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1.
南秦岭城口火山岩锆石LA-ICP-MS U-Pb定年和地球化学研究   总被引:3,自引:0,他引:3  
南秦岭大巴山城口断裂带出露一套玄武安山岩、安山岩组合,火山岩锆石LA-ICP-MS U-Pb定年测试结果为716±4Ma,表明其为新元古代岩浆产物;岩石地球化学研究表明火山岩富集轻稀土元素,原始地幔标准化微量元素蛛网图显示以富集大离子亲石元素Cs、Ba、Th、U及高场强元素分异为特征,Nb、Ta强烈亏损以及低的Ti(Ti O_20.85%)含量,与典型的岛弧火山岩相似;微量元素La/Nb、Th/Yb及Hf/Ta比值特征也显示岛弧岩浆属性,相对高的Zr/Y、Ta/Yb和低的Zr/Nb比值区别于大洋岛弧火山岩,具有明显的大陆亲缘性,表明城口火山岩形成于陆缘岛弧环境。综合已有的地质、地球化学及同位素年代学研究表明新元古代晚期扬子板块北缘及南秦岭地区为一活动陆缘岩浆杂岩弧,暗示中国华南板块很可能位于Rodinia超大陆的边缘部位。  相似文献   

2.
侯建光  苏尚国  周岱  王倩 《岩石学报》2014,30(12):3729-3740
内蒙古温根南岩体位于内蒙古中部,属于华北克拉通北缘中段,主要火成岩组合为纯橄岩-橄长岩-辉长岩,平面上呈NNE向延伸。元素地球化学分析结果显示,岩体富Mg、低碱和Ti O2,全岩氧化物含量主要受控于橄榄石、单斜辉石和斜长石的相对分配比例,微量元素含量总体较低,具Nb、Ta和Hf轻微亏损,Pb、Sr显著富集的特征。其中辉长岩表现出显著的Nb、Ta负异常和Pb、Sr正异常。辉长岩微量元素相对纯橄岩和橄长岩明显富集。辉长岩相-纯橄岩相中总稀土含量变化较大(1.41×10-6~111.6×10-6),稀土元素配分曲线表现为轻微右倾型与平坦型,岩体深部超基性岩类总稀土含量极低,随着其结晶分异程度的增大和堆晶作用的加强,岩石中稀土元素含量迅速升高,反映晶间残余熔体的比重不断升高。运用橄榄石与残余熔浆平衡方法制约母岩浆性质,结果表明温根南岩体初始岩浆MgO=11.73%,FeO=11.38%,属于高镁玄武质岩浆。温根南岩体基性-超基性岩中Sr-Nd同位素投点主要靠近EM I型富集地幔端元,推测幔源岩浆在源区或上升过程中受到了地壳物质的混染。运用Zr、Y、Th、Ta等不相容元素的比值(判别岩浆演化过程,基于Th/Nb比值(1)和低Nb/La比值(1)表明温根南岩体初始岩浆侵位过程中遭受到了地壳物质的混染。温根南岩体Ta/Th-Zr/Nb、Th/Yb-Th/Nb、Ta/Th-Th/Yb、Nb/Th-Nb构造环境判别图中主要落入板内玄武岩(WPB)范围,推测温根南基性-超基性岩体在早石炭纪形成于板内伸展构造环境。  相似文献   

3.
青海泽库东南赛日迪附近产出的印支期中基性岩体前人研究较少.对该岩体进行地球化学、构造背景及岩浆演化方面研究,结果表明,赛日迪岩体硅量中等、高镁铁、低铝、低钾钠,属准铝质钙碱性系列.富集Rb,K,Pb等大离子亲石元素(LILE)和Th,U,Ta,Nb,Hf等高场强元素(HFSE).普遍贫Ba,Sr等大离子亲石元素(LILE)和P,Zr,Ti等高场强元素(HFSE).稀土元素含量较低,轻稀土元素相对富集,轻稀土元素较重稀土元素分馏明显.Eu略显负异常,表现为同源岩浆成分特征.LREE与SiO2相关性不强,Nb/U、Nb/La远低于全球MORB、OIB值,Nb/Ta和Zr/Hf与原始地幔值相当,低Sm/Yb值,La/Nb和La/Ta指数指示赛日迪中基性岩可能为地幔源,岩浆经历部分熔融岩浆演化过程,上升过程中未受地壳物质混染.构造环境判别赛日迪中基性岩为钙碱性玄武岩,形成于板内环境,与板块碰撞作用有一定联系.  相似文献   

4.
武当山南缘青峰—襄广断裂是分隔南秦岭和扬子板块的重要界线,亦是勉略带东延的重要纽带。通过开展房县门古和五台地区路线地质调查和室内研究,查明门古地区发育的原定新元古代耀岭河群火山岩为晚奥陶世变玄武岩块体((444.9±2.5)Ma),并与原划震旦系—寒武纪的灰岩、硅质岩块体包裹于砂质片岩中,显示出构造混杂岩带特征;五台地区侵入志留系梅子垭组的辉绿岩为早志留世岩浆活动产物((432.4±3.3)Ma),岩石地球化学特征显示两地区样品均具有高TiO_2、富集高场强元素Nb、Ta、Zr等特征,不相容元素比值及稀土配分曲线和微量元素蛛网图等均表现出OIB亲缘性,两地区样品岩浆均起源于较深部的软流圈地幔,母岩浆为高压环境下石榴石二辉橄榄岩低度部分熔融形成,并发生了分离结晶作用,且受到地壳轻微混染;区域地质特征和构造判别图解共同指示二者非地幔柱成因,其形成环境与大陆裂谷无关,而是形成于大洋板内环境,这为进一步理解南秦岭显生宙构造演化提供了证据。  相似文献   

5.
为充分认识秘鲁北部海岸岩基带始新世以来的构造岩浆演化特征,探讨侵入岩形成时代、岩石成因及其构造环境,在海岸岩基带自西向东系统采集侵入岩样品。锆石U-Pb年代学数据显示侵入岩时代分两期,分别为52~47 Ma和36~28 Ma,具有自西向东逐渐变新的特征。样品岩石地球化学具有钙碱性-高钾钙碱性特征,明显富集Rb、Ba、K、U等大离子亲石元素,相对亏损Nb、Ta、P和Ti高场强元素;球粒陨石标准化稀土元素配分模式均表现为轻稀土元素富集的右倾型,具有弱的Eu负异常。Sr/Y-Y图解和Rb-(Y+Nb)图解显示岛弧岩浆岩的组成;Rb/Sr值和Th/U值接近壳源岩浆组成;Nb/Ta值和Zr/Hf值均接近平均陆壳组成;La/Ba-La/Nb图解指示具有岩石圈地幔源区的特征;A/MF-C/MF图解中多数样品落入基性岩的部分熔融区域。结合Nazca板块向南美大陆板块俯冲的构造背景及样品地球化学和年代学数据特征,认为两期侵入岩的岩浆具有同源特征,岩浆源区可能源于基性下地壳的部分熔融,并有岩石圈地幔物质混染;秘鲁北部在Nazca板块低角度平板俯冲作用下,岩浆弧向东迁移,同时地壳隆升和增厚时限较中南部地区的...  相似文献   

6.
岚皋碱质煌斑杂岩主量元素呈规律性演化,REE球粒陨石标准化配分型式呈强右倾型,富集不相容元素。岩石主元素和微量元素地球化学特征表明,煌斑岩浆在演化过程中存在2个平行的结晶分异演化趋势,岩浆演化过程中受地壳混染的程度很小。LREE、不相容元素的强烈富集及Dy/Yb、La/Yb、Zr/Sm、Ce/Y等微量元素的质量分数比值变化表明,煌斑杂岩不可能由尖晶石或石榴石二辉橄榄岩、含角闪石的尖晶石或石榴石二辉橄榄岩的部分熔融形成,它的源区应为含金云母和单斜辉石的交代地幔。Sr-Nd-Pb同位素结果显示,煌斑岩浆源区的地幔主要为HIMU端元组分。地幔柱的活动与煌斑岩浆的起源密切相关,并制约了其源区的地幔交代作用。  相似文献   

7.
骆驼山镁铁--超镁铁岩体主要岩石类型有单辉橄长岩、橄榄辉长苏长岩、橄长岩、辉长苏长岩、辉长岩。橄榄石Fo为76~83,为贵橄榄石。辉石化学特征以及主量元素特征表明其属拉斑玄武岩系列,稀土元素配分曲线总体表现为轻稀土稍富集、重稀土微分异的特征。微量元素具有大离子亲石元素(Rb、Ba、Sr)相对富集,高场强元素Ta、Hf、Th相对亏损的特征。岩浆演化过程中分离结晶作用主要受单斜辉石控制。Nb/U、Ce/Pb值更接近于地壳值以及敏感元素比值协变关系表明岩浆演化过程发生了同化混染作用。Th/Yb-Nb/Yb、La/Ba-La/Nb之间的关系指示岩浆源区可能为流体交代改造的富集型岩石圈地幔。  相似文献   

8.
通过对河北后城基性岩墙进行系统研究,SiO2=47.07%~50.28%,(Na2O+K2O)在2.83%~3.75%之间变化.具有明显的轻稀土元素富集 ((La/Yb)N=4.40~4.86)和大离子亲石元素(Rb、Th和U等)富集现象,亏损高场强元素Nb和Ta.地球化学特征表明,岩墙产于板内拉张的构造环境,经过了橄榄石、单斜辉石、角闪石和黑云母等矿物的分离结晶作用.对La/Sm、Ta/La、Nb/La的分析表明,本区岩浆在上升过程中受到地壳物质的混染作用影响不明显,岩墙的源区与深俯冲作用引起的地幔交代作用有关.通过对微量元素及稀土元素比值的研究证明,基性岩墙源区为过渡型地幔源区,岩墙的母岩浆来自石榴子石二辉橄榄岩地幔,主要经历了石榴石+尖晶石二辉橄榄岩部分熔融,熔融程度在10%~20%之间,岩浆的起源深度在75kin左右.  相似文献   

9.
白杨河地区中基性岩墙地球化学研究显示,该岩墙属于亚碱性系列,为岩浆高度演化的产物,轻稀土元素适度富集,轻重稀土分异中等,Nb、Ta强烈亏损,Ti、Zr和Hf适度亏损,不相容元素(K、Rb、Ba、Sr、LREE)与Pb富集,说明该岩墙源自与俯冲作用有关的交代地幔,且在侵位过程中受到地壳物质的混染。该岩墙侵位时期可能为270~250Ma左右,为造山期后伸展环境下的产物,是中亚造山带后碰撞阶段陆壳垂向生长的重要标志。  相似文献   

10.
对西天山伊宁县北琼阿希河谷出露的火山岩进行了地球化学特征研究,结果表明,该地区火山岩属于钙碱性火山岩系列,LREE强烈富集[(La/Yb)N介于2.76~7.03之间],具有弱的Eu负异常,样品的强不相容元素(Cs、Rb、Ba、Th、U)LILE均明显富集,总体在原始地幔的10倍以上,显示了岛弧火山岩的Nb-Ta负异常特征。但是,其(Th/Nb)N、(La/Nb)N的比值远远大于1,Ba/Nb、La/Nb的变化范围较大,Zr/Nb、Zr/Hf接近N-MORB的比值,Ta/Nb却接近上地壳的比值,暗示该地区的火山岩岩浆在上升过程中受到一定程度的地壳混染,所有样品均显示为中钾-高钾系列,这种钾质类型的优势地位也反映了陆壳基质在岩浆活动中占有重要的地位。样品的Zr均大于300、Zr/Y均大于4,显示了板内玄武岩的成分特征,在Zr-Zr/Y判别图解中,大多数样品投到板内玄武岩的构造环境区域内。结合区域上的地质特征,认为该地区在泥盆世一直处于抬升阶段,在石炭纪时碰撞结束并进入碰撞后伸展阶段,局部地区产生一定的裂谷化特征。琼阿希河谷的火山岩的Nb-Ta负异常特征应为地壳混染引起,火山岩的形成环境为碰撞后伸展的构造环境。  相似文献   

11.
填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。  相似文献   

12.
新疆维吾尔自治区阿图什市木吉地区邻近帕米尔,是印度板块与欧亚板块碰撞挤压应力最集中的地区,地层变质和变形强烈,研究基础薄弱。木吉群由变质砂岩、板岩、千枚岩、石英岩、钙质石英岩、变粒岩、二云石英片岩、大理岩等组成,一直未发现任何化石。最近,笔者在木吉乡的喀拉足克沟和阿拉木陶沟的粉砂岩、钙质粉砂岩中发现了一些植物管胞片和孢粉化石:Gran-ulatisporites sp.,Cycloranisporites sp.,Verrucosisporites sp.,Pityosporites sp.,Punetatosporites sp.,Leiotriletes sp.,Apicu-latisporites sp.,Platysaccus sp.,Cycodopites sp.等。从地层接触关系和孢粉化石的整体面貌看,木吉地区含上述孢粉化石的木吉群的时代可能为泥盆纪—石炭纪。  相似文献   

13.
西藏措勤县雄玛地区林子宗群帕那组火山岩大地构造位置位于冈底斯—念青唐古拉山板片,地层分区上属于冈底斯地层区、隆格尔—南木林地层分区。岩性主要为一套以浅灰色、灰绿色流纹质凝灰岩为主,夹浅黄绿色、灰绿色流纹岩及英安岩、火山角砾岩、杂砂岩及砾岩的岩石组合。之下与永珠组和拉嘎组呈喷发不整合接触。岩石地球化学特征表明该火山岩系属过铝质的高钾钙碱性—亚碱性系列,稀土元素地球化学中轻稀土元素明显富集,微量元素中大离子亲石元素(Rb、K、Th、U、LREE)富集,高场强元素(Nb、P、Ti)亏损。以上特征说明雄玛地区林子宗群帕那组火山岩岩浆源于陆壳重熔,属与俯冲造山有关的陆相火山岩,同时又兼具陆—陆碰撞的特点。推测帕那组火山岩形成于新特提斯洋壳俯冲基本结束,印度板块与欧亚板块碰撞开始的构造背景下,年龄大概在38Ma左右,为始新世晚期。  相似文献   

14.
Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.  相似文献   

15.
藏北羌塘丁固—加措地区康托组的时代   总被引:2,自引:0,他引:2  
自西藏区域地质调查大队创建康托组以来,康托组岩石地层单位广泛应用于羌塘地区,普遍认为其时代为新近纪.笔者于丁固-加措地区的康托组地层中采获古近纪轮藻化石Obtusocharat sp.,O.lanpingenis,Gyrogona qinajiangica和部分孢粉化石,并在康托组底部安山岩中获K-Ar年龄65.1~66.5Ma.上述轮藻组合与同位素年龄指示的地层时代为古新世-始新世,据此将测区康托组的时代确定为古近纪.由于测区康托组之上被唢纳湖组或鱼鳞山组角度不整合覆盖,因此康托组时代的确定不仅进一步完善了测区新生代地层系统,还指示测区在康托组与唢纳湖组或鱼鳞山组之间发生了一次强烈的构造运动.  相似文献   

16.
Summary The Middle Proterozoic Faraday Metagabbro in the Bancroft area of eastern Ontario has been subjected to syn-orogenic textural and mineralogical modifications resulting in the formation of scapolite-bearing metagabbro and gabbroic blastomylonite assemblages. The elemental flux during cryptic and overt scapolitization has been calculated usingGresens general metasomatic equation which applies corrections for density and volume changes during alteration. Metasomatic variation diagrams using analyses from two primary gabbros and six altered rocks indicate that Na, K, Cl, Li, Rb, and Ba are the principal introduced elements and that Cu and S were removed. These changes are very similar to those involved in the formation of metasomatic nepheline-bearing rocks elsewhere in the district and, furthermore, nephelinization and scapolitization were broadly coincident in time and space. It is concluded that the nephelin- and scapolite-bearing rocks and their cryptic facies are different manifestations of the same metasomatic agent and that the source of the fluids was a possible horizon of evaporitic sediments within the country rocks in which the gabbro was emplaced.
Metasomatose im Faraday-Metagabbro, Bancroft, Ontario, Kanada
Zusammenfassung Der Mittel-proterozoische Faraday-Gabbro in der Umgebung von Bancroft (Ost-Ontario) erfuhr synorogene Veränderungen in Textur und Mineralogie, die zur Bildung skapolit-haltiger Metagabbros und gabbroider Blastomylonite führten. Die während kryptischer und offener Skapolitisierung stattfindende Elementtransport wurde mit Hilfe der vonGresens entwickelten generellen metasomatischen Gleichung errechnet; Korrekturen für Varänderungen in spezifischer Dichte und Volumen wurden angebracht. Metasomatische Variationsdiagramme basierend auf Analysen an zwei primären Gabbros und sechs modifizierten Gesteinen zeigen, daß Na, K, Cl, Li, Rb und Ba die hauptsächlich zugeführten Elemente darstellen, und daß Cu-und S-Konzentrationen abgebaut wurden. Diese Veränderungen sind vergleichbar mit solchen, wie sie bei der Bildung metasomatischer, Nephelin-haltiger Gesteine erkannt wurden. Außerdem fallen Nephelinisierung und Skapolitisierung zeitlich und räumlich in etwa zusammen. Daraus kann geschlossen werden, daß Nephelin- und Skapolit-haltige Gesteine und deren kryptische Phasen durch den gleichen metasomatischen Prozeß entstanden sind, und daß die Herkunft der umwandelnden Lösungen möglicherweise in evaporitischen Sedimenten zu suchen ist, in die der Gabbro intrudierte.


With 3 Figures  相似文献   

17.
The paper reports newly obtained data on the geochronology of the Dovyren intrusive complex and associated metarhyolites of the Inyaptuk Formation in the Synnyr Range. The data were obtained by local LA-ICPMS analysis of zircons in samples. The U-Pb age of olivine-free gabbronorite from near the roof of the Yoko-Dovyren Massif is 730 ± 6 Ma (MSWD = 1.7, n = 33, three samples) is close to the estimated age of 731 ± 4 Ma (MSWD = 1.3, n = 56, five samples) of a 200-m-thick sill beneath the pluton. These data overlap the age of recrystallized hornfels found within the massif (“charnockitoid”, 723 ± 7 Ma, MSWD = 0.12, n = 10) and a dike of sulfidated gabbronorite below the bottom of the massif (725 ± 8 Ma, MSWD = 2.0, n = 15). The estimates are also consistent with the age of albite hornfels (721 ± 6 Ma, MSWD = 0.78, n = 12), which was produced in a low-temperature contact metamorphic facies of the host rocks. The average age of the Dovyren Complex is 728.4 ± 3.4 Ma (MSWD = 1.8, n = 99) based on data on the sill, near-roof gabbronorite, and “charnockitoid”) and is roughly 55 Ma older than the estimate of 673 ± 22 Ma (Sm-Nd; [13]). The U-Pb system of zircon in two quartz metaporphyre samples from the bottom portion of the Inyaptuk volcanic formation in the northeastern part of the Yoko-Dovyren Massif turns out to be disturbed. The scatter of the data points can be explained by the effect of two discrete events. The age of the first zircon population is then 729 ± 14 Ma (MSWD = 0.74, n = 8), and that of the second population is 667 ± 14 Ma (MSWD = 1.9, n = 13). The older value pertains to intrusive rocks of Dovyren, and the age of the “rejuvenated” zircon grains corresponds to the hydrothermal-metasomatic processes, which affected the whole volcano-plutonic sequence and involved the serpentinization of the hyperbasites. This is validated by the results of Rb-Sr isotopic studies with the partial acid leaching of two serpentinized peridotite samples from the Verblyud Sill. These studies date the overprinted processes at 659 ± 5 Ma (MSWD = 1.3, n = 3).  相似文献   

18.
Study of the cross-stratification and other sedimentary structures in the Lower Greensand of the Weald, England, and Bas-Boulonnais, France, indicates that the sediments were deposited by the lateral migration of sand waves in a neritic sea. Comparison of the Lower Greensand sea with the modern North Sea was attempted. If those sediments were deposited as a result of tidal current similar to the present-day North Sea then the Lower Greensand shoreline could be deduced as running northwest-southeast, indication that the western part of the London Platform was submerged.  相似文献   

19.
The Kaalamo massif is located in the Northern Ladoga region, Karelia, on the extension of the Kotalahti Belt of Ni-bearing ultramafic intrusions in Finland. The massif, 1.89 Ga in age, is differentiated from pyroxenite to diorite. Nickel–copper sulfide mineralization with platinoids is related to the pyroxenite phase. The ore consists of two mineral types: (i) pentlandite–chalcopyrite–pyrrhotite and (ii) chalcopyrite, both enriched in PGE. Pd and Pt bismuthotellurides, as well as Pd and Pt tellurobismuthides, are represented by the following mineral species: kotulskite, sobolevskite, merenskyite, michenerite, moncheite, keithconnite, telluropalladinite; Pt and Pd sulfides comprise vysotskite, cooperite, braggite, palladium pentlandite, and some other rare phases. High-palladium minerals are contained in pentlandite–chalcopyrite–pyrrhotite ore. Native gold intergrown with kotulskite commonly contains microinclusions (1–3 μm) of Pd stannides: paolovite and atokite. Ore with 20–60% copper sulfides (0.2–6.0% Cu) contains 5.1–6.6 gpt PGE and up to 0.13–2.3 gpt Au. Pd minerals, arsenides and sulfoarsenides of Pt, Rh, Ir, Os, and Ru are identified as well. These are sperrylite, ruthenium platarsite, hollingworthite, and irarsite; silvery gold and paolovite have also been noted. All these minerals have been revealed in the massif for the first time. The paper also presents data on the compositions of 25 PGE minerals (PGM) from Kaalamo ores.  相似文献   

20.
西藏阿里札达盆地上新统中犀类化石的发现及意义   总被引:9,自引:10,他引:9  
首次在西藏阿里札达盆地上新世河湖相沉积地层中发现了犀类化石,对其基本特征进行了描述,初步鉴定为犀类额鼻角犀亚科第三庶骨化石,在同一层位中还采集了大量孢粉、微体古生物和植物化石。结合区域地质特征和产出犀类化石地层的沉积学特征等的分析,认为札达盆地上新世时代表着温暖湿润向寒冷潮湿-温和干旱的气候变化过程。这一发现有助于进一步认识青藏高原新近纪上新世的生物演化、气候变化和构造活动,为研究青藏高原新近纪以来的生物进化、湖泊与河流演化、气候变化.古地理与古环境变迁,以及新生代地层的划分对比等提供了新资料。  相似文献   

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