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Doklady Earth Sciences - Phase relations in the phlogopite–carbonate system were studied at P = 3.8 GPa and T = 1200–1300°C. The interaction of phlogopite with the carbonate melt...  相似文献   
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Doklady Earth Sciences - The phase relations upon eclogitization of basalt and melting of H2O-bearing eclogite were studied experimentally for basalt–H2O in the range of P = 3.7–4.0 GPa...  相似文献   
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Doklady Earth Sciences - The liquid phases are represented by immiscible Fe–S and Fe–C melts under partial melting of the graphite-saturated Fe–S–C system at P = 0.5 GPa and...  相似文献   
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Fe, S, and Cu reduced partition function ratios (β-factors) allow calculation of equilibrium isotope fractionation factors. β-Factors for chalcopyrite are calculated from experimental and theoretical partial phonon densities of state states (Kobayashi et al., 2007). The Fe β-factors for mackinawite are calculated from Mössbauer spectroscopy data (Bertaut et al., 1965). Excellent agreement exists between Fe β-factors for chalcopyrite calculated from the experimental and theoretical 57Fe phonon densities of states, supporting the reliability of the Fe β-factors for chalcopyrite. The 34S β-factor for chalcopyrite is consistent with experimental data on equilibrium sulfur isotope fractionation factors among sulfides and theoretical 34S β-factors, except those recently calculated by a DFT approach.Up-to-date experimental isotope-exchange data on equilibrium Fe isotope fractionation factors between minerals and aqueous Fe were critically reevaluated in conjunction with Fe β-factors for minerals, and the following expressions for β-factors for aqueous Fe2+ and Fe3+ were obtained:
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