排序方式： 共有10条查询结果，搜索用时 15 毫秒
1
1.
2.
旱2井岩石抽提物中未成熟和成熟芳烃系列化合物组成分布的比较 总被引：2，自引：0，他引：2
Comparison has been made of the occurence of aromatic series in chloroform fraction between immature and mature sedimentary rocks from the Hang.2 well in Chaidamu Basin. According to the general formula CaH2n-p (p=6, 8, 10, ..., 20), the molecular ion distribution of 11 series have been studied by capillary gas chromatography and GC-MS. It has been found that the immature.mature evolution of aromatic homologous obeys the rules in thermodynamics and can be summaried as: (1) The alkyl side chains decrease and become shorter in compounds of each series. (2) Alkyl and cycloalkanes aromatics (1--3 ring) increase, but cycloalkanes aromatics with more (4-5) rings decrease. (3) Aromatization is observed in alkyl benzene, alkyl naphthalene and alkyl phe.nanthrene series. (4) The bimodal distribution of carbon number curve changes into unimodal distribution. It seems that the variation in aromatic homologous distribution can be used as a potential indicator of maturatlon or as fingerprints for source-rock correlation. 相似文献
3.
4.
原油似甲基二苯并噻吩含量与沉积环境及次生变化的关系 总被引：2，自引：0，他引：2
如果把芳烃TIC(总离子色谱图)上所有芳烃峰的峰面积之和作分母,以m/z198质量色谱图上三个甲基二苯并噻吩异构体峰面积之和作分子,计算出来的比值本文称为似甲基二苯并噻吩含量。它既是甲基二苯并噻吩化合物在原油中的丰度参数,也是苯并噻吩类化合物总和的含量参数。根据对中国含油气盆地112个原油样品中似甲基二苯并噻吩含量统计发现,当原油无TSR作用时,海相原油的似甲基二苯并噻吩含量要大于陆相原油;陆相原油中,盐湖相原油的似甲基二苯并噻吩含量又大于淡水湖相。当有TSR经历时,无论是海相或陆相原油,其似甲基二苯并噻吩含量都急剧增加,而且与伴生天然气中H2S的含量呈正相关。分析数据也表明,虽然原油的生物降解也可以使似甲基二苯并噻吩含量增加,但与TSR和烃源岩的沉积环境相比,生物降解的贡献可能并不大。似甲基二苯并噻吩含量可以作为沉积环境、TSR和原油的生物降解研究的地球化学参数。 相似文献
5.
用计算机进行生物标志化合物的地球化学研究，既可以节省科研人员的时间，又可以提高研究成果的水平。文中介绍了这一研究的流程、可行性讨论及今后改进的方向。 相似文献
6.
7.
随着色谱-质谱联用技术的引用,对原油及岩石抽提有机质开展了生物标志物的研究,使我们对陆相沉积岩中有机质的认识,深入到单烃化合物及其分子结构中了。这将使我们准确地鉴别出陆相沉积中特征有机化合物,对探讨石油起源、演化、运移等较复杂的地球化学问题,提供了可靠的信息,更好的为石油地质勘探服务。 相似文献
8.
沉积相是在特定环境条件下形成的地质体,沉积相的研究.在石油地质研究中占有重要地位。根据国内外油气勘探表明,油气的生成与分布.均与沉积相带有密切的关系[1]。我国陆相沉积盆地,与海相沉积盆地相比较,具有多物源,多沉积体系,相带多呈环状公布的特征。勘探实践及研究表明,沉积相带的分布与油气生成及聚集关系密切。 相似文献
9.
关于TM／TS指标的意义及应用 总被引：1，自引：0，他引：1
The TM/TS index as the ratio of two isomeric peaks of C27H46 trinurhopane in the m/e 191 fragmentogram is one of the important molecular parameters for petroIeum geochemistry, which has found xcide application in identifying the degree of maturation of organic matter in China. It has been observed that the TM/TS index not only depends on the burial depth and temperature with respect to terrestrial crude oils and source rocks(i.e., it decreases with increasing burial depth and temperature), but also on the type of organic matter and sedimentary facies. So the application of the index indicative of maturation of organic matter is conditional. 相似文献
10.
Microscopic and SEM observations of thin sections and kerogens and GC-MS analyses of aromatic fractions in sediment extracts and pyrolysis products of kerogens provide strong evidence suggesting that in the Lower Yangtze Valley area the Sinian and Lower Paleozoic carbonate formations of marine facies received no higher plant input,but there was produced abundant retene during diagenesis and abietic acid substances are still its precursors. 相似文献
1