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1.
A suite of dolerite dykes from the Ahlmannryggen region of westernDronning Maud Land (Antarctica) forms part of the much moreextensive Karoo igneous province of southern Africa. The dykecompositions include both low- and high-Ti magma types, includingpicrites and ferropicrites. New 40Ar/39Ar age determinationsfor the Ahlmannryggen intrusions indicate two ages of emplacementat 178 and 190 Ma. Four geochemical groups of dykes have beenidentified in the Ahlmannryggen region based on analyses of60 dykes. The groups are defined on the basis of whole-rockTiO2 and Zr contents, and reinforced by rare earth element (REE),87Sr/86Sr and 143Nd/144Nd isotope data. Group 1 were intrudedat 190 Ma and have low TiO2 and Zr contents and a significantArchaean crustal component, but also evidence of hydrothermalalteration. Group 2 dykes were intruded at 178 Ma; they havelow to moderate TiO2 and Zr contents and are interpreted tobe the result of mixing of melts derived from an isotopicallydepleted source with small melt fractions of an enriched lithosphericmantle source. Group 3 dyke were intruded at 190 Ma and formthe most distinct magma group; these are largely picritic withsuperficially mid-ocean ridge basalt (MORB)-like chemistry (flatREE patterns, 87Sr/86Sri 0·7035, Ndi 9). However, theyhave very high TiO2 (4 wt %) and Zr (500 ppm) contents, whichis not consistent with melting of MORB-source mantle. The Group3 magmas are inferred to be derived by partial melting of astrongly depleted mantle source in the garnet stability field.This group includes several high Mg–Fe dykes (ferropicrites),which are interpreted as high-temperature melts. Some Group3 dykes also show evidence of contamination by continental crust.Group 4 dykes are low-K picrites intruded at 178 Ma; they havevery high TiO2–Zr contents and are the most enriched magmagroup of the Karoo–Antarctic province, with ocean-islandbasalt (OIB)-like chemistry. Dykes of Group 1 and Group 3 aresub-parallel (ENE–WSW) and both groups were emplaced at190 Ma in response to the same regional stress field, whichhad changed by 178 Ma, when Group 2 and Group 4 dykes were intrudedalong a dominantly NNE–SSW strike. KEY WORDS: flood basalt; depleted mantle; enriched mantle; Ahlmannryggen; Karoo dyke  相似文献   

2.
The origin of large-volume Yellowstone ignimbrites and smaller-volumeintra-caldera lavas requires shallow remelting of enormous volumesof variably 18O-depleted volcanic and sub-volcanic rocks alteredby hydrothermal activity. Zircons provide probes of these processesas they preserve older ages and inherited 18O values. This studypresents a high-resolution, oxygen isotope examination of volcanismat Yellowstone using ion microprobe analysis with an averageprecision of ± 0·2 and a 10 µm spot size.We report 357 analyses of cores and rims of zircons, and isotopeprofiles of 142 single zircons in 11 units that represent majorYellowstone ignimbrites, and post-caldera lavas. Many zirconsfrom these samples were previously dated in the same spots bysensitive high-resolution ion microprobe (SHRIMP), and all zirconswere analyzed for oxygen isotope ratios in bulk as a functionof grain size by laser fluorination. We additionally reportoxygen isotope analyses of quartz crystals in three units. Theresults of this work provide the following new observations.(1) Most zircons from post-caldera low-18O lavas are zoned,with higher 18O values and highly variable U–Pb ages inthe cores that suggest inheritance from pre-caldera rocks exposedon the surface. (2) Many of the higher-18O zircon cores in theselavas have U–Pb zircon crystallization ages that postdatecaldera formation, but pre-date the eruption age by 10–20kyr, and represent inheritance of unexposed post-caldera sub-volcanicunits that have 18O similar to the Lava Creek Tuff. (3) Youngand voluminous 0·25–0·1 Ma intra-calderalavas, which represent the latest volcanic activity at Yellowstone,contain zircons with both high-18O and low-18O cores surroundedby an intermediate-18O rim. This implies inheritance of a varietyof rocks from high-18O pre-caldera and low-18O post-calderaunits, followed by residence in a common intermediate-18O meltprior to eruption. (4) Major ignimbrites of Huckleberry Ridge,and to a lesser extent the Lava Creek and Mesa Falls Tuffs,contain zoned zircons with lower-18O zircon cores, suggestingthat melting and zircon inheritance from the low-18O hydrothermallyaltered carapace was an important process during formation ofthese large magma bodies prior to caldera collapse. (5) The18O zoning in the majority of zircon core–rim interfacesis step-like rather than smoothly inflected, suggesting thatprocesses of solution–reprecipitation were more importantthan intra-crystalline oxygen diffusion. Concave-downward zirconcrystal size distributions support dissolution of the smallercrystals and growth of rims on larger crystals. This study suggeststhat silicic magmatism at Yellowstone proceeded via rapid, shallow-levelremelting of earlier erupted and hydrothermally altered Yellowstonesource rocks and that pulses of basaltic magma provided theheat for melting. Each post-caldera Yellowstone lava representsan independent homogenized magma batch that was generated rapidlyby remelting of source rocks of various ages and 18O values.The commonly held model of a single, large-volume, super-solidus,mushy-state magma chamber that is periodically reactivated andproduces rhyolitic offspring is not supported by our data. Rather,the source rocks for the Yellowstone volcanism were cooled belowthe solidus, hydrothermally altered by heated meteoric watersthat caused low 18O values, and then remelted in distinct pocketsby intrusion of basic magmas. Each packet of new melt inheritedzircons that retained older age and 18O values. This interpretationmay have significance for interpreting seismic data for crustallow-velocity zones in which magma mush and solidified areasexperiencing hydrothermal circulation occur side by side. Newbasalt intrusions into this solidifying batholith are requiredto form the youngest volcanic rocks that erupted as independentrhyolitic magmas. We also suggest that the Lava Creek Tuff magmawas already an uneruptable mush by the time of the first post-calderaeruption after 0·1 Myr of the climactic caldera-formingeruption. KEY WORDS: Yellowstone; oxygen isotopes; geochronology; isotope zoning; zircon; U–Pb dating; caldera; rhyolite; ion microprobe  相似文献   

3.
The Jozini and Mbuluzi rhyolites and Oribi Beds of the southernLebombo Monocline, southeastern Africa, have geochemical characteristicsthat indicate they were derived by partial melting of a mixtureof high-Ti/Zr and low-Ti/Zr Sabie River Basalt Formation types.Compositional variations within the different rhyolite typescan largely be explained by subsequent fractional crystallization.The Sr- and Nd-isotope composition of the rhyolites is uniqueamongst Gondwana silicic large igneous provinces, having Ndvalues close to Bulk Earth (–0·94 to 0·35)and low, but more variable, initial 87Sr/86Sr ratios (0·7034–0·7080).Quartz phenocryst 18O values indicate that the rhyolite magmashad 18O values between 5·3 and 6·7, consistentwith derivation from a basaltic protolith with 18O values between4·8 and 6·2. The low-18O rhyolites (< 6·0)come from the same stratigraphic horizon and are overlain andunderlain by rhyolites with more ‘normal’ 18O magmavalues. These low-18O rhyolites cannot have been produced byfractional crystallization or partial melting of mantle-derivedbasaltic material. The rhyolites have low water contents, makingit unlikely that the low 18O values are the result of post-emplacementalteration. Modification of the source by fluid–rock interactionat elevated temperatures is the most plausible mechanism forlowering the 18O magma value. It is proposed that the low-18Orhyolites were derived by melting of earlier altered rhyolitein calderas situated to the east, which were not preserved afterGondwana break-up. KEY WORDS: rhyolite; Lebombo; stable and radiogenic isotopes; low-18O magmas; partial melting  相似文献   

4.
The Skye igneous centre, forming part of the British Tertiarymagmatic province, developed over a 7 Myr period (61–54Ma) and is characterized by a complex suite of lavas, hypabyssaland intrusive rocks of picritic to granitic composition. Theintrusion of magma from mantle to crust at 2x10–3km3/yr(6 Mt/yr) advected magmatic heat of roughly 0·2 GW averagedover the period of magmatism supporting an ‘excess’heat flux of about 130 mW/m2, or about twice the present-dayaverage continental heat flow. The volume of new crust generatedat Skye (15000 km3) spread over the present-day area of Skyecorresponds to 9 km of new crust. The geochemical evolutionof the Skye magmatic system is constrained using the Energy-ConstrainedRecharge, Assimilation, and Fractional Crystallization (EC-RAFC)model to understand variations in the Sr- and Pb-isotopic andSr trace-element composition of the exposed magmatic rocks withtime. The character (composition and specific enthalpy) of bothassimilant and recharge magma appears to change systematicallyup-section, suggesting that the magma reservoirs migrated toprogressively shallower levels as the system matured. The modelof the magma transport system that emerges is one in which magmabatches are stored initially at lower-crustal levels, wherethey undergo RAFC evolution. Residual magma from this stagethen migrates to shallower levels, where mid-crustal wall rockis assimilated; the recharge magma at this level is characterizedby an increasingly crustal signature. For some of the stratigraphicallyyoungest rocks, the data suggest that the magma reservoirs ascendedinto, and interacted with, upper-crustal Torridonian metasediments. KEY WORDS: assimilation; EC-RAFC model; geochemical modelling; magma recharge; Skye magmatism  相似文献   

5.
Alcedo volcano is one of six shield volcanoes on Isabela Islandin the western Galpagos Islands. Although Alcedo is dominantiybasaltic, it is unusual in that it also has erupted 1 km3 ofrhyolite. The rhyolitic phase marked a 10-fold decrease in themass-eruption rate of the volcano, and the volcano has returnedto erupting basalt. The basalts are tholeiitic and range fromstrongly to sparsely porphyritic. Olivine and plagiodase arethe liquidus phases in the most primitive basalts. The MgO andNi concentrations in the most primitive basalts indicate thatthey have undergone substantial differentiation since extractionfrom the mantle. The rhyolites contain the assemblage oligoclase-augite-titanomagnetite-fayalite-apatiteand sparse xenoliths of quenched basalt and cumulate gabbros.Intermediate rocks are very rare, but some are apparently basaltrhyolitehybrids, and others resulted from differentiation of tholeiiticmagma. Several modeling approaches and Sr-, Nd-, and O-isotopicdata indicate that the rhyolites resulted from 90% fractionation(by weight) of plagiodase, augite, titanomagnetite, olivine,and apatite from the most primitive olivine tholeiite. The dataare inconsistent with the rhyolites originating by crustal anatexis.The extreme Daly gap may be caused by the large increase inviscosity as the basaltic magma differentiates to intermediateand siliceous compositions; highly evolved magmas are eruptibleonly after they become saturated with volatiles by second boiling.The close association of the hybrid intermediate magmas andmagmatic inclusions with the climactic plinian eruption indicatesmixing between mafic and silicic magmas immediately before eruption.Rhyolite production was favored by the decrease in supply ofbasaltic magma as Alcedo was carried away from the focus ofthe Galpagos hotspot. A three-stage model for the magmaticevolution of a Galpagos volcano is proposed. In the first stage,the supply of basaltic magma is large. Basaltic magma continuallyintrudes the subcaldera magma chamber, buffering the magmas'compositional and thermal evolution. As the volcano is carriedaway from the basaltic source, the magma chamber is allowedto cool and differentiate, as exemplified by Alcedo's rhyoliticphase. Finally, the volcano receives even smaller influx ofbasalt, so a large magma chamber cannot be sustained, and thevolcano shifts to isolated basaltic eruptions. KEY WORDS: Galpagos; oceanic rhyolites; fractional crystallization; Isabela Island *Corresponding author, e-mail: Geist{at}IDUI1.csrv.uidaho.edu. Telephone: 208-885-6491. Fax: 208-885-5724  相似文献   

6.
The Campanian Ignimbrite is a > 200 km3 trachyte–phonolitepyroclastic deposit that erupted at 39·3 ± 0·1ka within the Campi Flegrei west of Naples, Italy. Here we testthe hypothesis that Campanian Ignimbrite magma was derived byisobaric crystal fractionation of a parental basaltic trachyandesiticmelt that reacted and came into local equilibrium with smallamounts (5–10 wt%) of crustal rock (skarns and foid-syenites)during crystallization. Comparison of observed crystal and magmacompositions with results of phase equilibria assimilation–fractionationsimulations (MELTS) is generally very good. Oxygen fugacitywas approximately buffered along QFM + 1 (where QFM is the quartz–fayalite–magnetitebuffer) during isobaric fractionation at 0·15 GPa ( 6km depth). The parental melt, reconstructed from melt inclusionand host clinopyroxene compositions, is found to be basaltictrachyandesite liquid (51·1 wt% SiO2, 9·3 wt%MgO, 3 wt% H2O). A significant feature of phase equilibria simulationsis the existence of a pseudo-invariant temperature, 883 °C,at which the fraction of melt remaining in the system decreasesabruptly from 0·5 to < 0·1. Crystallizationat the pseudo-invariant point leads to abrupt changes in thecomposition, properties (density, dissolved water content),and physical state (viscosity, volume fraction fluid) of meltand magma. A dramatic decrease in melt viscosity (from 1700Pa s to 200 Pa s), coupled with a change in the volume fractionof water in magma (from 0·1 to 0·8) and a dramaticdecrease in melt and magma density acted as a destabilizingeruption trigger. Thermal models suggest a timescale of 200kyr from the beginning of fractionation until eruption, leadingto an apparent rate of evolved magma generation of about 10–3km3/year. In situ crystallization and crystal settling in density-stratifiedregions, as well as in convectively mixed, less evolved subjacentmagma, operate rapidly enough to match this apparent volumetricrate of evolved magma production. KEY WORDS: assimilation; Campanian Ignimbrite; fractional crystallization; magma dynamics; phase equilibria  相似文献   

7.
Rates of magmatic processes in a cooling magma chamber wereinvestigated for alkali basalt and trachytic andesite lavaserupted sequentially from Rishiri Volcano, northern Japan, bydating of these lavas using 238U–230Th radioactive disequilibriumand 14C dating methods, in combination with theoretical analyses.We obtained the eruption age of the basaltic lavas to be 29·3± 0·6 ka by 14C dating of charcoals. The eruptionage of the andesitic lavas was estimated to be 20·2 ±3·1 ka, utilizing a whole-rock isochron formed by U–Thfractionation as a result of degassing after lava emplacement.Because these two lavas represent a series of magmas producedby assimilation and fractional crystallization in the same magmachamber, the difference of the ages (i.e. 9 kyr) is a timescaleof magmatic evolution. The thermal and chemical evolution ofthe Rishiri magma chamber was modeled using mass and energybalance constraints, as well as quantitative information obtainedfrom petrological and geochemical observations on the lavas.Using the timescale of 9 kyr, the thickness of the magma chamberis estimated to have been about 1·7 km. The model calculationsshow that, in the early stage of the evolution, the magma cooledat a relatively high rate (>0·1°C/year), and thecooling rate decreased with time. Convective heat flux fromthe main magma body exceeded 2 W/m2 when the magma was basaltic,and the intensity diminished exponentially with magmatic evolution.Volume flux of crustal materials to the magma chamber and rateof convective melt exchange (compositional convection) betweenthe main magma and mush melt also decreased with time, from 0·1 m/year to 10–3 m/year, and from 1 m/yearto 10–2 m/year, respectively, as the magmas evolved frombasaltic to andesitic compositions. Although the mechanism ofthe cooling (i.e. thermal convection and/or compositional convection)of the main magma could not be constrained uniquely by the model,it is suggested that compositional convection was not effectivein cooling the main magma, and the magma chamber is consideredto have been cooled by thermal convection, in addition to heatconduction. KEY WORDS: convection; magma chamber; heat and mass transport; timescale; U-series disequilibria  相似文献   

8.
BAKER  A. J. 《Journal of Petrology》1990,31(1):243-260
Stable isotope compositions of Ivrea Zone marbles and associatedlithologies are in general heterogeneous. The oxygen isotopecomposition of quartz in pelites ranges from 18O +9 to + 17(SMOW) and does not vary systematically with metamorphic grade.Peridotites retain oxygen isotope signatures close to mantlevalues. Marble calcites vary in isotopic composition from 13C + 2(PDB),180 +24(SMOW)to 13C –6(PDB), 18O + 13 (SMOW).Depletions in 18O and 13C may be explained dominantly by interactionwith fluids derived from within the observed metasedimentarysequence during prograde metamorphism. 18O and 13C show gradients of greater than 5/m across marblemargins and within marbles. The preservation of such isotopicgradients is not consistent with the long-term presence of grain-boundary-scaleinterconnected fluid films in and around marbles. There is ageneral lowering of 18O within individual marble bodies althoughlarge carbon and oxygen isotopic gradients are present. Calcitein marbles may attain oxygen isotope equilibrium, but rarelycarbon isotope equilibrium, with surrounding metapelites. Infiltrationof marbles must involve a component of channelized fluid flow. The general lack of isotopic equilibration within the sequencerequires channelized fluid flow and limited fluid-rock ratios.Large pervasive mantle to crust fluid fluxes are not consistentwith the observations. *Present address: Natural Environment Research Council, Polaris House, North Star Avenue, Swindon SN2 1EU, England  相似文献   

9.
Leucocratic and Gabbroic Xenoliths from Hualalai Volcano, Hawai'i   总被引:1,自引:0,他引:1  
A diverse range of crustal xenoliths is hosted in young alkalibasalt lavas and scoria deposits (erupted 3–5 ka) at thesummit of Huallai. Leucocratic xenoliths, including monzodiorites,diorites and syenogabbros, are distinctive among Hawaiian plutonicrocks in having alkali feldspar, apatite, zircon and biotite,and evolved mineral compositions (e.g. albitic feldspar, clinopyroxeneMg-number 67–78). Fine-grained diorites and monzodioritesare plutonic equivalents of mugearite lavas, which are unknownat Huallai. These xenoliths appear to represent melt compositionsfalling along a liquid line of descent leading to trachyte—amagma type which erupted from Huallai as a prodigious lava flowand scoria cone at 114 ka. Inferred fractionating assemblages,MELTS modeling, pyroxene geobarometry and whole-rock norms allpoint to formation of the parent rocks of the leucocratic xenolithsat 3–7 kbar pressure. This depth constraint on xenolithformation, coupled with a demonstrated affinity to hypersthene-normativebasalt and petrologic links between the xenoliths and the trachyte,suggests that the shift from shield to post-shield magmatismat Huallai was accompanied by significant deepening of the activemagma reservoir and a gradual transition from tholeiitic toalkalic magmas. Subsequent differentiation of transitional basaltsby fractional crystallization was apparently both extreme—culminatingin >5·5 km3 of trachyte—and rapid, at 2·75x 106 m3 magma crystallized/year. KEY WORDS: geothermobarometry; magma chamber; xenolith; cumulate; intensive parameters  相似文献   

10.
Mount Galunggung is a historically active volcano in southwesternJava that has erupted four times in the last two centuries.During the most recent event, which occurred during a 9–monthinterval in 1982– 83, some 305 106 m3 of medium–K,calc–alkaline magma was erupted. This eruption was unusualbecause of its duration, the diversity of eruption dynamicsand products, and the range of lava compositions produced. Thecomposition of juvenile material changed gradually during thecourse of the eruption from initial plagioclase (An60–75)and two–pyrozene bearing andesites with 58% SiO2 to finalplagioclase (An85–90), diopside, and olivine (Fo85–90)bearing primitive magnesium basalts with 47% SiO2 Mineralogicaland compositional relationships indicate a magmatic evolutioninvolving differentitation of high–Mg parental melt. Theeruptive volumes of 35 106 m3 andesite, 120 106 m3 maficandesite, and 150 106 m3 basalt are consistent with the ideathat the 1982– 83 eruption progressively tapped and draineda magma chamber that had become chemically stratified throughextensive crystal fractionation. Separates of plagioclase and pyroxene have 18O( SMO W) rangesof + 5. 6 to + 6.0 and + 5.3 to + 5.6, respectively, with 18Oplag–pxvalues of + 0.4 to + 0.6o, indicating internal O–isotopeequiliburium at temperature of 1100–850 C. The magenesianbasalts have magmatic 18O/ 16O ratios similar to those of mid–oceanridge basalt, and the O–isotope ratios of compositionallyevolved derivative melts show no evidence for contaminationof the galunggung magmas by 18O–rich crust during differentiation.Andesites and transitional mafic and sites have a more variableO–isotope character, with laves and phenocrysts havingboth higher and lower 18O values than observed in the parentalmagnesium basalts. These features are interpreted to reflectintramagma chamber processes affecting the upper portions ofthe differentiating Galunggung magma body before the 1982–83eruption.  相似文献   

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