共查询到19条相似文献，搜索用时 352 毫秒
1.
鱼耳石微化学特征在湖库水质评价中的标型意义——以河北白洋淀和北京密云水库野生鲤鱼为例 总被引：1，自引：0，他引：1
对河北白洋淀和北京密云水库的野生鲤鱼耳石和水体中的微量元素进行了定量分析。白洋淀鱼耳石中诸微量元素含量均高于密云水库的鱼耳石,反映了白洋淀各水体较密云水库水体的环境复杂,污染程度高。统计分析结果表明,在鱼耳石中大致存在两类生物地球化学习性不同的元素,水体中第一类元素的变化不会引起耳石中相应元素的响应,如Au、K和Na;第二类元素的变化会引起耳石中相应元素的强烈响应,如As、Ba、Co、Cr、Fe、Sr和Zn。诸微量元素在耳石中富集的强弱顺序为,Zn>Sr>Se>Fe>As>Ba>K>Co>Au>Na>Cr。通过相关性分析发现,白洋淀和密云水库的鱼耳石和水体中对应微量元素平均含量的自然对数值之间均存在良好的线性关系。 相似文献
2.
不同水域鲤鱼耳石微化学特征及其环境指示意义 总被引：6，自引：0，他引：6
利用中子活化分析对密云水库与白洋淀水域两个不同水域（无污染水域和重污染水域）中鲤鱼耳石的微量元素进行分析，发现白洋淀鲤鱼耳石中Sr、Zn、As、Au、Ba、K、Na的含量明显比密云水库鲤鱼耳石的相应元素含量高。采用线性判别方法对两地耳石中Sr、Zn、As、Ba4种元素进行分析，表明存在明显的分组差异，而且两地的差别主要在于Sr含量不同，其次是Zn、As和Ba；白洋淀鲤鱼耳石中As、Ba、Sr、Na等元素含量变化幅度比密云水库鲤鱼耳石中相应元素含量的变化幅度大，与白洋淀水域废水排放时间上的周期性和短暂性导致元素在耳石部分日轮上沉淀等因素相吻合。两地鲤鱼耳石微量元素特征存在截然的区别，与两地水域水体中微量元素差异相一致，表明鲤鱼耳石微化学特征具有水化学环境指示意义，为进一步研究利用鲤鱼耳石进行水化学环境监测或恢复鲤鱼生长期水环境特征奠定了基础。 相似文献
3.
将激光剥蚀等离子质谱技术(LA-ICP-MS)及显微X射线断层扫描技术(Micro-CT)运用到鲤鱼耳石对水环境中重金属元素的响应关系研究中. LA-ICP-MS结果表明白洋淀水域鲤鱼耳石中的Cu和Pb含量大于密云水库相应元素的含量;Micro-CT数据统计表明白洋淀水域鲤鱼耳石的Micro-CT值高于密云水库鲤鱼耳石的Micro-CT值.原子序数大的重金属元素Cu和Pb的富集程度是导致两研究区水域Micro-CT值差异的主要原因.耳石中的元素与水体元素具有相似的分布趋势,且对水体中的相应元素有明显富集作用.因此,鲤鱼耳石Micro-CT特征与水环境中重金属元素存在一定的耦合关系,可作为标型特征指示水体中重金属元素信息. 相似文献
4.
东营凹陷古近系中深层湖盆演化中的无机元素响应 总被引：2，自引：1，他引：1
为查明无机元素分布与水深、盐度等沉积环境以及湖盆演化过程的关系,采用电感耦合等离子体发射光谱仪分析对东营凹陷郝科1科探井古近系深层微量元素含量进行了测试、分析,所涉及的研究层位是该凹陷的主要烃源岩层段（沙河街组三亚段、沙河街组四亚段、孔店组）,分析结果表明:在水体浅、蒸发作用强烈的孔店组—沙四下亚段强氧化性滨浅湖环境里,钙、锶含量和Ca/Mg、Sr/Ba、Sr/Ca参数值具低值响应,铁、铝、钡、钒含量和（Fe+Al）/(Ca+Mg)参数值具高值响应;在沙四中亚段膏岩、盐岩等普遍发育的盐湖环境中,钠、锶含量和Sr/Ba、Fe/Mn、Sr/Ca均出现高值响应,锰、钡、钒含量和V/Ni、(Fe+Al)/(Ca+Mg)出现低值响应;在还原性的沙四上亚段半咸化深湖环境中,钾、钠、铁含量和Fe/Mn值具低值响应,钙、锰含量具高值响应;在沙四中亚段膏盐与泥岩共生体系中元素分布离散性明显,呈现波动性特征;Sr/Ba、Sr/Ca在盐湖环境中出现显著的高值响应,被证实可以作为良好的水体盐度指标参数,Fe/Mn、(Fe+Al)/(Ca+Mg)随水体加深逐渐增大,是良好的水体深浅指标参数。元素分布受沉积环境、岩性特征等多种地质因素的影响,在利用元素含量分布及特征元素比值来判断某单个地质因素的变化时,应该应用多种参数,进行综合判断。 相似文献
5.
沉积物元素地球化学特征是盆地沉积环境变化的响应。本文根据元素Ti、Mn、Li、Cr、Co、Ni、Cu、Zn、Ga、Cd、Ba、Pb、Sr、Rb、V的含量及Sr／Ba、Ni／Co、Ni／V、Cu／Zn、V／（V＋Ni）比值的变化规律，并结合有机地球化学特征，对抚顺盆地始新统计军屯组油页岩的沉积环境进行了分析。以Li、Ti为代表的外源元素，贫矿段的含量高于富矿段；而Sr、Ba等湖盆内化学沉积元素，富矿段的含量高于贫矿。Sr／Ba、V／（V＋Ni）、Ni／Co、Cu／Zn比值从贫矿段到富矿段呈现逐渐增大的趋势。富矿段有机质类型主要为Ⅰ型，而贫矿段主要为Ⅱ1、Ⅱ2。分析表明，本区油页岩富矿段形成于水体盐度较贫矿段高、还原性强的深湖环境，而贫矿段则形成于还原性较弱的半深湖一浅湖环境。 相似文献
6.
在不同盐度环境下，由于不同元素的溶解度和活性等化学性质不同，因此在水体及岩石中的含量变化也不相同。B、K、Ga、Ba、Li、Rb、Ni、Sr等对古盐度反应较敏感的微量元素常用于判断古盐度。本文搜集前人已报道的泥岩地球化学分析的原始数据建立数据库，运用层次聚类、神经网络进行分类及判断，利用Logistic回归对泥岩地球化学特征进行系统性分析，建立判断模型，并综合元素相关性系数及前人对于元素比值的研究，优选出Sr/Ba值作为判断指标。结果表明，本次建立的逻辑回归模型可较为有效地判断古盐度，并提出判别指标值：Sr/Ba<0.2指示淡水沉积环境，0.2≤Sr/Ba≤0.8指示半咸水环境，Sr/Ba>0.8为咸水沉积环境。综合来看，逻辑回归模型综合元素的指标多，更加全面、准确，而Sr/Ba比值法更加简练、明确。 相似文献
7.
宁南盆地古近纪沉积岩地球化学特征对沉积环境的反映 总被引：1，自引：0，他引：1
《地质科技情报》2016,(5)
沉积物元素地球化学特征是盆地沉积环境变化的响应。通过分析沉积岩的微量元素和稀土元素含量变化特征,研究了宁南盆地古近纪气候条件、古盐度和氧化还原环境。Cu、Cs质量分数变化以及Rb/Sr比值、Sr/Cu比值特征,揭示寺口子组沉积时期至少存在一期由潮湿-干旱转变的气候事件,从寺口子组沉积末期到清水营组沉积初期,古气候由干旱变为潮湿。Sr/Ba比值和B/Ga比值反映清水营组沉积水体盐度与寺口子组相差不大,仅在石峡口水库处古盐度值极大,其他地区略有减小。寺口子组沉积过程中,水体盐度有所增加。氧化还原指标V/Cr、Ni/Co、U/Th、V/(V+Ni)、δU、δCe、Ce/La和Ce_(anom)以及氧化还原敏感元素V、U、Ni、Zn和Cr的质量分数变化指示清水营组沉积时期水体氧含量整体小于寺口子组沉积时期。寺口子组沉积环境以氧化环境为主,清水营组沉积水体为氧-贫氧环境。 相似文献
8.
《矿产与地质》2020,(1)
通过对研究区寒武系底部黑色岩系中微量元素和稀土元素研究分析,认为研究区黑色岩系属于开阔盆地和大陆边缘之间靠近陆地区域的还原环境条件下形成的,黑色岩系为热水沉积成因;区内找钒矿的可能性更大,找钼、镍矿的可能性较小。在亲铁元素中,Co、Ni、Mo元素相对富集,Mo富集程度最大,浓集系数达378.82;在亲铜元素中,Zn、Sb元素较富集,Zn元素浓集系数在0.18～17.25之间,Sb元素浓集系数在3.36～69.11之间;在亲石元素中,Ba、W、U三个元素较富集,Ba元素浓集系数在1.90～28.07之间,W元素浓集系数在130.1～387.40之间,U元素浓集系数在5.91～74.11之间,W元素富集程度最高,其浓集系数最大值达387.40,具有深入研究的意义。 相似文献
9.
碱尘暴期间松嫩平原西部碱尘气溶胶的主要元素质量浓度排序为Na、Al、Fe、Ca、Mg、K、Ti、Ba、Zn,与当地盐碱化土壤的元素组成吻合,而与沙尘、城市气溶胶的元素组成有差别。风力对碱尘气溶胶元素组成有明显的影响,当风速在8.0~17.1 m/s时,元素组成的质量浓度排序为Na、Ca、Al、Fe、Mg、K、Ba、Ti、Zn。Na元素质量浓度的激增是碱尘暴元素组分的一大特征,明显富集元素为Na和B;相对于当地背景大气气溶胶的富集情况,Zn、Cu、Ba、B的富集因子值在碱尘暴期间明显降低;在各种天气情况下,B、Cu均具有较高的富集因子。碱尘中Ti元素的富集因子值均小于1,而Ca、Fe、K、Mg、Mn、Sr、V的富集因子值为1~4。两个采样点的Ca、Na、Al、Fe、Mg、Ti、Zn的富集因子近似,表明该区碱尘的主要元素具有特定的一致性;而B、Ba、Cu、V的富集因子相差较大,可以作为区分不同碱尘源的标志性元素。 相似文献
10.
兰州盆地位于青藏高原东北部,祁连山以东,黄土高原以西,古近纪出露地层为细柳沟组、野狐城组和咸水河组下段。作为青藏高原寒区、东部季风区及西北干旱区的交汇地带,兰州地区新生代环境研究受到越来越多的关注,因此有必要对其沉积环境进行研究。本文通过对兰州盆地黄羊头地区古近系进行分段采样,并对泥岩样品的主量元素、微量元素及X射线衍射进行测定,运用硼法、B/Ga值及Sr/Ba值等方法定量—半定量分析兰州盆地古近系沉积时的古盐度特征,同时结合风化指数CIA值的变化特征,综合分析古近系的沉积环境。研究结果表明兰州盆地古近系细柳沟组、野狐城组及咸水河组下段Adams法古盐度值为9.5‰～14.0‰,平均值为11.8‰;Couch法古盐度值为8.2‰～12.8‰,平均值为10.8‰,为内陆半咸水—淡水湖泊。Adams法古盐度值与B/Ga值具有良好的正相关关系,而Adams古盐度值与Sr/Ba值相关性不明显,主要由于地层中生物对Sr的富集作用,导致Sr/Ba值偏大,表明Sr/Ba值不适用于生物富集地层的古盐度恢复。环境研究认为细柳沟期,气候湿润,以冲积扇沉积为主,水体较浅,盐度值较大;到野狐城中期水体加深,变为湖相沉积,气候温暖湿润,盐度值降低,同时存在明显的干冷气候间隙,该间隙期湖盆蒸发量大于补给量,盐度值升高;从野狐城晚期开始湖盆逐渐萎缩,以滨湖相沉积为主,到韩家井期变为河流相沉积,至甘家滩期再次转为湖相沉积,盐度值先升高后降低,但整体风化程度明显降低,表明从野狐城组晚期开始气候逐渐变冷变干。 相似文献
11.
Many applications of otolith chemistry use the ratios of strontium (Sr) and barium (Ba) to calcium (Ca) as indicators of salinity exposure, because typically, as salinity increases, Sr concentration increases and Ba concentration decreases. However, these relationships are nonlinear, can be confounded by temperature, and investigations of salinity and temperature effects on otolith chemistry produce varied results. To determine the relationships of temperature and salinity on Sr:Ca and Ba:Ca in otoliths, we used free ranging Gulf Killifish (Fundulus grandis) in the northern Gulf of Mexico. This species is ideal because it is euryhaline and exhibits limited movements. Otolith edge Sr:Ca and Ba:Ca ratios were related to the previous 30-day mean salinity and temperature experienced by fish. The best model to describe otolith Sr:Ca was one that included a positive asymptotic relationship for both salinity and temperature. However, the salinity asymptotic maximum was reached at 10 psu and changes in otolith Sr:Ca above 10 psu were indicative of temperature changes. Otolith Ba:Ca exhibited an exponential decreasing relationship with salinity, and an exponential increasing relationship with temperature, and these two models combined best explained otolith Ba:Ca. Above 10 psu, the modeled Ba:Ca ratio continued to decrease demonstrating that this ratio may be indicative of salinity changes beyond this value. Therefore, using both Sr:Ca and Ba:Ca could be beneficial in reconstructing fish environmental histories. Temperature effects on otolith element ratios could confound past salinity reconstructions as well and must be a result of endogenous processes, given that no relationship between temperature and water chemistry existed. 相似文献
12.
Graham E. Forrester 《Estuaries and Coasts》2005,28(6):974-981
Site-specific variation in the trace element composition of fish otoliths can be used to identify fish to source, but the
mechanisms controlling elemental composition are poorly understood. Environmental influences on the deposition of barium (Ba),
copper (Cu), manganese (Mn), and strontium (Sr) in the otoliths of mudsuckers (Gillichthys mirabilis) were tested using a reciprocal field transplant experiment, in which fish from 3 estuaries were transplanted to each of
the 3 estuaries. Fish originating from the 3 estuaries showed no differences in otolith chemistry that might reflect acclimation
to past conditions in their home estuary or genetic differences among populations, which simplifies the interpretation of
otolith chemistry. Cu and Mn concentrations in otoliths differed according to the site of transplant. Cu in otoliths showed
the same pattern of difference among estuaries as did Cu in sediments, but there was no correspondence between Cu in otoliths
and dissolved Cu. Ranked differences among estuaries in otolith Mn matched the ranking of estuary-specific differences in
dissolved Mn, and there was no correspondence between the concentration of Mn in otoliths and sediments. Fish transplanted
to different estuaries showed no differences in otolith concentrations of Ba or Sr, and the concentrations of Ba and Sr in
the water column showed a similar lack of difference among estuaries. This study provides field evidence supporting the conclusion
that the elemental composition of otoliths reflects environmental conditions to which fish have been recently exposed, but
whether that correlation is with trace elements in the sediment or water column can vary. 相似文献
13.
We tested the hypothesis that strontium:calcium (Sr:Ca) in otoliths are reflective of environmental salinity experienced by
two estuarine fishes during early life. Laboratory and field experiments were performed to examine the effects of salinity
and temperature on Sr:Ca in otoliths of black drum (Pogonias cromis) and red drum (Sciaenops ocellatus). Otolith Sr:Ca of juveniles reared at four salinities (5‰, 15‰, 25‰, 35‰) differed significantly forP. cromis while no salinity effect was observed forS. ocellatus. Otolith Sr:Ca of both species were not affected by temperature (23°C and 30°C), suggesting that partitioning of Sr in otoliths
of these taxa is constant over the temperature range examined. A field verification trial was conducted forP. cromis and a positive relationship between otolith Sr:Ca and ambient salinity was observed, even though the percent variability
explained was modest. A series of Sr:Ca point measurements were taken from the core to the edge of the otoliths of wildP. cromis andS. ocellatus, and otolith Sr:Ca chronologies of both species showed conspicuous declines during the first few months of life. While Sr:Ca
chronologies of both species suggest that ingress is associated with a reduction in otolith Sr:Ca, inconsistencies in laboratory
and field experiments intimate that Sr uptake in the otolith may be insensitive to salinity and regulated by other factors
(aqueous chemistry, ontogenetic shifts in habitat, or physiology). Results from early life history transects of otolith Sr:Ca
conform to expected patterns of estuarine ingress-egress during early life and indicate that the approach may be useful for
detecting large-scale habitat transitions (marine to estuarine habitats). 相似文献
14.
Jon N Weber 《Geochimica et cosmochimica acta》1973,37(9):2173-2190
Two thousand and twenty well-characterized coral specimens from 17 localities have been analyzed for Sr. Seventy-three genera and subgenera, mostly hermatypic scleractinians, are represented. For some genera, specimens living in surface reef environments are compared with those from 18.3 m depths on the same reefs. Growth rates for some species have also been measured at these depths at one of the sampling sites. Skeletal strontium for a given genus decreases with increasing water temperature, a relationship which previously eluded detection. Aragonite deposited by corals living on the reef at a depth of 18.3 m contains more strontium than the skeletal aragonite of the same coral genera from shallow-water, surface environments. Quantitative treatment of the data for Acropora, one of the most abundant and widely distributed of the reef-building corals, suggests that the observed strontium variations may reflect variations in the rate of skeletal calcification, rather than direct dependence upon temperature or water depth. There is evidence for ‘species effects’, apparently unrelated to growth rate differences, in that certain coral genera are consistently enriched or depleted in skeletal strontium content relative to other genera living in the same reef environments under identical ambient conditions. Temperature, salinity, water depth, seawater composition, and/or other such parameters may in part determine the levels of trace element concentration in carbonates deposited by corals and other marine invertebrates, but it would appear that these variables more directly affect physiological processes which in turn control skeletal chemistry. 相似文献
15.
针对塔北上寒武统下丘里塔格群复杂的白云石化作用,通过岩石学和地球化学分析认为下丘里塔格群埋藏后主要经历3期白云石化流体作用：早期浅埋藏环境下高浓度卤水在台缘带的迁移促进了渗透回流白云石化作用发生,形成残余颗粒幻影结构的粉晶白云岩,具有碳氧同位素负偏和微量元素Fe、Mn、Sr、Ba元素质量分数较低的特征;第二期流体主要为地层孔隙残余高盐度海水,在埋藏压实作用下白云岩发生重结晶作用,晶粒结构广泛发育,具有同位素碳正氧负和微量元素呈现富Mn贫Fe及低Sr高Ba的特征,该时期是晶间孔和晶间溶孔发育的主要时期;第三期流体主要为沿基底断裂上涌的高温富镁热液流体,发育构造-热液白云石化作用形成大量鞍状白云石,具有富Mn贫Fe和氧同位素负偏明显等特征。 相似文献
16.
Rubidium and strontium partitioning experiments between haplogranitic melts and aqueous fluids (water or 1.16-3.56 m (NaCl + KCl) ± HCl) were conducted at 750-950 °C and 0.2-1.4 GPa to investigate the effects of melt and fluid composition, pressure, and temperature. In addition, we studied if the applied technique (rapid and slow quench, and in-situ determination of trace element concentration in the fluid) has a bearing on the obtained data. There is good agreement of the data from different techniques for chloridic solutions, whereas back reactions between fluid and melt upon cooling have a significant effect on results from the experiments with water.The Rb fluid-melt partition coefficient shows no recognizable dependence on melt composition and temperature.For chloridic solutions, it is ∼0.4, independent of pressure. In experiments with water, it is one to two orders of magnitude lower and increases with pressure. The strontium fluid-melt partition coefficient does not depend on temperature. It increases slightly with pressure in Cl free experiments. In chloridic fluids, there is a sharp increase in the Sr partition coefficient with the alumina saturation index (ASI) from 0.003 at an ASI of 0.8 to a maximum of 0.3 at an ASI of 1.05. At higher ASI, it decreases slightly to 0.2 at an ASI of 1.6. It is one to two orders of magnitude higher in chloridic fluids compared to those found in H2O experiments. The Rb/Sr ratio in non-chloridic solutions in equilibrium with metaluminous melts increases with pressure, whereas the Rb/Sr ratio in chloridic fluids is independent of pressure and decreases with fluid salinity.The obtained fluid-melt partition coefficients are in good agreement with data from natural cogenetic fluid and melt inclusions. Numerical modeling shows that although the Rb/Sr ratio in the residual melt is particularly sensitive to the degree of fractional crystallization, exsolution of a fluid phase, and associated fluid-melt partitioning is not a significant factor controlling Rb and Sr concentrations in the residual melt during crystallization of most granitoids. 相似文献
17.
M. Ichikuni 《Chemical Geology》1973,12(4):315-317
The partition coefficient of strontium between calcite and solution is increased by the presence of a small amount of manganese substituting for calcium in calcite. Divalent cations in calcite, if smaller in size than the calcium ion, may behave quite similarly toward the incorporation of strontium into calcite. 相似文献
18.
Pb、Sr和REE在矿物中的扩散补偿关系及其对扩散系数的预测 总被引：4，自引：2，他引：4
对现有实验扩散数据的检查发现，不仅Pb、Sr和REE元素在不同矿物中存在着扩散补偿关系，不同元素在同一矿物或同族矿物中也满足扩散补偿关系。阴离子孔隙度作为矿物内部离子堆积密度的一种量度，它与Pb和REE扩散活化能之间存在负的线性相关性，在固定温度下与Sr扩散系数（lnDT)之间呈正的线性相关，因而可以用于预测元素在矿物中的扩散系数。本文分别采用离子孔隙度法和双补偿法预测了Pb、Sr和REE在不同矿物中的扩散系数，这些结果与已有的实验数据在实验误差范围内是一致的，因此可以应用到与扩散有关的地球化学动力学研究中。 相似文献
19.
X射线断层扫描技术在鲤鱼耳石对环境响应研究中的应用初探 总被引：1，自引：1，他引：0
作为生命矿物文石和球文石的载体,鱼耳石(fish otoliths)记载了鱼体生长过程中大量的环境信息。近30年来,其研究取得了很多成果,但利用医学技术的研究尚未见报道。文中尝试应用医学X射线断层扫描技术(CT)对取自河北白洋淀和北京密云水库的野生鲤鱼耳石进行分析研究。结果表明:白洋淀鲤鱼的星耳石和微耳石CT值均大于密云水库鲤鱼耳石相应的CT值,与白洋淀水体中的重金属元素含量明显高于密云水库水体中的重金属含量存在较好的相关性;同一水域星耳石与微耳石的CT值也存在明显差异,分析认为这种差异可能与元素的亲和性及占位方式有关。 相似文献