite crystallinity Kbler index(KI) of the 2μm fractions ranges from 0.225 to 0.485°Δ2θ while chlorite crystallinity Arkai index(AI) ranges from 0.244 to 1.500°Δ2θ.This indicates that the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang were overprinted with diagenesis and anchi- to epimetamorphism.Peak metamorphic temperature is estimated with the IV site chlorite geothermometer roughly at 360℃.The b_0 cell dimension values of illites(K-mica) range from 0.9002 to 0.9054 nm and,on average,at 0.9030 nm for the Meso-Neoproterozoic.Based on cumulative frequency curves of illite(K-mica) b_0 cell dimension,the peak metamorphic pressure of the MesoNeoproterozoic along the profile Yueyang-Linxiang is derived of an intermediate pressure type.Most illites occur in the 2M_1 polytype and some of them in a mixture of 2M1+1M types especially those in the Paleozoic.This result partly agrees with the conclusion of the lower greenschist and greenschist facies of the Lengjiaxi and Banxi Groups.However,it is not agreed with the sedimentary cover from the Sinian to the Lower Paleozoic or from the Banxi Group to the Lower Paleozoic.Crustal thickening due to "collision" between the Yangtze and Cathaysia blocks led to an increase in the thickness of the Meso-Neoproterozoic to ca.14 km and resulted in a temperature increase in those rocks due to burial.The very low grade to low grade metamorphism overprinting the Meso-Neoproterozoic implies that the so called "Chiangnania or Jiangnan orogen" was no relative with the "Grenvillian orogeney;instead,it might be a continuous amalgamation product between the Yangtze and Cathaysia blocks. 相似文献