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1.
为探讨广西钦州石夹剖面晚泥盆世—早石炭世硅质岩成因及其沉积背景,应用X荧光光谱、等离子质谱等分析方法对硅质岩稀土元素地球化学特征进行了研究。结果显示,研究区晚泥盆世—早石炭世硅质岩ΣREE平均为94.81×10-6,ΣCe/ΣY为3.66~9.28(平均5.99),δCe为1.02~1.37(平均1.18),δEu为0.89~1.30(平均1.04),(La/Yb)N为1.38~3.20(平均2.02),(La/Ce)N为0.74~1.14(平均0.87),表明稀土元素组成与北美页岩相似,而明显有别于开阔洋盆和洋中脊的硅质岩,为古大陆边缘盆地(陆内海槽)硅质岩;在泥盆纪-石炭纪界线处δCe、(La/Yb)N降低,(La/Ce)N升高,结合(La/Ce)N对Al2O3/(Al2O3+Fe203)判别图以及硅铝铁成分比值成因判别图,推测此时沉积盆地短暂受到热液活动的影响。  相似文献   

2.
贵州镇宁重晶石矿中硅质岩稀土元素地球化学研究   总被引:1,自引:0,他引:1  
通过对镇宁泥盆系重晶石矿中硅质岩稀土元素地球化学特征研究,发现硅质岩稀土总量较低,轻稀土富集,δCe呈弱的负异常,δEu呈负异常到正异常,{La/Sm}N和{Gd/Yb}N值表明轻稀土分异强;通过∑REE、Ce/Ce*、Eu/Eu*、{La/Ce}N和{La/Lu}N参数综合分析,硅质岩沉积成岩过程中有明显的热水参与,...  相似文献   

3.
扬子地台东南缘黑色岩系(荷塘组)地球化学研究   总被引:1,自引:1,他引:0  
扬子地台东南缘下寒武统荷塘组地层代表性剖面,主要由碳质硅度泥岩及硅质岩类石煤层组成,黑色岩系则分布于底部,岩石为层状,岩性为磷块岩或含磷结核硅质岩,其稀土元素在含钼钒高碳泥岩中富集,稀土总量达233.43×10-6~258.95×10-6,其他岩层的稀土元素总量在89.15×10-6~144.70×10-6之间;相对富轻稀土,轻重稀土、轻稀土分馏作用明显,重稀土分馏作用不明显;铕、铈负异常(δEu值0.55~0.71,δCe值0.46~0.88,(La/Yb)N平均值4.65~10.89;(La/Sm)N平均值9.55~18.44,(Gd/Lu)N平均值0.91~1.67)。沉积的构造环境为被动的大陆边缘,沉积环境为干燥气候的还原环境,不同的古地理条件或海平面的升降,造成了稀土元素特征的差异。  相似文献   

4.
通过对西山布拉克组第一岩性段硅质岩岩石学、地球化学特征研究,探讨其沉积环境和成因,推测其与库鲁克塔格早古生代地壳演化关系。研究区硅质岩夹泥质硅岩、流纹质晶屑凝灰岩的岩石组合,硅质岩的Al/(Al+Fe)值(~0.6)、Ce/Ce*值(~0.57)、(La/Yb)n值(~0.66)等特征指示为欠补偿、缺氧的深水盆地沉积环境。其Fe/Ti值(~29.2),Al/(Al+Fe+Mn)值(~0.54),(Fe+Mn)/Ti值(~31.3),富集Ag,As,Sb,Ba元素等特征,表明该区硅质岩为热水和海水混合成因,形成过程中海水有较高的生产力。硅质岩∑REE在剖面底部为14.9×10-6,向上减小为8.6×10-6,至顶部增加到105.6×10-6,表明剖面底部到顶部热水活动强度呈减弱趋势。早寒武世硅质岩岩石学、地球化学特征表明,硅质岩形成于裂陷槽盆地中,是上升洋流将海底热水物质带至沉积地点与海水发生不同程度混合的产物,为库鲁克塔格早寒武世早期处于拉张裂解环境提供了岩石学和地球化学证据。  相似文献   

5.
东海盆地丽水凹陷古新统沉积岩的稀土元素地球化学特征   总被引:23,自引:6,他引:17  
采用等离子体质谱分析法测试了东海盆地丽水凹陷古新统砂泥岩样品的稀土元素含量,结果表明,稀土总量在82 2×10-6~182×10-6之间,平均为144×10-6;w(LREE)/w(HREE)比值在4 54~10 02之间,平均为8 67,相对富集LREE;Eu基本为负异常,δEu在0 59~1 03之间,平均为0 73;δCe在0 92~1 09之间,平均为0 98,Ce正常或具微弱的负异常;(w(La)/w(Yb))N在8 23~11 61之间,样品的分布曲线为轻稀土元素富集、重稀土元素亏损型。样品稀土元素的地球化学特征反映当时丽水凹陷为海陆交替的沉积环境,水介质环境为缺氧的还原条件,盆地类型应为稳定的克拉通盆地,物源区母岩主要为花岗岩。  相似文献   

6.
新疆库鲁克塔格地区早寒武世硅质岩地球化学特征及其意义   总被引:17,自引:0,他引:17  
新疆库鲁克塔格地区寒武系底部硅质岩发育,主要分布于西山布拉克组和西大山组中,厚度达到120m,发育有火山岩-硅质岩,硅质岩夹黑色页岩组合。通过对兴地大坂穷木库杜克剖面硅质岩的系统地球化学研究,硅质岩常量元素Al、Fe、Mn在Al-Fe-Mn三元图上投影落入热水沉积域中。西山布拉克组底部硅质岩富集As、Sb、Sr、Ba、U元素,Th/U值偏低,为0.758,往上逐渐增大,到西大山组硅质岩Th/U值达到8.448。寒武系底部西山布拉克组底部硅质岩具有稀土总量∑REE显著偏低(小于10×10-6)、LREE/HREE值偏低、Ce负异常显著、低的Ce/Ce值(小于0.8)、(La/Ce)N值(1.0~2.89)、Eu/Eu值(≥1)较大、(La/Lu)N值(3.63~6.98)较小等特征,说明有强烈的热水沉积作用。往上到西大山组硅质岩则具有稀土总量∑REE较高(大于10×10-6)、LREE/HREE值较高、Ce负异常明显、Ce/Ce值较大(0.8~1.29)、(La/Ce)N值变化不明显、Eu/Eu值较低(0.5~0.8)、(La/Lu)N值大(平均大于10)等特征,说明热水沉积作用减弱,但仍属热水沉积特征。硅质岩δ30Si和δ18O同位素分析表明,西山布拉克组和西大山组硅质岩为典型的热水成因硅质岩。硅质岩氧同位素测温表明,从下往上热水沉积硅质岩形成温度降低。西大山组底部硅质岩形成温度较高,达到80℃以上,随后温度逐渐降低,西大山组硅质岩形成的温度为69℃左右。新疆库鲁克塔格地区寒武系底部硅质岩地球化学特征表明,在早寒武世早期库鲁克塔格地区地壳发生强烈的拉张裂解作用,这种拉张裂解作用形成火山岩和硅质岩、硅质岩和黑色页岩组合,它们为早寒武世早期Rodinia大陆发生快速裂解作用提供了岩石学和地球化学证据。  相似文献   

7.
在滇西镇康地块东缘龙塘寨地区新发现的张家田组为一套斜坡-盆地相碎屑岩-放射虫硅质岩-灰岩-玄武岩建造,可见浊流远端低密度流序列、鲍马序列、深水的静水沉积序列,具典型浊流沉积特征。灰岩中采获大量的杜内阶至祥播阶牙形石分子,特别是维宪阶和杜内阶的深水盆地相远洋型分子Gnathodusbilineatus和Scaliognathodusanchoralis类群的出现,说明早石炭世地史时期该区已形成深海槽盆。硅质岩Al/(A1+Fe+Mn)比值为0. 22~0. 40,说明张家田组硅质岩为受热水作用影响的生物成因硅质岩; MnO/TiO_2比值为0. 13~0. 59,Ce异常值在1. 0左右,无明显异常,(La/Yb)_N值为0. 93~1. 93,(La/Ce)_N值为1. 01~1. 09,表现出大陆边缘型硅质岩的特征。结合区域地质资料,本文认为晚古生代时期,在东侧昌宁-孟连洋演化的同时,在镇康地块与耿马被动大陆边缘之间曾发育有一个裂陷海槽,而张家田组斜坡-盆地相浊流沉积正是这一构造事件的沉积记录。  相似文献   

8.
云南墨江金矿床硅质岩沉积环境的地球化学探讨   总被引:13,自引:0,他引:13  
墨江金矿床金厂组中下段硅质岩的形成与热水沉积作用有关,但中段受到正常化学沉积作用的影响。根据硅质岩的地球化学特征,初步讨论了硅质岩的沉积(构造)环境。硅质岩的δCe,稀土元素对Ce/La-La/Yn图解、δ^30Si和Sr/Ba值的特征表明它形成于海水较深的沉积环境。根据硅质岩MnO/TiO2,Al/(Al Fe),(La/Ce)N,δCe和(La/Yb)N的特征推测它形成于大陆边缘-远洋盆地过渡位置。结合岩石组合、地球化学特 征和同位素年代学,认为墨江金矿床硅质岩的沉积环境可能为晚泥盆世后期扬子地块被动大陆边缘快速裂陷的深海槽盆,它不是哀牢山蛇绿岩套“三位一体” 中的一部分。  相似文献   

9.
天山北部上石炭统前峡组火山岩地球化学特征及构造意义   总被引:1,自引:0,他引:1  
上石炭统前峡组火山岩位于早石炭世巴音沟蛇绿岩北侧,为一套以火山碎屑岩为主夹熔岩和陆源碎屑岩建造。岩石及地球化学特征显示,该组火山岩是以安山岩为主的玄武岩+玄武安山岩+安山岩+英安岩组合,里特曼指数介于1.20~3.43,属钙碱性系列。稀土总量(ΣREE)为69.53×10-6~111.32×10-6,(Ce/Y)N=1.12~2.25,(La/Yb)N=1.86~5.39,δEu=0.79~1.21,为轻稀土略富集、Eu亏损不明显的火山岩类型。岩石显著富集大离子亲石元素K、Rb、Ba、Th,亏损高场强元素Nb、Ta、Hf、Ti、Y,其中Nb含量绝大多数介于1.89×10-6~2.65×10-6,与大洋地壳Nb含量平均值2.2×10-6接近。锶初始比值为0.70425~0.70428,与岛弧区玄武岩的0.70437接近,这些特征均与俯冲带大陆岛弧火山岩一致。与之伴生的滨浅海-半深海相沉积地层和南部早石炭世巴音沟蛇绿岩的存在,表明前峡组火山岩是巴音沟蛇绿岩所代表的早石炭世洋壳在晚石炭世时期向北俯冲消减的产物。  相似文献   

10.
为了深入探讨黔南地区早石炭世黑色岩系沉积-构造环境,笔者对页岩气钻孔CY1井打屋坝组黑色岩系进行了详细采样测试,并重点分析了页岩稀土元素地球化学特征。分析结果表明,该区早石炭世页岩稀土元素总量(ΣREE)为(213.08~308.1)×10-6,平均值为251.43×10-6,大于北美页岩的平均值(173.21×10-6);w(ΣLREE)/w(ΣHREE)及w(Ce)N/w(Yb)N等地球化学参数表明,轻、重稀土元素分异明显;REE分布模式呈平坦状,表现出轻稀土富集、重稀土元素亏损;δEu值为0.53~0.671,显示中等程度的负Eu异常,Ce异常表现不明显。根据δCe和Ce异常值的变化,反映研究区早石炭世为缺氧还原环境。根据稀土元素组合特征、δEu值的变化及w(La)N/w(Yb)N-ΣREE的图解特征,结合区域地质背景,认为黔南地区打屋坝组黑色页岩的物源来自黔中隆起和雪峰山隆起,母岩为沉积岩和花岗岩的混合,沉积区构造环境为被动大陆边缘构造背景。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
15.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

16.
正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.)  相似文献   

17.
正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology,  相似文献   

18.
正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.)  相似文献   

19.
正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se-  相似文献   

20.
正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with  相似文献   

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