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本文分析了不同矿石中Ａｇ与Ｐｂ、Ｚｎ、Ｃｕ、Ｓ等元素的相关性，并根据银含量变化规律，银矿物组合特征，划分Ｐｂ（Ｚｎ）－Ａｇ－Ｓｎ－Ｓｂ和Ｃｕ（Ｍｏ）－Ａｇ－Ｔｅ－Ｂｉ两个不贩银的矿化组合。 相似文献
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本文从地质背景、样品分析方法、气液包体特征、包一显微测温和温度气压计等几个方面扼要介绍了布阿泽尔地区不同矿床内矿前、矿后石英以及矿后方解石中卤水包体的特征，提出布阿泽尔钴矿和Ｃｏｂａｌｔ银矿代表了同一类型的Ｃｏ－Ａｇ－Ａｓ矿化中Ａｇ－Ｃｏ含量的差异。 相似文献
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黄沙坪铅锌矿床中银矿化组合特征 总被引：6，自引：0，他引：6
研究黄沙坪铅锌矿床中银矿化组合表明：与３０１花岗斑岩和３０４花斑岩岩体有关铅（锌）－银－锡－锑矿化组合，银矿化伴随铅矿化出现，其微量元素富Ｓｎ、Ｓｂ、Ａｇ，低Ｂｉ、Ｔｅ、Ｍｏ、Ｗｏ、Ｗ为特征；银矿物组合以硫银锡矿－银黄锡矿－深红银矿－螺状硫银矿－硫锑铜银矿组合为特征，与石英斑岩有关的铜（钼）－银－碲矿化组合，铜矿石以高Ｔｅ、Ｂｉ、Ｍｏ和Ｗ，低Ｓｂ为特征，银矿物组合以碲银矿－六方碲银矿－粒碲银组合和硫银铋矿－块辉铋铅银矿－碲银矿组合为特征 相似文献
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哈密铜山多金属矿中银赋存于蚀变构造破碎带区，矿石含Ａｇ、Ｃｕ、Ｐｂ、Ｚｎ，均达工业品位要求．银以独立银矿物：辉银矿、自然银出现，矿床属中高温热液充填交代成因． 相似文献
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黑西哥ＦｒｅｓｎｉｌｌｏＡｇ－Ｐｂ－Ｚｎ地区的ＳａｎｔｏＮｉｎｏ脉中，银含在螺状硫银矿及三个含银矿盐固溶体系列的矿物中，这些硫盐矿物是：浓红银矿、淡红银矿、硫锑铜银矿、硒硫铜银矿、黝铜矿及脆银矿。 相似文献
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太白维山大型银矿床地质地球化学特征 总被引：1，自引：0，他引：1
太白维山大型银矿床为典型的中低温火山－次火山隐爆角砾岩型矿床，受岩性和断裂构造控制明显，矿体的产出部位和矿石品级与隐爆角砾岩关系密切。本文通过对基岩和１：２０万水系沉积物资料的分析与处理，得出基岩中主成矿元素组合为Ａｇ－Ｃｕ－Ｐｂ－Ａｓ－Ｓｂ－Ｚｎ，水系沉积物中主成矿元素组合为Ａｇ－Ｐｂ－Ｚｎ－Ｃｄ－Ｍｎ－Ｈｇ的结论，同时指出Ｐｂ可作为此矿床最重要的间接指示元素，而主成矿元素中各单元素异常浓集中心对银矿床的产出部位有很好的指示作用，为找矿的重要指标。 相似文献
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江西银山矿田伴生金银综合回收利用研究 总被引：2，自引：0，他引：2
叙述了银山铜铅锌多金属矿田铅锌成矿系列和铜硫成矿系列６个成矿带中伴生金银的赋存状态、富集特征和成矿规律，并进行伴生金银相关性分析。认为伴生金银是以独立矿物存在为主，主要载体矿物有黄铜矿，含砷铜矿物、黄铁矿、方铅矿和闪锌矿。Ａｕ、Ａｇ与Ｐｂ、Ｚｎ、Ｃｕ、Ｓ密切相关。同时分析了金银生产中存在的具体问题，提出综合回收金银的措施和建议。 相似文献
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浙东火山岩型银矿床成矿作用与浙东地区火山岩浆活动演化有着密切的关系，认为具有高丰度值的火山岩浆是成矿物质来源，其矿东地质成因属浅成低温火山岩浆混合热液贵金属矿床。建立银矿床蚀变矿化模式：分为硅化带（Ａｕ、Ａｇ、Ｚｎ、Ｂａ）、富银带（Ａｇ、（Ａｕ）１Ｐｂ、Ｚｎ、Ｍｎ、Ｓｂ）和贱金属带（Ｃｕ、Ｐｂ、Ｚｎ、（Ａｇ））三部分。 相似文献
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广西老厂铅锌矿田方铅矿和闪锌矿微量元素特征及其成因探讨 总被引：2，自引：0，他引：2
老厂铅锌矿床不同成因类型矿脉中的方名矿、闪锌矿微量元素组成有明显差别。石英方 矿脉的方铅矿以高Ａｇ、Ｓｂ、Ｓｎ和低Ｇｅ、Ｃｄ、Ｔｅ为特征，与区域上典型岩浆热液矿床相一致。与闪锌矿共生的方铅矿则以低Ａｇ、Ｓｂ、Ｓｎ和高Ｇｅ、Ｃｄ、Ｔｅ为特征。所有闪锌矿以低Ｆｅ、Ｍｎ、Ｉｎ、Ａｇ、Ｓｎ和高Ｇａ、Ｇｅ为特征，均与国内典型的沉积改造型矿床相一致。根据这些特征可把本区叠回在一起的不同成因类型矿床区分开来。因 相似文献
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New data on the composition of the major minerals from the skarn and vein polymetallic deposits of the Dal’negorskii ore region are reported. Analysis of galena and sphalerite was carried out by the X-ray fluorescent energy-dispersive method of synchrotron radiation for the first time. It is shown that the minor elements in major minerals of different deposits are typomorphic. Among these elements are Fe, Cu, Ni, Cd, Ag, Sn, and Sb, as well as In in sphalerite and Te in galena. The high concentrations of Ag, Cu, Te, Cd, and In in the extracted minerals indicate the complex character of mineralization. The compositional patterns of ore minerals characterize the sequence of mineral formation from the skarn to vein ores, and the sequence of deposits from the mesothermal to epithermal conditions. This provides geochemical evidence for the stage model of the formation of mineralization in the Dal’negorskii ore region. 相似文献
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小秦岭金矿田中的两种罕见矿物—碲铅铋矿和自然碲 总被引：2，自引：0，他引：2
碲铅铋矿和自然碲产于河南省小秦岭含金石英脉矿床中。碲铅铋矿化学成分平均值(%)为:Te44.06,Bi40.24,Pb14.23,并含有微量的Ag、Au、Hg、Fe、Ni、Cu等元素。理论化学式为(Bi,Pb)_3Te_4,其中Bi>Pb。共生矿物有自然金、碲金矿、破银矿、碲铅矿、碲金银矿、碲铋矿;方铅矿、闪锌矿、黄铁矿、黄铜矿等。 自然碲反射色为纯白微带乳色,非均质性清楚,偏光色为蓝灰-棕灰色。显微硬度为H_v=85.1kg/mm~2(25g)。共生矿物有碲金银矿、碲银矿、黄铜矿等。化学成分中碲含量达98.44％,并含Ag、Cu、W、Fe、Pt等微量元素。 相似文献
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《Resource Geology》2018,68(3):209-226
Shin‐Otoyo, Suttsu, Teine, Date, Chitose, and Koryu are sites rich in precious and base metal Miocene–Pleistocene epithermal deposits, and located in southwestern Hokkaido, Japan. The deposits are predominantly hosted by the Green Tuff Formation of Middle Miocene age. Ore petrographic study of these deposits shows the occurrence of variable quantities of Cu–As–Sb–Ag–Bi–Pb–Te sulfosalt minerals. Determination of mineralogical and chemical compositions of the sulfosalt minerals was undertaken to elucidate the time and spatial changes of the sulfide‐sulfosalt minerals. Various types of sulfosalt minerals identified from gold–silver and base metal quartz–sulfide veins represented some sulfosalt mineralization phases, such as the Cu–Fe–Sn–S phase of mawsonite and stannite; Cu–(As,Sb)–S phase of tetrahedrite–tennantite and luzonite–famatinite series minerals; (Cu,Ag)–Bi–Pb–S phase of emplectite, pavonite, friedrichite, aikinite, and lillianite–gustavite series minerals; (Ag,Cu)–(As,Sb)–S phase of proustite–pyrargyrite and pearceite–polybasite series minerals; and Bi–Te–S phase of tetradymite and kawazulite minerals. There are some trends in the paragenetic sequence of sulfosalt mineralization in southwestern Hokkaido (in complete or partial) as follows: sulfide → Cu–Fe–Sn–S → (Cu,Ag)–Bi–Pb–S → (Bi–Te–S) → Cu–(As,Sb)–S → ([Ag,Cu]–[As,Sb]–S). The formation of sulfosalt minerals is characterized by the introduction of some elements such as Sn, Bi, and Te at an earlier stage and an increase or decrease of some elements such as As and Sb, followed by the introduction of Ag at the later stage of ore mineral paragenesis sequence. Mineral composition of the Chitose and Koryu deposits are slightly different from those of Shin‐Otoyo, Suttsu, Teine, and Date due to their lack of Sn (tin) and Bi (bismuth) mineralization. The variable concentrations and relationships are not simply with redistributed trace elements from the original sulfide minerals of chalcopyrite, pyrite, galena, and sphalerite. Some heavier elements were also introduced during the replacement reaction, which is consistent with the occurrence of their associated minerals. 相似文献
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The chemistry and mode of occurrences of native tellurium in the epithermal gold ores from Teine, Kobetsuzawa, Mutsu, Kawazu, Suzaki and Iriki in Japan are examined. Mineral assemblages in contact with native tellurium are: quartz‐sylvanite at Teine, quartz‐hessite‐sylvanite‐tellurantimony at Kobetsuzawa, quartz at Mutsu, quartz‐stutzite‐hessite‐sylvanite‐tetradymite at Kawazu, quartz at Suzaki, and quartz‐goldfieldite at Iriki. The peak patterns of XRD for native tellurium from these six ores are nearly identical to that of JCPDS 4–554. Their chemical compositions of Te range from 98.16 to 100.73 wt.%, showing nearly pure tellurium. Other elements detected are: Se of 0–0.85 and Cu of 0–0.74 at Teine, Sb of 0.45–0.47 and Se of 0.19–0.27 at Kawazu, Se of 0.22–1.11 and Sb of 0–0.49 at Suzaki, and Cu of 0.69–0.98, As of 0.22–0.28 and Bi of 0–0.22 wt.% at Iriki. No other elements are detected in the ores of Kobetsuzawa and Mutsu. The ranges of associated minor compositions are consistent with those of the experimental phase. The differences would be related to associate minerals. The mineral assemblages in these ores agree well with the previously proposed experimental phase relations in Au‐Ag‐Te ternary system for 120–280°C. The Suzaki ore has high Te‐Au assemblage: from calaverite‐sylvanite‐krennerite via native tellurium to petzite, with changing mineralization stage, whereas the Kobetsuzawa and the Kawazu ores have high Te‐Ag assemblage of tellurium‐hessite, and native tellurium‐stutzite‐hessite‐sylvanite, respectively. The Teine ore has intermediate assemblage of native tellurium‐sylvanite. The mineral assemblages in the Au‐Ag‐Te system are related to the hydrothermal environment especially to the pH condition, i.e. Au rich assemblages under acidic and Ag rich assemblages under intermediate pH conditions, being supported by alteration mineral species. The other telluriferous epithermal gold deposits not in association with native tellurium such as Agawa, Date, Takeno, Chugu, Chitose, Sado and Kushikino are estimated to have been formed under higher pH conditions as adularia and calcite occur in these deposits. The pH‐Eh diagram for aqueous tellurium species and tellurium minerals at 250°C indicates that the region of native tellurium occurs between those of aqueous telluride and tellurous species at lower pH, being consistent with their mineral assemblages in ores and alteration envelopes. 相似文献
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Shoji Kojima María Constanza San Martín Toshiro Nagase Daisuke Nakashima Claudio Bisso Andrew Menzies 《Resource Geology》2021,71(1):80-90
Modes of occurrence of Au‐ and Ag‐bearing phases and their relation with associated hypogene ore minerals were examined with the objective to elucidate Au‐Ag distribution at the Esperanza porphyry deposit in the Eocene Centinela copper belt, using ore‐microscope modal analysis, semi‐quantitative analyses by automated mineralogy, electron probe microanalysis, and secondary ion mass spectrometer. The Esperanza hypogene mineralization is characterized by early‐stage chalcopyrite‐rich veinlets in the potassic alteration zone and later polymetallic stage with tennantite and galena in the chlorite‐sericitic alteration zone. Only the early‐stage chalcopyrite contains fine‐grained electrum (Au68Ag32 ‐ Au81Ag19) and hessite (Ag2Te), and thus yields positive correlations in Cu vs. Au and Cu vs. Ag grades that are clearly recognized in the hypogene sulfide zone. The early‐stage chalcopyrite grains frequently exhibit polysynthetic twinning suggestive of inversion from intermediate solid solution. These features suggest that the fine‐grained electrum and hessite are products exsolved in the cooling process with the intermediate solid solution to chalcopyrite inversion. In contrast, tennantite and galena of the later‐stage mineralization contain no detectable Ag, and it is thus proposed that the early‐stage inverted chalcopyrite is the principal storage of economically important precious metals. 相似文献
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《Russian Geology and Geophysics》2015,56(10):1367-1383
New data on the mineral composition and the first data on the geochemical composition of ores of the Rogovik gold-silver deposit (Omsukchan ore district, northeastern Russia) have been obtained. Study of the regularities of the spatial distribution of ore mineralization shows that the deposit ores formed in two stages. Epithermal Au-Ag ores of typical poor mineral and elemental compositions were generated at the early volcanic stage. The major minerals are low-fineness native gold, electrum, acanthite, silver sulfosalts, kustelite, and pyrite. The typomorphic elemental composition of ores is as follows: Au, Ag, Sb, As, Se, and Hg. The content of S is low, mostly < 1%. Silver ores of more complex mineral and elemental compositions were produced under the impact of granitoid intrusion at the late volcanoplutonic stage. The major minerals are high-Hg kustelite and native silver, silver sulfosalts and selenides, fahlore, pyrite, chalcopyrite, galena, and sphalerite. The typomorphic elemental composition of ores is as follows: Ag, As, Sb, Se, Hg, Pb, Zn, Cu, and B. The content of S is much higher than 1%. The ores also have elevated contents of Mo, Ge, F, and LREE (La, Ce, and Nd). At the volcanoplutonic stage, polychronous Au-Ag ores formed at the sites of the coexistence of silver and epithermal gold-silver mineralization. Their specific feature is a multicomponent composition and a strong variability in chemical composition (both qualitative and quantitative). Along with the above minerals, the ores contain high-Hg gold, hessite, argyrodite, canfieldite, orthite, fluorapatite, and arsenopyrite. At the sites with strongly rejuvenated rocks, the ores are strongly enriched in Au, Ag, Hg, Cu, Pb, Zn, Ge, Se, La, Ce, Nd, S, and F and also contain Te and Bi. The hypothesis is put forward that the late silver ores belong to the Ag-complex-metal association widespread in the Omsukchan ore district. A close relationship between the ores of different types and their zonal spatial distribution have been established. In the central part of the Rogovik deposit, epithermal Au-Ag ores are widespread in the upper horizons, Ag ores are localized in the middle horizons, and rejuvenated polyassociation Au-Ag ores occur at the sites (mostly deep-seated) with ore-bearing structures of different ages. 相似文献
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广东陆丰硫铁矿床为一个中低温热液交代充填型脉状矿床。伴生有综合利用价值的Ｃｕ、Ａｕ、Ａｇ、Ｔｅ、Ｂｉ等元素。其中Ａｕ主要呈微细粒自然金、次显微金包裹在黄铁矿中，Ａｇ主要呈自然银、螺状硫银矿等独立矿物充填在脉石矿物中。Ｔｅ、Ｂｉ呈碲铋矿、硫盐矿物嵌布在黄铁矿或充填在黄铁矿微裂隙中。多数硫盐矿物为矿区首次发现。通过矿石物质组分的研究，查清了上述元素的赋存状态，为硫铁矿床的综合评价，有益组分的合理回收提供了依据 相似文献