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1.
Two types of eclogite pebbles were discovered in Middle to Upper Jurassic conglomerates from the Hefei Basin north of the Dabie ultrahigh-pressure (UHP) terrain, China. Type A eclogite pebbles are characterized by idioblastic garnet with well preserved chemical zonation. Si content in phengite is lower than 3.5 per formula unit (pfu). The maximum metamorphic pressure is lower than 2.5 GPa, and the temperature is below 600 °C. Type B eclogite pebbles contain coesite pseudomorphs in xenoblastic garnet. Si content in phengite is higher than 3.5 pfu. The maximum metamorphic pressure is 2.8–4.0 GPa at 700 °C indicating UHP metamorphism.

Types A and B eclogite pebbles are comparable with eclogites occurring in the southern portion of the Dabie UHP terrain. Based on the petrologic similarities and northeastwards directed paleocurrents, we infer that the eclogite pebbles were eroded from the Dabie UHP terrain. Sandstones containing detrital phengite with Si content higher than 3.5 pfu are also derived from UHP rocks. These petrologic and stratigraphic data place time constraints on exhumation and erosion history of the Dabie UHP terrain.  相似文献   


2.
New evidence for high-pressure, eclogite facies metamorphism in the crystalline basement of the Tisza Megaunit (southern Hungary) is reported. The retrogressed mafic eclogite forms a small lens in the orthogneiss and it was found in the borehole near Jánoshalma. The carbonated eclogite contains the peak metamorphic assemblage omphacite + garnet + phengite + kyanite + clinozoizite + rutile + K-feldspar + quartz. Omphacite (Xjd0.40–0.41Xdio0.52–0.53Xhd0.05Xaug1.55–2.85) occurs in the matrix and as inclusions in garnet (Xpy0.37–0.38Xgrs0.21–0.22Xalm0.39–0.40Xsps0–0.01Xadr0–0.01) and kyanite. Thermobarometry based on net-transfer reactions between garnet, omphacite, kyanite and phengite yields P–T conditions of 710 ± 10 °C and 2.6 ± 0.75 GPa. Retrogression during decompression is manifested by formation of symplectites; the most typical are diopside + plagioclase after omphacite, corundum + spinel + plagioclase after kyanite and biotite + plagioclase after phengite. Carbonatization along the veins of the retrogressed eclogite was probably coeval with formation of these symplectites. At places where carbonate is absent the rock was completely hydrated and retrogressed down to the greenschist facies with the development of actinolite. Similar eclogites together with abundant orthogneisses occur mainly in the eastern parts of the Tisza Megaunit, suggesting the existence of an ancient (possibly Variscan) subduction/accretionary complex.  相似文献   

3.
The Shuanghe ultrahigh-pressure (UHP) slab in the Dabie Mountains consists of layered coesite-bearing eclogite, jadeite quartzite, marble and biotite gneiss, and is fault bounded against hosting orthogneiss. Representative assemblages of eclogite are Grt+Omp+Coe+Rt±Ky±Phn±Mgs; it formed at P>27 kbar and 680–720±50 °C. During exhumation, these UHP rocks experienced multistage retrograde metamorphism. Coesite was overprinted by quartz aggregates, phengite by biotite±muscovite and rutile by titanite. Garnet was successively replaced by a thin rim of Amp, Amp+Pl, and Amp+Ep±Bt+Pl (minor). Omphacite and kyanite were replaced by Amp+Pl±Cpx (or ±Bt) and by Zo+Pl+Ms±Mrg±Bt, respectively. Secondary calcite occurs as irregular pockets in some layers. An outcrop near the UHP slab border is composed of 20 thin, concordant layers of foliated eclogites, amphibolite and gneissic rocks of variable bulk composition. These layers exhibit mineral assemblages and textures transitional from less altered through extensively retrograded eclogite to gneissic rock of low-amphibolite facies through hydration, metasomatism and recrystallization. Retrograde metamorphism has caused oxygen and hydrogen isotope disequilibria between some of the minerals, but the fluid for retrograde reactions was internally buffered in the stable isotope compositions. Retrograde metamorphism of variable extent may be attributed to selective infiltration of retrograde fluids of CO2-rich and low-salinity aqueous, intensity of deformation and mineral resistance to alteration. The fluid phase for retrogression may have occurred either as discontinuous flow along grain boundaries in completely retrograded eclogites, and/or as isolated pockets in extensive or less altered eclogite layers.  相似文献   

4.
D. A. Carswell  R. N. Wilson  M. Zhai 《Lithos》2000,52(1-4):121-155
As is typical of ultra-high pressure (UHP) terrains, the regional extent of the UHP terrain in the Dabieshan of central China is highly speculative, since the volume of eclogites and paragneisses preserving unequivocal evidence of coesite and/or diamond stability is very small. By contrast, the common garnet (XMn=0.18–0.45)–phengite (Si=3.2–3.35)–zoned epidote (Ps38–97)–biotite–titanite–two feldspars–quartz assemblages in the more extensive orthogneisses have been previously thought to have formed under low P–T conditions of ca. 400±50°C at 4 kbar. However, certain orthogneiss samples preserve garnets with XCa up to 0.50, rutile inclusions within titanite or epidote and relict phengite inclusions within epidote with Si contents p.f.u. of up to 3.49 — overlapping with the highest values (3.49–3.62) recorded for phengites in samples of undoubted UHP schists. These and other mineral composition features (such as A-site deficiencies in the highest Si phengites, Na in garnets linked to Y+Yb substitution and Al F Ti−1 O−1 substitution in titanites) are taken to be pointers towards the orthogneisses having experienced a similar metamorphic evolution to the associated UHP schists and eclogites. Re-evaluated garnet–phengite and garnet–biotite Fe/Mg exchange thermometry and calculated 5 rutile+3 grossular+2SiO2+H2O=5 titanite+2 zoisite equilibria indicate that the orthogneisses may indeed have followed a common subduction-related clockwise P–T path with the UHP paragneisses and eclogites through conditions of Pmax at ca. 690°C–715°C and 36 kbar to Tmax at ca. 710°C–755°C and 18 kbar, prior to extensive re-crystallisation and re-equilibration of these ductile orthogneisses at ca. 400°C–450°C and 6 kbar. The consequential conclusion, that it is no longer necessary to resort to models of tectonic juxtapositioning to explain the spatial association of these Dabieshan orthogneisses with undoubted UHP lithologies, has far-reaching implications for the interpretation of controversial gneiss–eclogite relationships in other UHP metamorphic terrains.  相似文献   

5.
This paper first reports a high precision U–Pb age of 218±1.2 Ma for rutile in coesite-bearing eclogite from Jinheqiao in the Dabie Mounteins, east–central China. This work shows that the U–Pb mineral (rutile+omphacite) isochron age of 218±2.5 Ma and conventional rutile U–Pb concordia age of 218±1.2 Ma obtained by common Pb correction based on the Pb isotopic composition of omphacite in the same eclogite sample are consistent, proving that the omphacite with low U/Pb ratio (μ=2.8) can be used for common Pb correction in U–Pb dating of rutile. Oxygen isotope analysis of rutile aliquots gave the consistent δ18O values of −6.1±0.1%, demonstrating oxygen isotope homogenization in the rutile of different grains as inclusion in garnet and grain in matrix. Oxygen isotope thermometry yields temperatures of 695±35 and 460±15 °C for quartz–garnet and quartz–rutile pairs, respectively. These oxygen isotopic observations suggest that the diffusion of oxygen in rutile as inclusion in garnet is not controlled by garnet. According to field-based thermochronological studies of rutile, an estimate of the Tc of about 460 °C for U–Pb system in rutile under rapid cooling conditions (20 °C/Ma) was advised. Based on this U–Pb age as well as the reported chronological data with their corresponding metamorphic and/or closure temperature, an improved T–t path has been constructed. The T–t path confirms that the UHPM rocks in South Dabie experienced a rapid cooling following the peak metamorphism before 220 Ma and a long isothermal stage from 213 to 180 Ma around 425 °C.  相似文献   

6.
Ferric iron solid solution in synthetic orthopyroxene has been studied along the joins MgSiO3-Al2O3 · Fe2O3 and MgSiO3-Fe2O3. The partially reduced synthetic orthopyroxenes showed that major incorporation of ferric iron can only occur together with a concomitant incorporation of Al. Maximum solid solution of ferric iron along the join MgSiO3-Fe2O3 was found to be only 0.63 wt% Fe2O3 at 1000°C and 2 kb total pressure. From the observed Mössbauer parameters octahedral ferric iron can be assigned to the MI position in orthopyroxene. Incorporation of Fe3+ and/or Al will increase the disorder of Fe2+ and Mg between the M1 and M2 sites, which is also observed in a ferric iron-containing aluminous orthopyroxene of metamorphic origin. In the assemblage orthopyroxene + sillimanite + quartz the ferric iron content of orthopyroxene is directly related to oxygen fugacity.  相似文献   

7.
T. H. Green  P. L. Hellman 《Lithos》1982,15(4):253-266
The Fe---Mg exchange reaction between coexisting garnet and phengite has been studied by reacting a natural phengite (mg = 67) in the presence of quartz and water at pressures of 20–35 kb and temperatures of 800–1000°C. Compositions of coexisting garnet and mica indicate a linear relation between both the InKD((Fe/Mg) garnet/(Fe/Mg) phengite) and temperature, and InKD and pressure in the above P.T range. This Fe---Mg exchange reaction between garnet and phengite is shown to be dependent on the Ca-content of the garnet, and on the mg number of the bulk composition. These two composition effects have been studied by usin phengitic mica mixes with mg numbers of 23 and 46, and by using a synthetic basaltic composition. The overall results allow broad empirical calibration of separate geothermometers for pelitic and basaltic systems, respectively. However, because of non-ideality in the exchange reaction, this geothermometer should not be used in any practical application outside the composition ranges studied. Also, careful consideration of the presence of Fe3+ in phengite must be made. If the Fe3+ content of the natural phengite is unknown, then the temperatures obtained will be maximum temperatures only.  相似文献   

8.
Minor granulites (believed to be pre-Triassic), surrounded by abundant amphibolite-facies orthogneiss, occur in the same region as the well-documented Triassic high- and ultrahigh-pressure (HP and UHP) eclogites in the Dabie–Sulu terranes, eastern China. Moreover, some eclogites and garnet clinopyroxenites have been metamorphosed at granulite- to amphibolite-facies conditions during exhumation. Granulitized HP eclogites/garnet clinopyroxenites at Huangweihe and Baizhangyan record estimated eclogite-facies metamorphic conditions of 775–805 °C and ≥15 kbar, followed by granulite- to amphibolite-facies overprint of ca. 750–800 °C and 6–11 kbar. The presence of (Na, Ca, Ba, Sr)-feldspars in garnet and omphacite corresponds to amphibolite-facies conditions. Metamorphic mineral assemblages and P–T estimates for felsic granulite at Huangtuling and mafic granulite at Huilanshan indicate peak conditions of 850 °C and 12 kbar for the granulite-facies metamorphism and 700 °C and 6 kbar for amphibolite-facies retrograde metamorphism. Cordierite–orthopyroxene and ferropargasite–plagioclase coronas and symplectites around garnet record a strong, rapid decompression, possibly contemporaneous with the uplift of neighbouring HP/UHP eclogites.

Carbonic fluid (CO2-rich) inclusions are predominant in both HP granulites and granulitized HP/UHP eclogites/garnet clinopyroxenites. They have low densities, having been reset during decompression. Minor amounts of CH4 and/or N2 as well as carbonate are present. In the granulitized HP/UHP eclogites/garnet clinopyroxenites, early fluids are high-salinity brines with minor N2, whereas low-salinity fluids formed during retrogression. Syn-granulite-facies carbonic fluid inclusions occur either in quartz rods in clinopyroxene (granulitized HP garnet clinopyxeronite) or in quartz blebs in garnet and quartz matrices (UHP eclogite). For HP granulites, a limited number of primary CO2 and mixed H2O–CO2(liquid) inclusions have also been observed in undeformed quartz inclusions within garnet, orthopyroxene, and plagioclase which contain abundant, low-density CO2±carbonate inclusions. It is suggested that the primary fluid in the HP granulites was high-density CO2, mixed with a significant quantity of water. The water was consumed by retrograde metamorphic mineral reactions and may also have been responsible for metasomatic reactions (“giant myrmekites”) occurring at quartz–feldspar boundaries. Compared with the UHP eclogites in this region, the granulites were exhumed in the presence of massive, externally derived carbonic fluids and subsequently limited low-salinity aqueous fluids, probably derived from the surrounding gneisses.  相似文献   


9.
The Tso Morari Complex, which is thought to be originally the margin of the Indian continent, is composed of pelitic gneisses and schists including mafic rock lenses (eclogites and basic schists). Eclogites studied here have the mineral assemblage Grt + Omp + Ca-Amp + Zo + Phn + Pg + Qtz + Rt. They also have coesite pseudomorph in garnet and quartz rods in omphacite, suggesting a record of ultrahigh-pressure metamorphism. They occur only in the cores of meter-scale mafic rock lenses intercalated with the pelitic schists. Small mafic lenses and the rim parts of large lenses have been strongly deformed to form the foliation parallel to that of the pelitic schists and show the mineral assemblages of upper greenschist to amphibolite facies metamorphism. The garnet–omphacite thermometry and the univariant reaction relations for jadeite formation give 13–21 kbar at 600 °C and 16–18 kbar at 750 °C for the eclogite formation using the jadeite content of clinopyroxene (XJd = 0.48).

Phengites in pelitic schists show variable Si / Al and Na / K ratios among grains as well as within single grains, and give K–Ar ages of 50–87 Ma. The pelitic schist with paragonite and phengite yielded K–Ar ages of 83.5 Ma (K = 4.9 wt.%) for paragonite–phengite mixture and 85.3 Ma (K = 7.8 wt.%) for phengite and an isochron age of 91 ± 13 Ma from the two dataset. The eclogite gives a plateau age of 132 Ma in Ar/Ar step-heating analyses using single phengite grain and an inverse isochron age of 130 ± 39 Ma with an initial 40Ar / 36Ar ratio of 434 ± 90 in Ar/Ar spot analyses of phengites and paragonites. The Cretaceous isochron ages are interpreted to represent the timing of early stage of exhumation of the eclogitic rocks assuming revised high closure temperature (500 °C) for phengite K–Ar system. The phengites in pelitic schists have experienced retrograde reaction which modified their chemistry during intense deformation associated with the exhumation of these rocks with the release of significant radiogenic 40Ar from the crystals. The argon release took place in the schists that experienced the retrogression to upper greenschist facies metamorphisms from the eclogite facies conditions.  相似文献   


10.
Marbles from Dabieshan and Sulu, China, suffered ultra high pressure (UHP) metamorphism in the coesite–eclogite facies at approximately 700°C and 30 kbars during Triassic continental collision and subduction. The marbles range in isotopic composition from +7 to +25 δ18OVSMOW and from 0 to +6 δ13CVPDB. High δ13C values are representative of unmodified protoliths and are similar to those of 13C-enriched Sinian carbonate rocks from the Yangtze craton. High oxygen isotope ratios reflect pristine protoliths but the low values may have been caused by infiltration of low 18O meteoric water during diagenesis and dolomitization, by fracture-controlled infiltration of water during subduction, by metamorphic mineral reactions, or by a combination of these processes. No evidence of regional isotopic transport during UHP metamorphism has been found. Sampling on scales of 1 to 100 m shows marbles to be inhomogeneous in both carbon and oxygen isotopes. Only samples separated by less than 10 cm have equilibrated oxygen and carbon isotope compositions. Limited isotopic equilibration between adjacent rocks is consistent with the preservation of unaltered UHP minerals and indicates that the metamorphic fluid–rock system was rock-dominated during and following peak metamorphism. A freely flowing, pervasive fluid phase was not present during UHP metamorphism. There is no evidence of isotopic exchange between marble and the upper mantle into which it was subducted. Correlation of geochemical similarities of UHP marbles with Sinian limestones implies that the subducted edge of the Yangtze craton extends at least as far north as the coesite–eclogite facies rocks of Dabieshan. Deposition of protolith carbonates may have taken place in a cold climate either preceding or following but not coincident with Neoproterozoic glaciation.  相似文献   

11.
In a recent study, Qiu and Wijbrans (2006) [Qiu, H.-N. and Wijbrans, J. R. (2006). Paleozoic ages and excess 40Ar in garnets from the Bixiling eclogite in Dabieshan, China: new insights from 40Ar/39Ar dating by stepwise crushing. Geochimica et Cosmochimica Acta70, 2354-2370.] analyzed Ar-isotopes extracted by crushing garnets from the Dabie Shan Bixiling eclogite and claimed to have constrained a pre-Triassic (∼450 Ma) episode of UHP metamorphism from primary fluid inclusions.However, in the absence of careful sample characterization and stepped heating analyses, the reported ages are more easily explained as experimental artifacts related to Ar extracted from either mineral inclusions or the interface sites between mineral inclusions and the garnet matrix: Dabie Shan garnets commonly contain mineral impurities such as K-rich omphacite and/or K-feldspar.If Dabie Shan UHP metamorphism is of the generally accepted Triassic age (210-240 Ma), the apparent age of a phengite sample in equilibrium with the garnet can be explained by the presence of an extraneous 40Ar∗ component with mean 40Ar/36Ar value of ∼5000. This value is similar to the composition of extraneous 40Ar∗ in other eclogite facies terrane.  相似文献   

12.
Zhang Zeming  Xu Zhiqin  Xu Huifen 《Lithos》2000,52(1-4):35-50
The 558-m-deep ZK703 drillhole located near Donghai in the southern part of the Sulu ultrahigh-pressure metamorphic belt, eastern China, penetrates alternating layers of eclogites, gneisses, jadeite quartzites, garnet peridotites, phengite–quartz schists, and kyanite quartzites. The preservation of ultrahigh-pressure metamorphic minerals and their relics, together with the contact relationship and protolith types of the various rocks indicates that these are metamorphic supracrustal rocks and mafic-ultramafic rock assemblages that have experienced in-situ ultrahigh-pressure metamorphism. The eclogites can be divided into five types based on accessory minerals: rutile eclogite, phengite eclogite, kyanite–phengite eclogite, quartz eclogite, and common eclogite with rare minor minerals. Rutile eclogite forms a thick layer in the drillhole that contains sufficient rutile for potential mining. Two retrograde assemblages are observed in the eclogites: the first stage is characterized by the formation of sodic plagioclase+amphibole symplectite or symplectitic coronas after omphacite and garnet, plagioclase+biotite after garnet or phengite, and plagioclase coronas after kyanite; the second stage involved total replacement of omphacite and garnet by amphibole+albite+epidote+quartz. Peak metamorphic P–T conditions of the eclogites were around 32 to 40 kbar and 720°C to 880°C. The retrograde P–T path of the eclogites is characterized by rapidly decreasing pressure with slightly decreasing temperature. Micro-textures and compositional variations in symplectitic minerals suggest that the decompression breakdown of ultrahigh-pressure minerals is a domainal equilibrium reaction or disequilibrium reaction. The composition of the original minerals and the diffusion rate of elements involved in these reactions controlled the symplectitic mineral compositions.  相似文献   

13.
The stability and phase relations of phengitic muscovite in a metapelitic bulk composition containing a mixed H2O+CO2 fluid were investigated at 6.5–11 GPa, 750–1050°C in synthesis experiments performed in a multianvil apparatus. Starting material consisted of a natural calcareous metapelite from the coesite zone of the Dabie Mountains, China, ultrahigh-pressure metamorphic complex that had experienced peak metamorphic pressures greater than 3 GPa. The sample contains a total of 2.1 wt.% H2O and 6.3 wt.% CO2 bound in hydrous and carbonate minerals. No additional fluid was added to the starting material. Phengite is stable in this bulk composition from 6.5 to 9 GPa at 900°C and coexists with an eclogitic phase assemblage consisting of garnet, omphacite, coesite, rutile, and fluid. Phengite dehydrates to produce K-hollandite between 8 and 11 GPa, 750–900°C. Phengite melting/dissolution occurs between 900°C and 975°C at 6.5–8 GPa and is associated with the appearance of kyanite in the phase assemblage. The formation of K-hollandite is accompanied by the appearance of magnesite and topaz-OH in the phase assemblage as well as by significant increases in the grossular content of garnet (average Xgrs=0.52, Xpy=0.19) and the jadeite content of omphacite (Xjd=0.92). Mass balance indicates that the volatile content of the fluid phase changes markedly at the phengite/K-hollandite phase boundary. At P≤8 GPa, fluid coexisting with phengite appears to be relatively CO2-rich (XCO2/XH2O=2.2), whereas fluid coexisting with K-hollandite and magnesite at 11 GPa is rich in H2O (XCO2/XH2O=0.2). Analysis of quench material and mass balance calculations indicate that fluids at all pressures and temperatures examined contain an abundance of dissolved solutes (approximately 40 mol% at 8 GPa, 60 mol% at 11 GPa) that act to dilute the volatile content of the fluid phase. The average phengite content of muscovite is positively correlated with pressure and ranges from 3.62 Si per formula unit (pfu) at 6.5 GPa to 3.80 Si pfu at 9 GPa. The extent of the phengite substitution in muscovite in this bulk composition appears to be limited to a maximum of 3.80–3.85 Si pfu at P=9 GPa. These experiments show that phengite should be stable in metasediments in mature subduction zones to depths of up to 300 km even under conditions in which aH2O1. Other high-pressure hydrous phases such as lawsonite, MgMgAl-pumpellyite, and topaz-OH that may form in subducted sediments do not occur within the phengite stability field in this system, and may require more H2O-rich fluid compositions in order to form. The wide range of conditions under which phengite occurs and its participation in mixed volatile reactions that may buffer the composition of the fluid phase suggest that phengite may significantly influence the nature of metasomatic fluids released from deeply subducted sediments at depths of up to 300 km at convergent plate boundaries.  相似文献   

14.
There are two types of gneisses, biotite paragneiss and granitic orthogneiss, to be closely associated with UHP eclogite at Shuanghe in the Dabie terrane. Both concentration and isotope composition of bulk carbon in apatite and host gneisses were determined by the EA-MS online technique. Structural carbonate within the apatite was detected by the XRD and FTIR techniques. Significant 13C-depletion was observed in the apatite with δ13C values of −28.6‰ to −22.3‰ and the carbon concentrations of 0.70–4.98 wt.% CO2 despite a large variation in δ18O from −4.3‰ to +10.6‰ for these gneisses. There is significant heterogeneity in both δ13C and δ18O within the gneisses on the scale of several tens meters, pointing to the presence of secondary processes after the UHP metamorphism. Considerable amounts of carbonate carbon occur in some of the gneisses that were also depleted in 13C primarily, but subjected to overprint of 13C-rich CO2-bearing fluid after the UHP metamorphism. The 13C-depleted carbon in the gneisses is interpreted to be inherited from their precursors that suffered meteoric–hydrothermal alteration before plate subduction. Both low δ13C values and structural carbonate in the apatite suggest the presence of 13C-poor CO2 in the UHP metamorphic fluid. The 13C-poor CO2 is undoubtedly derived from oxidation of organic matter in the subsurface fluid during the prograde UHP metamorphism.

Zircons from two samples of the granitic orthogneiss exhibit low δ18O values of −4.1‰ to −1.1‰, demonstrating that its protolith was significantly depleted in 18O prior to magma crystallization. U–Pb discordia datings for the 18O-depleted zircons yield Neoproterozoic ages of 724–768 Ma for the protolith of the granitic orthogneiss, consistent with protolith ages of most eclogites and orthogneisses from the other regions in the Dabie–Sulu orogen. Therefore, the meteoric–hydrothermal alteration is directly dated to occur at mid-Neoproterozoic, and may be correlated with the Rodinia supercontinental breakup and the snowball Earth event. It is thus deduced that the igneous protolith of the granitic orthogneiss and some eclogites would intrude into the older sequences composing the sedimentary protoliths of the biotite paragneiss and some eclogites along the northern margin of the Yangtze plate at mid-Neoproterozoic, and drove local meteoric–hydrothermal circulation systems in which both 13C- and 18O-depleted fluid interacted with the protoliths of these UHP rocks now exposed in the Dabie terrane.  相似文献   


15.
The Qinling–Dabie–Sulu belt is the world's largest ultrahigh pressure (UHP) metamorphic belt. The UHP metamorphism is well dated at 220–245 Ma in the Dabie–Sulu belt but at 507 Ma in the Qinling belt. The Tongbaishan is located between the Qinling orogenic belt to the west and the Dabie–Sulu UHP metamorphic belt to the east. It is the key area for studying the tectonic relation between the Qinling and Dabie–Sulu belts and the diachronous UHP metamorphism. The Jigongshan granitic pluton (t=128 Ma) with a total area of 1200 km2, composed of monzogranite, was mostly emplaced into the Tongbai complex, an exposed basement in the Tongbaishan. The Jigongshan granites have SiO2=69.85–72.35%, K2O/Na2O=0.87–1.13, A/CNK=0.91–1.03, Rb/Sr=0.14–0.25 and Th/U=3.3–12. Their REE compositions show strongly fractionated patterns with (La/Yb)N=14–58 and Eu*/Eu=0.79–1.05. The granites are characterized by low radiogenic Pb isotopic composition. The present-day whole-rock Pb isotopic ratios are 206Pb/204Pb=16.707–17.055, 207Pb/204Pb=15.239–15.326 and 208Pb/204Pb=37.587–37.853, which are similar to that of the continental lower crust. Their Nd(t) values range from −16 to −20, and depleted-mantle Nd model ages (TDM) from 1.8 to 2.2 Ga. The above evidence indicates that the magma of the Jigongshan granites was derived from the partial melting of the continental crust. The Pb and Nd isotopic compositions of the Jigongshan granites resemble those of the Dabie core complex in the Dabieshan but are distinct from those of the Tongbai complex in the Tongbaishan. Thus, the Dabie core complex would be the magma source of the Jigongshan granites. The result implies that the Dabie core complex is extended to the west and constitutes the unexposed basement underlaying the Tongbai complex in the Tongbaishan.  相似文献   

16.
Amphiboles containing up to 4.2 wt.% Cl are found in felsic granulites from Yanzihe within the North Dabie area of the Dabie–Sulu ultrahigh- and high-pressure metamorphic belt in eastern China. Most amphibole grains show considerable zonations with Cl contents ranging from 0 to 4.2 wt.%. Based on their textural features, amphiboles can be divided into four generations: (1) amphibole occurring as inclusions in orthopyroxene (Am-in) with Cl contents around 3.5 wt.%; (2) amphibole forming cores of grains in the matrix (AM-I) with Cl contents between 3.0 and 4.2 wt.%; (3) amphibole with Cl contents of 0.2 to 2.5 wt.% (Am-II) occurring as hydrothermally altered parts of the original amphibole; (4) Cl-free amphibole (Am-III) usually developed at the outermost rim of the grain. Major and rare earth elements show significant variations for Am-I, Am-II and Am-III.

Different generations of amphiboles are related to different metamorphic stages of the granulite in Yanzihe, and provide a monitor for fluid/rock interactions and P–T evolution during the high-pressure metamorphism of Dabie Shan. Pressure and temperature estimates suggest that Am-in was formed during prograde metamorphism of 10 kbar and 700–800 °C; Am-I was formed under peak metamorphic conditions (20 kbar, 800–960 °C), whereas Am-II and Am-III were formed during retrograde metamorphic stages (560–770 °C and 5–7 kbar, and 520–670 °C and <5 kbar, respectively). In contrast to most previous studies, in which the earliest amphiboles to form are typically Cl-poor and later amphiboles become progressively Cl-rich, we show that the earliest amphiboles in the investigated rock are Cl-rich and later formed amphiboles are Cl-poor. The present study also demonstrates that the fluid system of the granulites in North Dabie Shan did not evolve in a simple way: while it behaved as a closed system during prograde and peak metamorphism, after the metamorphic peak it probably acted as an open system in which new fluids were introduced. The varying magnitude of Cl contents in amphiboles stresses the very local fluid control during metamorphism.  相似文献   


17.
豫南——鄂北大别山北部高压角闪石榴辉岩的研究   总被引：6，自引：0，他引：6       下载免费PDF全文
刘景波  国连杰 《地质科学》1997,32(4):409-422
一个高压角闪石榴辉岩带出现在豫南——鄂北大别山高压超高压变质单元的最北部。榴辉岩的矿物组合为石榴石+绿辉石+角闪石+绿帘石+多硅白云母+石英+金红石。采用Powell等(1994)的Thermocalc估计的温压条件:压力为1.8-2.4GPa,温度为490-592℃。这个带的榴辉岩在矿物组合,矿物成分和温压条件上明显不同于该高压变质单元中其它带的榴辉岩。  相似文献   

18.
Hydrogen and oxygen isotope studies were carried out on high and ultrahigh pressure metamorphic rocks in the eastern Dabie Mountains, China. The δ18O values of eclogites cover a wide range of −4.2 to +8.8‰, but the δD values of micas from the eclogites fall within a narrow range of −87 to −71‰. Both equilibrium and disequilibrium oxygen isotope fractionations were observed between quartz and the other minerals, with reversed fractionations between omphacite and garnet in some eclogite samples. The δ18O values of −4 to −1‰ for some of the eclogites represent the oxygen isotope compositions of their protoliths which underwent meteoric water–rock interaction before the high to ultrahigh pressure metamorphism. Heterogeneous δ18O values for the eclogite protoliths implies not only the varying degrees of the water–rock interaction before the metamorphism at different localities, but also the channelized flow of fluids during progressive metamorphism due to rapid plate subduction. Retrograde metamorphism caused oxygen and hydrogen isotope disequilibria between some of the minerals, but the fluid for retrograde reactions was internally buffered in the stable isotope compositions and could be derived from structural hydroxyls dissolved in nominally anhydrous minerals.  相似文献   

19.
The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.

Abundant H2O–CO2, H2O- or CO2-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H2O- and/or CO2-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation.  相似文献   


20.
The high-pressure (HP) eclogite in the western Dabie Mountain encloses numerous hornblendes,mostly barroisite.Opinions on the peak metamorphic P-T condition,PT path and mineral paragenesis of it are still in dispute.Generally,HP eclogite involves garnet,omphacite, hornblendes and quartz,with or without glaucophane,zoisite and phengite.The garnet has compositional zoning with X_(Mg) increase,X_(Ca) and X_(Mn) decrease from core to rim,which indicates a progressive metamorphism.The phase equilibria of the ...  相似文献   

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