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1.
J.S. Myers  R.G. Platt 《Lithos》1977,10(1):59-72
Variations of mineral chemistry are described in a layered sheet of partly metamorphosed anorthosite, leucogabbro, gabbro and peridotite. The rocks appear to represent part of two major cycles of crystal deposition in which the anorthite content of plagioclases decreases upwards from An98?94 to An90?75 and hornblendes show upward iron enrichment. The composition of corona minerals formed by subsolidus reaction between plagioclase and olivine in gabbro, suggests that these coronas formed under pressures of between 6 and 9 kb and at a temperature of about 800°C during a late magmatic or early metamorphic stage.  相似文献   

2.
The late Palaeoproterozoic (1.72–1.70 Ga) ferroan granites of the Khetri complex, northern Aravalli orogen, NW India, were extensively metasomatised ~900 Ma after their emplacement, at around 850–830 Ma by low-temperature (ca. 400 °C) meteoric fluids that attained metamorphic character after exchanging oxygen with the surrounding metamorphic rocks. Albitisation is the dominant metasomatic process that was accompanied by Mg and Ca metasomatism. A two-stage metasomatic model is applicable to all the altered ferroan intrusives. The stage I is represented by a metasomatic reaction interface that developed as a result of transformation of the original microcline–oligoclase (An12–14) granite to microcline–albite (An1–3) granite, and this stage is rarely preserved. In contrast, the stage II metasomatic reaction front, where the microcline-bearing albite granite has been transformed to microcline-free albite granite, is readily recognisable in the field and present in most of the intrusives. Some of them lack an obvious reaction interface due to the presence of stage II albite granites only. When studied in isolation, these intrusives were incorrectly classified and their tectonic setting was misinterpreted. Furthermore, our results show that the mafic mineralogy of metasomatised granites has a significant impact on the characterisation of such rocks in the magmatic classification and discrimination diagrams. Nevertheless, the stage I metasomatised granites can be appropriately characterised in these diagrams, whereas the characterisation of the stage II granites will lead to erroneous interpretations. The close spatial association of these high heat producing ferroan granites with iron oxide–copper–gold (IOCG), U and REE mineralisation in the region indicates a genetic link between the metasomatism and the mineralisation. World-class IOCG, U and REE deposits are associated with metasomatised ferroan granites, suggesting that such a relationship may act as a critical first-order exploration target for undiscovered mineral deposits.  相似文献   

3.
The Western Sonobari Complex in northwestern Mexico consists of metamorphosed rocks mostly derived from Palaeozoic (?) sedimentary and Mesozoic igneous protoliths. Rocks of this complex display amphibolite facies orogenic metamorphism, pervasive foliation, migmatization, and four folding phases. These features are ascribed to a contractional tectonic event with NNW–SSE shortening direction, which caused thrusting, thickening of the crust, and sinking of the lithological units. U–Pb geochronology of migmatitic leucosome bands indicates that peak metamorphic conditions were reached between ~93 and 89 Ma. Post-tectonic Late Cretaceous peraluminous aplite-pegmatite dikes transect the metamorphic foliation. Traditional thermobarometry in the metamorphic rocks yields average pressures and temperatures of 9.0–7.1 kbar and 745–663°C, typical of intermediate P/T Barrovian metamorphism. On the basis of its age and contractional character, the thickening event originating the metamorphism may be related to collision of the Alisitos island arc against crustal blocks of Mexico. Thermobarometric data of post-tectonic intrusives including Late Cretaceous granodiorite and Eocene gabbro indicate emplacement within an overthickened crust, while P-T conditions of post-tectonic dikes point towards an almost isothermal decompression path along the amphibolite facies field. Rock units of similar age and metamorphic character are discontinuously exposed from the Islas Marias offshore the Nayarit coast to the Peninsular Ranges batholith of Baja California, and even extend north into the Sierra Nevada batholith and the Sevier hinterland. This extensive belt of Barrovian metamorphic rocks thus provides a record of middle Cretaceous shortening and crustal thickening related to arc-continent collision followed by subduction resuming.  相似文献   

4.
The Samchampi-Samteran alkaline complex occurs as a plug-like pluton within the Precambrian granite gneisses of Mikir Hills, Assam, northeastern India and it is genetically related to Sylhet Traps. The intrusive complex is marked by dominant development of syenite within which ijolitemelteigite suite of rocks is emplaced with an arcuate outcrop pattern. Inliers of alkali pyroxenite and alkali gabbro occur within this ijolite-melteigite suite of rocks. The pluton is also traversed by younger intrusives of nepheline syenite and carbonatite. Development of sporadic, lumpy magnetite ore bodies is also recorded within the pluton. Petrographic details of the constituent lithomembers of the pluton have been presented following standard nomenclatorial rules. Overall pyroxene compositions range from diopside to aegirine augite while alkali feldspars are typically orthoclase and plagioclase in syenite corresponds to oligoclase species. Phase chemistry of nepheline is suggestive of Na-rich alkaline character of the complex. Biotite compositions are typically restricted to a uniform compositional range and they belong to ‘biotite’ field in the relevant classification scheme. Garnets (developed in syenite and melteigite) typically tend to be Ti-rich andradite, which on a closer scan can be further designated as melanites. Opaque minerals mostly correspond to magnetite. Use of Lindsley’s pyroxene thermometric method suggests an equilibration temperature from ∼450°–600°C for melteigite/alkali gabbro and ∼400°C for syenite. Critical assessment of other thermometric methods reveals a temperature of equilibration of ∼700°–1350°C for ijolite-melteigite suite of rocks in contrast to a relatively lower equilibration temperature of ∼600°C for syenite. Geobarometric data based on pyroxene chemistry yield an equilibration pressure of 5.32–7.72 kb for ijolite, melteigite, alkali pyroxenite, alkali gabbro and nepheline syenite. The dominant syenite member of the intrusive plug records a much higher (∼11 kb) equilibration pressure indicating a deeper level of intrusion. Major oxide variations of constituent lithomembers with respect to differentiation index (D.I.) corroborate a normal magmatic differentiation. A prominent role of liquid immiscibility is envisaged from field geological, petrographic and petrochemical evidences. Tectonic discrimination diagrams involving clinopyroxene chemistry strongly suggest within plate alkaline affinity for the parental magma which is in conformity with the regional plume tectonics.  相似文献   

5.
The Elagiri complex (12°31′ N: 78°35′ E) represents one of the important silica — oversaturated syenite plutons of the Southern Granulite Terrane of the Indian shield. This article for the first time reports the mineral chemistry of the Elagiri complex and brings out important petrogenetic significance. The litho-members of Elagiri complex are intrusive into high grade country rocks viz. granite gneiss, amphibolite and pyroxene granulite. The country rocks are foliated bearing evidences of multiple folding and deformation. On the other hand, the constituent litho members of the Elagiri complex (syenites, gabbro and later intrusives marked by lamprophyre and carbonatite) show preservation of igneous layering in terms of discernible parallelism of the constituent minerals. The Elagiri complex shows presence of sharp contacts among litho members and marked absence of chilled facies peripheral to the margin. Electron microprobe data have been critically used to systematize the constituent mineral-phases of the different lithomembers of the complex. Geothermobarometric data indicate a temperature of equilibration in the range of ∼700° to 500°C at ∼2.0 to 5.2 kb which corresponds to shallow level (cf. 18.2 km) equilibration-depth of the complex. Field observations and mineral chemistry data suggest that liquid immiscibility plays an important role during the evolution of the Elagiri complex.  相似文献   

6.
The Halls Creek Orogen in northern Australia records the Palaeoproterozoic collision of the Kimberley Craton with the North Australian Craton. Integrated structural, metamorphic and geochronological studies of the Tickalara Metamorphics show that this involved a protracted episode of high‐temperature, low‐pressure metamorphism associated with intense and prolonged mafic and felsic intrusive activity in the interval ca 1850–1820 Ma. Tectonothermal development of the region commenced with an inferred mantle perturbation event, probably at ca 1880 Ma. This resulted in the generation of mafic magmas in the upper mantle or lower crust, while upper crustal extension preceded the rapid deposition of the Tickalara sedimentary protoliths. An older age limit for these rocks is provided by a psammopelitic gneiss from the Tickalara Metamorphics, which yield a 207Pb/206Pb SHRIMP age of 1867 ± 4 Ma for the youngest detrital zircon suite. Voluminous layered mafic intrusives were emplaced in the middle crust at ca 1860–1855 Ma, prior to the attainment of lower granulite facies peak metamorphic conditions in the middle crust. Locally preserved layer‐parallel D1 foliations that were developed during prograde metamorphism were pervasively overprinted by the dominant regional S2 gneissosity coincident with peak metamorphism. Overgrowths on zircons record a metamorphic 207Pb/206Pb age of 1845 ± 4 Ma. The S2 fabric is folded around tight folds and cut by ductile shear zones associated with D3 (ca 1830 Ma), and all pre‐existing structures are folded around large‐scale, open F4 folds (ca 1820 Ma). Construction of a temperature‐time path for the mid‐crustal section exposed in the central Halls Creek Orogen, based on detailed SHRIMP zircon data, key field relationships and petrological evidence, suggests the existence of one protracted thermal event (>400–500°C for 25–30 million years) encompassing two deformation phases. Protoliths to the Tickalara Metamorphics were relatively cold (～350°C) when intruded by the Fletcher Creek Granite at ca 1850 Ma, but were subsequently heated rapidly to 700–800°C during peak metamorphism at ca 1845 Ma. Repeated injection of mafic magmas caused multiple remelting of the metasedimentary wall rocks, with mappable increases in leucosome volume that show a strong spatial relationship to these intrusives. This mafic igneous activity prolonged the elevated geotherm and ensured that the rocks remained very hot (≥650°C) for at least 10 million years. The Mabel Downs Tonalite was emplaced during amphibolite facies metamorphism, with intrusion commencing at ca 1835 Ma. Its compositional heterogeneity, and the presence of mutual cross‐cutting relations between ductile shear zones and multiple injections of mingled magma suggest that it was emplaced syn‐D3. Broad‐scale folding attributable to F4 was accompanied by widespread intrusion of granitoids, and F4 fold limbs are truncated by large, mostly brittle retrograde S4 shear zones.  相似文献   

7.
Granitic pebbles occurring in the Permotriassic metasedimentary sequence of eastern Papuk, Slavonian Mountains, Croatia, were recognized to represent a coherent group of felsic, muscovite-albite metagranites. Fabrics, modal compositions and geochemical data imply that the rocks are derivatives of S-type granites formed through a combination of igneous and subsequent metasomatic processes. A Variscan formation age is demonstrated by K-Ar dating on coarse muscovite (range of 329?C317?Ma) as well as by electron microprobe based Th-U-Pb monazite dating (338?±?15?Ma). Additionally to the Variscan metasomatic processes of albitization and greisenisation, which led to an almost complete replacement of K-feldspar and biotite by albite and coarse muscovite, pebbles were affected by a younger phase of alteration resulting in the formation of a fine-grained sericitic matrix. The fine sericite yields K-Ar ages of 91?C83?Ma. A substantial reheating of the rocks during the Cretaceous is also indicated by the growth of new monazite dated at 106?±?10?Ma. Yttrium-contents of the Cretaceous monazite from the granite pebbles (0.3?C0.9?wt% Y2O3) are compatible with metamorphic temperatures of ~350?C400°C. These data confirm recent concepts according to which large parts of the Slavonian Mountains received a pervasive Cretaceous low-T regional metamorphic overprint. Furthermore, the pebbles provide useful information on the nature of the eroded Variscan crust of the Tisia Terrain, which has obviously contained considerable amounts of evolved high-level S-type granites modified through albitization and greisenization.  相似文献   

8.
Geochemical studies of the Paiting and Miaolong Carlin-type gold deposits in the Sandu-Danzhai metal-logenic zone,Guizhou Province,have shown that the mineralized-altered rocks show LREE-enrichment patterns,generally displaying negative Eu anomalies(δEu=0.51?0.97) and unobvious negative Ce anomalies(δCe=0.86?0.99).Calcite and fluorite in relation with metallogenesis show MREE-enrichment patterns,generally displaying rather weak negative Eu anomalies(δEu=0.74?0.93) and weak negative Ce(δCe=0.70?0.98) anomalies.The δ13CPDB values of carbon in calcite are-1.61‰?-5.82‰,the δ18OSMOW values of oxygen are 13.97‰?19.24‰,and the δ34SCDT values of sulfur in stibnite are 17.72‰?21.68‰.In regard to δD and δ18O,ore-forming fluids pos-sess the characteristics of metamorphic water.The process of metallogenesis of the Carlin-type gold deposits is con-trolled by the Yanshanian tectonic activities.The Yanshanian movement promoted the migration and mobilization of metamorphic fluids in the extensively developed medium-to high-grade metamorphic rocks in this region,carrying primarily enriched gold and associated elements such as Hg,As,and Sb in the Sinian metamorphosed black shales and Lower Cambrian black shales.The ore-forming fluids found their way into a suitable metallogenic environment along the fault zone,followed by gold precipitation to form gold deposits.  相似文献   

9.
The area of investigation at and around Mashak Pahar, Bankura district, West Bengal, India comprises a number of rock types namely: granite gneiss, migmatized quartz tourmaline gneiss, quartz pebble conglomerate, ferruginous quartzite, quartz tourmaline veins (as veins) and graphite schists. Interestingly, the study area lies in the region extending South Purulia Shear Zone (～Tamar–Porapahar Shear Zone) which marks the boundary between two contrasting tectonic blocks of eastern India, namely, the Chhotanagpur Gneissic Terrane (CGC) to the north and Singhbhum Group of rocks to the south. The rocks of the study area are poly-phasedly deformed by three phases of folding, namely, F1, F2 and F3. All the tourmalines are classified to be of ‘Alkali Group’. Chemistry of tourmalines from migmatized quartz tourmaline gneiss and those from quartz tourmaline veins are in conformity with their relation to (earthquake induced) shear system evolution in this terrain. In general, the compositional evolution of tourmaline during prograde metamorphism (～400°–730°C) has been supported by both petrographic and chemical evidences. Assessment of mineral–chemical data of constituent tourmaline grains clearly suggests compositional variations across zonal boundaries within tourmaline that was controlled by changing metamorphic milieu in this terrane. Field and petrographic evidences clearly indicate activation of earlier and later shears in this region accompanied by infiltration of boron and formation of zoned tourmaline crystals.  相似文献   

10.
The compositions of metamorphic pyroxenes from blueschists in northern New Caledonia are investigated. Aegerine-augite occurs in siliceous metasediments and aegerine in some low-grade sodic basic schists. Calcic metamorphic pyroxene (omphacite and chloromelanite) appears first in metabasalts in higher grades of the lawsonite zone and is widespread in metamorphosed igneous rocks and quartzofeldspathic gneisses of the epidote zone. Omphacites in basic rocks have higher Mg∶Fe ratios and are less jadeitic than omphacites from adjacent interbedded quartzofeldspathic gneisses. With increasing metamorphic grade pyroxenes become more jadeitic and diopsidic at the expense of their acmite component. Elemental partitioning between coexisting pyroxenes, garnets and amphiboles from in situ regional metamorphic rocks is generally regular, suggesting equilibrium crystallization. Omphacite appears to be a stable phase within blueschist facies over a temperature range of at least 350° to 550° C. The “eclogitic” assemblage almandine-omphacite is stable within the earth's crust in metamorphosed sediments and igneous rocks over a temperature range of 400° to at least 550° C. No estimate of absolute pressures involved in metamorphism in the Ouégoa district can yet be made.  相似文献   

11.
The presence of ternary feldspar in high‐grade meta‐igneous rocks, and the recognition of the thermometric significance of this mineral, has led recent researchers to postulate peak metamorphic temperatures in excess of 1000 °C. However, it needs to be established that such ternary feldspar is not in fact a survivor of the original high‐temperature crystallization of the igneous protolith. After exsolution, the host and lamellae in the ternary feldspar grains may be stable throughout subsequent history as long as recrystallization does not occur. Such a history may involve rehydration and metamorphism, including H2O‐saturated conditions, with the compositions and proportions of the host and lamellae being modified to reflect the P–T conditions experienced. In the case of the high‐grade meta‐igneous rocks from the Moldanubian of the Bohemian Massif, some samples that contain ternary feldspar preserve a substantial measure of their igneous heritage. Orthopyroxene‐bearing granulites not only include types that are barely affected by the metamorphism, but also others that have undergone hydration of the igneous protolith prior to the development of a metamorphic overprint. A key to establishing the igneous origin of the ternary feldspar grains is their preservation in garnet that is either itself igneous, or of a relatively low‐temperature metamorphic origin. Applying the logic to the other ternary feldspar‐bearing meta‐igneous rocks deprives the Moldanubian of its ultrahigh temperature (UHT) metamorphic status.  相似文献   

12.
This study uses clay mineral assemblages, illite ??crystallinity?? (IC), chlorite ??crystallinity?? (CC), illite polytypes, the b cell-dimension of K-white mica, mineral geothermo-geobarometers and homogenization temperatures of fluid inclusions to investigate the transition from diagenesis to metamorphism in a 7?km thick Triassic flysch sequence in the well Hongcan 1, eastern Tibetan plateau. The 7,012.8?m deep borehole penetrated flysch of Upper to the Middle Triassic age and represents a unique chance to characterize low temperature metamorphic processes in an unusually thick sedimentary sequence developed on thickened continental crust. Mineral assemblage analysis reveals a burial metamorphic pattern with kaolinite and chlorite/smectite mix-layer phases present in the upper 1,500?m, and illite/smectite mixed-layer phases extending to a depth of 3,000?m. The metamorphic index mineral, graphite, was detected in sedimentary rock below 5,000?m using Raman spectroscopy. There exists a good correlation between IC and CC within the prograde burial sequence; with CC anchizonal boundaries of 0.242 and 0.314°2?? (upper and lower boundaries, respectively) corresponding to Kübler??s IC limits at 0.25 and 0.42°2??. Illite polytypism also shows an increase in the 2M 1 polytype with increasing depth, with ca. 60?% 2M 1 abundance compared to the 1M type at the surface, to 100?% 2M 1 at the bottom of the borehole. Fluid inclusion analysis show HHC-rich bearing fluids correspond to the diagenetic zone, CH4-rich bearing fluids appear at transitional zone from diagenetic to low anchizone and H2O-rich bearing fluids mark the high anchizone to epizone. Based on chlorite chemical geothermometer, calcite?Cdolomite geothermo-barometers as well as homogenization temperature of fluid inclusions, a paleotemperature range of 118?C348?°C is estimated for the well with a pressure facies of low to intermediate type.  相似文献   

13.
The Whitestone Anorthosite (WSA), located in southern Ontario, underwent granulite facies metamorphism during the Grenville orogeny at 1.16 Ga. During the waning stages of metamorphism fluids infiltrated the outer portions of the anorthosite and promoted the formation of an envelope comprised of upper amphibolite facies mineral assemblages. Also, this envelope corresponds to portions of the anorthosite that underwent deformation related to movement along a high-grade ductile shear zone. Samples from this portion of the anorthosite (the margin) contain CO2-rich inclusions in plagioclase porphyroclasts (relict igneous phenocrysts), matrix plagioclase and garnet. These inclusions have features which normally are interpreted as indicating that they are texturally primary, but they have relatively low CO2 densities (0.61–0.95 g cm-3). Plagioclase from the anorthosite interior contains texturally secondary inclusions with relatively high CO2 densities (generally from 0.99 to 1.10 g cm-3). The high CO2 densities suggest that the inclusions in the plagioclase of the anorthosite core formed prior to inclusions in porphyroclast minerals of the outer portions of the anorthosite, an interpretation that is apparently inconsistent with inclusion textures. This apparent paradox indicates that most fluid inclusions from the anorthosite margin were formed during, or were modified by, the dynamic recrystallization that affected this portion of the WSA. In either case, late formation or modification, the texturally primary fluid inclusions do not contain pristine samples of the peak metamorphic fluid. Furthermore, because shear-related deformation is apparently associated with entrapment of the lowest fluid densities, some strain localization persisted to relatively low temperatures (e.g. less than approximately 500° C). These results constrain a part of the retrograde P–T path for this portion of the Grenville Orogen to temperatures of approximately 400–500° C at pressures of approximately 1–2 kbar.  相似文献   

14.
Metapelitic gneisses occuring as lenses and bands within the migmatites of the Gruf-Complex in the eastern Pennine Alps contain various combinations of the minerals quartz, biotite, cordierite, garnet, sillimanite, plagioclase. K-feldspar, spinel, orthopyroxene, anthophyllite and muscovite. The most common rock type is represented by a darkschistosebiotiterichcordierite-garnet-sillimanite-gneiss. A consistent pressure-temperature range of 3–4 kb and 600–650° C has been calculated for the last metamorphic equilibration from six geological thermobarometers. However, from textural evidence it may be concluded that the rocks were at both higher temperatures and pressures prior to the PT-conditions calculated from thermobarometry. Although the maximum conditions reached are unknown and earlier stages are poorly preserved it is suggested that they coincide with the maximum conditions deduced from rare occurrences of sapphirine granulite in the Gruf-Complex. These are 10 kb and 800° C (Droop and Bucher 1983). Sillimanite+K-feldspar, orthopyroxene+quartz, spinel+quartz and garnet-K-feldspar persisting in rocks with low activity of H2O are strong evidence for this. The H2O required to make the observed high degree of equilibration at 3–4 kb and 600–650° C possible was presumably released by crystallizing migmatitic melts present in the quartzo-feldspathic gneisses of the Gruf-Complex. Further evidence comes from the PT-coordinates of the H2O-saturated muscovite granite solidus which coincides with the high temperature limits of inferred equilibration above and which the rocks must have crossed along the decompression and cooling path during their metamorphic evolution.  相似文献   

15.
Reports of shoshonitic rocks in Precambrian terrains are relatively rare. Pl-Grt amphibolites and Hbl-Bt mafic granulites occurring in the migmatitic gneisses of the Chhotanagpur Gneissic Complex(CGC) show calc-alkaline and shoshonitic characteristics. Relict porphyritic, sub-ophitic and poikilitic textures are noted in these rocks. Their parent magma was emplaced during the waning phase of the regional metamorphism. Geochemically, these metamafics are similar to the Group Ⅲ potassic and ultrapo...  相似文献   

16.
Quartz–garnet oxygen isotope thermometry of quartz‐rich metasedimentary rocks from the southern Adirondack Highlands (Grenville Province, New York) yields metamorphic temperatures of 700–800 °C, consistent with granulite facies mineral assemblages. Samples from the Irving Pond quartzite record Δ18O(Qtz–Grt) = 2.68 ± 0.21‰ (1 s.d. , n = 15), corresponding to peak metamorphic conditions of 734 ± 38 °C. This agrees well with the estimates from garnet–biotite exchange thermometry. Similar temperature estimates are obtained from Swede Pond (682 ± 47 °C, n = 3) and King's Station (c. 700 °C). The Whitehall area records higher temperatures (798 ± 25 °C, n = 3). All of these temperatures are higher than previous regional temperature estimates. The c. 800 °C temperatures near Whitehall are consistent with preservation of pre‐granulite contact temperatures adjacent to anorthosite. The preservation of peak metamorphic temperatures in garnet of all sizes is consistent with slow oxygen diffusion in garnet, and closure temperatures of at least 730 °C. Peak metamorphic fractionations are preserved in rocks with varying quartz:feldspar ratios, indicating that the modal percentage of feldspar does not affect retrograde oxygen exchange in these rocks. The lack of this correlation suggests slow rates of oxygen diffusion in quartz and feldspar, consistent with the results of anhydrous oxygen diffusion experiments.  相似文献   

17.
The massif-type anorthosite complex at Bolangir in the northern part of the Eastern Ghats belt occurs in a milieu of predominantly supracrustal granulite-grade rocks. The massif is separated from the host gneisses by coarse-grained garnetiferous granitoid gneisses which are interpreted as coeval crustallyderived melts. Melanocratic ferrodiorite rocks occur at the immediate contact with the anorthosite massif which they intrude in cross-cutting dikes and sheets. The emplacement age of the anorthosite diapir and the associated igneous suites is deemed to be pre-D2. Recrystallization of the igneous assemblages of the ferrodiorite suite (750–800°C, 7–8kbar, ) during a period of near-isobaric cooling from the igneous crystallization stage to the regionalP-T regime led to extensive development of coronitic garnet at the interface of plagioclase phenocrysts with the mafic matrix assemblage (opx + fay + cpx + ilm ± amph, bio). Abundant accessory phases are zircon, apatite and thorite. The mafic phases have extremely ferrous compositions (XFe gar: 0.93-0.87, fay: 0.90-0.87, opx: 0.80-0.60, cpx: 0.70-0.47, amph: 0.81-0.71) reflecting the low Mg-number (16-8) of the rocks. Compared to worldwide occurrences of similar rocks, the Bolangir ferrodiorites (SiO2 36–58 wt.%, FeO*: 39-10 wt.%) are characterized by exceptionally high concentrations of HFSE and REE (TiO2: 4.8-1.0 wt.%, P2O5: 1.7-0.5 wt.%, Zr: 5900-1300 ppm, Y: 240-80 ppm, La: 540-100 ppm, Ce: 1100-200 ppm, Yb: 22-10 ppm, Th: 195-65 ppm). Well defined linear variation trends for major and trace elements reflect progressive plagioclase accumulation towards the felsic members of the suite. The ferrodiorites are interpreted to represent residual liquids of anorthosite crystallization which after segregation and extraction from the ascending diapir became enriched in HFSE and REE through selective assimilation of accessory phases (zircon, monazite, apatite) from crustal felsic melts. Ferromonzodioritic rock presumably formed through hybridization between the ferrodiorite and overlying felsic melts.  相似文献   

18.
Xenoliths of metamorphic rocks with ferroglaucophane + albite + stilpnomelane + muscovite ± lawsonite ± pumpellyite are described fromn the rhylolitic tephra deposits of the Late Quaternary Phyriplaka Volcano, Milos, Aegean Island, Greece. The chemical bulk analyses reveal metabasaltic parent rocks with strongly modified chemical compositions. Unusual for common fresh basalt types is extreme Na2O combined with low K2O and rather low CaO. These are chemical characteristics of spilitic basalts. High iron in the bulk rock and very high Fe/Mg is probably the cause of extreme ferroglaucophane compositions. The metamorphic assemblages point to a high-p/low-T metamorphism in the pressure range 4–8 kb and with temperatures of about 350°C. Phyriplaka Volcano is likely to have only a shallow explosive center and ferroglaucophane rocks were ejected from the immediate basement of the island, which was uplifted after the metamorphic event.  相似文献   

19.
The Sangan Magmatic complex (SMC) is, a large I-type magmatic complex, located in the northeastern Iran. Zircons extracted from the intrusive and volcanic rocks within the SMC record a similar Hf compositions and REE patterns, indicating that these chemical signatures have likely been inherited from the same source and simple history of magmatic crystallization during the evolution of the orogeny. The zircon from volcanic rocks yield Ti-in-zircon crystallization temperatures of 667–1145?°C with average temperatures of 934?°C while those from granitoids indicate crystallization temperatures of 614–898?°C with an average of 812?°C. Ti-in-zircon, Ti in biotite thermometries also indicates that the crystallization temperatures of volcanic rocks are relatively higher than those of granitoids. The biotite chemistry studies reveal that this mineral crystallized at approximately 725°–800?°C and 758° to 816?°C for granitoid and volcanic rocks, respectively, which is similar to obtained temperatures by Zir-saturation of Eq. (1). Tzicsat and Tmagma trend lines on the T-SiO2 diagram cross at high silica contents of ～68?wt.%, at which temperature the magma becomes zircon-saturated and new zircons are crystallized. The zircon REE data including Ce/Ce*, Eu/Eu*, and Th/U ratios suggest that SMC igneous rocks are formed from oxidized magma. However, the zircon Th/U and Hf data suggest that the SMC became progressively more oxidized and also indicate lower temperatures from volcanic and plutonic rock with decreasing time.  相似文献   

20.
《International Geology Review》2012,54(15):1864-1875
ABSTRACT

In the mines of the Nacional de Grafite Company around Itapecerica (Minas Gerais), located in the southern Sao Francisco Craton, occurs a supracrustal succession of high-grade metamorphic rocks including quartzite, garnet-biotite gneiss, and graphite schist formed in the Palaeoproterozoic (2.0 Ga). During metamorphic processes, organic matter was progressively transformed into graphite. From four graphite samples of three different mines (two samples from high-grade metamorphic graphite schist and two generated by hydrothermal recrystallization of the graphite schist), the origin and formation temperature of this mineral was obtained by C isotopes, X-ray diffraction (XRD), and Raman spectroscopy. The values of δ13C range between ?21.23 and ?27.89 ‰, indicating that the source of the graphite was a primitive biogenic carbon material. High-grade metamorphic graphites show average temperatures around 729°C, while hydrothermal recrystallizated graphites (vein-graphites) show temperatures around 611°C by XRD, which correspond to granulite- to amphibolite facies conditions. The hydrothermal process with percolation of C-O-H fluids leads to a decrease in the crystal size along stacking direction (Lc(002)) when compared with the previously formed high-grade metamorphism graphites. An update of the current tectonic model about the collisional process during Rhyacian-Orosirian orogeny in the Sao Francisco Craton is proposed to insert the formation of the Itapecerica graphite-rich metasedimentary sequence.  相似文献   

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