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1.
中高含硫量煤中硫的形态分析 总被引：5，自引：0，他引：5
利用超声提取、高速离心分离和加入助分散剂等手段，实现了中，高含硫量煤中单质硫，硫酸盐硫，硫化物硫，有机硫等主要形态硫的分步提取和顺序测定。所建分析方法测定了国家一级标样，统样样品和部分有分析结果的样品，其主要形态硫的加和与标准样品参考值，统检样品定值，原样品的总硫分析结果相符，RSD（n=3)为0．80％－4．23％，方法可用于煤中各主要形态硫的测定。 相似文献
2.
Priv.-Doz. Dr. Manfred Schidlowski 《International Journal of Earth Sciences》1973,62(3):840-863
The economically important sulfide deposits of Precambrian age can be subdivided into two principal groups. The first group is represented by Ni- and Cu-bearing differentiates within either layered intrusions of the Sudbury-Bushveld type or within smaller ultramafic bodies (sometimes of greenstone belt association). The relatively narrow spread around the meteorite standard of the 34S values of these deposits suggests a mantle provenance of the sulfide sulfur.The second group (which is quantitatively more important) is represented by stratiform concentrations of base metal sulfides in sedimentary sequences lacking normally any ties to potentially ore-bearing magmas (Copper Belt, Broken Hill, Mount Isa, etc.). Although the problems related to the origin of such strata-bound deposits are rather complex, the majority of the latter probably formed as syngenetic sulfide precipitates in reducing aqueous environments characterized by the presence of bacteriogenic H2S. Sulfur isotope data furnished by some of the principal deposits actually suggest that hydrogen sulfide produced by bacterial sulfate reduction was instrumental in bringing about a precipitation of the metal sulfides, thus underlining the decisive role played by the biosphere in processes of supergene metal concentration.
Zusammenfassung Die wirtschaftlich wichtigen sulfidischen Metallkonzentrationen in präkambrischen Gesteinen lassen sich im wesentlichen zwei Lagerstättengruppen zuordnen. Die erste Gruppe bilden Ni- und Cu-führende sulfidische Differentiate in geschichteten Intrusionen vom Typ Sudbury-Bushveld oder innerhalb kleinerer ultrabasischer Komplexe. Die nur geringe Streubreite der 34S-Werte um den Meteoriten-Standard legt eine abyssische Herkunft des sulfidischen Materials (Magnetkies, Pentlandit, Kupferkies u. a.) derartiger Lagerstätten nahe.Die zweite und quantitativ wichtigere Gruppe bilden schichtige Anreicherungen von Buntmetallsulfiden in Sedimenten, die in der Regel keinerlei Beziehungen zu potentiell erzbringenden Magmatiten erkennen lassen (Copper Belt, Broken Hill, Mount Isa u. a.). Obwohl die beträchtlichen Probleme dieser stratiformen Sulfidlagerstätten eine genetische Deutung schwierig machen (und insbesondere die oft enorme Streubreite der Schwefelisotopen auf eine polygene Herkunft der Sulfide schließen läßt), dürfte es sich bei der Mehrzahl der Vorkommen um primär synsedimentäre Metallausfällungen in einem H2S-führenden reduzierenden Milieu handeln, wobei spätere tektonischmetamorphe Stoffmobilisierungen möglicherweise eine weitere Konzentration der Lagerstättensubstanz bewirkt haben. Die starke Beteiligung von bakteriogenem Schwefelwasserstoff bei der Ausfällung der Sulfide wird durch die Schwefelisotopen-Verteilung in verschiedenen derartigen Lagerstätten gestützt. Dieser Befund unterstreicht gleichzeitig die entscheidende Rolle der Biosphäre bei der Bildung von Metallanreicherungen im exogenen Zyklus.
Résumé Les concentrations de sulfures métalliques économiquement importantes dans les terrains précambriens peuvent essentiellement être subdivisées en deux groupes de gisements. Le premier groupe comprend les différenciats de sulfures nickelifères et cuprifères dans les intrusions litées du type Sudbury-Bushveld ou dans l'intérieur de complexes ultrabasiques plus petits. La faible distribution des valeurs du soufre 34 des météorites standard suggère une provenance abyssale des matériaux sulfurés de ces gisements (pyrrhotine, pentlandite, sulfures de Cu, etc.). Le deuxième groupe quantitativement plus important comprend les enrichissements «stratiformes »de sulfures métalliques dans les sédiments qui, en règle générale, ne montrent aucune liaison avec des magmatites potentiellement minéralisantes (Copper Belt, Broken Hill, Mount Isa, etc.). Quoique les problèmes importants relatifs à ces gisements sulfurés stratiformes rendent difficile une interprétation génétique (et en particulier la dispersion souvent énorme des isotopes du soufre qui permet de conclure à une provenance polygène des sulfures), il doit s'agir dans la plupart des cas de précipitations de métaux synsédimentaires primaires dans un milieu réducteur contenant H2S; à la suite de quoi une mobilisation ultérieure tectonico-métamorphique pourrait avoir exercé une nouvelle concentration de la matière du gisement. La forte participation d'H2S bactériogène au cours de la précipitation des sulfures est confirmée par la distribution des isotopes du soufre dans différents de ces gisements. Ce fait souligne simultanément le rôle décisif de la biosphère au cours de la formation des enrichissements métalliques dans le cycle exogène.
, . , . - , . 34S ( , , .. .) , , , (r Belt, Broken Hill, Mount Isa .). ( , ), , , , - , , , . . .相似文献
3.
红外碳硫仪测定矿石中高含量硫的探讨 总被引：4，自引：3，他引：1
探讨了用红外碳硫测定仪测定矿石中高含量硫需注意的一些影响因素,包括标样的选择、减少天平误差、称样量、样品的充分燃烧以及仪器的稳定性,说明了用红外碳硫仪测定矿石中高含量硫的可行性。 相似文献
4.
David T. Johnston James Farquhar Yanan Shen Andrew L. Masterson 《Geochimica et cosmochimica acta》2008,72(17):4278-4290
Previous geochemical and biomarker studies of the late Paleo-Mesoproterozoic propose a stratified world, with strongly reducing (possibly sulfidic) deep-ocean conditions overlain by an oxygenated surface-ocean and atmosphere. To investigate such a scenario, we look to the structure of the biogeochemical sulfur cycle. We present sulfur (32S, 33S, 34S, and 36S in sulfides) isotope data from the McArthur Basin (Barney Creek, Reward, Velkerri, and McMinn formations) that allows for a direct evaluation of the surface biosphere. We are interested in investigating the types of information that can be gained by including 33S and 36S. When the 34S/32S fractionations are small, the inclusion of 33S and 36S provides little additional information, but does provide ancillary evidence for relative isotopic homogeneity (with the internal consistency of 33S/32S and 36S/32S). When the 34S/32S fractionations are large, direct information about the fractionation mechanisms can be obtained, with the potential to distinguish the biological from abiological processes. For example, the reconstruction of the Roper Group suggests that seawater sulfate concentrations were high enough to buffer against spatial heterogeneities. Overall, our findings agree with previously proposed redox structure of the Proterozoic ocean, highlight contributions from the oxidative sulfur cycle, and outline a new tool for interpreting the state of the surface sulfur cycle. 相似文献
5.
Jens Gröger Jennifer Franke Kay Hamer Horst D. Schulz 《Geostandards and Geoanalytical Research》2009,33(1):17-27
Chromium-reducible sulfur (CRS) distillations are intended to recover only reduced inorganic sulfur compounds (RIS) including elemental sulfur. However, the quantitative recovery of elemental sulfur is not ensured in common CRS-distillations. The new method presented here was designed to remedy this deficiency. An increase in ethanol concentration assured the quantitative recovery of elemental sulfur in various forms and, in addition, all other RIS-compounds were quantitatively recovered. Furthermore, the selectivity of the procedure was improved by an additional filtration step to eliminate zinc particles from the Cr(II)-solution. Thus, the recovery of sulfates and organic sulfur compounds was significantly decreased by a factor of up to 35, depending on the compound analysed. Exhaustive testing with a variety of pure phases, rock and soil samples demonstrated the precision and accuracy of the new method. The new protocol eliminated the constraints of previous procedures. The improved distillation efficiency for elemental sulfur ensured the quantitative recovery of all RIS-compounds in a single-step distillation. 相似文献
6.
通过塔西南缘铅锌矿带金属硫化物(方铅矿、黄铁矿、黄铜矿、闪锌矿)的硫同位素测试研究,结果显示δ34S值范围在-38.3‰～24.0‰,具双峰式分布,推测两种或两种以上流体相混合是导致矿床硫同位素组成变化的主要原因,一类硫化物的δ34S值集中在-6‰～6‰,组成的矿石呈细粒、草莓状结构及浸染状构造;另一类硫化物的δ34S值集中在-32‰～-24‰,组成的矿石呈粗粒、脉状或角砾状构造。两种流体受构造应力和压实作用的影响,沿着断裂或岩石的裂隙运移并相混合,发生热化学硫酸盐还原反应,产生的HS-与Zn2+、Pb2+结合形成闪锌矿、方铅矿,在有利部位沉淀成矿。硫主要来源于海水硫酸盐。 相似文献
7.
电感耦合等离子体质谱法测定硫时不同形态硫的影响 总被引：1，自引：0，他引：1
电感耦合等离子体质谱(ICP-MS)常常被应用于矿石、蛋白质和化石燃料等材料中硫含量的测定。文章综合研究比较了四极杆电感耦合等离子体质谱(Q-ICP-MS)和扇形磁场电感耦合等离子体质谱(SF-ICP-MS)测定硫的灵敏度、检出限及空白干扰。重点考察了两种不同的样品介质(水和2% HNO3)中不同形态的硫对SF-ICP-MS测定硫信号的影响,并且深入研究了影响的原因。结果表明,硫含量相同但形态不同的含硫阴离子(S2-、S2O32-、SO32-、SO42-)在2%的HNO3介质中的信号比在水介质中的信号稳定,2%的HNO3更适合于作为ICP-MS测定硫的介质。在2%的HNO3介质中,S2-、SO32-中S的ICP-MS测量灵敏度(即标准曲线的斜率)分别为7828 cps/(μg·L-1)、5528 cps/(μg·L-1),SO42-和S2O32-的测量灵敏度分别是为1321 cps/(μg·L-1)、1299 cps/(μg·L-1)。S2-和SO32-的灵敏度分别约为SO42-的6倍和4倍;而S2O32-的灵敏度与SO42-基本一致。主要原因在于S2-、SO32-形态的硫在HNO3介质中形成了气态的H2S和SO2,相当于提高了雾化效率,从而使这两种形态硫的灵敏度大幅度提高。 相似文献
8.
《Applied Geochemistry》2005,20(4):673-681
Lead-210 chronologies, vertical S concentration gradients and δ34S values are presented for 5 Sphagnum-dominated peat bogs located in Central Europe (Rybarenska slat and Ocean Bog; Czech Republic) and the British Isles (Thorne Moors, England; Connemara, Ireland; and Mull, Scotland). Sulfur concentrations were measured in three 40-cm deep peat cores per site, sectioned into 2-cm segments. The coefficient of variation in S concentrations was low across all depths and sites (mean of 16%), indicating a high degree of within-site homogeneity in vertical S patterns. Similar S concentration trends and similar δ34S trends were found at all study sites. With an increasing peat depth, S concentrations first increased and then decreased. S concentrations peaked in layers which were deposited in ca. 1959, 1907, 1945, 1899 and 1799 at Rybarenska slat, Ocean, Thorne Moors, Connemara and Mull, respectively. Atmospheric S deposition peaked in 1972 in the UK and in 1987 in the Czech Republic. Due to downward S mobility in peat, S concentration maxima were found in layers 59 (±19) a older that the year of the actual peak in S input. With an increasing depth, the maturating peat substrate at all sites exhibited first a negative δ34S shift, resulting from dissimilatory bacterial SO4 reduction, and then a positive δ34S shift, which may be related to advancing S mineralization. Minimum δ34S values were detected in layers which were deposited in ca. 1988, 1982, 1945, 1940 and 1978. A comparison of historical δ34S signatures of atmospheric S in England, measured on archived grain from the Broadbalk experiment (1845–1994), with δ34S values of Thorne Moors peat (1830–1994) also indicated mobility of S in peat. Sulfur mobility in water-logged peat is of concern during the present period of easing industrial pollution because SO4 released from peatlands may increase the acidity of the output. 相似文献
9.
热解硫酸钡制备硫同位素分析试样二氧化硫 总被引：1，自引：1，他引：0
改进了硫同位素分析中由ＢａＳＯ４制备ＳＯ２的方法：ＢａＳＯ４和Ｖ２Ｏ５及ＳｉＯ２混合后覆盖铜丝,在真空状态９８０℃加热２０ｍｉｎ,用液氮捕集ＳＯ２。与火焰直接加热分解法相比,用高温炉方便,改善了制样环境,避免污染。经国际标样和国家标准物质分析验证,结果与标准值相符,标准偏差（１σ）在±００９‰～±０２０‰,符合分析要求。 相似文献