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1.
The impact of past mining activities on the quality of groundwater and surface water has been investigated in the mining district of La Carolina (southern Spain, province of Jaén), a region characterised by the presence of mineralisations of Pb–Ag, Cu and Fe sulphides and Ba sulphates. The chemistry of waters from flooded galleries, shafts and drainage adits has been compared with that of surface waters in the same area. Generally, waters present neutral pH, since carbonates neutralise the acidity produced by the oxidation of Fe-bearing sulphide minerals in the mine impacted water. Despite of this natural attenuation process, in most of the cases, the mine groundwater is of low quality and shows high dissolved SO4 (up to 3.7 g/l), Fe and Mn contents (tens to hundreds mg/l), exceeding the limit established by the guidelines of the World Health Organization for drinking water. Generally, the surface waters are of the sulphate calcium–magnesium to magnesium types, with moderate mineralisation. Post-rebound mine waters caused degradation of receiving watercourses in which the Fe contents are usually high, with values close to 3 g/l, and the mineralisation is greater as the channels run down in the mining zone. During dry seasons a considerable increase of salts and metals dissolved in stream waters was found, due to the decreasing contributions by run-off in this semiarid region, whereas the abandoned mine discharges remained practically constant.  相似文献   

2.
Detailed hydrogeochemical and isotopic data of groundwaters from the Hammamet–Nabeul unconfined aquifer are used to provide a better understanding of the natural and anthropogenic processes that control the groundwater mineralization as well as the sources of different groundwater bodies. It has been demonstrated that groundwaters, which show Na–Cl and Ca–SO4–Cl water facies, are mainly influenced by the dissolution of evaporates, the dedolomitization and the cation-exchange process; and supplementary by anthropogenic process in relation with return flow of irrigation waters. The isotopic signatures permit to classify the studied groundwaters into two different groups. Non-evaporated groundwaters that are characterized by depleted δ 18O and δ 2H contents highlighting the importance of modern recharge at higher altitude. Evaporated groundwaters with enriched contents reflecting the significance infiltration of return flow irrigation waters. Tritium data in the studied groundwaters lend support to the existence of pre-1950 and post-1960 recharge. Carbon-14 activities in shallow wells that provide evidence to the large contamination by organic 14C corroborate the recent origin of the groundwaters in the study area.  相似文献   

3.
A long mining history and unscientific exploitation of Jharia coalfield caused many environmental problems including water resource depletion and contamination. A geochemical study of mine water in the Jharia coalfield has been undertaken to assess its quality and suitability for domestic, industrial and irrigation uses. For this purpose, 92 mine water samples collected from different mining areas of Jharia coalfield were analysed for pH, electrical conductivity (EC), major cations (Ca2+, Mg2+, Na+, K+), anions (F−, Cl−, HCO3 −, SO4 2−, NO3 −), dissolved silica (H4SiO4) and trace metals. The pH of the analysed mine water samples varied from 6.2 to 8.6, indicating mildly acidic to alkaline nature. Concentration of TDS varied from 437 to 1,593 mg L−1 and spatial differences in TDS values reflect the variation in lithology, surface activities and hydrological regime prevailing in the region. SO4 2− and HCO3 − are dominant in the anion and Mg2+ and Ca2+ in the cation chemistry of mine water. High concentrations of SO4 2− in the mine water of the area are attributed to the oxidative weathering of pyrites. Ca–Mg–SO4 and Ca–Mg–HCO3 are the dominant hydrochemical facies. The drinking water quality assessment indicates that number of mine water samples have high TDS, total hardness and SO4 2− concentrations and needs treatment before its utilization. Concentrations of some trace metals (Fe, Mn, Ni, Pb) were also found to be above the desirable levels recommended for drinking water. The mine water is good to permissible quality and suitable for irrigation in most cases. However, higher salinity, residual sodium carbonate and Mg-ratio restrict its suitability for irrigation at some sites.  相似文献   

4.
Hydrogeochemical surveys were carried out in SW Sardinia (Italy) to investigate the impact of past mining activities on the quality of groundwater. The chemistry of waters from flooded galleries, adits and dumps has been compared with that of springs and wells in the same area at sites relatively far from any mine legacy. A feature, common to all waters, is the circumneutral pH, since the carbonate formations in the area neutralise the acidity produced by the oxidation of Fe-bearing sulphide minerals in the mine impacted water. However, groundwater interacting with mine workings is degraded in quality; it shows high dissolved SO4, Zn, Cd and Pb contents. In some cases groundwater exceeds the limit established by the guidelines of the World Health Organization for Pb content in drinking water, so that groundwater is mixed before entering the local aqueducts. Results from this study suggest that more attention needs to be paid to the impact on the streams from contaminated water flowing out from some mine areas because during the dry season these streams are only fed by mine groundwater. We recommend focusing efforts to reduce the chemical contamination prior to discharge.  相似文献   

5.
 The Sanggok mine used to be one of the largest lead-zinc mines in the Hwanggangri mining district, Republic of Korea. The present study characterizes the heavy metal contamination in the abandoned Sanggok mine creek on the basis of physico-chemical properties of various kinds of water samples (mine, surface and groundwater). Hydrochemistry of the water samples is characterized by the relatively significant enrichment of Ca2+, HCO3 –, NO3 – and Cl– in the surface and groundwaters, whereas the mine water is relatively enriched in Ca2+, Mg2+, heavy metals, and HCO3 – and SO4 2–. The more polluted mine water has a lower pH and higher Eh, conductivity and TDS values. The concentrations of some toxic elements (Al, As, Cd, Cu, Fe, Mn, Pb, Se, Sr, Pb and Zn) are tens to hundreds of times higher in the mine water than in the unpolluted surface and groundwaters. However, most immobile toxic pollutants from the mine drainage were quickly removed from the surface water by the precipitation of Al and Fe oxyhydroxides. Geochemical modeling showed that potentially toxic heavy metals might exist largely in the forms of MSO4 2– and M2+ in the mine water. These metals in the surface and groundwaters could form M2+, CO3 2– and OH– complex ions. Computer simulation indicates that the saturation indices of albite, alunite, anhydrite, chlorite, fluorite, gypsum, halloysite and strontianite in the water samples are undersaturated and have progressively evolved toward the saturation condition. However, barite, calcite, chalcedony, dolomite, gibbsite, illite and quartz were in equilibrium, and only clay minerals were supersaturated. Ground and mine waters seemed to be in equilibrium with kaolinite field, but some surface water were in equilibrium with gibbsite and seceded from the stability field of quartz. This indicates that surface water samples in reaction with carbonate rocks would first equilibrate with carbonate minerals, then gibbsite to kaolinite. Investigations on water quality and environmental improvement of the severely polluted Sanggok creek, as well as remediation methods on the possible future pollution of the groundwater by the acid mine drainage from the abandoned metal mines, are urgently required. Received: 4 February 2000 · Accepted: 9 May 2000  相似文献   

6.
In order to assess the extent of groundwater contamination by nitrate (NO3 −–N) and to provide information about the deterioration of the groundwater quality in Zhangye Oasis, Northwest China, a study was conducted in this area. The mean value of NO3 −–N concentrations in groundwater samples was 10.66 ± 0.19 mg l−1. NO3 −–N concentrations exceeding 10 mg l−1 (the threshold for drinking water set by the World Health Organization) were found in 32.4% of 71 wells, and were 13, 33.3, 52.4 and 50.0% in the groundwater samples from drinking wells, irrigation wells, hand-pumping wells and groundwater table observation wells, respectively. The result showed that the groundwater samples that had NO3 −–N concentrations exceeding the threshold for drinking water were mostly collected from a depth of less than 20 m. Groundwater NO3 −–N concentrations in areas used for the cultivation of vegetables, seed maize and intercropped maize were significantly higher than those in urban or paddy areas. NO3 −–N contamination of groundwater in areas with sandy soil was more severe than in those with loam soil.  相似文献   

7.
The chemical analysis of 59 water wells in Meshkinshar area, Ardabil province NW of IRAN has been evaluated to determine the hydrogeochemical processes and ion concentration background in the region. The dominated hydrochemical types are Na–SO4, Ca–HCO3, Na–HCO3 and Na–Cl in the whole area. Based on the total hardness, the groundwater is soft. According to electrical conductivity and sodium adsorption ratio, the most dominant classes are C1–S1, C2–S1 and C3–S1. The major ion concentrations are below the acceptable level for drinking water. The groundwater salinity hazard is medium to high but the Na hazard is low to medium and in regard of irrigation water the quality is low to medium. So the drainage system is necessary to avoid the increase of toxic salt concentrations.  相似文献   

8.
The aim of this study was to determine geochemical properties of groundwater and thermal water in the Misli Basin and to assess thermal water intrusion into shallow groundwater due to over-extraction. According to isotope and hydrochemical analyses results, sampled waters can be divided into three groups: cold, thermal, and mixed waters. Only a few waters reach water–rock chemical equilibrium. Thermal waters in the area are characterized by Na+–Cl−–HCO3−, while the cold waters by CaHCO3 facies. On the basis of isotope results, thermal waters in the Misli basin are meteoric origin. In particular, δ18O and δ2H values of shallow groundwater vary from −10.2 to −12.2‰ and −71.2 to −82‰, while those of thermal waters range from −7.8 to −10.1‰ and from −67 to −74‰, respectively. The tritium values of shallow groundwater having short circulation as young waters coming from wells that range from 30 to 70 m in depth vary from 10 to 14 TU. The average tritium activity of groundwater in depths more than 100 m is 1.59 ± 1.16, which indicates long circulation. The rapid infiltration of the precipitation, the recycling of the evaporated irrigation water, the influence of thermal fluids and the heterogeneity of the aquifer make it difficult to determine groundwater quality changes in the Misli Basin. Obtained results show that further lowering of the groundwater table by over-consumption will cause further intrusion of thermal water which resulted in high mineral content into the fresh groundwater aquifer. Because of this phenomenon, the concentrations of some chemical components which impairs water quality in terms of irrigation purposes in shallow groundwaters, such as Na+, B, and Cl−, are highy probably expected to increase in time.  相似文献   

9.
Groundwater from 73 municipal and 21 private wells were analyzed for Ag, Al, As, B, Ba, Cd, Co, Cr, Cu, Fe, Hg, Li, Mn, Ni, Pb, Sr and Zn over a 3 year monitoring program in the Gaza Strip. The results show that the trace elements of the groundwater of the Gaza Strip do not generally pose any health or environmental hazard. In spite of that, only 10% of the municipal wells meet the WHO standards. Cl-, NO 3 − and F- concentrations exceeded 2–9 times the WHO standards in 90% of the wells tested with maximum concentrations of 3,000, 450 and 1.6 mg/l, respectively. Several private wells should not be used for drinking purposes as the average of Zn, Cd, Pb, Fe and As was 58, 30, 270, 468 and 10 μg/l, respectively. A severe water dilemma will appear in the near future from both quality and quantity aspects.  相似文献   

10.
The oxidation of sulfide minerals generates acidic waters containing high levels of SO4 and Fe. The study area has active Pb?CZn?CCu mining. It is thought that the surface/subsurface/underground sulfide minerals in the region generally contribute to the acidification of groundwater. Low pH values are also responsible for dissolved metals (Al, Fe, Mn, SO4, Pb, Zn) in the groundwater and river. Furthermore, current mining wastes have affected concentrations of trace elements in the water. High Fe and Mn concentrations are generally found in the spring which has acidic and low Eh values, while Al, Fe and Mn concentrations in the acidic waters show notable increases with the maximum values reaching 8,829, 19,084 and 1,708?ppb, respectively. These values exceed the Turkish drinking water standard of 200, 200 and 50?ppb, respectively.  相似文献   

11.
An attempt has been made to study the groundwater geochemistry in part of the NOIDA metropolitan city and assessing the hydrogeochemical processes controlling the water composition and its suitability for drinking and irrigation uses. The analytical results show that Na and Ca are the major cations and HCO3 and Cl are the major anions in this water. The higher ratios of Na+K/TZ+ (0.2–0.7), Ca+Mg/HCO3 (0.8–6.1); good correlation between Ca-Mg (0.75), Ca-Na (0.77), Mg-Na (0.96); low ratio of Ca+Mg/Na+K (1.6), Ca/Na (1.03), Mg/Na (0.64), HCO3/Na (1.05) along with negative correlation of HCO3 with Ca and Mg signify silicate weathering with limited contribution from carbonate dissolution. The hydro-geochemical study of the area reveals that many parameters are exceeding the desirable limits and quality of the potable water has deteriorated to a large extent at many sites. High concentrations of TDS, Na, Cl, SO4, Fe, Mn, Pb and Ni indicate anthropogenic impact on groundwater quality and demand regional water quality investigation and integrated water management strategy. SAR, %Na, PI and Mg-hazard values show that water is of good to permissible quality and can be used for irrigation. However, higher salinity and boron concentration restrict its suitability for irrigation uses at many sites.  相似文献   

12.
The area in Guntur district, Andhra Pradesh, India, is selected to discuss the impact of seasonal variation of groundwater quality on irrigation and human health, where the agriculture is the main livelihood of rural people and the groundwater is the main source for irrigation and drinking. Granite gneisses associated with schists and charnockites of the Precambrian Eastern Ghats underlie the area. Groundwater samples collected seasonally, pre- and post-monsoons, during three years from forty wells in the area were analyzed for pH, EC, TDS, TA, TH, Ca2+, Mg2+, Na+, K+, CO32−, HCO3−, Cl−, SO42−, NO3−and F−. The chemical relationships in Piper’s diagram, Chebotarev’s genetic classification and Gibbs’s diagram suggest that the groundwaters mainly belong to non-carbonate alkali type and Cl− group, and are controlled by evaporation-dominance, respectively, due to the influence of semi-arid climate, gentle slope, sluggish drainage conditions, greater water–rock interaction, and anthropogenic activities. A comparison of the groundwater quality in relation to drinking water quality standards proves that most of the water samples are not suitable for drinking, especially in post-monsoon period. US Salinity Laboratory’s and Wilcox’s diagrams, and %Na+ used for evaluating the water quality for irrigation suggest that the majority of the groundwater samples are not good for irrigation in post-monsoon compared to that in pre-monsoon. These conditions are caused due to leaching of salts from the overlying materials by infiltrating recharge waters. A management plan is suggested for sustainable development of the area.  相似文献   

13.
Muzaffarnagar is an economically rich district situated in the most fertile plains of two great rivers Ganga and Yamuna in the Indo-gangetic plains, with agricultural land irrigated by both surface water as well as groundwater. An investigation has been carried out to understand the hydrochemistry of the groundwater and its suitability for irrigation uses. Groundwater in the study area is neutral to moderately alkaline in nature. Chemistry of groundwater suggests that alkaline earths (Ca + Mg) significantly exceed the alkalis (Na + K) and weak acids exceed the strong acids (Cl + SO4), suggesting the dominance of carbonate weathering followed by silicate weathering. Majority of the groundwater samples (62%) posses Ca–Mg–HCO3 type of hydrochemical species, followed by Ca–Na–Mg–HCO3, Na–Ca–Mg–HCO3, Ca–Mg–Na–HCO3–Cl and Na–Ca–HCO3–SO4 types. A positive high correlation (r 2 = 0.928) between Na and Cl suggests that the salinity of groundwater is due to intermixing of two or more groundwater bodies with different hydrochemical compositions. Barring a few locations, most of the groundwater samples are suitable for irrigation uses. Chemical fertilizers, sugar factories and anthropogenic activities are contributing to the sulphate and chloride concentrations in the groundwater of the study area. Overexploitation of aquifers induced multi componential mixing of groundwater with agricultural return flow waters is responsible for generating groundwater of various compositions in its lateral extent.  相似文献   

14.
The Heihe River Basin is a typical arid inland river basin for examining stress on groundwater resources in northwest China. The basin is composed of large volumes of unconsolidated Quaternary sediments of widely differing grain size, and during the past half century, rapid socio-economic development has created an increased demand for groundwater resources. Understanding the hydrogeochemical processes of groundwater and water quality is important for sustainable development and effective management of groundwater resources in the Heihe River basin. To this end, a total of 30 representative groundwater samples were collected from different wells to monitor the water chemistry of various ions and its quality for irrigation. Chemical analysis shows that water presents a large spatial variability of chemical facies (SO4 2−–HCO3−, SO4 2−–Cl−, and Cl−–SO4 2−) as groundwater flow from recharge area to discharge area. The ionic ratio indicates positive correlation between the flowing pairs of parameters: Cl− and Na+(r = 0.95), SO4 2− and Na+ (r = 0.84), HCO3 − and Mg2+(r = 0.86), and SO4 2− and Ca2+ (r = 0.91). Dissolution of minerals, such as halite, gypsum, dolomite, silicate, and Mirabilite (Na2SO4·10H2O) in the sediments results in the Cl−, SO4 2−, HCO3 −, Na+, Ca2+ and Mg2+ content in the groundwater. Other reactions, such as evaporation, ion exchange, and deposition also influence the water composition. The suitability of the groundwater for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. The results show that most of the groundwater samples are suitable for irrigation uses barring a few locations in the dessert region in the northern sub-basin.  相似文献   

15.
 An unconfined aquifer system suggests an open system in the study area. Hydrochemical evolution is related to the flow path of groundwater. The groundwaters are divided into two hydrochemical facies in the study area, 1) Ca–Mg–HCO3 and 2) Ca–Mg–SO4HCO3. Facies 1 has shallow (young) waters which dominate in recharge areas during rapid flow conditions, whereas facies 2 may show shallow and mixed waters which dominate intermediate or discharge areas during low flow conditions. Ionic concentrations, TDS, EC and water quality are related to groundwater residence time and groundwater types. The groundwaters in the plain are chemically potable and suitable for both domestic and agricultural purposes. Received: 20 May 1996 · Accepted: 30 July 1996  相似文献   

16.
Unplanned exploitation of groundwater constitutes emerging water-related threats to MayoTsanaga River Basin. Shallow groundwater from crystalline and detrital sediment aquifers, together with rain, dams, springs, and rivers were chemically and isotopically investigated to appraise its evolution, recharge source and mechanisms, flow direction, and age which were used to evaluate the groundwater susceptibility to contamination and the basin’s stage of salinization. The groundwater which is Ca–Na–HCO3 type is a chemically evolved equivalent of surface waters and rain water with Ca–Mg–Cl–SO4 chemistry. The monsoon rain recharged the groundwater preferentially at an average rate of 74 mm/year, while surface waters recharge upon evaporation. Altitude effect of rain and springs show a similar variation of −0.4‰ for δ18O/100 m, but the springs which were recharged at 452, 679, and 773 m asl show enrichment of δ18O through evaporation by 0.8‰ corresponding to 3% of water loss during recharge. The groundwater which shows both local and regional flow regimes gets older towards the basins` margin with coeval enrichment in F− and depletion in NO3 −. Incidentally, younger groundwaters are susceptible to anthropogenic contamination and older groundwaters are sinks of lithologenic fluoride. The basins salinization is still at an early stage.  相似文献   

17.
In the Rocca Busambra area (mid-west Sicily, Italy), from November 1999 to July 2002, 23 water points including wells and springs were sampled and studied for their chemical and isotopic compositions. Two rain gauges were also installed at different altitudes, and rainwater was collected monthly to determine the isotopic composition. The obtained results revealed the Rocca Busambra carbonate complex as being the main recharge area on account of its high permeability value. From a chemical view point, two main groups of water can be distinguished: calcium–magnesium–bicarbonate-type and calcium–magnesium–chloride–sulphate-type waters. The first group reflects the dissolution of the carbonate rocks; the second group probably originates from circulation within flyschoid sediments. Three water wells differ from the other samples due to their relatively high Na and K content, which probably is to be referred to a marked interaction with the “Calcareniti di Corleone” formation, which is rich in glauconite [(K, Na)(Fe3+, Al, Mg)2(Si, Al)4O10(OH)2]. In accordance with WHO guidelines for drinking water (2004), almost all the samples collected can be considered drinkable, with the exception of four of them, whose NO3 −, F− and Na+ contents exceed the limits. On the contrary, the sampled groundwater studied is basically suitable for irrigation.  相似文献   

18.
Groundwater is a critical resource in Deoria district, as it is the main source of drinking water and irrigation. The aquifer has deteriorated to a high degree, during the last two to three decades, in quality and quantity due to high population growth and environmental pollution. More than 90% of the population get their drinking water from subsurface waters. Fifteen wells were sampled in June 2006 to probe the hydrogeochemical components that influence the water quality. The results show that groundwater have EC, TDS, Na+, Mg2+, HCO3− and TH higher than the WHO, 1997 maximum desirable limits. A hydrogeochemical numerical model for carbonate minerals was constructed using the PHREEQC package. The regression analysis shows that there are three groups of elements which are significantly and positively correlated. The main hydrochemical facies of the aquifer (Ca + Mg–HCO3) represents 33.33% of the total wells. The geochemical modeling demonstrated that the reactions responsible for the hydrochemical evolution in the area fall into three categories: (1) dissolution of salts, (2) precipitation of dolomite, (3) ion exchange. Solubility of dolomite, calcite, aragonite and gypsum were assessed in terms of the saturation index. The thermodynamic prerequisites for dolomite supersaturation reactions are satisfied by subsurface waters, since they are supersaturated with respect to dolomite, undersaturated (or in equilibrium) with respect to calcite, and undersaturated with respect to gypsum. The Ca2+ versus SO42− and Mg2+ versus SO42− trends are also compatible with homologous trends resulting from dolomite supersaturation.  相似文献   

19.
The purpose of this work is to characterize the hydrochemical behavior of acid mine drainages (AMD) and superficial waters from the Adoria mine area (Northern Portugal). Samples of superficial and mine drainage water were collected for one year, bi-monthly, with pH, temperature, Eh, conductivity and HCO3 determined in situ with chemical analyses of SO4, Ca, K, Mg, Na, Cl, Ag, As, Bi, Co, Cu, Fe, Mn, Ni, Pb, Zn and Cd. In the mine, there are acidic waters, with low pH and significant concentrations of SO4, and metals (Fe, Mn, Zn, Cu, Pb, Cd and Ni), while in the superficial natural stream waters outside the mine, the pH is close to neutral, with low conductivity and lower metal concentrations. The stream waters inside the mine influence are intermediate in composition between AMD and natural stream waters outside the mine influence. Principal Component Analysis (PCA) shows a clear separation between AMD galleries and AMD tailings, with tailings having a greater level of contamination.  相似文献   

20.
The Salí River hydrogeological basin is one of the most productive artesian basins in Argentina. It is located in the southeastern part of the province of Tucumán, northwestern Argentina, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow pattern and time of residence. Three hydrochemical zones are defined in the study area and the processes that control the chemical composition of the water are manifestly different in each zone. The dissolution of halite, sodium sulphate, and gypsum explains part of the contained Na+, K+, Cl–, SO4 2–, and Ca2+, but other processes, such as cation exchange, calcite precipitation, weathering of aluminosilicates, and gas exchange with the atmosphere, also contribute to the water composition. The assessment of contamination indicators, such as pH, dissolved organic matter, dissolved oxygen, phosphate, and nitrate, indicates that the groundwater is suitable for human consumption. However, biological contamination has been detected in samples from some wells, especially those near the Salí River. Electronic Publication  相似文献   

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