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AN ION PROBE CONTRIBUTION TO RARE EARTH ELEMENT INVESTIGATION OF GABBRO GOG-1 USING SECONDARY ION MASS SPECTROMETRY 总被引：1，自引：0，他引：1
Luisa OTTOLINI Piero BOTTAZZI Riccardo VANNUCCI Massimo ODDONE 《Geostandards and Geoanalytical Research》1992,16(1):13-19
An updated REE measurement of Gabbro GOG-1 was carried out by means of secondary ion mass spectrometry (SIMS). The availability of high amount of rock powder allowed the sample to be well ground and homogenized before analysis. Fused glass pellets were employed for SIMS investigations. REE data were compared with new ICP-AES and NAA analyses. REE results from all employed analytical techniques show good agreement and are consistent with in-situ SIMS measurements of REE in major mineral phases forming GOG-1. Extensive homogeneity tests seem to confirm the possibility to using this rock as a reference material for earth sciences. 相似文献
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赞比亚卢菲利安弧中西段有大量辉长岩体发育。由于本区风化严重,辉长岩常被厚土壤层覆盖。辉长岩中的铜含量常高于其沉积围岩,易于形成铜异常。为了将辉长岩形成的异常与矿致异常区别开,有必要对土壤覆盖层下的辉长岩进行识别。作者对卡皮萨比地区的化探数据采用相关分析和因子分析进行了研究,认为铜异常与基性岩浆作用有关。根据野外地质观察、音频大地电磁测量、高精度磁法测量、槽探和钻探等工作,认为:地表砖红色土壤、高磁高阻地质体和Sc-Ti-V-Fe-Co-Ni-Cu的元素组合是识别强风化条件下隐伏基性岩体的标志。 相似文献
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西藏东巧蛇绿岩的地球化学特征及其形成的构造环境 总被引：7，自引：3，他引：4
西藏东巧蛇绿岩主要由变质橄榄岩、辉长岩及玄武岩等组成。变质橄榄岩以富Mg、Fe、Cr,贫Ti、ΣREE为特征。辉长岩和玄武岩的主量元素、微量元素特征显示其具有扩张洋脊拉斑玄武岩的地球化学特征,其中高场强元素Nb、Ta、zr、Hf等亏损,大离子亲石元素Rb、sr、Ba等相对富集;在球粒陨石标准化稀土元素配分模式图上为LREE亏损的平坦型,无负Eu异常,与洋中脊玄武岩的特征类似。根据其地球化学属性,推测该区蛇绿岩形成于大洋盆地扩张的构造环境。 相似文献
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The Alpine peridotite massif of Lanzo (Italy) contains three generations of basic dikes (gabbros and basalts). The older gabbros are plagioclase-rich mantle segregates while the younger gabbro dikes are cumulates very similar in chemical composition to recent oceanic gabbros and gabbros from ophiolitic complexes. They both were derived from the N-type mid-ocean ridge basalt (MORB) magmas which were progressively more depleted in incompatible elements and were probably generated during a dynamic melting of a rising mantle diapir. The basaltic dikes are the N-type MORB and closely resemble the Alpine-Apennine ophiolitic basalts. They were derived from a different upper mantle source than the parental magmas of the gabbros. The source of the basalts was less depleted in light REE. The presence of basic magmas with N-type MORB affinities in the Lanzo massif is consistent with the close genetic relationship between the Alpine peridotite body and the ophiolites of the Liguro-Piemontese basin. 相似文献
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判别岩浆岩产出的构造环境已经成为岩石学、地球化学及其地球动力学研究的重要内容。作为岩浆岩中的一种喷出岩,玄武岩被视为判别构造环境的最佳成员。对其中单斜辉石的研究,由于其数据本身的利用程度有限而效果欠佳。理论上,不同构造环境的辉长岩也会存在一定差异。为此,利用机器学习算法研究全球新生代辉长岩的单斜辉石势在必行。本文主要针对岛弧(IAB)、洋岛(OIB)及大洋中脊(MORB)3种构造背景辉长岩的单斜辉石进行特征筛选和数据分类。从GEOROC数据库中,经数据收集与清洗,我们分别获得岛弧辉长岩单斜辉石数据385条,洋岛辉长岩单斜辉石数据756条,大洋中脊辉长岩单斜辉石数据5 500条。其中绝大部分为主量元素数据,其余为微量元素数据。在特征提取部分,我们选用卡方检验判断特征独立性,F检验估计两个随机变量之间的线性依赖程度,互信息法捕获其他种类的统计相关性。3种检验方法互相印证,得出了统计学可靠的重要分类特征。在数据分类过程中,本文对比了K-近邻、决策树和支持向量机3种主流机器学习分类算法在辉长岩数据上的表现。研究表明,对于上述3种构造背景,Al2O3、TiO2为最有区分度的辉长岩单斜辉石主量元素成分,Sr为最有区分度的微量元素成分。另外,对于3种构造背景的辉长岩单斜辉石主量元素和微量元素数据,机器学习模型分类准确率均达94%。 相似文献
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大别造山带祝家铺辉长岩的铂族元素特征 总被引：8，自引：2，他引：8
采用镍锍火试金法结合ICP-MS分析了祝家铺14个辉长岩样品中的Ir，Ru，Rh，Pt和Pd的含量。结果显示其PGE的含量较低，原始地幔标准化后的PGE分布模式呈正斜率型，PPGE相对原始地幔略微亏损，而IPGE强烈亏损，Pd／Ir值(22—138)远高于相应的地幔比值，表明铂族元素发生了分异。对祝家铺辉长岩的铂族元素研究表明，在其源区发生过硫化物的分异作用，地壳的混入可能促进了硫化物的饱和。祝家铺辉长岩中铂族元素的分异是因为在地幔部分熔融和岩浆演化过程中，PPGE主要受硫化物控制，而Ir则存在于非硫化物相如尖晶石、可能还有合金之中。 相似文献
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西藏永珠——果芒错蛇绿岩的地球化学特征及其构造意义 总被引：8，自引：1，他引：7
永珠-果芒错蛇绿岩位于西藏永珠藏布-纳木错蛇绿岩带西段,主要由变质橄榄岩、辉长辉绿岩及玄武岩等组成。变质橄榄岩以富Mg,贫Ti、∑REE为特征。辉绿岩和玄武岩的主量元素、微量元素分析显示其含有洋脊拉斑玄武岩和岛弧拉斑玄武岩的双重成分特征,其中高场强元素（Nb、Ta、Zr、Hf等）亏损,大离子亲石元素（Rb、Sr、Ba等）相对富集,具有岛弧玄武岩的特点;在球粒陨石标准化稀土元素配分模式图上显示稀土元素特征为LREE亏损的平坦型,无负Eu异常,与洋中脊玄武岩的特征类似。通过与典型地区作对比和应用构造环境判别图解,推断永珠-果芒错蛇绿岩形成于弧后盆地的构造环境。 相似文献
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《International Geology Review》2012,54(8):936-955
ABSTRACTThe Ordovician plutons in the Erguna Block, NE China, can be classified into two groups: Early Ordovician diorites with zircon U–Pb ages ranging from 486 to 485 Ma and Middle Ordovician gabbros and granites with zircon U–Pb ages ranging from 466 to 463 Ma. The diorites are calc-alkaline in nature and are characterized by weak to moderate enrichments of large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to high field strength elements (HFSE) and heavy rare earth elements (HREE). The gabbros and granites have high total alkali contents, and all samples are enriched in LREE and LILE and depleted in HFSE such as Nb, Ta, and Ti. Isotopically, Early Ordovician diorites display values that are less radiogenic [εHf(t) = + 9.9–+16.8] compared to those of Middle Ordovician gabbros [εHf(t) = ? 3.0–+5.0]. Middle Ordovician granites have positive εHf(t) values of +1.4 to +4.3 and two-stage Hf model ages (TDM2) of 1167 to 1356 Ma. These data indicate that the diorites may have been generated by the partial melting of a recently metasomatized mantle source, whereas the gabbros and granites may have been formed by the partial melting of enriched lithospheric mantle and Mesoproterozoic crust, respectively. Our results, combined with other regional results, suggest that Early Ordovician magmatism was likely associated with the northward subduction of the Heihe–Xilinhot oceanic plate beneath the Erguna–Xing’an Block, whereas the Middle Ordovician gabbros and granites were most likely formed in an extensional setting controlled by the rollback of this subducted oceanic plate. 相似文献
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富铌辉长岩往往与高镁闪长岩、埃达克岩共生,被认为是具有指相意义的岩石构造组合,但豫西地区北秦岭造山带南侧该类岩浆活动却很少被发现.对寨根地区秦岭岩群中的斜长角闪岩类进行岩石学、地球化学、同位素地球化学和年代学研究,在该深成杂岩中发现了富铌辉长岩,并且测得富铌辉长岩的变质锆石U-Pb年龄为484.3±1.8 Ma,与区内超高压榴辉岩变质峰值年龄相近.富铌辉长岩地球化学特征表现为富集Rb、Th等大离子亲石元素,亏损Nb、Ta、P等高场强元素,εNd（t）介于-1.61~+0.49,相应的（87Sr/86Sr）i范围为0.714 273~0.723 936.推测其成因与秦岭古陆壳深俯冲过程中部分熔融的板片熔体交代地幔楔橄榄岩再熔融有关,经受深俯冲时有大量陆壳物质的加入,该发现为秦岭造山带早古生代早期存在多个微陆块提供了证据. 相似文献
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New analytical data on three elements are presented for the two USGS manganese nodule reference materials, Nod-A-1 and Nod-P-1. Arsenic and tungsten were determined by instrumental neutron activation analysis, and uranium by delayed-néutron counting. 相似文献
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Both field relationships and geochemical characteristics indicate two suites of plagiogranitic and related rocks coexisting in the higher parts of the Karmoy ophiolite of western Norway. The plutonic zone of this ophiolite can be subdivided into three complexes; the East-Karmoy Igneous Complex, the Visnes High Level Complex and the Veavagen Igneous Complex and plagiogranitic rocks are well developed in the first two of these.Within the East-Karmoy Igneous Complex, plagiogranites are associated with high temperature, pre-basic dyke, shear zones. Rare earth element modelling indicates that these plagiogranites were derived by anatexis of amphibolite (hydrated diabase) assuming a starting material consisting of 40% hornblende and 60% plagioclase and that batch melting occurred within the stability field of hornblende.In comparison, plagiogranite occurs in a number of bodies in the upper part of the Visnes High Level Complex and forms a sandwich horizon together with biotite diorites and epidosites between a roof assemblage of dykes, microgabbros and magnetite gabbros, and a floor assemblage of layered and non-layered gabbros. The R.E.E. modelling of the petrogenesis of this series of plagiogranites indicates that they were derived by filter pressing of a differentiated interstitial liquid to the vari-textured gabbros, although the distribution of highly hygromagmatophile elements such as K, Rb, Ba, etc. cannot be explained satisfactorily by this model alone. Depletion in these elements appears to be an autometasomatic effect. 相似文献
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The SW Antalya Complex is an assemblage of Mesozoic carbonate platform, margin and ophiolitic rocks which record the formation and tectonic emplacement of a small Mesozoic ocean basin. The late Cretaceous ophiolitic rocks are located at two localities, namely the relatively intact Tekirova ophiolite to the east of Kemer zone and the dismembered Gödene ophiolite to the west of Kemer zone. The Tekirova (Antalya) ophiolite comprises harzburgitic tectonites, ultramafic to mafic cumulates, isotropic gabbros and sheeted dikes. Numerous isolated dikes, ranging in thickness from 5 cm to 10 m, intruded the crustal rocks at different structural levels. The isotropic gabbros are represented by gabbro, diorite and quartz diorite rocks with granular to ophitic–subophitic textures. The isolated dikes are characterized by dolerite, diabase and microdiorite with ophitic, intersertal and microgranular textures. These rocks exhibit tholeiitic to alkaline compositions. New geochemical data presented in this paper from the isolated dikes and isotropic gabbros suggest that there are three main types of parental basic magmas that form the oceanic crustal rocks of the Tekirova (Antalya) ophiolite. These are (1) IAT series which can be referred to the Group I isolated dikes and isotropic gabbros; (2) low-Ti boninitic series characterized by the Group II isolated dike and isotropic gabbros; and (3) OIB-type including the Group III isotropic gabbros. The geochemical evidence suggests that the crustal rocks of the Tekirova (Antalya) ophiolite were generated from a progressive source depletion from island arc tholeiites (IAT) to boninites. Therefore, a fore-arc tectonic setting seems likely for the generation of the crustal rocks from the Tekirova (Antalya) ophiolite in the southern branch of Neotethys during the Late Cretaceous. The OIB-type alkaline isotropic gabbros are thought to have resulted from either (1) a late-stage magmatic activity fed by melts that originated within an asthenospheric window due to slab break-off or (2) subduction of a ridge system which generated OIB source across the asthenospheric window that has been no influence of fluids from the subducted slab into the overlying mantle wedge, shortly before the emplacement of the Tekirova (Antalya) ophiolite onto the Tauride platform. 相似文献
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滇西北金沙江带中基性火山岩的地球化学特征 总被引：3，自引：0，他引：3
对滇西北金沙江带出露的东竹林火山岩、辉长岩和奔子栏、维西攀天阁、石鼓地区中基性火山岩进行了系统的主量元素、微量元素、Sr-Nd同位素的地球化学研究,并对东竹林辉长岩进行了Sm-Nd等时线年龄的测定,以探讨金沙江地区的大地构造背景及其演化.研究表明,金沙江带出露的从泥盆纪到三叠纪的火山岩形成于弧后盆地、初始裂谷和岛弧等各种不同的构造环境.研究为金沙江带构造演化的多次裂开,多次俯冲消减的多岛洋模式提供了新的证据. 相似文献
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Sherif Kharbish 《Chemie der Erde / Geochemistry》2010,70(3):257-266
Wadi El-Markh gabbro–diorite complex is composed of pyroxene hornblende gabbros, hornblende gabbros, diorites and quartz diorites. According to their bulk rock geochemistry and mineral chemistry, the gabbroic and dioritic rocks represent fractionates along a single line of descent and crystallized from a calc-alkaline mafic magma. When compared to the primitive mantle, all members of the gabbroic–dioritic rock suite are enriched in the large ion lithophile elements relative to the high field strength elements and display distinctive negative Nb and P2O5 anomalies. This signals an arc setting. Fractionation modeling involving the major elements reveals that the hornblende gabbros were generated from the parent pyroxene hornblende gabbros by 61.86% fractional crystallization. The diorites were produced from the hornblende gabbros by fractional crystallization with a 58.97% residual liquid, whereas the quartz diorites were formed from the diorites by 26.58% fractional crystallization. According to geothermobarometry based on amphibole mineral chemistry, the most primitive pyroxene hornblende gabbros crystallized at ～830 °C/～5 kbar. The crystallization conditions of the quartz diorites were estimated at ～570 °C/～2 kbar. In consequence the Wadi El-Markh gabbro–diorite complex represents a single magmatic suite of which fractionates crystallized in progressively shallower levels of an arc crust. 相似文献
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西藏泽当—罗布莎蛇绿岩的地球化学特征及其构造意义 总被引：3，自引：0，他引：3
西藏泽当—罗布莎蛇绿岩是雅鲁藏布江蛇绿岩带的重要组成部分,受控于板块碰撞结合带。该蛇绿岩主要由变质橄榄岩、辉长辉绿岩及玄武岩等组成。变质橄榄岩具有低的A l2O3和CaO含量,以富Mg,贫Ti、∑REE为特征,与世界上典型蛇绿岩中方辉橄榄岩的特征值一致。辉长岩和玄武岩的主量元素、微量元素特征显示其含有洋脊拉斑玄武岩和大洋岛弧拉斑玄武岩的双重成分,其中高场强元素Nb、Ta、Zr、H f等亏损,大离子亲石元素Rb、Sr、Ba等相对富集,具有大洋岛弧玄武岩的特点。辉长岩在球粒陨石标准化稀土元素配分模式图上为LREE亏损的平坦型,无负Eu异常,与洋中脊玄武岩类似。根据上述特征并结合区域地质构造特征,认为泽当?罗布莎蛇绿岩可能形成于边缘海盆地的海底慢速扩张环境。 相似文献
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Eologites interlayered with serpentinites of the Voltri Group show a distinctive chemical composition, high in total iron and titania, and low in magnesia, silica and certain trace elements. Petrographic evidence indicates that they were formed by high-pressure metamorphism of coarse-grained gabbros, as well as from fine-grained gabbros or diabases. Their composition does not compare well with that of other eclogites, either those included in ultramafic rocks or those occurring in blueschist facies terrains. However it matches relatively well with that of certain gabbros from the Mid-Atlantic Ridge which are strongly fractionated with iron and titanium enrichment. The hypothesis that the Voltri Group maficultramafic association formed as a part of an oceanic ridge receives support. 相似文献
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扬子陆块西南缘发育一系列中-新元古代岩浆岩,对认识扬子陆块构造演化具有重要意义.对会理地区天宝山组流纹岩和盐边地区辉长岩进行SHRIMP锆石U-Pb年代学、地球化学研究.天宝山组流纹岩时代为1 011.9±8.9 Ma,辉长岩时代为910.6±4.7 Ma.天宝山组流纹岩具有高硅、高FeOt/MgO、高钾等特征;稀土含量（∑REE=292×10-6~401×10-6）较高,表现出轻稀土富集重稀土弱亏损的特征[（La/Yb）N=1.77~6.74],Eu负异常明显（δEu=0.43~0.56）,与A型花岗岩相似;天宝山组流纹岩来自古老的地壳物质的部分熔融,形成于大陆裂谷环境.盐边群辉长岩稀土含量（∑REE=54×10-6~98×10-6）较低,轻重稀土分异较弱[（La/Yb）N=1.46~4.72],Eu具有轻微的异常（δEu=0.81~1.31）;岩石具有明显的Nb-Ta、Ti负异常,无Zr-Hf正异常;地球化学数据显示辉长岩来自被俯冲板片释放的流体/熔体交代的地幔楔部分熔融,形成于岛弧环境.两期岩浆活动指示了扬子西南缘1 000~910 Ma之间构造动力学背景发生了转变,由伸展背景转变为挤压背景. 相似文献
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Many Neo-Tethyan ophiolitic bodies are well exposed as thrust-slices in Central Anatolia and are predominantly represented by massive hornblende gabbros, most of which are cut by Supra Subduction Zone (SSZ) plagiogranites. The allochthonous gabbros are distinct from their autochthonous counterparts, with their mineralogy including both igneous hornblende, relict diopside rimmed by replacement hornblende and their chemical composition corresponding mostly to gabbro rather than diorite.The results of major and trace element analyses of forty-two samples, and REE analyses of nine samples, indicate that the hornblende gabbros are SSZ-type and formed from a wet magma by high-degree partial melting of peridotite possibly coupled with contamination by predominantly neighbouring-slab derived fluids within an intra-oceanic back-arc basin. The mafic magmas then underwent high-level fractional crystallization involving titaniferous magnetite, diopside, tschermakite and possibly olivine. Emplacement was followed by extensive ocean–floor metamorphism, which has induced crystallization (or recrystallization) of chlorite, biotite, amphiboles and mobilisation of most of the major elements such as alkali and alkali earth elements, and some LREE. 相似文献