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1.
 Nd, Sr and O isotope systematics were used to investigate the petrogenesis of two adjacent plutons of the Bethlehem Gneiss (BG) and the Kinsman Quartz Monzonite (KQM), exposed within the Central Maine Terrane (CMT) of New England. Both are Acadian-aged (≈413 Ma) synmetamorphic and syntectonic members of the New Hampshire Plutonic Series (NHPS). Potential source rocks analyzed for this study include Silurian and Devonian metasedimentary rocks of the CMT, and Ordovician metasedimentary rocks and granitic gneisses of the Bronson Hill Anticlinorium (BHA), which border the CMT to the west. The ɛSr(413),  ɛNd(413) and δ18O values for the KQM range from 56.3 to 120.0, 2.8 to −6.4, and 7.6‰ to 12.9‰, respectively; values for the BG range from 7.4 to 144.7, 0.6 to −9.3, and 8.3‰ to 11.3‰, respectively; and values for possible source rocks range from 38.1 to 654.2, −10.7 to 5.4, and 6.2‰ to 14.1‰, respectively. Both the BG and KQM have extremely heterogeneous initial isotopic compositions consistent with mixing of multiple crustal source rocks, and neither contains a volumetrically significant (i.e., ≥10%) mantlederived component. Overlapping values of ɛNd(413),  ɛSr(413) and δ18O values for both the BG and KQM samples resemble values for metasedimentary host rocks of the CMT and BHA. We observe no systematic correlations between ɛNd and ɛSr values for either the BG or the KQM. The ɛSr and δ18O values for the BG do not form any simple mixing trends, nor is there any direct correlation between the isotopic compositions of contact BG samples and their adjacent host rocks, in contrast to our observations for the KQM (Lathrop et al. 1994). We propose that the KQM and BG magmas were generated through anatexis of metasedimentary rocks from both the BHA and CMT in response to crystal thickening during the Acadian orogeny. Melting may have been initiated within CMT metasediments in response to high heat production in these mid-crustal rocks combined with crustal thickening, whereas melting of BHA rocks with normal crustal heat production, which were located at lower-crustal levels than CMT rocks, is likely to have been driven by crustal thickening alone. Following upward advection of mobile BHA magmas, BHA- and CMT-derived magmas may have mingled during complex Acadian deformation in the CMT, thus accounting for the isotopic similarities we observe between the BG and the KQM. Received: 13 September 1994/Accepted: 31 January 1996  相似文献   

2.
Abstract The Lajimiao norite-gabbro complex, as a part of the ophiolites on the southern side of the North Qinling belt, consists of gabbro and norite-gabbro. They were derived from different magma series: the gabbro was derived from tholeiitic magma series with higher TiO2, REE abundance and Fe3+ / Fe2+ ratio; norite-gabbro was derived from calc-alkali magma series with lower TiO2, Fe3+ / Fe2+ ratio and REE abundance and much lower HREE abundance, which suggests that the source of the norite-gabbro magma was deeper and controlled by eclogite facies. Geochemical characteristics of both plutonic rocks are similar to those of island-arc basalts, such as relatively high contents of Ba, Pb and Sr and relatively low contents of Nb, Zr and Ni. The Sr, Nd isotopic characteristics of the Lajimiao norite-gabbro complex are similar to those of ophiolites. Its 8Nd values are constant, about +2; whereas 8Sr values have wide variation from — 6.4 to +31.2 and positively correlate with Na2O, H2O+ and CO2 contents and the Fe3+ / Fe2+ ratio. The ?Nd—Nd / Th, ?Nd—La/Nb and ?Nd—Ba/Nb diagrams clearly show that there were significant components of terrigenous sediments in the mantle source of the Lajimiao norite-gabbro complex. It suggests that large amount of sediments had been carried into the mantle by the subducted ancient Qinling sea plate during the Palaeozoic.  相似文献   

3.
The North Lhasa terrane in Tibet is generally interpreted to be paleotectonically unrelated to the East African Orogen (EAO) and is instead thought to have derived from northeastern India or northwestern Australia. In this study, we present petrogenetic and geochronological results pertaining to the analysis of gabbros (ca. 652 Ma), diorites (ca. 658 and 646 Ma), and tonalites (ca. 652 Ma) from the North Lhasa terrane. The gabbros are calc-alkaline and exhibit arc-like geochemical features. Low positive zircon εHf(t) values (+1.0 to +3.8), high zircon δ18O (6.25‰ to 7.94‰), and low negative whole-rock εNd(t) values (−3.5 to −1.4) indicate that the gabbros were derived from the lithospheric mantle, with geochemical modification by a subduction component. The diorite suite is characterized by a wide range of whole-rock chemistries (e.g., SiO2 = 51.33–61.98 wt%) and Hf–O–Sr isotopic compositions (εHf(t) = −10.8 to −0.1; δ18O = 5.17‰ to 7.11‰; ISr = 0.706 to 0.710), and negative whole-rock εNd(t) values (−7.0 to −4.7). These diorites are geochemically similar to OIB and are interpreted to be products of the partial melting of a relatively deep mantle source (>85 km) prior to extensive modification by continental crustal material. The tonalites are adakitic and have moderate Mg# values (47–54), low compatible element abundances, positive zircon εHf(t) values (+3.4 to +6.2), high ISr values (0.714 to 0.715), and small negative whole-rock εNd(t) values (−1.6 to −0.4). These tonalites most likely formed by the melting of thickened Mesoproterozoic continental crust. The generation of these ca. 650 Ma magmatic rocks was related to slab break-off in a collision zone. By integrating the findings of previous studies with the data of the present study, we suggest that the North Lhasa terrane was most likely located in the northern segment of the EAO in paleotectonic reconstructions of the Gondwana supercontinent.  相似文献   

4.
Isotopic and mineralogic data from an 8500-m thick section of the Great Valley sequence, northern California, indicate that changes in the δ18O values of authigenic minerals resulted from the conversion of smectite to a 10 Å clay-mineral as temperature increased with burial in the Jurassic- Cretaceous outer-arc basin. The clay-mineral assemblage in mudstone is characterized by a proportional increase of the 10 Å clay-mineral with increasing stratigraphic depth, and by a depletion in the δ18O value of the mixed-layer smectite/10 Å clay-mineral with descending stratigraphic position from +21.9 to + 15.5%. SMOW. Modeling of the oxygen isotopic data from authigenic phases, based on equilibrium fractionation during clay-mineral diagenesis, indicates that δ18O values of calcite in mudstones and of calcite cements in sandstone precipitated along a temperature gradient of about 25°C/km during maximum burial to about 6–7 km. δD values of the mixed-layer smectite/10 Å clay-mineral range between ?69 to ?44%. SMOW. Using temperatures calculated from the oxygen isotopic data, the deuterium and oxygen isotopic data indicate that the smectite underwent late-stage dehydration and probably buffered the composition of formation waters from sea water values to isotopic compositions of δ18O ≈ +8%. SMOW and δD ≈ ?25%. SMOW. The δ13C values of calcite from mudstone and sandstone imply that crystallization of authigenic calcite was linked to organic diagenesis during which dissolved HCOt-3 was continuously enriched in 13C as temperature increased with burial. At the base of the sequence and immediately overlying the ophiolitic basement rocks, several hundred meters of strata were altered by more oxygen-depleted (δ18O ? +4 to +5%.) hydrothermal fluids emanating from the ophiolitic rocks, probably at maximum burial depth.  相似文献   

5.
In the present work we studied Mg-ilmenite megacrysts from the Arkhangelsk kimberlites (the Kepino kimberlite field and mantle xenoliths from the Grib pipe). On the basis of isotopic (Rb/Sr, Sm/Nd, δ18O) and trace-element data we argue that studied Mg-ilmenite megacrysts have a genetic relation to the “protokimberlitic” magma, which was parental to the host kimberlites. Rb-Sr ages measured on phlogopite from ilmenite-clinopyroxenite xenoliths and the host Grib kimberlite overlap within the error (384 Ma and 372 ± 8 Ma, respectively; Shevchenko et al., 2004) with our estimation of the Kotuga kimberlite emplacement (378 ± 25 Ma). Sr and Nd isotopic compositions of megacrysts are close to the isotopic composition of host kimberlites (Mg-ilmenites from kimberlites have 87Sr/86Sr(t = 384) = 0.7050–0.7063, ?Nd(t = 384) = + 1.7, +1.8, ilmenite from ilmenite-garnet clinopyroxenite xenolith has 87Sr/86St(t = 384) = 0.7049, ?Nd(t = 384) = +3.5). Oxygen isotopic composition of ilmenites (δ18O = +3.8–+4.5‰) is relatively “light” in comparison with the values for mantle minerals (δ18O = +5–+6‰). Taking into account ilmenite-melt isotope fractionation, these values of δ18O indicate that ilmenites could crystallize from the “protokimberlitic” melt. Temperatures and redox conditions during the formation of ilmenite reaction rims were estimated using ilmenite-rutile and titanomagnetite-ilmenite thermo-oxybarometers. New minerals within the rims crystallized at increasing oxygen fugacity and decreasing temperature. Spinels precipitated during the interaction of ilmenite with kimberlitic melt at T = 1000–1100°C and oxygen fugacity $\Delta \log f_{O_2 }$ [QFM] ≈ 1. Rims comprised with rutile and titanomagnetite crystallized at T ≈ 1100°C, $\Delta \log f_{O_2 }$ [NNO] ≈ 4 and T = 600–613°C, $\Delta \log f_{O_2 }$ [QFM] ≈ 3.7, respectively. Rutile lamellae within ilmenite grains from clinopyroxenitic xenolith were formed T ≥ 1000–1100°C and oxygen fugacity $\Delta \log f_{O_2 }$ [NNO] = ?3.7. Since the pressure of clinopyroxene formation from this xenolith was estimated to be 45–53 kbar, redox conditions at 135–212 km depths could be close to $\Delta \log f_{O_2 }$ [NNO] = ?3.7.  相似文献   

6.
The Fuchuan ophiolite suite in Shexian County, Anhui Province, was formed in the Middle-Late Proterozoic. It is characterized by varying Nd [∈Nd (T) =0.7−3.8], Sr [∈Sr(T) = 30.7−53.9] and O(δ18O=3.2−11.0%.) and low ratios of Nd/La (<0.8), Ti/Y (<350) and Ti/V (<30). These characteristics, in combination with geological features, indicate that the ophiolite suite was formed in the axial part of the back-arc basin of the Jiangnan ancient island arc at the southeastern margin of the Yangtze Plate. The varying ∈Nd (T) was caused by the contamination of the underlying inmature sialic crust during the formation of the ophiolite and variations in ∈Sr(T) and δ18 O may have resulted from hydrothermal alteration by seawater during or shortly after its formation.  相似文献   

7.
The geochemistry and environment of formation of the Precambrian Fuchuan ophiolite, situated in the eastern part of the southern margin of the Yangtze block in southern Anhui province, China, are discussed. The serpentinized peridotites have high Mg# (94–95) and low CaO and Al2O3 contents, high Cr# (100?Cr/(Cr + Al)) spinels, and LREE-enriched patterns. The pyroxenites and gabbros exhibit flat to LREE-depleted patterns and positive εNd(T) (+2.1 to +2.6). The spilites have LREE-enriched patterns [(La/Yb)N = 1.5-3.7], positive εNd(T) (+3.2), negative Eu anomalies [(Eu/Eu?)N = 0.71-0.87], and low ratios of Nb/La(<0.8), Ti/Y (<350), and Ti/V (<30). Both diorites and keratophyres have LREE-enriched patterns and negative Eu anomalies. Seawater alteration is suggested by: (1) negative Ce anomalies exhibited by all samples, (2) large variations in δ18O, and (3) a horizontal trajectory to the higher εSr values in the εNd(T)-εSr (T) diagram. The geochemical data for the Fuchuan ophiolite are consistent with formation in an arc-related setting, where fluids derived from a subducting slab induced further melting in an overlying lherzolite source.  相似文献   

8.
Newly obtained data on Pb isotopic ratios in feldspars from Early Proterozoic granitoids of the Sangilen block of the Tuva-Mongolian microcontinent and Caledonian structures surrounding it, considered together with earlier data on the O and Nd isotopic systems, indicate that ancient (approximately 2 Ga) crustal material mixed in the sources of granites of the Tuva-Mongolian microcontinent with younger juvenile material. Positive ɛNd values of granitoids from the Bashkimugor and Chgargalant massifs are accounted for by processes of crustal contamination during the interaction of the melt with crustal material. Similar Nd isotopic characteristics of granitoids in the Khoromnug pluton were caused by the melting of the Late Riphean crust. In granitoids of the massifs in the Kaakhem and Eastern Tannuola zones of the surrounding Caledonian structures, the involvement of juvenile material from oceanic crust increases away from the Sangilen block. Granites in the junction zone between the Tuva-Mongolian microcontinent and surrounding structures display evidence of the presence (up to 10–20%) of an ancient crustal component, and the melting history of granitoids in the Eastern Tannuola zone is dominated by an Early Paleozoic juvenile component in combination with material similar to the Vendian ophiolites of the Agardag-Erzin zone. An increase in the δ18O value, the 206Pb/204Pb ratio, and the TNd(DM) values within a single complex (from older to younger granitoid phases) is explained by the systematic involvement of crustal material in the melting processes.  相似文献   

9.
This paper presents a study of the petrography, mineral chemistry, geochemistry, and Sr–Nd–Pb–C–O isotope systematics of carbonatite dykes and associated rocks from the northeastern part of the Song Da intracontinental rift in South Nam Xe (northwest Vietnam) aimed at constraining the origin of the carbonatite magmas. The carbonatites are characterized by SiO2 < 12.18 wt.% and by wide ranges in FeO, MgO and CaO content that define them as calciocarbonatite and ferrocarbonatite. On U–Th–Pb isochron diagrams, whole rocks and mineral separates from the ferrocarbonatites form linear arrays corresponding to ages of 30.2–31.6 Ma (Rupelian, Oligocene). The South Nam Xe carbonatites are extremely enriched in Sr, Ba, and light rare earth elements (LREE), and depleted in high field strength elements (HFSE) (e.g. Ti, Nb, Ta, Zr and Hf). The age–corrected Sr–Nd–Pb isotope ratios and C isotope data are relatively uniform (87Sr/86Sr(t) = 0.708193–0.708349; 143Nd/144Nd(t) = 0.512250–0.512267; εNd(t) = ?6.46 to ?6.80; 206Pb/204Pb(t) = 18.26–18.79; 207Pb/204Pb(t) = 15.62–15.64; 208Pb/204Pb(t) = 38.80–39.38; δ13CV-PDB = –2.7?‰ to ?4.1?‰). These isotopic compositions indicate source contamination that occurred before the production of the carbonatite magmas, and did not change noticeably during or after emplacement. The variation in oxygen isotopes is consistent with the change in mineral compositions and trace element abundances: the lower δ18O values (9.1–11.0?‰) coupled with Sr-rich, Mn-poor calcite, and igneous textures such as triple junctions among calcite grain boundaries, define a magmatic origin. However, the elevated δ18O values of the ferrocarbonatites (12.0–13.3?‰) coupled with a volatile-bearing mineral assemblages (including REE fluorcarbonates, sulfates, sulfides and fluorite) may be due to interaction with meteoric water during low-temperature alteration. High δ13C values and Sr–Pb ratios, and low Rb/Sr (0.00014–0.00301), Sm/Nd (0.089–0.141) and 143Nd/144Nd ratios, coupled with very high Sr-Nd concentrations, suggest the involvement of an enriched mantle component, which probably resulted from metasomatism due to the migration of subducted material. Because of the lack of tectonic data and the limited number of samples studied, this conclusion is still ambiguous and requires further study.  相似文献   

10.
ABSTRACT

The Eastern Pontides orogenic belt in NE Turkey hosts numerous I-type plutons of Eocene epoch. Here, we report new U–Pb SHRIMP zircon ages and in situ zircon Lu-Hf isotopes along with bulk-rock geochemical and Sr-Nd-Pb-O isotope data from the Kemerlikda??, Ayd?ntepe and Pelitli plutons and mafic microgranular enclaves (MMEs) to constrain their parental melt source(s) and evolutionary processes. U-Pb SHRIMP zircon dating yielded crystallization ages between 45 and 44 Ma for the studied plutons and their MMEs. The plutons range from gabbro to granite and have I-type, medium to high-K calc-alkaline, and metaluminous to slightly peraluminous characteristics. On the primitive mantle-normalized multi-trace-element variations, the plutons and their MMEs are characterized by signi?cant enrichment in LILE/HFSE. Chondrite-normalized REE patterns of the plutons and their MMEs are close to each other and show moderate enrichment with variable negative Eu anomalies. The studied plutons have fairly homogeneous isotope composition (87Sr/86Sr(i) = 0.70502 to 0.70560; εNd(i) = +0.9 to – 1.4; δ18O = +5.0 to +8.7‰, εHf(i) = – 2.2 to +13.5). The MMEs show medium to high-K calc-alkaline and metaluminous character. Although the isotope signatures of the MMEs (87Sr/86Sr(i) = 0.70508 to 0.70542; εNd(i) = +0.9 to ?1.1; δ18O = +5.8 to +8.0, εHf(i) = +4.3 to +10.4) are very similar to those of the host rocks. Fractionation of plagioclase, amphibole, pyroxene and Fe-Ti oxides played an important role in the evolution of the plutons. The isotopic composition of the studied plutons and MMEs are similar to I-type plutons derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. The parental magma(s) of the studied plutons were generated from the enriched lithospheric mantle and then modified by fractional crystallisation, and lesser assimilation and mixing/mingling in the crustal magma chambers.  相似文献   

11.
The In Ouzzal granulitic unit (IOGU) consists predominantly of felsic orthogneisses most of which correspond to granitoids emplaced during the Archaean, plus metasediments, including olivine-spinel marbles, of late Archaean age. All units were metamorphosed at granulite facies during the Eburnean (2 Ga). The stable isotope signature of the marbles (δ13C=–0.8 to –4.2‰/PDB; δ18O = 7.9 to 18.9‰/SMOW) does not record a massive streaming of C-bearing fluids during metamorphism. Most of the isotopic variation in the marbles is explained in terms of pregranulitic features. Metasomatic transformation of granulites into layered potassic syenitic rocks and emplacement of carbonate veins and breccias occurred during retrogressive granulite facies conditions. The chemistry of these rocks is comparable with that of fenites and carbonatites with high contents of (L)REEs, Th, U, F, C, Ba and Sr but, with respect to these elements, a relative depletion in Nb, Ta, Hf, Zr and Ti. The isotopic compositions of Nd (?Nd(T)=–6.3 to –9.9), of Sr (87Sr/86Sr(T)= 0.7093–0.7104), and the O isotopic composition of metasomatic clinopyroxene (δ18O = 6.9 to 8‰), all indicate that the fluid had a strong crustal imprint. On the basis of the C isotope ratios (δ13C =–3.5 to –9.7‰), the fluid responsible for the crystallization of carbonates and metasomatic alteration is thought to be derived from the mantle, presumably through degassing of mantle-derived magmas at depth. Intense interaction with the crust during the upward flow of the fluid may explain its chemical and isotopic signatures. The zones of metasomatic alteration in the In Ouzzal granulites may be the deep-seated equivalents of the zones of channelled circulation of carbonated fluids described at shallower levels in the crust.  相似文献   

12.
We present new data on the U-Pb age of zircons, geochemistry of trace elements, and isotope (Nd, Sr, O) composition of rocks of the Kogtakh gabbro-monzonite complex on the eastern slope of the Kuznetsk Alatau Ridge. The established age of zircon in the rocks of the main intrusive phases (500-480 Ma) is taken as the time of formation of the Kogtakh complex in the Late Cambrian-Early Ordovician, during the accretion-collision stage of evolution of the Central Asian Orogenic Belt. The distribution and ratios of LILE and HFSE in the rocks suggest that the intrusions proceeded under interaction of the PREMA + EM/OIB mantle plume and the suprasubductional lithospheric IAB mantle. The mantle-crust interaction led to the heterogeneous isotopic composition of neodymium in the magma source (?Nd(T) ~ 3.5-5.4). The mixing of different mantle and continental-crust materials resulted in an increase in isotope parameters: (87Sr/86Sr)T ~ 0.7039-0.7052, ?Sr(T) ~ 0-19, and δ18O ~ 6.5-8.8‰ (SMOW). The REE ratio in the least differentiated gabbroids indicates different depths of probable magma chambers and the formation of their primary (Tb/YbPM > 1.8) mafic melts at different degrees of melting of the model garnet peridotite.  相似文献   

13.
We present the results of a study on gabbroic rocks, syenites, pegmatites, carbonatites, and hydrothermal products of the Oshurkovo apatite-bearing massif. The results include Nd and Sr isotope ratios; the isotope compositions of carbon and oxygen in calcite; oxygen in apatite, magnetite, and silicate minerals (phlogopite, titanite, diopside, amphibole, K-feldspar, and quartz); sulfur in barite; and hydrogen in mica. The isotopic data are close to the EM-1 enriched mantle values and confirm a comagmatic relationship between the gabbros and carbonatites. The binary plot ?Nd vs. 87Sr/86Sr demonstrates strong differentiation between silicate rocks and carbonatites, as is the case with the other Late Mesozoic carbonatite occurrences of southwestern Transbaikalia. The oxygen isotope composition of all comagmatic phases also falls within the range of mantle values. A clear trend toward heavier oxygen and lighter carbon isotope compositions is observed in all successively emplaced phases, which is consistent with a trend defined by hydrothermal products formed under the influence of the parent magma chamber. Carbonates formed during the greenstone alteration of gabbroic rocks are enriched in the light oxygen isotope (δ18O from ?2.8 to ?7.3‰), suggesting a contribution of vadose water.  相似文献   

14.
Peralkaline syenite and granite dykes cut the Straumsvola nepheline syenite pluton in Western Dronning Maud Land, Antarctica. The average peralkalinity index (PI?=?molecular Al/[Na?+?K]) of the dykes is 1.20 (n?=?29) and manifests itself in the presence of the Zr silicates eudialyte, dalyite and vlasovite, and the Na–Ti silicate, narsarsukite. The dykes appear to have intruded during slow cooling of the nepheline syenite pluton, and the petrogenetic relationship of the dykes and the pluton cannot be related to closed-system processes at low pressure, given the thermal divide that exists between silica-undersaturated and oversaturated magmas. Major and trace element variations in the dykes are consistent with a combination of fractional crystallization of parental peralkaline magma of quartz trachyte composition, and internal mineral segregation prior to final solidification. The distribution of accessory minerals is consistent with late-stage crystallization of isolated melt pockets. The dykes give an Rb–Sr isochron age of 171?±?4.4 Ma, with variable initial 87Sr/86Sr ratio (0.7075?±?0.0032), and have an average ε Nd of ? 12.0. Quartz phenocrysts have δ18O values of 8.4–9.2‰, which are generally in O-isotope equilibrium with bulk rock. Differences in the δ18O values of quartz and aegirine (average Δquartz?aegirine = 3.5‰) suggest aegirine formation temperatures around 500 °C, lower than expected for a felsic magma, but consistent with poikilitic aegirine that indicates subsolidus growth. The negative ε Nd (< ? 10) and magma δ18O values averaging 8.6‰ (assuming Δquartz?magma = 0.6‰) are inconsistent with a magma produced by closed-system fractional crystallization of a mantle-derived magma. By contrast, the nepheline syenite magma had mantle-like δ18O values and much less negative ε Nd (average ??3.1, n?=?3). The country rock has similar δ18O values to the granite dykes (average 8.0‰, n?=?108); this means that models for the petrogenesis of the granites by assimilation are unfeasible, unless an unexposed high-δ18O contaminant is invoked. Instead, it is proposed that the peralkaline syenite and granite dykes formed by partial melting of alkali-metasomatised gneiss that surrounds the nepheline syenite, followed by fractional crystallization.  相似文献   

15.
The western Kunlun orogen occupies a key position along the tectonic junction between the Pan-Asian and Tethyan domains, reflecting Proto- and Palaeo-Tethys subduction and terrane collision during early Palaeozoic to early Mesozoic time. We present the first detailed zircon U–Pb chronology, major and trace element, and Sr–Nd–O–Hf isotope geochemistry of the Qiukesu pluton and its microgranular enclaves from this multiple orogenic belt. SHRIMP zircon U–Pb dating shows that the Qiukesu pluton was emplaced in the early Silurian (ca. 435 Ma). It consists of weakly peraluminous high-K calc-alkaline monzogranite and syenogranite, with initial 87Sr/86Sr ratios of 0.7131–0.7229, ?Nd(T) of –4.1 to –5.7, δ18O of 8.0–10.8‰, and ?Hf(T) (in situ zircon) of –4.9. Elemental and isotopic data suggest that the granites formed by partial melting of lower-crustal granulitized metasedimentary-igneous Precambrian basement triggered by underplating of coeval mantle-derived enclave-forming intermediate magmas. Fractional crystallization of these purely crustal melts may explain the more felsic end-member granitic rocks, whereas such crustal melts plus additional input from coeval enclave-forming intermediate magma could account for the less felsic granites. The enclaves are intermediate (SiO2 57.6–62.2 wt.%) with high K2O (1.8–3.6 wt.%). They have initial 87Sr/86Sr ratios of 0.7132–0.7226, ?Nd(T) of –5.0 to –6.0, δ18O of 6.9–9.9‰, and ?Hf(T) (in situ zircon) of –8.1. We interpret the enclave magmas as having been derived by partial melting of subduction-modified mantle in the P–T transition zone between the spinel and spinel-garnet stability fields. Our new data suggest that subduction of the Proto-Tethyan oceanic crust was continuous to the early Silurian (ca. 435 Ma); the final closure of the Proto-Tethys occurred in the middle Silurian.  相似文献   

16.
Isotopic analyses of Nd and Sr on individual microtektites and a bulk microtektite sample from Barbados show them to have a very well defined isotopic composition. These data plot on an εSrεNd diagram precisely within the narrow field determined by North American tektites (εSr ≈ 111; εNd ≈ ?6.2). They yield an Nd model age of 0.6 AE. These results show that the microtektites from the Oceanic beds of late Eocene age are derived from the same target as the North American tektites and should be associated with the same event. Samples of the deep sea sediments in which the Barbados microtektites occur are found to have isotopic signatures which appear to reflect ambient sea water and detrital sediments. They cannot be the source of Sr or Nd in the tektites. Following the arguments of Shaw and Wasserburg (1982) we conclude that the target area which produced the North American tektite field was composed of sediments (Eocambrian or younger) derived from very late Precambrian crust. Glass beads from Lake Wanapitei Crater are isotopically different from all other tektites (εSr ≈ 960; εNd ≈ ?31.4) and cannot be related to the North American tektites.  相似文献   

17.
Nd, Sr and U-Pb isotopic data for the late Triassic West Coast Province batholiths and Permian to Triassic East Coast Province batholiths of Peninsular Malaysia allow estimates of the ages of the crustal fragments comprising the peninsula to be made. Initial ?Nd and ?Sr values for granitoids from the West Coast Province range from ?6 to ?10 and +160(0.716) to +660(0.751) respectively. Nd model ages calculated based on a depleted mantle evolution model (TDMNd) range from 1300 Ma to 1800 Ma and are in general agreement with the mid-Proterozoic upper intersection ages of U-Pb zircon reverse discordia (1500–1700 Ma). Initial ?Nd and ?Sr values for granitoids from the East Coast Province range from ?0.8 to ?6 and +10(0.705) to +130(0.714) respectively. Calculated TDMNd ages of 900–1400 Ma for these granitoids are comparable to two U-Pb zircon reverse discordia intercepts that yield 800 Ma and 1350 Ma. The general agreement of U-Pb zircon inheritance ages and TDMNd ages are interpreted to correspond to the Proterozoic ‘crust formation’ ages of the continental fragments represented by the West Coast and East Coast batholithic provinces. Mid-Proterozoic (~ 1300–1900 Ma) ‘crust formation’ ages are commonly shown by other Phanerozoic continental margin plutonic and volcanic belts. The ubiquitous mid-Proterozoic ‘crust formation’ ages and the absence of Archaean signatures suggest voluminous juvenile additions to the continental crust in the mid-Proterozoic. Such ages at continental margins would imply that many continental blocks had achieved very much their present-day extent by the mid-Proterozoic.  相似文献   

18.
Based on the Rb-Sr isochron dating results, this paper suggests that the alkaline intrusive belt at the east foot of the Taihang-Da Hinggan Mountains were formed between 135 and 122 Ma. And the alkaline intrusives in the north and south sections of this belt have entirely different Sr, Nd and Pb isotopic characteristics, i.e., all the rocks in the south section have positive εSr(t) and negative εNd(t) values and all those in the north have the opposite values. On the εSr(t) versus εNd(t) correlation diagram, the samples from the south are concentrated along the enriched mantle evolution trend lines and nearby, while those from the north fall along the depleted mantle trend lines and nearby. On the Pb isotope composition diagram, most of the samples from the south section fall on the mantle Pb evolution line and nearby, while those from the north lie between the Pb evolution lines of the mantle and the erogenic belt. The above-stated isotopic characteristics not only indicate that the source rocks of  相似文献   

19.
Oxygen isotopic compositions of silicates in eclogites and whiteschists from the Kokchetav massif were analyzed by whole‐grain CO2‐laser fluorination methods. Systematic analyses yield extremely low δ18O for eclogites, as low as ?3.9‰ for garnet; these values are comparable with those reported for the Dabie‐Sulu UHP eclogites. Oxygen isotopic compositions are heterogeneous in samples of eclogite, even on an outcrop scale. Schists have rather uniform oxygen isotope values compared to eclogites, and low δ18O is not observed. Isotope thermometry indicates that both eclogites and schists achieved high‐temperature isotopic equilibration at 500–800 °C. This implies that retrograde metamorphic recrystallization barely modified the peak‐metamorphic oxygen isotopic signatures. A possible geological environment to account for the low‐δ18O basaltic protolith is a continental rift, most likely subjected to the conditions of a cold climate. After the basalt interacted with low δ18O meteoric water, it was tectonically inserted into the surrounding sedimentary units prior to, or during subduction and UHP metamorphism.  相似文献   

20.
Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ13Ccalcite values of –2 to –7% and δ18Ocalcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ18Owhole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ13Ccalcite of –1.6 to –0.6%, and δ18Ocalcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ18O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ18O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ13C vs. δ18O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.  相似文献   

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