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1.
Molecular biomarkers are the important maturity parameters for sedimentary organic matter.They have also been widely used for determining the maturity of organic matter in ore deposits. However,during the study of organic matter in the Kupferschiefer from the Lubin mine, it had been found that the biomarkers were influenced by sulfide formation. In order to probe into the degree of influence on biomarkers, seven samples collected from a Kupferschiefer section from the Lubin mine were analyzed by various geochemical methods. The results indicated that in the samples with higher copper contents, the values of biomarkers are lower than in the samples with lower copper contents. In highly mineralized samples, hydrogen donation for thermochemical sulfate reduction (TSR) occurred in alkylated phenanthrenes and naphthalenes, leading to the decrease of 12 biomarker parameters during the Kupferschiefer mineralization.  相似文献   

2.
洛川黄土剖面的古地磁研究   总被引：28，自引：1，他引：28  
Paleomagnetic measurements were conducted on 96 ariented loess specimens collected from the Lochuan section in Shanxi Prov., the total thickness of which is up to 130 m and more. The results have provided evidence that the deposition of Late Pleistocene Malan Loess and Middle Pleistocene Lishih Loess in the Lochuan section took place during the Brunhes normal epoch. The lower limit of the Lishih Loess which represents the boundary between the Brunhes epoch and the Matuyama epoch is located at the top of the lower silt bed, corresponding to a depth of 75 m. The Wucheng Loess, which recorded the Jalomillo normal polarity event, deposited during the middle-late period of the Matuyama reversed epoch. The upper limit of the Jalamillo is set at a depth of 100 m. and the lower limit at 110 m. Experiments have shown that rotated remanent magnetization of the specimen resulted from AF demagnetization Can be effectively eliminated by means of magnetic cleaning in opposite directions,despite of the differences in magnetic stability and ages of various strata (loess, silt bed, buried soil and weathered beds) in the Lochuan section.  相似文献   

3.
China has been the leading country worldwide in direct geothermal utilization for a rather long time, which has contributed significantly to reducing carbon emissions. But the installed capacity of geothermal power generation in China is very small, and there are only a few geothermal power plants in China, specifically in Tibet, including the well-known Yangbajing geothermal power plant. Therefore, it is anticipated that more high-temperature geothermal resources will be discovered in order to promote China’s power generation. There is potential for high-enthalpy geothermal in the Eastern Linqing Depression in Shandong Province, where geothermal energy is stored in Ordovician and Cambrian carbonate strata. Based on the geothermal gradient in Cenozoic strata and the depth of the target geothermal reservoir, the temperature distribution pattern of the reservoir was analyzed, and two “sweet points” were identified in the Yucheng geothermal field and the Guanxian geothermal field, where the reservoir temperature is predicted to be higher than 200°C at a depth of less than 8000 m. Due to the low karst fissure ratio and the insufficient geothermal fluid in the geothermal reservoir, it is recommended that an enhanced geothermal system be set up, to increase the permeability of the natural fracture system in the carbonate formations and provide sufficient fluid for power generation through reinjection of used geothermal fluid. The power generation capacity of the two geothermal fields was estimated using a volumetric method, revealing a power generation capacity of 1621.02 MWe for the Yucheng geothermal field, and 1287.19 MWe for the Guanxian geothermal field.  相似文献   

4.
Heavy water eoutcnts were determined for brines from Some salt lakes, and for water samples from rivers, springs and oil field by temperature-float method. Because the salt lakes studied are situated in cold, arid region of high altitude, the heavy water content in concentrated brines is much higher than that in rivers and springs due to vigorons evaporation, with a maximum value of 5.9 γ higher than that in running water of Peking. Discussion is also given to the dependence of heavy water variation upon season, depth of lake water, density, the degree of brine metamorphism,and crystallization of minerals containing crystalline water.  相似文献   

5.
关于TM／TS指标的意义及应用   总被引：1，自引：0，他引：1  
The TM/TS index as the ratio of two isomeric peaks of C27H46 trinurhopane in the m/e 191 fragmentogram is one of the important molecular parameters for petroIeum geochemistry, which has found xcide application in identifying the degree of maturation of organic matter in China. It has been observed that the TM/TS index not only depends on the burial depth and temperature with respect to terrestrial crude oils and source rocks(i.e., it decreases with increasing burial depth and temperature), but also on the type of organic matter and sedimentary facies. So the application of the index indicative of maturation of organic matter is conditional.  相似文献   

6.
Burial Metamorphism of the Ordos Basin in Northern Shaanxi   总被引：1，自引：0，他引：1  
Burial metamorphism has been found in the Ordos basin of northern Shaanxi. On the basis of a rather intensive study of burial metamorphism of sandstone, it has been shown that the evolution from diagenesis to metamorphism involves four stages: cementation of clay minerals, regrowth of pressolved quartz and feldspar, cementation of carbonates and formation of laumontite. On that basis it has been put forward that the laumontite is formed by burial metamorphism of clay and carbonate minerals. According to the thermodynamic data of minerals, the conditions under which laumontite is formed are T<250℃ and X_(CO_2)<0.17. High-resolution SEM and TEM studies of clay minerals in mudstone show that there occur a mixed layer assemblage of bertherine and illite/chlorite and transformation from bertherine to chlorite. On that basis coupled by the X-ray diffraction analysis the author suggests the following transformation of clay minerals during burial metamorphism: the earliest smectite-kaolinite assemblage changes into the bertherine-illite mixture with increasing depth, then into the illite/chlorite mixed layer assemblage and finally into dispersed individual illite and chlorite. The reaction of the transformation is:smectite+kaolinite+K~+=illite+chlorite+quartz According to the study of the oxygen isotope thermometry of the coexisting illitequartz pair, the temperature of the above transformation is lower than 180℃.  相似文献   

7.
The depth is important for ore finding in Jiaodong gold deposit. However, many geologis tsare still discussing how to confirm the depth for the tectonic and metallogenesis formation. The authors of this paper propose a new method—the correction of metallogenic depth via its structure to calculate the depth. This method, based on the crust rock in a solid stress state, emphasizes the elastic pattern rather than the static-fluid pattern. In addition, this method is more appropriate to the actual situation in the crust than the method of weight/special weight. The authors of this paper illustrating, with the Jiaodong gold deposit as an example, the metallogenic depth correction via structure conclude that the depth of the most deposits, lower than 4-6 km, is often 2.5 kin. Therefore, the authors suggest that there exists a second enrichment belt and that ore resources are more potential at the belt of Jiaodong area. These results have been demonstrated by years of exploration.  相似文献   

8.
Sourthern China referred to in this paper embraces all the provinces to the south of latitude 32° N within the territory of China, exclusive of Tibet and Taiwan.The paper is based on the data obtained from temperature measurements of 680 boreholes drilled for petroleum, coal and hydrogeology. The depth of these boreholes ranges between 1,000 and 2,000m in most cases, being generally not less than 400m and reaching 7,000m in maximum.Through the elaboration and analysis of the temperature data, isotherm maps showing the temperatures at depths of 1,000m, 2,000m and 3,000m respectively and a geothermal gradient map of southern China have been compiled. These maps indicate that the earth's temperature distribution in southern China is characterized by a elatively low value in areas of its central part and those to the west of the Anning River valley of the western part(30℃, 40℃ and 70℃ at depths of 1,000m, 2,000m and 3,000m respectively), and a comparatively high value in the southeastern coastal areas and western Yunnan(60℃, 80℃ and over 120℃ respectively), and that the geothermal gradient also increases from less than 1.5℃/100 m in the central part towards both the east and the west to 2.0-3.0℃/100m or even over 4.0℃/100m.The earth's temperature distribution is strictly controlled by the deep structure of the earth's crust and is very closely related to the character of the regional geological structure, The stable central areas remarkably differ in the earth's temperature distribution from the tectonicalty active areas such as the southeastern coastal areas and the Jinggu-Tengchong area in western Yunnan, the former being lower than the latter. Meanwhile, due to the well-developed karst features in southern China, the strong groundwater flow may exert certain cooling effect on the temperature down to a depth of about 1,500m.According to the regularity of the earth's temperature distribution, regional deep structure of the earth's crust, regional geological structure and hydrogeological conditions, the following four models are proposed to explain the mechanism of formation and distribution of the earth's temperature fields in southern China: 1) onduction type; 2) convection type; 3) deep heat-source conduction-convection type; and 4) precipitation infiltration cooling type.  相似文献   

9.
碳酸盐岩生油岩的有机地球化学、岩石学特征   总被引：13，自引：1，他引：13  
Features of oil-generating carbonate rocks are studied in terms of petrology and organic geochemistry of fluorescent materials in rocks. It is postulated by the authors that the organic carbon content in oil-generatlng carbonate rocks is necessarily lower than that in shales, and the possible cause of this observation is discussed. The quality of oil-ganerating carbonate rocks may be judged by aromatic structure index,amino acid, pigment index, and DTA data on organic matter. However, the application of presently available organic geochemical criteria to non-oil-generating reservoir rocks may always give misleading results. To circumvent this difficulty, it is necessary first to make distinction between primary and secondary organic matter by cxamining the fluorescent materials under a fluorescence microscope. Measurementof radical content of the organic substances and DTA are useful techniques to determine the degree of maturation. The maturation of organic substances proceeds at a lower rate in carbonate rocks than in shales. It is likely, therefore, that some older carbonate strata can also be promising areas for petroleum exploration. Oil-generating carbonate rocks consist mainly of mierite limestones rich in organic matter and are thought to be formed under low-encrgy environment. Consequently, petrological(especially mierolithofacies) studies are very important in evaluating carbonate source rocks.  相似文献   

10.
Multiple coal seams and interbedded rock assemblages formed in vertical progression due to the influence of multiple stages of sea level transgressions.Based on mercury injection experiment,low temperature liquid nitrogen experiment,porosity and permeability experiment and breakthrough pressure experiment,the vertical variation characteristics of coal-bearing strata in Gujiao block are explained in detail.The results of the mercury injection and low temperature liquid nitrogen experiments show that the pore structure characteristics fluctuate with increasing depth in the strata,with fewer micropores followed by transition pores.The BET specific surface area and average pore diameter of the Shanxi Formation are generally larger than those of the Taiyuan Formation.Due to the continuous cyclic sequence stratigraphy changes,the porosity,permeability,breakthrough pressure and breakthrough time of the samples show a certain cyclicity.Within the same sequence,the porosity is larger,and the permeability is smaller near the maximum flooding surface.Although the permeability of the sandstone samples is higher,the porosity is lower,and the breakthrough pressure and breakthrough times are greater.The strata in the study area formed in an oxidized environment that was affected by freshwater,and the pore structure of different lithologies is quite different.After the formation of sandstone,the intergranular pores generally underwent filling with secondary quartz,clay minerals and organic matter,resulting in low porosity and permeability.  相似文献   

11.
Based on the studies of geological history during the Paleozoic time. depoaitional esvironment, the evolution of organisms, the content of organic substances and the distribution of oil-generatlng strata, various indicators concerning oil generation are discussed and. compared in terms of Organic substance composition, the alkane and isopronoid in saturated hydrocarbon, characteristic functional group of the aromatic hydrocarbon and its structure, element composition and free radical concentration in asphaltene as well as carbon isotopes. The following conclusions can be drawn: (1) During the Later Paleozoic, the mud stone of the two oil-generating depressions of the Ponhsi Group on the western part of the basin was the most important reservoir and the black mud stone and limestone were secondary in importance. (2) Both the Ordovicoan Machiakou limestone and the shale of grapholithic facies are main oil (gas) generating strata in the western part of the basin. The Changhsia Group of the middle Cambrian system may also be oil-generatlng but is of little consequence. (3) Oil and gas formation in the Upper and. Lower Paleozoic groups represent two. different evolutionary stages. In the Upper Paleozoic group the petroleum formed is a kind of light oil, and large quantities of natural gas had been formed from the coal-bearing Taiyuan and Shansi Groups as a result of metamorphism. In response to the action of temperature and. presses over the prolonged geological period, oil sad gas formation in the lower Paleozoie group corresponds to a more advanced evolutionary stage, during which the generation of natural gas is the dominant process in comparation with oil condensation. Therefore the lower Paleozoic group is believed to be more promising for gas prospecting.  相似文献   

12.
The successful exploration and production of shale-gas resources in the United States and Canada sets a new possible solution towards the energy crisis presently affecting most countries of Asia. This study focuses on the use of well log and 2D seismic data for the characterization of the shale oil/gas potential of a Paleocene–Eocene succession — the Meyal area in the Potwar Basin of Pakistan. Two shaly plays are identified in Paleocene–Eocene strata in well logs using ΔLogR and modified ΔLogR cross-plot techniques. The results indicate that Paleocene shale(the Patala Formation) and the lower shaly part of Eocene limestone(Sakesar Formation) can be potentially mature source rocks. However, the thermal maturity modelling proves that only the Paleocene shale is mature. Our results also suggest that the maturity responses on ΔLogR models for the lower shaly part of the Eocene limestone are due to trapped hydrocarbons in the intra-formational fractures. Petroelastic/petrophysical analysis of the Patala Formation reveals two potential shale oil/gas zones on the basis of Young's modulus, Poisson's ratio, Brittleness index and Total Organic Content at an exploitation depth of 3980–3988 m. This work can provide valuable insight for estimating shale oil/gas potential in highly deformed basins not only in Asia but in other parts of the world.  相似文献   

13.
Using the long-term ground temperature monitoring data of the permafrost zone along the Qinghai-Tibet Railway from 2006 to 2020,three types of typical roadbed structures were analyzed. Traditional embankment（TE）,U-shaped crushed rock embankment（UCRE）and crushed rock revetment embankment（CRRE）were included the three types of typical roadbed,which were selected to the long-term monitoring sections within the warm permafrost zones. The evolution of ground temperature field,mean annual ground temperature （MAGT）and annual maximum ground temperature（AMGT）in the depth range of 20 m under the embankment were analyzed and studied since 15 years of operation. The monitoring and analysis results show that：the growth rate of MAGT under the left and right shoulders of the TE is always higher than that of the same depth in the natural site. The MAGT under the UCRE is always lower than the natural site and always maintains a certain difference,whereas,the difference in ground temperature under the left and right shoulders is also not negligible. The MAGT of the left shoulder in the CRRE is not much different from that of the natural hole,while the MAGT of the right shoulder is always lower than that of the natural hole,and the differ in ground temperature between the left and right shoulders is smaller than that of the UCRE. The artificial permafrost table（APT）under the TE is always lower than that of in the natural site. Both the UCRE and CRRE,the APT in the left and right shoulders of them has been elevated into the embankment,and the differ of APT between the left and right shoulders is about 1. 0~1. 5 m. the differ of APT between the left and right shoulders in the CRRE is slightly lower than that of UCRE. Overall,because of the influence of thermal disturbance about engineering and climate warming,the TE in the warm permafrost zones cannot keep the thermal stability of permafrost under the embankment. Some active-cooling and reinforcement measures need to be taken. Both of the UCRE and CRRE,have a certain active-cooling effect on the permafrost under embankment,but the differ in ground temperature between the left and right shoulders still needs to be taken seriously. © 2022 Science Press (China).  相似文献   

14.
Based on studies of the reflectance of Ordovician and Silurian zooclasts from 11 sections around the Huangling Anticline, Hubei, China, combined with determination of the conodont colour alteration indices (CAI) and of infrared spectroscopy of dispersed organic matter from the same or adjacent horizons, it is further proved that reflectances of graptolites, chitinozoans and scolecldonts, like vitrinite and natural bitumen, increase with increasing maturation, but follow different reflectance paths. They may be used, therefore, as thermal maturation indicators. Graptolites display optically strong anisotropy. The maximum reflectance measured from graptolite on polished section cut parallel to the bedding plane is the most suitable for determination of maturation of their host rocks. In polished section chitinozoan and scolecodont show reflectance, but no bireflectance owing to their isotropy. The random reflectance of chitinozoans is higher than that of scolecodonts in the case of the same maturity. By analysing the distribution trends of graptolite, chitionzoan and scolecodont reflectances, the Ordovician and Silurian strata can be subdivided into three areas of maturation in the present region. The potential of oil or gas generation is discussed for each area. The result is basically coincident with the distribution pattern of regional organic maturation presented by CAI and infrared spectroscopic determination of organic matter.  相似文献   

15.
《地质学报》1973,46(1)
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16.
Stable isotope composition of syngenetic and epigenetic ice wedges, radiocarbon age, and pollen spectra of the surrounding deposits were studied during long term investigations at the "Belyi Klyuch" site on the first(6-8 m height) terrace of the Chara River(720 m.a.s.l.) in northern Transbaikalia to assess climatic conditions during ice-wedge formation. It was revealed that Holocene ice wedges had been formed from 10 to 7.5 ka 14 C BP. The isotope composition(δ~(18)O, δ~2 H) of relict ice wedges is the lightest and amounts-23‰ and-185‰, correspondingly. The isotopic compositions of ice lenses from sandy loam above ice wedges are-15.7‰, and-133‰; of small ice wedge in peat and sand are-15.3‰ and-117.9‰, accordingly.Interpretation of the ice wedge isotope composition has yielded that mean winter temperatures during cold stages of Holocene optimum were lower than today, during warm stages they were close to modern ones. During the coldest stages of Holocene optimum the total annual freezing index varied from-5100 to-5700 ℃ degree days, i.e. 300-600 ℃ degree days colder than during extremely severe modern winters. The total annual thawing index varied from 1300 to 1800 ℃ degree days, which was slightly higher than modern ones.  相似文献   

17.
试论稀土铁建造   总被引：7，自引：0，他引：7  
Geological and geochemical characteristics of REE iron formation, a term proposed by Prof. Tu Kuang-chih to specify a special type of Precambrian iron formation rich in REE, are discussed in this paper with special reference to its REE contents, REE distribution patterns, model of formation, the relationship between its development and the multistage evolution of terrestrial crust in China, and its role as an indicator of oxidation status for ancient atmosphere. Major conclusions are as follows: (1) REE iron formation is characterized by high REE concentrations as opposed to very low REE level in normal Precambrian iron formations. (2) REE iron formation was resulted from marine sedimentary-diagenetic process in miogeosyncline or intermediate regions during Proterozoic Era. To some extent,volcanic activity may be responsible for the deposition of ore-forming materials. In a broader sense, it belongs to Fe-bearing dolomite formation. On most REE iron formations there may be later mineralizations such as hydrothermo-metasomatisn, migmatitization and metamorphism superimposed. Generally, REE iron formations share common fundamental features with stratabound ore deposits. (3) It is similar to Precambrian iron formation in the enrichment of light REE.But, the degree to LREE is enriched in REE iron formation is noticed to increase with the increase of total REE eontent. Most REE iron formations are characterized hy the high ratios of ∑Ce/∑Y, Mg Fe/Ca, Na/K, Nb/Ta, Zr/Hf, Th/U, Ba/Sr, and etc. (4) The widespread occurrence of REE iron formation indicates a higher REE abundance in terrestrial crust of China and adds further support to the multistage theory regarding the chemical element evolution and differentiation in the terrestrial crust of China. (5) Preliminary data seem to support the time dependence of REE pattern and relative Eu content,  相似文献   

18.
This paper presents the general situation and key techniques of the drilling well M-1 in Matouying dry hot rock exploration hole, Leting, Tangshan, Hebei Province. A series of problems have been studied on the sea water drilling fluid, high temperature resistant fresh water drilling fluid, screw composite drilling technique, screw hole coring technology, and high temperature, thus solving the difficulty of sea water drilling fluid well protection, poor stability of drilling fluid under high temperature, and low efficiency in hot dry rock drilling and coring drilling to ensure the safety of the borehole and improve drilling efficiency. The high temperature resistant double condensation and double density cement slurry system and relevant technical measures are adopted to ensure the quality of cementing in the high temperature environment. Through the understanding and analysis of the strata in this area, this work provides valuable experience for drilling in the same strata in the future. The final hole depth of the M-1 well in Matouying is 4502. 11m, and hot dry rock with a temperature of 150t is found at 3965 m, which is the first hot dry rock well with a temperature of more than 150°C in the Beijing-Tianjin-Hebei region so far. © 2022 Editorial Board of Geology and Exploration. All rights reserved.  相似文献   

19.
The Naij Tal Group-complex is a suite of tectonic-sedimentary melange aggregation of the Eastern Kunlun orogenic belt, which is composed of two parts, i.e. the exotic blocks of various ages and the matrix strata. On the basis of coral, brachiopod and gastropod fossils found in the exotic blocks, the age of this group-complex was once defined to the Late Ordovician or the Paleozoic. This paper reports for the first time 44 genera and 31 species of Mid-Late Oligocene sporopollen in samples from the matrix strata in this group-complex and the Paleogene Quercoidites-Persicarioipollis assemblage is named. The paper aims to provide some detailed evidence for determining the age of the matrix strata in this group-complex based upon a study at the Caiyuanzigou section, which would be of great geological significance for further understanding this group-complex as a suite of tectonic-sedimentary melange aggregation. The new finding will certainly benefit from now on the investigation of formation and evolution mechanism for the Eastern Kunlun orogenic belt.  相似文献   

20.
The palynomorph assemblage of lake sediments younger than 51.9 kaBP from Wulagai Gobi in Inner Mongolia was analyzed to reconstruct the vegetation and climate.From 51.9 to 30.6kaBP,the vegetation was arid to semi-arid grassland with only slight changes.According to the palynomorphs,trees and shrubs were very rare.The large number and diversity of algae indicate the presence of a lake.Quantitative climatic conditions were reconstructed using the Best Analogues Method.The results indicate that the annual mean temperature was higher than that at present.The combination of temperature and annual precipitation suggests a change in the climate from cool dry to warm dry and then cool humid.Our results show that the annual precipitation values were mostly higher than that at present but were lower than 400 mm.It infers that the study area was already within the arid to semi-arid regions but with a stronger influence of the summer monsoon during 51.9to 30.6 kaBP than at present.With slight differences mainly in time scale,the changing trend of the annual temperature curve is consistent with the other climatic records from Antarctica,Greenland,Hulu Cave(East China),and the Tibetan Plateau during the last glacial period.From 30.6 kaBP to present,very few palynomorphs were detected in the samples.Hence,no information about the vegetation and climate could be extracted.Combined with other studies during Late Pleistocene,we presume that the reason for the lack of pollen during this period was caused by an abrupt temperature fall after 30.6 kaBP or that the lacustrine conditions were unsuitable for pollen deposition.It was probably incurred by the oxidation on land prior to deposition.But for those samples only with algae,it might be caused by the fact that algae could finish their life history in a very short time in a seasonal lake.  相似文献   

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