Phase Distribution of Rare and Rare-Earth Elements in the Silicate–Fluoride Systems at Т = 800–1200°С and Р = 1–2 kbar (Experimental Investigations)     

Kotelnikov  A. R.  Suk  N. I.  Korzhinskaya  V. S.  Kotelnikova  Z. A.  Shapovalov  Yu. B. 《Doklady Earth Sciences》2019,484(2):185-188

Doklady Earth Sciences - The melt in the alumosilicate (granite) melt–molten fluoride salt system is experimentally studied at Т = 800–1200°С and Р = 1–2...  相似文献   

Experimental Study of the Formation of Ba–Cr Titanates in the Fluid-Bearing Chromite–Rutile/Ilmenite System at Т = 1000–1200°С and Р = 1.8–5.0 GPa     

Butvina  V. G.  Safonov  O. G.  Bondarenko  G. V.  Shapovalov  Yu. B. 《Doklady Earth Sciences》2022,504(1):248-253

Doklady Earth Sciences - The results of experimental study of crystallization of chromium-bearing Ba-titanates (redlegeite, lindsleyite, and hawthorneite) in the chromite–rutile/ilmenite...  相似文献   

Phase Relations in the Fe–S–C System at P = 0.5 GPa,T = 1100–1250°C: Fe–S–C Liquation and Its Role in the Formation of Magmatic Sulfide Deposits     

Gorbachev  N. S.  Shapovalov  Yu. B.  Kostyuk  A. V.  Gorbachev  P. N.  Nekrasov  A. N.  Soultanov  D. M. 《Doklady Earth Sciences》2021,497(1):206-210

Doklady Earth Sciences - The liquid phases are represented by immiscible Fe–S and Fe–C melts under partial melting of the graphite-saturated Fe–S–C system at P = 0.5 GPa and...  相似文献   

Experimental Study of REEs,Ba, and Sr Interphase Partitioning in Fluid–Magmatic Silicate Systems at T = 1250°C and P = 2 kbar     

Suk  N. I.  Kotelnikov  A. R.  Shapovalov  Yu. B. 《Doklady Earth Sciences》2018,478(2):237-240

The results of study of the alkaline silicate melt–hydrous saline (carbonate, sulfate, and fluoride) fluid system, as well as partitioning of ore metals (Ba, Sr, and REEs) between coexisting phases at T = 1250°C and P = 2 kbar are reported. It is shown that aqueous solutions with the compositions studied cannot be effective concentrators and transporters of ore elements such as REEs, Sr, and Ba. The sulfate melt accumulates Sr and Ba in the alkaline silicate melt–hydrous sulfate fluid system, which provides evidence for the efficiency of sulfate ore extraction of Sr and Ba from the melt. The results obtained support the important oregenerating role of dense saline phases formed upon the development of liquid heterogeneity in fluid–magmatic systems.

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Pyrochlore Solubility in NaF Solutions at 800°C and p = 170–230 MPa     

Redkin  A. F.  Kotova  N. P.  Shapovalov  Yu. B. 《Doklady Earth Sciences》2022,507(1):887-890

Doklady Earth Sciences - The solubility of pyrochlore (NaCa)Nb2O6F was studied experimentally in the NaF–H2O system covering both the homogeneous region of hydrothermal solutions and the...  相似文献   

Experimental study of the apatite–carbonate–H2O system at P = 0.5 GPa and T = 1200°C: Efficiency of fluid transport in carbonatite     

Gorbachev  N. S.  Shapovalov  Yu. B.  Kostyuk  A. V. 《Doklady Earth Sciences》2017,473(1):350-353

Partitioning of more than 35 elements between coexisting phases in the apatite (Apt)–carbonate (Carb)–H₂O system was studied experimentally at P = 0.5 GPa and T = 1200°C for estimation of the efficiency of fluid transport during the formation of carbonatite in platform alkaline intrusions. The interphase partition coefficients of elements (D) range from n × 10^–2 to 100 and higher, which provides evidence for their effective fractionation in the system. The following elements were distinguished: (1) Apt-compatible (REE, Y, Th, Cu, and W), which are concentrated in apatite; (2) hydrophile (Na, K, Mg, Ba, S, Mn, Pb, U, W, and Re), which are preferably distributed into fluid or the carbonate melt. The high hydrophilicity of alkali metals controls the alkaline character of postmagmatic fluids and related metasomatic rocks, whereas the high D(Fl/Apt) and D(Fl/L_Carb) for S, Zr, W, Re, and U show their high potential in relation to U–W–Re mineralization.

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Cyclic and Dynamic Behavior of Sand–Rubber and Clay–Rubber Mixtures     

Rios  Sara  Kowalska  Magdalena  Viana da Fonseca  António 《Geotechnical and Geological Engineering》2021,39(5):3449-3467

Geotechnical and Geological Engineering - In this paper, the possibility of using fine scrap tyre rubber to improve the mechanical properties of soil subjected to cyclic loading is...  相似文献   

P–T–X controls on Ca and Na distribution between Mg–Al tourmaline and fluid     

Eleanor J. Berryman  Bernd Wunder  Dieter Rhede  Georg Schettler  Gerhard Franz  Wilhelm Heinrich 《Contributions to Mineralogy and Petrology》2016,171(4):31

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Sound velocity and elastic properties of Fe–Ni and Fe–Ni–C liquids at high pressure     

Soma Kuwabara  Hidenori Terasaki  Keisuke Nishida  Yuta Shimoyama  Yusaku Takubo  Yuji Higo  Yuki Shibazaki  Satoru Urakawa  Kentaro Uesugi  Akihisa Takeuchi  Tadashi Kondo 《Physics and Chemistry of Minerals》2016,43(3):229-236

The sound velocity (V _P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V _P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V _P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V _P of liquid Fe, whereas alloying with C is likely to increase the V _P. However, a difference in V _P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V _P data with the Murnaghan equation of state, the adiabatic bulk modulus (K _S0) and its pressure derivative (K _S ^′ ) were obtained to be K _S0 = 103 GPa and K _S ^′  = 5.7 for liquid Fe–Ni and K _S0 = 110 GPa and K _S ^′  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V _P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V _P decreased, whereas the effect of C dissolution was to decrease ρ but increase V _P. In contrast, alloying with S significantly reduces both ρ and V _P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V _P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.  相似文献   

Rare graphic textures of cinnabar–stibnite and cinnabar–chalcopyrite pairs and their genesis     

V.I. Vasil’ev 《Russian Geology and Geophysics》2013,54(11):1385-1391

We consider the rare graphic textures of cinnabar–stibnite and cinnabar–chalcopyrite pairs from the Khaidarkan Sb–Hg deposit (Kyrgyzstan) and the Idermeg-Bayan-Haan-Uul polysulfide–fluorite complex deposit (Mongolia). They resemble the ridge pattern on finger skin. Typical signs suggest the formation of the cinnabar–stibnite graphic texture in two stages of hypogene mineralization: (1) interstitial replacement of granulated stibnite by cinnabar and (2) local recrystallization of combined aggregates during the dynamic metamorphism of the ores with partial migration of substance and the formation of “ordered” graphic textures. This texture is named “the graphic texture of hypogene recrystallization.”The formation of the cinnabar–chalcopyrite graphic texture, which has been observed for the first time, is attributed to direct hypogene replacement of cinnabar by chalcopyrite. Chalcopyrite crystallization along the contacts of cinnabar grains is accompanied by the growth of the replacement area. It is proposed to name this texture “the graphic texture of hypogene replacement.” The causes of the selective replacement of cinnabar by chalcopyrite, which gave rise to this peculiar texture, remain uncertain.  相似文献   

The Fe–C–O–H–N system at 6.3–7.8 GPa and 1200–1400 °C: implications for deep carbon and nitrogen cycles     

Alexander?G.?SokolEmail authorView author&#;s OrcID profile  Anatoly?A.?Tomilenko  Taras?A.?Bul’bak  Alexey?N.?Kruk  Pavel?A.?Zaikin  Ivan?A.?Sokol  Yurii?V.?Seryotkin  Yury?N.?Palyanov 《Contributions to Mineralogy and Petrology》2018,173(6):47

Interactions in a Fe–C–O–H–N system that controls the mobility of siderophile nitrogen and carbon in the Fe⁰-saturated upper mantle are investigated in experiments at 6.3–7.8 GPa and 1200–1400 °C. The results show that the γ-Fe and metal melt phases equilibrated with the fluid in a system unsaturated with carbon and nitrogen are stable at 1300 °C. The interactions of Fe₃C with an N-rich fluid in a graphite-saturated system produce the ε-Fe₃N phase (space group P6₃/mmc or P6₃22) at subsolidus conditions of 1200–1300 °C, while N-rich melts form at 1400 °C. At IW- and MMO-buffered hydrogen fugacity (fH₂), fluids vary from NH₃- to H₂O-rich compositions (NH₃/N₂?>?1 in all cases) with relatively high contents of alkanes. The fluid derived from N-poor samples contains less H₂O and more carbon which mainly reside in oxygenated hydrocarbons, i.e., alcohols and esters at MMO-buffered fH₂ and carboxylic acids at unbuffered fH₂ conditions. In unbuffered conditions, N₂ is the principal nitrogen host (NH₃/N₂?≤?0.1) in the fluid equilibrated with the metal phase. Relatively C- and N-rich fluids in equilibrium with the metal phase (γ-Fe, melt, or Fe₃N) are stable at the upper mantle pressures and temperatures. According to our estimates, the metal/fluid partition coefficient of nitrogen is higher than that of carbon. Thus, nitrogen has a greater affinity for iron than carbon. The general inference is that reduced fluids can successfully transport volatiles from the metal-saturated mantle to metal-free shallow mantle domains. However, nitrogen has a higher affinity for iron and selectively accumulates in the metal phase, while highly mobile carbon resides in the fluid phase. This may be a controlling mechanism of the deep carbon and nitrogen cycles.  相似文献   

Genesis of the Au–Bi–Cu–As, Cu–Mo ± W, and base–metal Au–Ag mineralization at the Mountain Freegold (Yukon, Canada): constraints from Ar–Ar and Re–Os geochronology and Pb and stable isotope compositions     

Thierry Bineli Betsi  David Lentz  Massimo Chiaradia  Kurt Kyser  Robert A. Creaser 《Mineralium Deposita》2013,48(8):991-1017

The genesis of mineralized systems across the Mountain Freegold area, in the Dawson Range Cu–Au?±?Mo Belt of the Tintina Au province was constrained using Pb and stable isotope compositions and Ar–Ar and Re–Os geochronology. Pb isotope compositions of sulfides span a wide compositional range (²⁰⁶Pb/²⁰⁴Pb, 18.669–19.861; ²⁰⁸Pb/²⁰⁴Pb, 38.400–39.238) that overlaps the compositions of the spatially associated igneous rocks, thus indicating a magmatic origin for Pb and probably the other metals. Sulfur isotopic compositions of sulfide minerals are broadly similar and their δ³⁴S (Vienna-Canyon Diablo Troilite (V-CDT)) values range from ?1.4 to 3.6 ‰ consistent with the magmatic range, with the exception of stibnite from a Au–Sb–quartz vein, which has δ³⁴S values between ?8.1 and ?3.1 ‰. The δ³⁴S values of sulfates coexisting with sulfide are between 11.2 and 14.2 ‰; whereas, those from the weathering zone range from 3.7 to 4.3 ‰, indicating supergene sulfates derived from oxidation of hypogene sulfides. The δ¹³C (Vienna Peedee Belemnite (VPDB)) values of carbonate range from ?4.9 to 1.1 ‰ and are higher than magmatic values. The δ¹⁸O (V-SMOW) values of magmatic quartz phenocrysts and magmatic least-altered rocks vary between 6.2 and 10.1 ‰ and between 5.0 and 10.1 ‰, respectively, whereas altered magmatic rocks and hydrothermal minerals (quartz and magnetite) are relatively ¹⁸O-depleted (4.2 to 7.9 ‰ and ?6.3 to 1.5 ‰, respectively). Hydrogen isotope compositions of both least-altered and altered igneous rock samples are D-depleted (from ?133 to ?161 ‰ Vienna-Standard Mean Ocean Water (V-SMOW)), consistent with differential magma degassing and/or post-crystallization exchange between the rocks and meteoric ground water. Zircon from a chlorite-altered dike has a U–Pb crystallization age of 108.7?±?0.4 Ma; whereas, the same sample yielded a whole-rock Ar–Ar plateau age of 76.25?±?0.53 Ma. Likewise, molybdenite Re–Os model ages range from 75.8 to 78.2 Ma, indicating the mineralizing events are genetically related to Late Cretaceous volcano-plutonic intrusions in the area. The molybdenite Re–Os ages difference between the nearby Nucleus (75.9?±?0.3 to 76.2?±?0.3 Ma) and Revenue (77.9?±?0.3 to 78.2?±?0.3 Ma) mineral occurrences suggests an episodic mineralized system with two pulses of hydrothermal fluids separated by at least 2 Ma. This, in combination with geological features suggest the Nucleus deposit represents the apical and younger portion of the Revenue–Nucleus magmatic-hydrothermal system and may suggest an evolution from the porphyry to the epithermal environments.  相似文献   

Metallogenesis and ore-forming time of the Changtuxili Mn–Ag–Pb–Zn deposit in Inner Mongolia: Evidence from C–O–S isotopes and U–Pb geochronology     

《地学前缘(英文版)》2020,11(4):1369-1380

This paper reports new geochronological (U–Pb) and isotope (C, O, and S) data to investigate the timing of mineralization and mode of ore genesis for the recently discovered Changtuxili Mn–Ag–Pb–Zn deposit, located on the western slopes of the southern Great Hinggan Range in NE China. The mineralization is hosted by intermediate–acidic lavas and pyroclastic rocks of the Baiyingaolao Formation. Three stages of mineralization are identified: quartz–pyrite (Stage I), galena–sphalerite–tetrahedrite–rhodochrosite (Stage II), and quartz–pyrite (Stage III). δ¹³C and δ¹⁸O values for carbonate from the ore vary from −8.51‰ to −4.96‰ and 3.97‰ to 15.90‰, respectively, which are indicative of a low-temperature alteration environment. δ³⁴S_V-CDT values of sulfides range from −1.77‰ to 4.16‰ and show a trend of equilibrium fractionation (δ³⁴S_Py ​> ​δ³⁴S_Sp ​> ​δ³⁴S_Gn). These features indicate that pyrite, sphalerite, and galena precipitated during the period of mineralization. The alteration mineral assemblage and isotope data indicate that the weakly acidic to weakly alkaline ore-forming fluid was derived largely from meteoric water and the ore-forming elements C and S originated from magma. During the mineralization, a geochemical barrier was formed by changes in the pH of the ore-forming fluid, leading to the precipitation of rhodochrosite. On the basis of the mineralization characteristics, new isotope data, and comparison with adjacent deposits, we propose that the Changtuxili Mn–Ag–Pb–Zn deposit is an intermediate-to low-sulfidation epithermal deposit whose formation was controlled by fractures and variability in the pH of the ore-forming fluid. The surrounding volcanic rocks yield zircon U–Pb ages of 160−146 ​Ma (Late Jurassic), indicating that the mineralization is younger than 146 ​Ma.  相似文献   

Conjunctive K–Ca and Rb–Sr dating of glauconies     

K. Gopalan 《Chemical Geology》2008,247(1-2):119-123

The glaucony series (of which glauconitic mica is the K-rich end member) is one of the few widely occurring minerals in the sedimentary record. So their isotopic ages determined mainly by the K–Ar method represent a major database for the geologic time scale. Many K–Ar ages were, however, found to be too young and often also discordant with available corresponding Rb–Sr ages. This discrepancy may reflect the disparate responses of the chemically contrasting daughter elements, Ar and Sr to postdepositional processes, and renders either age equivocal. A potentially promising approach to evaluate the intrinsic potential of glauconies and other K-rich minerals for direct and reliable dating of sediments is the conjunctive use of the chemically very similar K–Ca and Rb–Sr systems. The relationship between K–Ca and Rb–Sr ages may show a coherence or regularity indicative of a geologically meaningful age like in the case of the well known chemically identical dual U–Pb decay systems. As a crucial first step, this report presents the first successful precise K–Ca dating in conjunction with Rb–Sr dating of an Ordovician glauconite using the same sample aliquot, chemical procedure and mass spectrometer.  相似文献   

Re–Os and U–Pb geochronology of the Laochang Pb–Zn–Ag and concealed porphyry Mo mineralization along the Changning–Menglian suture,SW China: implications for ore genesis and porphyry Cu–Mo exploration     

Xiao-Dong Deng  Jian-Wei Li  Xin-Fu Zhao  Hong-Qiang Wang  Liang Qi 《Mineralium Deposita》2016,51(2):237-248

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Formation of gold–silver sulfides and native gold in Fe–Ag–Au–S system     

G.A. Pal'yanova  K.A. Kokh  Yu.V. Seryotkin 《Russian Geology and Geophysics》2012,53(4):347-355

We carried out experiments on crystallization of Fe-containing melts FeS₂Ag_0.1–0.1xAu_0.1x (x = 0.05, 0.2, 0.4, and 0.8) with Ag/Au weight ratios from 10 to 0.1. Mixtures prepared from elements in corresponding proportions were heated in evacuated quartz ampoules to 1050 ºC and kept at this temperature for 12 h; then they were cooled to 150 ºC, annealed for 30 days, and cooled to room temperature. The solid-phase products were studied by optical and electron microscopy and X-ray spectroscopy. The crystallization products were mainly from iron sulfides: monoclinic pyrrhotite (Fe_0.47S_0.53 or Fe₇S₈) and pyrite (Fe_0.99S_2.01). Gold–silver sulfides (low-temperature modifications) are present in all synthesized samples. Depending on Ag/Au, the following sulfides are produced: acanthite (Ag/Au = 10), solid solutions Ag_2–xAu_xS (Ag/Au = 10, 2), uytenbogaardtite (Ag/Au = 2, 0.75), and petrovskaite (Ag/Au = 0.75, 0.12). They contain iron impurities (up to 3.3 wt.%). Xenomorphic micro- (<1–5 μm) and macrograins (5–50 μm) of Au–Ag sulfides are localized in pyrite or between the grains of pyrite and pyrrhotite. High-fineness gold was detected in the samples with initial ratio Ag/Au ≤ 2. It is present as fine and large rounded microinclusions or as intergrowths with Au–Ag sulfides in pyrite or, more seldom, at the boundary of pyrite and pyrrhotite grains. This gold contains up to 5.7 wt.% Fe. Based on the sample textures and phase relations, a sequence of their crystallization was determined. At ~1050 ºC, there are probably iron sulfide melt L₁ (Fe,S ? Ag,Au), gold–silver sulfide melt L₂ (Au,Ag,S ? Fe), and liquid sulfur L_S. On cooling, melt L₁ produces pyrrhotite; further cooling leads to the crystallization of high-fineness gold (macrograins from L₁ and micrograins from L₂) and Au–Ag sulfides (micrograins from L₁ and macrograins from L₂). Pyrite crystallizes after gold–silver sulfides by the peritectic reaction FeS + L_S = FeS₂ at ~743 ºC. Elemental sulfur is the last to crystallize. Gold–silver sulfides are stable and dominate over native gold and silver, especially in pyrite-containing ores with high Ag/Au ratios.  相似文献   

OH defects in quartz in the system quartz–albite–water and granite–water between 5 and 25?kbar     

Roland Stalder  Jürgen Konzett 《Physics and Chemistry of Minerals》2012,39(10):817-827

The incorporation of OH defects in quartz from the systems quartz–water, quartz–albite–water and granite–water at pressures between 5 and 25?kbar and temperatures between 800 and 1,000?°C was investigated by IR spectroscopy. The two most important OH absorption features can be assigned to hydrogarnet defects (absorption band at 3,585?cm^?1) and coupled substitutions involving Al³⁺ (Al–H defects, absorption bands at 3,310, 3,378 and 3,430?cm^?1). Al incorporation in quartz is controlled by mineral/melt partitioning (D _Al ^Qz/Melt ?=?0.01) and exhibits a negative pressure dependence. This trend is not clearly reflected by the concentration of Al–H defects, which shows positive deviations from the theoretical 1:1 correlation of Al/H for some samples. In contrast to the Al–H defects, formation of hydrogarnet defects appears to be positively correlated to pressure and water activity, and may be used a petrological indicator. The overall water concentration exhibits only minor changes with pressure and temperature, but a clear correlation of water activity (controlled by various amounts of dissolved salts) and hydrogarnet substitution could be established.  相似文献   

Geochronology,geochemistry and Sr–Nd–Hf–S–Pb isotopes of the Early Cretaceous Taoxihu Sn deposit and related granitoids,SE China     

《Ore Geology Reviews》2017

The Taoxihu deposit (eastern Guangdong, SE China) is a newly discovered Sn polymetallic deposit. Zircon U-Pb dating yielded 141.8 ± 1.0 Ma for the Sn-bearing granite porphyry and 145.5 ± 1.6 Ma for the biotite granite batholith it intruded. The age of the granite porphyry is consistent (within error) with the molybdenite Re–Os isochron age (139.0 ± 1.1 Ma) of the Sn mineralization, indicating a temporal link between the two. Geochemical data show that the granite porphyry is weakly peraluminous, contain high Si, Na and K, low Fe, Mg, Ca and P, and relatively high Rb/Sr and low K/Rb values. The rocks are enriched in Rb, Th, U, K, and Pb and depleted in Ba, Sr, Ti and Eu, resembling highly fractionated I-type granites. They contain bulk rock initial ⁸⁷Sr/⁸⁷Sr of 0.707371–0.707730 and εNd(t) of −5.17 to −4.67, and zircon εHf(t) values from −6.67 to −2.32, with late Mesoproterozoic T_DM2 ages for both Nd and Hf isotopes. This suggests that the granite porphyry was likely formed by the partial melting of the crustal basement of Mesoproterozoic overall residence age with minor mantle input.δ³⁴S_CDT values of the Taoxihu chalcopyrite and pyrite range from 0.1 to 2.1‰ (average: 0.9‰), implying a dominantly magmatic sulfur source. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of the Taoxihu sulfide ores are 18.497–18.669, 15.642–15.673 and 38.764–38.934, respectively, indicating a mainly upper continental crustal lead source with minor mantle contribution. The highly fractionated and reduced (low calculated zircon Ce⁴⁺/Ce³⁺ and Eu_N/Eu_N¹ values) nature of the ore-forming granitic magma may have facilitated the Sn enrichment and played a key role in the Sn mineralization. We propose that the ore-forming fluids at Taoxihu were of magmatic-hydrothermal origin derived from the granite porphyry, and that both the granite porphyry and the Sn mineralization were likely formed in an extensional setting, possibly related to the subduction slab rollback of the Paleo-Pacific Plate.  相似文献   

Structure and Evolution of Ancient and Modern Tectonic–Sedimentary Systems     

Chamov  N. P.  Sokolov  S. Yu.  Garetskii  R. G.  Patina  I. S. 《Geotectonics》2019,53(3):337-355

Geotectonics - The article discusses the ratio of the size and spatial position of ancient and modern areas of geodynamic processes (tectonic-sedimentary systems) and the resulting geological...  相似文献   

Geochemistry,geochronology and Sr–Nd–Pb–Hf isotopic compositions of Middle to Late Jurassic syenite–granodiorites–dacite in South China: Petrogenesis and tectonic implications     

《Gondwana Research》2016

In situ zircon U–Pb ages and Hf isotope data, major and trace elements and Sr–Nd–Pb isotopic compositions are reported for coeval syenite–granodiorites–dacite association in South China. The shoshonitic syenites are characterized by high K₂O contents (5.9–6.1 wt.%) and K₂O/Na₂O ratios (1.1–1.2), negative Eu anomalies (Eu/Eu* = 0.65 to 0.77), enrichments of Rb, K, Nb, Ta, Zr and Hf, but depletion of Sr, P and Ti. The adakitic granodiorite and granodiorite porphyry intrusions are characterized by high Al₂O₃ contents (15.0–16.8 wt.%), enrichment in light rare earth elements (LREEs), strongly fractionated LREEs (light rare earth elements) to HREEs (heavy rare earth elements), high Sr (438–629 ppm), Sr/Y (29.2–53.6), and low Y (11.7–16.8 ppm) and HREE contents (e.g., Yb = 1.29–1.64 ppm). The calc-alkaline dacites are characterized by LREE enrichment, absence of negative Eu anomalies, and enrichment of LILEs such as Rb, Ba, Th, U and Pb, and depletion of HFSEs such as Nb, Ta, P and Ti.Geochemical and Sr–Nd–Hf isotopic compositions of the syenites suggest that the shoshonitic magmas were differentiated from parental shoshonitic melts by fractional crystallization of olivine, clinopyroxene and feldspar. The parent magmas may have originated from partial melting of the lithospheric mantle with small amount contribution from crustal materials. The adakitic granodiorite and granodiorite porphyry have Sr–Nd–Pb isotopic compositions that are comparable to that of the mafic lower crust. They have low Mg# and MgO, Ni and Cr contents, abundant inherited zircons, low ε_Nd(t) and ε_Hf(t) values as well as old whole-rock Nd and zircon Hf model ages. These granodiorites were likely generated by partial melting of Triassic underplated mafic lower crust. The Hf isotopic compositions of the dacites are relatively more depleted than the Cathaysia enriched mantle, suggesting those magmas were derived from the partial melting of subduction-modified mantle sources. The coeval shoshonitic, high-K calc-alkaline and calc-alkaline rocks in Middle to Late Jurassic appear to be associated with an Andean-type subduction. This subduction could have resulted in the upwelling of the asthenosphere beneath the Cathaysia Block, which induced partial melting of the mantle as well as the mafic lower crust, and formed an arc regime in the coastal South China during Middle to Late Jurassic.  相似文献