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贵州遵义寒武系底部黑色页岩中含Mo、Ni、U等重金属的富集层，它们一直被认为与热水沉积作用有关。本文通过对贵州遵义松林小竹一带的寒武系底部地层的系统的岩石、矿物、地球化学研究，认为遵义松林小竹一带寒武系底部黑色页岩中富含Mo、Ni、U等重金属层属于热液（水）喷流沉积，主要依据有：①含大量的黄铁矿、针镍矿、硫钼矿及较多的锑硫镍矿、黄铜矿、闪锌矿、重晶石、石英、石膏等矿物；②具有大量的同生砾屑，砾屑成分为黑色碳质体和碎屑状黄铁矿、针镍矿、硫钼矿等矿石，它们堆积成层状结构，碎屑呈被撕裂状、棱角状、熔蚀港湾状等结构，球状、脸盆状、枕头状等构造，它们类似海底喷流沉积；③硅同位素、锶同位素、Re／Os值、Th／Sc值、Th／U值都表明有深部物质加入；④黑色岩系中夹碳酸盐岩透镜体，碳同位素具有强烈负异常特征，表明有热液作用；⑤超强富集元素Mo、As、Se、Re和T1都属于典型的气相迁移元素，而钼是典型的高温气相迁移元素，暗示了可能存在火山射气作用；而强富集的Ni、U、Au、Ag、PGE元素组合是超基性岩浆活动的产物，表明有热液活动。研究发现在热液（水）喷流沉积形成的富集Mo、Ni、U等重金属硫化物层之上，产出丰度大、分异度低、含大型海绵类、双壳类、菌藻类和少量大型蠕虫化石的生物群，它的特征与现代太平洋海底热喷口附近的生物群类似，因此认为遵义小竹一带寒武系底部生物群属于与海底热喷口相关生物群，这一新发现对研究寒武纪生态和生物爆发具有重要意义。 相似文献
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贵州省遵义松林地区下寒武统牛蹄塘组镍钼多金属层富集U、Mo、Ni、Re、Tl等元素.本文以松林地区镍钼多金属层磷块岩为主要研究对象,在松林系统取样的基础上,开展化学分析、径迹蚀刻、扫描电镜、能谱面扫描、浸出实验等工作.结果表明下寒武统牛蹄塘组镍钼多金属层中Ni、Mo显著富集,达到工业品位,U、Re、Tl明显富集.径迹蚀刻实验揭示铀主要富集于磷块岩碎屑边缘有机碳外带,为进一步确定铀的赋存形式圈定重点观察区.该区镍钼多金属层中铀呈晶质铀矿形式赋存于溶蚀重结晶磷块岩的溶蚀孔洞、微裂隙或微孔隙中,并与中高温热液矿物针镍矿、辉砷镍矿、闪锌矿、方铅矿、磷灰石共生.浸出实验采用去离子水、H2 SO4、NaHCO3+MnO2三种介质浸出样品中水溶态、酸可溶态、氧化可溶态的铀.80℃,48 h条件下浸出实验结果显示多金属磷块岩由黑色褪色为浅灰色、灰色,碳质页岩实验前后颜色均为黑色.遵义地区镍钼多金属层及碳质页岩中铀主要以吸附状态或独立矿物形式存在,以类质同象形式存在的难溶铀占比较小.研究认为,该区镍钼多金属层磷块岩中铀以独立矿物形式存在并与中高温热液矿物共生,为揭示扬子陆块东缘陆源裂陷环境下发生海底喷流和热水沉积作用提供新的微观证据. 相似文献
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贵州遵义黄家湾下寒武统牛蹄塘组镍-钼富集层电子探针研究 总被引：8，自引：1，他引：7
对贵州遵义黄家湾下寒武统牛蹄塘组镍-钼富集层进行电子探针研究,发现镍主要赋存于黄铁矿、针镍矿、辉砷镍矿、铁辉砷镍矿、紫硫镍矿、赫硫镍矿;钼主要以"碳硫钼矿"的形式存在。镍钼硫化物多与黄铁矿、白铁矿交代共生,反映矿物经历了不同的成矿阶段。岩石中不仅富集Ni、Mo元素,而且Se元素存在超常富集,可以视为热液作用或生物作用的结果。遵义黄家湾下寒武统Ni-Mo富集层应为海底热液沉积和生物沉积混合成因,其物源较为复杂。 相似文献
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刘英辉 《吉林大学学报(地球科学版)》2022,52(1):80-93
准噶尔盆地乌—夏地区二叠系风城组发育一套特殊的云质岩类,其沉积环境及成因复杂,目前仍存在较多争议。本文基于岩心观察（13口井）与系统取样测试分析（64个样品）,揭示了目标层位云质岩的岩石学和地球化学特征,探讨了不同类型云质岩的沉积环境及成因机制。研究结果表明：根据云质岩宏观结构特征,风城组可识别纹层状、星散状、丝絮状、团块状和不规则层状5种云质岩类型;高δ13CPDB值（平均4.0‰）、高古盐度值（平均13.0%）和深水沉积构造等特征表明目标层位沉积环境具有陆相低能、深水还原和咸水高矿化度等特点;纹层状云质岩为“高山深盆”盐湖卤水分层形成的准同生白云岩,团块状、不规则层状、丝絮状和星散状云质岩为埋藏交代白云岩。 相似文献
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遵义新土沟下寒武统镍钼钒矿矿石特征及成矿条件 总被引：1，自引：2，他引：1
新土沟矿区位于松林背斜东翼,呈单斜构造。镍钼矾矿层产于下寒武统牛蹄塘组底部黑色炭质泥岩中,属黄铁矿型矿层。 矿物组份有黄铁矿,针镍矿、锑硫镍矿、硫钼矿、黄铜矿、闪锌矿、炭泥质、水云母。高岭石,绢云母。胶磷矿、方解石、重晶石、石膏等。矿石结构有砾屑结构、生物碎屑结构、核形石、叠层石、显微莓粒等。局部见有滑动构造及生物搅动构造。 依矿石组份、结构、构造及生物特征说明沉积矿层时水浅,气候温暧、潮湿,宜藻类繁殖。矿层之顶底部为水平、微波状及穹状迭层石,中部为豆状、饼状、竹叶状砾屑及(偏心)核形石。砾屑及核形石普遍见水流击碎及冲刷现象,属浅海台地相,弱还原环境。本区硫化物的生成主要与生物及生物化学作用有关。 相似文献
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A two‐part basal till at Knud Strand, Denmark reveals a uniform fabric pattern and strength, petrographical composition and clay mineralogy. The nature of the contact with the underlying sediments, ductile deformation structures, partly intact soft sediment clasts, small meltwater channels and thin horizontal outwash stringers dispersed in the till indicate both bed deformation and basal decoupling by pressurised subglacial water. A time‐transgressive model is suggested to explain the lack of vertical gradation in till properties in which debris released from the active ice sole is sheared in a thin zone moving upward as till accretion proceeds. It is suggested that, although strain indicators occur throughout the entire till thickness, the deformation at any point of time encompassed the uppermost part of the till only, allowing preservation of fragile clasts below. The substantial thickness of the till (up to 6 m) coupled with a much smaller (by more than one order of magnitude) inferred thickness of the deforming bed suggests that the bulk of till material was transported englacially prior to deposition. The lack of petrographical gradation in the till is attributed to effective mixing and homogenisation of material along the ice flow path. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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老石旦矿区的高岭土(木节土)呈灰白、灰紫及灰黑色,质地松软,可塑性高,是一种良好的耐火材料和陶瓷原料。对其成因过去有两种看法:(1)原生沉积的;(2)由煤层风化淋滤形成的。作者认为是煤层风化残积形成的。即煤层经地壳运动抬升到地表以后,受到强烈的风化淋滤作用,使有机组分分解,流失和逸散,铝硅矿物相对富集,在表生条件下形成木节土。 相似文献
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Results of the microscopic study of sandy rocks from the Bugrovaya and lower Khvalynian sequences at the lower course of the Volga River are discussed. The terrigenous material of these deposits represents a mixture of clasts of two types: argillic (clayey) and nonargillic. The argillic component (clasts of chocolate clays) predominates in the clastic material and imparts the brownish red color to sands and sandstones of the Bugrovaya sequence. The nonargillic component includes fragments of crystals and rocks, the assemblage of which is similar to the clastic material of the underlying Khvalynian sand. The combination of clay clasts, which are not prone to long-range transport, with redeposited crystallo-and lithoclasts indicates the presence of different provenances. Their thin banding (lamination) related to differentiation of the clastic material by composition and grain size and the presence of glauconite grains testify to the aqueous origin of the Bugrovaya sequence. 相似文献
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Xiaoqi Ding Osman Salad Hersi Xin Hu Ying Zhu Shaonan Zhang Changsheng Miao 《Arabian Journal of Geosciences》2018,11(11):287
Thick conglomerate and sandstone lithofacies of Yingcheng Formation in Changling Sag are tight gas reservoirs. The formation contains a fair amount of volcanic clasts and accumulated in a deltaic system that spans from delta plain to prodelta depositional setting. High-quality reservoirs are only a small fraction of these thick siliciclastic rocks. Petrographic analysis has been used to assess diagenetic processes, paragenetic sequence, and their effects on the reservoir qualities. The major loss of primary porosity is due to compaction along with grain-coating, pore-filling clay, and quartz cements. Alteration of volcanic rock fragments supplied alkali cations which favored formation of chlorite, smectite, and zeolite cements. The thickness of the chlorite coating decreases from the delta plain to the distal part of the delta front. On the contrary, the content of the zeolite cement increases toward the distal part of the delta front. Quartz and feldspar cements were ubiquitous due to high SiO2 concentration and alkali cations. Early dissolution of volcanic rock fragments and feldspars by freshwater increased porosity but did not contribute much to the permeability because pore-throats are predominantly occluded with clay and pseudomatrix. Late-stage dissolution of the zeolite cement was caused by organic acid expelled from maturation of organic matter. Although the reservoirs with chlorite coatings have moderate porosity, the permeability in situ is very low and pore-throat sizes are small. The high-quality reservoirs are medium- to fine-grained zeolite-dissolved sandstones developed in the distal part of the delta front and shallow lacustrine. 相似文献
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大塘坡组锰矿石由菱锰矿内碎屑和碳泥质基质组成。菱锰矿内碎屑是浅水沉积环境中的锰质沉积物破碎而成。它们沿着盆地斜坡流入深水地区与碳、粘土和粉砂沉积在一起形成内碎屑菱锰矿。一部分矿石有递变层理,具有浊流沉积特征。 相似文献
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桂林地区红土砾石层的工程地质特征及其应用 总被引：1，自引：1，他引：1
桂林地区的红土砾石层以其独特的工程地质特征引起了许多中外学者的注意, 对它的成因至今还存在争议。本文主要讨论红土砾石层的工程应用, 即不仅可作为一般低层建筑物的天然持力层, 而且可以作为沟、塘等低洼地带的回填土料 ;而且厚度较大的红土砾石层坚硬部分可作为桩端持力层。 相似文献
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《Sedimentology》2018,65(1):151-190
This study documents the character and occurrence of hybrid event beds (HEBs) deposited across a range of deep‐water sub‐environments in the Cretaceous–Palaeocene Gottero system, north‐west Italy. Detailed fieldwork (>5200 m of sedimentary logs) has shown that hybrid event beds are most abundant in the distal confined basin‐plain domain (>31% of total thickness). In more proximal sectors, hybrid event beds occur within outer‐fan and mid‐fan lobes (up to 15% of total thickness), whereas they are not observed in the inner‐fan channelized area. Six hybrid event bed types (HEB‐1 to HEB‐6) were differentiated mainly on basis of the texture of their muddier and chaotic central division (H3). The confined basin‐plain sector is dominated by thick (maximum 9·57 m; average 2·15 m) and tabular hybrid event beds (HEB‐1 to HEB‐4). Their H3 division can include very large substrate slabs, evidence of extensive auto‐injection and clast break‐up, and abundant mudstone clasts set in a sandy matrix (dispersed clay ca 20%). These beds are thought to have been generated by highly energetic flows capable of delaminating the sea floor locally, and carrying large rip‐up clasts for relatively short distances before arresting. The unconfined lobes of the mid‐fan sector are dominated by thinner (average 0·38 m) hybrid event beds (HEB‐5 and HEB‐6). Their H3 divisions are characterized by floating mudstone clasts and clay‐enriched matrices (dispersed clay >25%) with hydraulically fractionated components (mica, organic matter and clay flocs). These hybrid event beds are thought to have been deposited by less energetic flows that underwent early turbulence damping following incorporation of mud at proximal locations and by segregation during transport. Although there is a tendency to look to external factors to account for hybrid event bed development, systems like the Gottero imply that intrabasinal factors can also be important; specifically, the type of substrate available (muddy or sandy) and where and how erosion is achieved across the system producing specific hybrid event bed expressions and facies tracts. 相似文献
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Soft-sediment clasts composed of silt and clay are contained within glacial outwash sands in the Puget Sound, Washington State, USA. The outwash was deposited during ice retreat of the Cordilleran ice sheet around 17 cal kyr BP. The soft-sediment clasts have a distinctive and consistent morphology and disposition within the sand beds. The sedimentology, sedimentary structures and presence of soft-sediment clasts suggest sand was deposited as proglacial outwash with silts and clays deposited in meltwater pools. Following drying-out of the pools and subaerial cracking, lumps of silt and clay were excavated by meltwater and transported distally as soft-sediment clasts within high-density flows. The most likely final depositional setting is as a Salisbury-type ‘delta’ in which subaqueous outwash grades distally into deeper water. This interpretation shows the power of soft-sediment clasts to inform on past processes and palaeogeography for which there is often little evidence in the geologic record. 相似文献
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V. I. Belousov 《Lithology and Mineral Resources》2002,37(3):251-265
Based on the detailed study of outcrops, two generations of ore clasts were recognized in clastic haloes around allochthonous antimony–mercury deposits: (1) early generation composed of in situ fragments of older autochthonous deposits (ore clasts) and (2) late generation of fragments related to the destruction of ore-bearing allochthons and found as exotic inclusions in flysch and olistostromes. Ore clasts reside in the terrigenous (pre-flysch) sequence that makes up the upper part of terrigenous–carbonate nappes and olistoplaques in the lower flysch–olistostrome sequence. Thus, they belong to allochthonous units. The terrigenous sequence differs from the younger flysch sediments by a relatively small thickness, predominantly clayey composition, and absence of rhythmic bedding and large erratic blocks. It is also characterized by the synsedimentary volcanic activity with the eruption of intermediate and acid igneous rocks, silicification, and ore mineralization in the lower part of the sequence, the maximal mineralization being confined to the boundary with underlying limestones. Relative to the terrigenous sequence the flysch–olistostrome sequence, which hosts ore-bearing allochthons, is distinguished by the primary attitude, greater abundance of ore clasts, and higher extent of ore disintegration. Some genetic features of autochthonous and allochtonous jasperoid deposits are considered. Their differences in age, host environment, formation depth, vertical extent of ore deposition, and zoning are also outlined. 相似文献
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为探讨贵州下寒武统黑色岩系中铂族元素物质来源及钼-镍、钒多金属形成的沉积环境与成矿作用,在钼-镍、钒多金属层及其顶底页岩、底部硅质岩中采集样品测试分析。通过对样品中金、铂族元素含量(质量分数)及其地球化学特征值研究,结果表明：黑色岩系中金及铂族元素含量显示协同变化特征;Pd富集,Ru、Ir亏损明显,Pt、Rh、Os基本持平或略有变化;样品的原始地幔标准值标准化模式配分曲线从Os、Ru、Rh、Ir、Pt到Pd大致呈“W”型,配分曲线略呈左倾,总体上呈现w(Pd)>w(Pt)>w(Os)>w(Rh)>w(Ru)>w(Ir)的变化关系;黑色岩系铂族元素来源与正常海水及海底热水喷流作用关系密切,地外来源可能性极小;黑色岩系钼-镍、钒多金属层中铂族元素的富集存在单独成矿作用或成矿作用的叠加,而且在钒多金属层内局部存在分层或条带分异。 相似文献