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1.
Present study reports the PGE-geochemistry of mantle peridotites and Nd-isotope geochemistry of arc related mafic rocks from the Indus Suture Zone (ISZ), western Ladakh. The total PGE concentration of the Shergol and Suru Valley peridotites (∑PGE = 96–180 ppb) is much higher than that of the primitive mantle and global ophiolitic mantle peridotites. The studied peridotites show concave upward PGE-distribution patterns with higher palladium-group PGE/Iridium-group PGE ratios (i.e., 0.8–2.9) suggesting that the partial melting is not the sole factor responsible for the evolution of these peridotites. The observed PGE-distribution patterns are distinct from residual/refractory mantle peridotites, which have concave downward or flat PGE-distribution patterns. Relative enrichment of palladium-group PGE as well as other whole-rock incompatible elements (e.g., LILE and LREE) and higher Pd/Ir ratio (1.1–5.9) reflects that these peridotites have experienced fluid/melt interaction in a supra-subduction zone (SSZ) tectonic setting. Also, the Shergol mafic intrusives and Dras mafic volcanics, associated with the studied peridotites, have high 143Nd/144Nd ratios (i.e., 0.512908–0.513078 and 0.512901–0.512977, respectively) and positive εNd(t) (calculated for t = 140 Ma) values (i.e., +5.3 to +8.6 and + 5.1 to +6.6, respectively), indicating derivation from depleted mantle sources within an intra-oceanic arc setting, similar to Spongtang and Nidar ophiolites from other parts of Ladakh Himalaya. The transition from SSZ-type Shergol and Suru Valley peridotites to Early Cretaceous tholeiitic Shergol mafic intrusives followed by tholeiitic to calc-alkaline Dras mafic volcanics within the Neo-Tethys Ocean exhibit characteristics of subduction initiation mechanism analogous to the Izu-Bonin-Mariana arc system within western Pacific.  相似文献   

2.
ABSTRACT

The Neo-Tethys-related Chaldoran ophiolite peridotites in NW Iran are remnants of mantle lithosphere, exhumed tectonically during the Late Cretaceous. Harzburgite is the predominant peridotite type, associated with oceanic lower crust cumulate gabbros occasionally. The ophiolite rocks are unconformably overlain by Late Cretaceous-Paleocene sediments. New whole-rock geochemistry of the variably serpentinized harzburgites shows a depleted nature, exemplified by low Al2O3, CaO, TiO2, V and Y and high Ni, Cr and Mg and also low rare earth element (REE) contents. The harzburgites present LREE enrichment. Positive correlations between some LREEs and high field strength elements (HFSE) suggest enrichment of LREEs by melt re-fertilization processes. Cr-spinels have Cr number of [Cr# = Cr/(Cr + Al) = 0.53–0.67], showing medium to high degree of partial melting (F = ~17-20%). Both whole-rock and mineral chemistry data show a supra-subduction zone setting and progressive depletion along with increase in spinel Cr# (MOR to fore arc). The cumulate gabbros have high MgO and SiO2, low TiO2 and Ti/V < 10 and also low chondrite normalized Dy (<8.5). The gabbro samples show enriched LREEs and LILEs and depleted HREEs and HFSEs with respect to MORBs.

Subduction initiation (SI) model in a fore-arc/proto-fore-arc environment is suggested for the upper mantle evolution of the Chaldoran ophiolite. The rocks have experienced depletion in a second melting process at the later stages of SI and compositions were probably modified by extraction of island arc tholeiitic (IAT) and possibly boninitic (BON) melts. The chemostratigraphic progression for ‘subduction initiation rule (SIR)’ is likely traceable in Chaldoran mafic-ultramafic sequence, which corresponds to the most Neo-Tethyan ophiolites and is similar to MOR to supra-subduction zone (SSZ) evolution of most Iranian ‘Inner’ and ‘Outer Zagros’ ophiolitic peridotites.  相似文献   

3.
The Wadi Allaqi ophiolite along the Egyptian-Sudanese border defines the southernmost ophiolitic assemblage and suture zone in the Eastern Desert. Ophiolite assemblages comprise nappes composed mainly of mafic and ultramafic rocks that were tectonically emplaced and replaced by serpentine and carbonates along shear zones probably due to CO2-metasomatism. Serpentinites, altered slices of the upper mantle, represent a distinctive lithology of dismembered ophiolites of the western YOSHGAH suture. Microscopically, they are composed of more than 90 % serpentine minerals with minor opaque minerals, carbonate, brucite and talc. The mineral chemistry and whole-rock chemical data reported here indicate that the serpentinized peridotites formed as highly-depleted mantle residues. They show compositions consistent with formation in a suprasubduction zone environment. They are depleted in Al2O3 and CaO similar to those in fore-arc peridotites. Also, high Cr# (Cr/ (Cr+Al)) in the relict chrome spinels (average ~0.72) indicates that these are residual after extensive partial melting, similar to spinels in modern fore-arc peridotites. Therefore, the studied serpentinites represent fragments of an oceanic lithosphere that formed in a fore-arc environment, which belongs to an ophiolitic mantle sequence formed in a suprasubduction zone.  相似文献   

4.
The study of geology, geochemistry, rare earth elements, trace elements, Pb and Sr isotopes of representative ophiolite bodies from four ophiolitic belts in the western Qinghai-Tibetan Plateau, shows that the mantle peridotites of these ophiolites are mainly harzburgite in composition, with minor dunite. They are characterized by high magnesium (MgO) and low aluminum, calcium and alkali oxide contents. Enrichment of light rare earth elements in mantle peridotites may be due to two geological processes: relatively strong partial melting; and later metasomatism by the liquids released during the subduction of oceanic crust. Mantle peridotites are characterized by low contents of the trace elements Sr, Ti and Y and relatively high contents of Rb, Nb, Zr, Hf and Th, similar to metasomatic pyrolite. The isotopic compositions of Sr and Pb show evidence of contamination by a crustal component. All the evidence indicates that the four ophiolite belts in the western Qinghai-Tibetean Plateau have undergone metasomatism by liquids released during the subduction of oceanic crust, suggesting that they were formed in a supra-subduction zone (SSZ) tectonic setting. The mantle peridotites in ophiolite belts located in eastern Qinghai-Tibetan Plateau, e.g. Sanjiang and West Kunlun, may be compared with the Troodos, which is regarded as a typical SSZ complex, having the same geochemical characteristics, i.e. high MgO and LREE-rich. The geochemistry, combined with the occurrence of boninite and adakite rocks, which are associated with subduction magmatism, suggest that ophiolites formed at different times in Qinghai-Tibetan Plateau, including Sanjiang and West Kunlun, are all SSZ-type ophiolites formed in a supra-subduction zone tectonic setting.  相似文献   

5.
马雪盈  刘庆  闫方超  何苗  张宏远 《岩石学报》2021,37(8):2562-2578
强亲铁元素与亲石元素具有不同的地球化学行为，因此能够从不同的角度为造山带中超镁铁岩的成因及演化提供重要信息。位于苏鲁造山带东北端的胶东海阳所超镁铁岩主要由橄榄岩和辉石岩组成，它们常以团块状赋存于花岗质片麻岩中。虽然前人对这些超镁铁岩已经开展大量岩石学研究，但关于其成因及构造属性仍存在较大争议。本文开展了海阳所超镁铁岩的全岩主微量元素、强亲铁元素及Re-Os同位素的分析工作，结果显示蛇纹石化橄榄岩具有较高的MgO和Fe2O3T含量，较低的Al2O3、TiO2和CaO含量，明显富集流体迁移元素（U、Pb），亏损高场强元素（Zr、Hf），强亲铁元素没有发生明显分异，但Ru显示正异常，表明海阳所蛇纹石化橄榄岩是经历了低-中等程度部分熔融及熔/流体交代作用影响的残余地幔橄榄岩。海阳所辉石岩的主量元素表现出明显的结晶分异特征，稀土元素较原始地幔富集，铂族元素（PGEs）含量较低且发生了明显的分异，表明辉石岩的地幔源区经历过高程度的部分熔融和硫化物的分离。海阳所蛇纹石化橄榄岩的Os同位素地球化学特征表现出大洋亲和性，与辉石岩不具有熔体-残留体的关系。由于该地区发育较深层次的韧性剪切带，蛇纹石化橄榄岩中的橄榄石与辉石表现出韧性变形的特征，同时有辉石岩侵入到橄榄岩的现象，表明该地区的蛇纹石化地幔橄榄岩与辉石岩既不同时，也不同源，因此，暗示了该套岩石组合可能形成于大洋核杂岩（OCC）与洋脊型蛇绿岩（MOR）堆晶岩交互发育环境。  相似文献   

6.
巴雷公蛇绿混杂岩位于西南天山阔克萨彦岭地区, 代表了南天山古生代洋盆的洋壳残片.通过其中的地幔橄榄岩进行详细的地球化学研究, 分析其岩石成因及其形成环境.主量和微量元素特征显示巴雷公蛇纹石化橄榄岩Ti, Al含量低, Cr (1604~3863), Ni (1719×10-6~2375×10-6) 和Mg#值(0.90~0.92) 高; 样品的稀土强烈亏损(ΣREE=0.28×10-6~0.35×10-6, Yb=0.1~0.11×CI), 呈宽缓的U型REE配分模式; 原始地幔标准化蛛网图显示, 强烈富集Rb、U和Sr, 从LILE (Cs、Rb、Ba、U、K和Sr) 到HREE, 元素含量自左向右随不相容性的逐渐降低, 呈右倾标准化微量元素配分型式; 橄榄岩熔融程度在20%~25%之间, 为俯冲带氧化条件下的熔融残留物.上述特征显示了俯冲板片流体与俯冲带上地幔楔物质的相互作用, 具有俯冲带型地幔橄榄岩特征.结合区域新获得的资料, 指示了南天山早古生代洋盆为一成熟的大洋, 早古生代曾发生过洋内俯冲作用.巴雷公蛇纹石化橄榄岩可能产生在南天山古生代洋内俯冲作用中的大洋岛弧的弧前地幔楔部位.   相似文献   

7.
东巧蛇绿岩位于班公湖—怒江缝合带中段,根据地理位置特征并以强玛镇为中心将东巧岩体划分为东西两个岩体。其中西岩体相对面积较大,由地幔橄榄岩、枕状玄武岩、辉长辉绿岩等组成;而东岩体面积较小,仅含地幔橄榄岩部分,各个不同单元之间呈断层接触关系。对东巧地幔橄榄岩开展岩石学、矿物学及地球化学研究发现:(1)东巧地幔橄榄岩以方辉橄榄岩为主,纯橄岩所占比例较小,约15%。豆荚状铬铁矿主要呈条带浸染状赋存在厚层且延伸较远的纯橄岩中。(2)东巧地幔橄榄岩中单斜辉石含量小于3%,矿物地球化学和全岩地球化学特征显示其来源于尖晶石相地幔源区的部分熔融,且部分熔融程度较高,估算在22%～28%,高于深海地幔橄榄岩的部分熔融程度(10%～22%)。(3)东巧地幔橄榄岩中的副矿物铬尖晶石Cr#值较高大于60,全岩具有U型球粒陨石标准化稀土元素配分模式,同时Rb、U、Zr和Sr相对富集,Hf和Nb相对亏损。全岩的地球化学特征指示了俯冲带之上的残余地幔与流体/熔体发生了反应,致使轻稀土元素以及部分微量元素选择性富集。综合东巧地幔橄榄岩的矿物化学组成成分以及全岩的地球化学特征,认为东巧地幔橄榄岩形成于大洋中脊的扩张环境中,后受到洋内俯冲作用的影响,导致俯冲带之上高度部分熔融的地幔橄榄岩与流体/熔体发生相互作用。  相似文献   

8.
ABSTRACT

The dismembered ophiolites in Wadi Arais area of the south Eastern Desert of Egypt are one of a series of Neoproterozoic ophiolites found within the Arabian–Nubian Shield (ANS). We present new major, trace, and rare earth element analyses and mineral composition data from samples of the Wadi Arais ophiolitic rocks with the goal of constraining their geotectonic setting. The suite includes serpentinized ultramafics (mantle section) and greenschist facies metagabbros (crustal section). The major and trace element characteristics of the metagabbro unit show a tholeiitic to calc-alkaline affinity. The serpentinized ultramafics display a bastite, or less commonly mesh, texture of serpentine minerals reflecting harzburgite and dunite protoliths, and unaltered relics of olivine, orthopyroxene, clinopyroxene, and chrome spinel can be found. Bulk-rock chemistry confirms harzburgite as the main protolith. The high Mg# (91.93–93.15) and low Al2O3/SiO2 ratios (0.01–0.02) of the serpentinized peridotite, together with the high Cr# (>0.6) of their Cr-spinels and the high NiO contents (0.39–0.49 wt.%) of their olivines, are consistent with residual mantle rocks that experienced high degrees of partial melt extraction. The high Cr# and low TiO2 contents (0.02–0.34 wt.%) of the Cr-spinels are most consistent with modern highly refractory fore-arc peridtotites and suggest that these rocks probably developed in a supra-subduction zone environment.  相似文献   

9.
SUPRA-SUBDUCTION ZONE ENVIRONMENT AND ECONOMIC POTENTIAL OF THE NIDAR OPHIOLITE OF INDUS SUTURE ZONE, EASTERN LADAKH,THE HIMALAYA  相似文献   

10.
《International Geology Review》2012,54(15):1839-1855
ABSTRACT

The Late Cretaceous accretionary complex of the ?zmir–Ankara–Erzincan suture zone, near Artova, is composed mainly of peridotites (variably serpentinized), amphibolite, garnet-micaschist, calc-schist, marble, basalt, sandstones, neritic limestones. The metamorphic rocks were interpreted as the metamorphic sole rocks occurring at the base of mantle tectonites, because: (i) amphibolites were observed together with the serpentinized peridotites suggesting their occurrences in the oceanic environment; (ii) foliation in amphibolites and serpentinized peridotites run subparallel to each other; (iii) all these metamorphic rocks and serpentinized peridotites are cross-cut by the unmetamorphosed dolerite dikes with island arc tholeiite-like chemistry. Geochemical characteristics of the amphibolites display enriched mid-ocean ridge basalt (E-MORB)- and ocean island basalt (OIB)-like signatures. The dolerite dikes, on the other hand, yield an island arc tholeiite-like composition. Geothermobarometric investigations of the metamorphic sole rocks suggest that the metamorphic temperature was ~650 ± 30°C and the pressure condition was less than 0.5 GPa. Dating of hornblende grains from amphibolite yielded age values ranging from 139 ± 11 to 157 ± 3.6 Ma (2σ). The oldest weighted average age value is regarded as approximating the timing of the intra-oceanic subduction. These cooling ages were interpreted to be the intra-oceanic subduction/thrusting time of the ?zmir–Ankara–Erzincan oceanic domain.  相似文献   

11.
The Xigaze ophiolite in the central part of the Yarlung–Zangbo suture zone, southern Tibet, has a well-preserved sequence of sheeted dykes, basalts, cumulates and mantle peridotites at Jiding and Luqu. Both the basalts and diabases at Jiding have similar compositions with SiO2 ranging from 45.9 to 53.5 wt%, MgO from 3.1 to 6.8 wt% and TiO2 from 0.87 to 1.21 wt%. Their Mg#s [100Mg/(Mg + Fe)] range from 40 to 60, indicating crystallization from relatively evolved magmas. They have LREE-depleted, chondrite-normalized REE diagrams, suggesting a depleted mantle source. These basaltic rocks have slightly negative Nb- and Ti-anomalies, suggesting that the Xigaze ophiolite represents a fragment of mature MORB lithosphere modified in a suprasubduction zone environment. The mantle peridotites at Luqu are high depleted with low CaO (0.3–1.2 wt%) and Al2O3 (0.04–0.42 wt%). They display V-shaped, chondrite-normalized REE patterns with (La/Gd)N ratios ranging from 3.17 to 64.6 and (Gd/Yb)N from 0.02 to 0.20, features reflecting secondary metasomatism by melts derived from the underlying subducted slab. Thus, the geochemistry of both the basaltic rocks and mantle peridotites suggests that the Xigaze ophiolite formed in a suprasubduction zone.Both the diabases and basalts have Pd/Ir ratios ranging from 7 to 77, similar to MORB. However, they have very low PGE abundances, closely approximating the predicted concentration in a silicate melt that has fully equilibrated with a fractionated immiscible sulfide melt, indicating that the rocks originated from magmas that were S-saturated before eruption. Moderate degrees of partial melting and early precipitation of PGE alloys explain their high Pd/Ir ratios and negative Pt-anomalies. The mantle peridotites contain variable amounts of Pd (5.99–13.5 ppb) and Pt (7.92–20.5 ppb), and have a relatively narrow range of Ir (3.47–5.01 ppb). In the mantle-normalized Ni, PGE, Au and Cu diagram, they are relatively rich in Pd and depleted in Cu. There is a positive correlation between CaO and Pd. The Pd enrichment is possibly due to secondary enrichment by metasomatism. Al2O3 and Hf do not correlate with Ir, but show positive variations with Pt, Pd and Au, indicating that some noble metals can be enriched by metasomatic fluids or melts carrying a little Al and Hf. We propose a model in which the low PGE contents and high Pd/Ir ratios of the basaltic rocks reflect precipitation of sulfides and moderate degrees of partial melting. The high Pd mantle peridotites of Xigaze ophiolites were formed by secondary metasomatism by a boninitic melt above a subduction zone.  相似文献   

12.
The Mersin ophiolite, represented by approximately 6-km-thick oceanic lithospheric section on the southern flank of the Taurus calcareous axis, formed in the Mesozoic Neo-Tethyan ocean some time during Late Cretaceous in southern Turkey. The ultramafic and mafic cumulates having over 3 km thickness consist of dunite ± chromite, wehrlite, clinopyroxenite at the bottom and pass into gabbroic cumulates in which leucogabbro, olivine-gabbro and anorthosite are seen. Crystallization order is olivine (Fo91−80) ± chromian spinel (Cr# 60-80), clinopyroxene (Mg#95−77), plagioclase (An95.6−91.6) and orthopyroxene (Mg#68−77). Mineral chemistry of ultramafic and mafic cumulates suggest that highly magnesian olivines, clinopyroxenes and absence of plagioclase in the basal ultramafic cumulates are in good agreement with products of high-pressure crystal fractionation of primary basaltic melts beneath an island-arc environment. Major, trace element geochemistry of the cumulative rocks also indicate that Mersin ophiolite was formed in an arc environment. Coexisting Ca-rich plagioclase and Forich olivine in the gabbroic cumulates show arc cumulate gabbro characteristics. Field relations as well as the geochemical data support that Mersin ophiolite formed in a supra-subduction zone tectonic setting in the southern branch of the Neo-Tethys in southern Turkey.  相似文献   

13.
We present the whole-rock and the mineral chemical data for upper mantle peridotites from the Harmanc?k region in NW Turkey and discuss their petrogenetic–tectonic origin. These peridotites are part of a Tethyan ophiolite belt occurring along the ?zmir-Ankara-Ercincan suture zone in northern Turkey, and include depleted lherzolites and refractory harzburgites. The Al2O3 contents in orthopyroxene and clinopyroxene from the depleted lherzolite are high, and the Cr-number in the coexisting spinel is low falling within the abyssal field. However, the orthopyroxene and clinopyroxene in the harzburgites have lower Al2O3 contents for a given Cr-number of spinel, and plot within the lower end of the abyssal field. The whole-rock geochemical and the mineral chemistry data imply that the Harmanc?k peridotites formed by different degrees of partial melting (~%10–27) of the mantle. The depleted lherzolite samples have higher MREE and HREE abundances than the harzburgitic peridotites, showing convex-downward patterns. These peridotites represent up to ~16 % melting residue that formed during the initial seafloor spreading stage of the Northern Neotethys. On the other hand, the more refractory harzburgites represent residues after ~4–11 % hydrous partial melting of the previously depleted MOR mantle, which was metasomatized by slab-derived fluids during the early stages of subduction. The Harmanc?k peridotites, hence, represent the fragments of upper mantle rocks that formed during different stages of the tectonic evolution of the Tethyan oceanic lithosphere in Northern Neotethys. We infer that the multi-stage melting history of the Harmanc?k peridotites reflect the geochemically heterogeneous character of the Tethyan oceanic lithosphere currently exposed along the ?zmir-Ankara-Erzincan suture zone.  相似文献   

14.
The Coast Range ophiolite (CRO) of California is one of the most extensive tracts of oceanic crust preserved in the North American Cordillera, but its origin has long remained controversial. We present here new data on mineral compositions in mantle peridotites that underlie crustal sections of the ophiolite, and show that these are dominantly refractory harzburgites related to high apparent melting in a supra-subduction zone (SSZ) setting. Abyssal peridotite (characterized by high-Al spinels and relatively high Ti, Na, Nd, Sm, Lu, and Hf in pyroxene) occurs at one location where it is associated with SSZ mantle peridotite and volcanic rocks with both oceanic and arc-like geochemistry. SSZ mantle peridotites (characterized by intermediate-Cr/Al or high-Cr spinels, and by extremely low Ti, Na, Nd, Sm, Lu, and Hf in pyroxenes) are associated with crustal sections containing arc-related volcanic rocks, including boninites. This convergence between conclusions based on crustal lithologies and their underlying mantle sections confirms previous proposals that link the CRO to SSZ processes, and seriously undermines hypotheses that invoke formation of the ophiolite at a mid-ocean ridge spreading center.  相似文献   

15.
Petrographic and geochemical studies of peridotites and melagabbros from the Maures massif (SE France) provide new constraints on the Early Palaeozoic evolution of the continental lithosphere in Western Europe. Peridotites occur as lenses along a unit rooted in the main Variscan suture zone. They are dominantly spinel peridotites and minor garnet–spinel peridotites. Spinel peridotites represent both residual mantle and ultramafic cumulates. Mantle-related dunites and harzburgites display high temperature textures, with olivine (Mg#0.90), orthopyroxene (Mg#0.90) and spinel (TiO2 < 0.2%; Cr#0.64–0.83) compositions typical of fore-arc upper mantle. Ultramafic cumulates are dunite adcumulates, harzburgite heteradcumulates and mesocumulates, melagabbro heteradcumulates and amphibole peridotites, with olivine (Mg#0.85–0.89), orthopyroxene (Mg#0.86–0.89) and Cr-spinel (TiO2 = 0.5–3.3%; Cr#0.7–0.98) compositions typical of ultramafic cumulates. Cr-spinel compositions of both spinel peridotite types suggest their genesis in a supra-subduction zone lithosphere. Core to rim zoning in spinel is related to the incomplete influence of regional metamorphism and serpentinisation. The covariation of major and minor elements with Al2O3 for cumulates is consistent with igneous processes involving crystal accumulation. Both mantle and cumulate dunites and harzburgites have U-shaped REE patterns and extremely low trace element contents, similar to peridotites from modern fore-arc peridotites (South Atlantic) and from ophiolites related to supra-subduction zones (Semail, Cyclops, Pindos, Troodos). Melagabbros also have U-shaped REE patterns similar to xenoliths from the Philippine island arc, but also similar to intrusive ultramafic cumulates from the Semail nappe of Oman related to a proto-subduction setting. A wehrlite has a REE pattern similar to that of amphibole peridotites reflecting metasomatism of clinopyroxene-bearing peridotites due to subduction-related fluids. The Maures spinel peridotites and melagabbros are therefore interpreted as the lowermost parts of a crustal sequence and minor residual mantle of lithosphere generated in a supra-subduction zone during Early Palaeozoic time. Garnet–spinel peridotites are chemically close to melagabbros, but have recorded high pressure metamorphism before their retrogression similar to spinel peridotites into amphibolites to greenschists facies metamorphism. They indicate burial to mantle depths of the margin of the supra-subduction lithosphere during the Early Palaeozoic continental subduction. Both peridotite types were exhumed during the Upper Palaeozoic continental collision. Comparable observations from other Variscan-related peridotites, in particular of the Speik complex of the Autroalpine basement, and a common age for the subduction stage allow extension of these regional conclusions to a broad area sharing the Cambrian suture zone, extending from the Ossa-Morena to the Bohemian massif.  相似文献   

16.

Serpentinized rocks closely associated with Paleoproterozoic eclogitic metabasites were recently discovered at Eseka area in the northwestern edge of the Congo craton in southern Cameroon. Here, we present new field data, petrography, and first comprehensible whole-rock geochemistry data and discuss the protolith and tectonic significance of these serpentinites in the region. The studied rock samples are characterized by pseudomorphic textures, including mesh microstructure formed by serpentine intergrowths with cores of olivine, bastites after pyroxene. Antigorite constitutes almost the whole bulk of the rocks and is associated (to the less amount) with tremolite, talc, spinel, and magnetite. Whole-rock chemistry of the Eseka serpentinites led to the distinction of two types. Type 1 has high MgO (> 40 wt%) content and high Mg# values (88.80) whereas Type 2 serpentinite samples display relatively low MgO concentration and Mg# values (< 40 and 82.88 wt%, respectively). Both types have low Al/Si and high Mg/Si ratios than the primitive mantle, reflecting a refractory abyssal mantle peridotite protolith. Partial melting modeling indicates that these rocks were derived from melting of spinel peridotite before serpentinization. Bulk rock high-Ti content is similar to the values of subducted serpentinites (> 50 ppm). This similarity, associated with the high Cr contents, spinel-peridotite protolith compositions and Mg/Si and Al/Si ratios imply that the studied serpentinites were formed in a subduction-related environment. The U-shaped chondrite normalized-REE patterns of serpentinized peridotites, coupled with similar enrichments in LREE and HFSE, suggest the refertilized nature due to melt/rock interaction prior to serpentinization. Based on the results, we suggest that the Eseka serpentinized peridotites are mantle residues that suffered a high degree of partial melting in a subduction-related environment, especially in Supra Subduction Zone setting. These new findings suggest that the Nyong series in Cameroon represents an uncontested Paleoproterozoic suture zone between the Congo craton and the São Francisco craton in Brazil.

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17.
During cruise SO201-1b of the joint Russian-German expedition on the R/V Sonne in 2009, mantle peridotites affected by varying secondary alteration were dredged on the eastern slope of the northwestern segment of the Stalemate transverse ridge adjacent to the eponymous fracture zone. The collection discussed in this paper included four samples of silicified serpentinites after dunites and 11 lherzolite samples serpentinized to a varying degree. The abundance of amorphous silica and quartz, very high SiO2 content (up to 88.7 wt %), and unusually low MgO (up to 1.4 wt %) in the serpentinized dunites strongly distinguish these rocks from the known products of hydrothermal alteration and low-temperature (seafloor) weathering of peridotites in the oceanic crust. In order to determine the conditions and processes resulting in the silicification of peridotites at the Stalemate Fracture Zone, thermodynamic modeling accounting for the kinetics of mineral dissolution implemented in the GEOCHEQ program package was used in this study. The results of modeling allowed us to suppose that the geochemical and mineralogical effects observed in the silicified serpentinized dunites of the Stalemate Fracture Zone are consequences of low-temperature deserpentinization of oceanic materials under subaerial conditions.  相似文献   

18.
对来自滇东南马关木厂的尖晶石二辉橄榄岩中名义上无水矿物(NAMs)进行显微傅里叶变换红外光谱(Micro-FTIR)分析,结果显示,单斜辉石、斜方辉石和橄榄石中均含有以羟基形式存在的结构水,单斜辉石的水含量为160×10~(-6)~557×10~(-6)(质量分数,下同),斜方辉石的水含量为85×10~(-6)~207×10~(-6),橄榄石的水含量为5×10~(-6)~12×10~(-6),根据矿物百分比含量估算的全岩水含量为46×10~(-6)~137×10~(-6);元素地球化学特征表明,本次研究的橄榄岩包体是岩石圈地幔经历较低程度部分熔融的残余;低(La/Yb)N值(0.22~0.57)以及高Ti/Eu比值(4 076~6 772)暗示橄榄岩可能经历了以硅酸盐熔体为交代介质的微弱地幔交代作用;单斜辉石的微量元素组成比较单一,整体表现出高场强元素、大离子亲石元素以及轻稀土元素的同步亏损;结合中国东部地区已经发表的橄榄岩包体含水量数据来看,滇东南马关木厂岩石圈地幔具有明显富水的特征,可能与该区自中生代以来遭受的新特提斯洋壳大规模俯冲流体交代作用有关;与华北克拉通含水量的明显差异有可能反映的是两地岩石圈地幔正处于不同的演化阶段。  相似文献   

19.
Serpentinites in the Eastern Desert of Egypt are the most distinctive lithological unit in the Arabian–Nubian Shield (ANS) ophiolite sequence which associated with major suture zones. Khor Um-Safi (KUS) serpentinites represent dismembered fragments of ophiolitic rocks located in the central Eastern Desert (CED) of Egypt.KUS serpentinites exhibit affinity to the typical metamorphic peridotites with harzburgitic protolith compositions. Their opaque mineral assemblage (pentlandite, heazlewoodite and magnetite) is similar to that observed in oceanic serpentinites and implies serpentinization under highly reducing conditions. They have refractory major element compositions with Al2O3 contents comparable to oceanic and active margin peridotites as well as Pan-African serpentinites. The Cr and TiO2 contents reflect evolution within a supra-subduction zone (SSZ) environment. This implication is confirmed by the Al2O3/SiO2 and MgO/SiO2 ratios which akin to ANS ophiolitic peridotites in fore-arc setting. Their enrichment in compatible trace elements (Cr, Ni and Co) reveals a depleted mantle peridotite protolith.Modelling trace elements indicates that they represent the mantle residues from 15 to 20 % melting of spinel peridotite at oxygen fugacity conditions of the QFM + 1 buffer. This range of melt extraction is consistent with the typical range of SSZ peridotite. Oxygen fugacity estimation suggests evolution under more oxidizing regime similar to modern fore-arc basin system. Moreover, this implication indicates that the KUS mantle represents arc lithosphere interacted with arc melt.  相似文献   

20.
李源  杨经绥  刘钊  贾毅  徐向珍 《岩石学报》2011,27(11):3239-3254
巴尔蛇绿岩属于雅鲁藏布江缝合带的西延部分,距拉萨约1200km,主要由地幔橄榄岩、少量的橄长堆晶岩和玄武岩组成.地幔橄榄岩主体为合单辉方辉橄榄岩,少量为二辉橄榄岩.根据巴尔蛇绿岩地幔橄榄岩的结构构造特征,将矿物组合划分为3个世代,第一世代残余地幔矿物组合:橄榄石+斜方辉石+单斜辉石;第二世代部分熔融及熔-岩反应矿物组合:橄榄石+斜方辉石+单斜辉石+尖晶石;第三世代地幔交代作用矿物组合,主要为含水矿物角闪石.将3个世代的矿物组合归并为2个演化阶段:第一阶段,包括第一世代和第二世代矿物组合,形成于MOR(mid-ocean ridge)构造环境下的洋脊扩张阶段;第二阶段,为第三世代矿物角闪石,形成于SSZ(super-subduction zone)环境下的俯冲阶段.对比雅鲁藏布江缝合带不同区段蛇绿岩中地幔橄榄岩的特征,发现雅鲁藏布江缝合带存在MOR和SSZ两种类型的蛇绿岩,其中中段的蛇绿岩主要以典型的SSZ型地幔橄榄岩为主,而东、西段则以受到不同程度SSZ环境改造的MOR型地幔橄榄岩为主,认为雅鲁藏布江缝合带蛇绿岩地幔橄榄岩演化分段性的特征,与新特提斯洋沿弧方向上板块活动的动力学机制的不均一有关.  相似文献   

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