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1.
Two types of soil (fluvisols and anthrosols) were collected from different environmental settings (suburb and industrial area)
in Wuhan, central China, aiming to examine the applicability of magnetic mapping for heavy metal pollution of urban soil in
a large region. Magnetic measurements and chemical analysis indicated elevated magnetization and heavy metal concentrations
of topsoils in the industrial area. Magnetic susceptibility (χ), anhysteretic remanent magnetization (ARM) and saturation
isothermal remanent magnetization (SIRM) of fluvisols are much higher than those of anthrosols, but contrary for frequency-dependent
susceptibility, indicating that soil magnetism strongly depends on the soil type/condition. Predominant magnetic carrier in
topsoils in industrial area is pseudo-single-domain/multi-domain magnetite. Environmental scanning electron microscope/energy
dispersive X-ray examination of the magnetic extracts from these topsoils revealed abundant spherical particles with diameters
of 10–50 μm that are rich in iron-oxides, and could be attributed to the nearby industrial activities (e.g., steel work and
power generation). Significant correlations were observed between magnetic concentration-related parameters (e.g., χ, ARM
and SIRM) and concentrations of Cu, Pb, Zn, Hg and Tomlinson pollution load index. These results proposed that magnetic proxy
mapping of soil pollution is an effective, fast and inexpensive tool for delineation of heavy metal pollution. However, interpretation
of magnetic properties for such a purpose must be done on a site-specific basis, taking into account the possibilities of
pedogenic enhancement/depletion under the specific soil conditions. 相似文献
2.
《Physics and Chemistry of the Earth, Part A: Solid Earth and Geodesy》1999,24(6):541-543
A non-conventional way of utilizing magnetic susceptibility — soil kappametry — was tested in the area of a major metallurgical plant VSŽ Košice (East Slovakia). Magnetic susceptibility values above background in soil samples indicate higher concentrations of heavy metals in soil, i.e. the soil kappametry can be used as a preliminary quick and inexpensive method for detection of higher heavy metal contents in soils. 相似文献
3.
Lynda Attoucheik Neli Jordanova Boualem Bayou France Lagroix Diana Jordanova Said Maouche Bernard Henry Abdelhak Boutaleb 《Environmental Earth Sciences》2017,76(7):298
Former zinc and lead mines that have been operating for half a century are located in the massif of Bou Caid (Tissemsilt, Algeria). Hazardous heavy metals emitted from the mines are abundant in the surrounding soil and cause strong metal pollution in the region. This paper investigates the extent of lead and zinc mine activity derived pollution by characterizing both magnetic and geochemical properties of samples collected in the vicinity of the mines. The results of the magnetic study show the coexistence of magnetic minerals such as magnetite, hematite and goethite. Analyses on surface soils and weathered rocks suggest that hematite and goethite have ore-related lithogenic origins. Magnetic susceptibility shows a positive correlation with lead content when present in low-to-medium concentrations (< ~500 mg/kg). At higher lead concentrations, there is no correlation with magnetic susceptibility. The relationship between magnetic susceptibility and zinc content is not straightforward. These observations are explained by the higher affinity of Pb to iron oxides at lower pollution levels and their preferential bonding to carbonates when Pb and Zn contents are extremely high, as demonstrated by Iavazzo et al. (J Geochem Explor 113:56–67, 2012) in a study of former Zn–Pb mine in Morocco. Based on the general features of the spatial maps of field-measured magnetic susceptibility, mass-specific magnetic susceptibility, Pb and Zn contents, it is concluded that field magnetic measurements provide a good qualitative proxy of pollution spread out of the mining galleries, while laboratory measurements afford a more detailed investigation of the links between iron oxides and the main heavy metals in the ore. 相似文献
4.
利用直流电测深、环境磁学以及矿物学方法,开展对一钢铁厂周边土壤的污染评价研究,获得了土壤垂向电阻率与磁化率分布特征。研究表明,随着污染土剖面的深度由底部至地表,土壤电阻率逐渐减小,磁化率和重金属含量反而增高;该变化特征反映了土壤受污染的程度与钢铁公司历年粗钢产量及武汉市历年汽车保有量的变化程度相对应。通过对污染样品的磁滞回线、热磁曲线和SEM/EDX等矿物学分析,污染样品的矿物成分以磁铁矿和赤铁矿为主,以准单畴(PSD)颗粒存在,形貌特征和物质成分与成土过程中形成的磁性颗粒明显不同。由于土壤的电性与磁性都具有良好的污染程度指示作用,所以土壤的电性与磁性研究可以应用于土壤污染程度的评价,两者联合运用可大大提高土壤污染程度评价的分辨率。 相似文献
5.
Airborne gamma-ray and magnetic anomaly signatures of serpentinite in relation to soil geochemistry, northern California 总被引：2，自引：1，他引：1
Serpentinized ultramafic rocks and associated soils in northern California are characterized by high concentrations of Cr and Ni, low levels of radioelements (K, Th, and U) and high amounts of ferrimagnetic minerals (primarily magnetite). Geophysical attributes over ultramafic rocks, which include airborne gamma-ray and magnetic anomaly data, are quantified and provide indirect measurements on the relative abundance of radioelements and magnetic minerals, respectively. Attributes are defined through a statistical modeling approach and the results are portrayed as probabilities in chart and map form. Two predictive models are presented, including one derived from the aeromagnetic anomaly data and one from a combination of the airborne K, Th and U gamma-ray data. Both models distinguish preferential values within the aerogeophysical data that coincide with mapped and potentially unmapped ultramafic rocks. The magnetic predictive model shows positive probabilities associated with magnetic anomaly highs and, to a lesser degree, anomaly lows, which accurately locate many known ultramafic outcrops, but more interestingly, locate potentially unmapped ultramafic rocks, possible extensions of ultramafic bodies that dip into the shallow subsurface, as well as prospective buried ultramafic rocks. The airborne radiometric model shows positive probabilities in association with anomalously low gamma radiation measurements over ultramafic rock, which is similar to that produced by gabbro, metavolcanic rock, and water bodies. All of these features share the characteristic of being depleted in K, Th and U. Gabbro is the only rock type in the study area that shares similar magnetic properties with the ultramafic rock. The aerogeophysical model results are compared to the distribution of ultramafic outcrops and to Cr, Ni, K, Th and U concentrations and magnetic susceptibility measurements from soil samples. Analysis of the soil data indicates high positive correlation between magnetic susceptibilities and concentration of Cr and Ni. Although the study focused on characterizing the geophysical properties of ultramafic rocks and associated soils, it has also yielded information on other rock types in addition to ultramafic rocks, which can also locally host naturally-occurring asbestos; specifically, gabbro and metavolcanic rocks. 相似文献
6.
磁化率对土壤重金属污染的指示性研究——以沈阳新城子区为例 总被引：4，自引：0，他引：4
通过对399件表层土壤磁化率参数与化学组成的分析测试,较系统地总结了沈阳新城子区土壤磁化率特征,并初步进行了磁化率对土壤重金属污染的指示研究。结果表明:(1)不同土壤类型中磁化率差异较大,棕壤中由于人为作用较大,其均值最高。不同堆积类型中磁化率差别较大,洪积物和残坡积物中平均值最高,冲积物中最低。不同农作物对元素的需求不一样导致磁化率的含量变化范围存在着区别。(2)土壤的磁化率与土壤中Cd、Pb、Hg、Cu、Zn等重金属元素含量呈显著正相关,且与土壤pH值呈显著负相关关系,能反映出土壤酸化的状况,对土壤污染程度有较好的指示性。(3)利用磁化率可以快捷地划分污染区。 相似文献
7.
This investigation was carried out within the scope of EU-FP5 project MAGPROX. In parallel with the work of Kalinski et al. (2004, submitted), in which the magnetic signatures of the same soil profiles were analysed in more detail. The ‘hot spot’ under investigation was situated in the Lausitz area, Eastern Germany, between two major power plants, Schwarze Pumpe and Boxberg. This heavily industrialized region is known as the Black Triangle, named after the large lignite deposits and the old-technology power plants, among other petrochemical plants, refineries, textile manufacturing and glasswork industries. The relationship between magnetic parameters and heavy metal concentrations (Fe, Mn, Zn, Pb, Cu, Cr, Cd, Co and Ni) in soil profiles was determined statistically using linear regression analysis. Strong positive correlation was observed between heavy metal concentrations as viewed preliminarily from the heavy metal and magnetic susceptibility distributions with depth (soil profiles), and from the correlation coefficients obtained.MAGPROX team–FP5 RTD Project No. EVK2-CT-1999-00019 相似文献
8.
This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from cul-tivated farmlands in and around the mine, the unmineralized site and a nearby forest (the control site). The samples were analyzed for heavy metals (Fe, Zn, Mn, Cu, Pb, Cr and Cd) by Atomic Absorption Spectrophotometry (AAS). The physical properties of soils (pH and LOI) were also measured. Results showed that soils from cultivated farm-lands have neutral pH values (6.5-7.5), and low organic matter contents (10%). Levels of Zn, Pb and Cd in culti-vated soils were higher than the concentrations obtained from the control site. These heavy metals are most probably sourced from mining and agricultural activities in the study area. Heavy metal concentrations measured in plant parts decreased in the order of rice leavescassava tuberspeelings. In the same plant species, metal levels decreased in the order of ZnFeMnCuPbCrCd. Most heavy metals were found in plant parts at average concentrations normally observed in plants grown in uncontaminated soil, however, elevated concentrations of Pb and Cd were found in a few cassava samples close to the mine dump. A stepwise linear regression analysis identified soil metal contents, pH and LOI as some of the factors influencing soil-plant metal uptake. 相似文献
9.
石英尾砂对旱地表土磁性的影响及其环境意义 总被引：1，自引：0，他引：1
对安徽省凤阳县石英尾砂、受尾砂影响的表土、旱地表土和城镇表土进行了磁学测量,结果表明这4类样品的磁性特征明显不同。尽管这4类样品的磁化率均由磁铁矿主导,但旱地表土中可能含少量磁赤铁矿,石英尾砂、受尾砂影响的表土和城镇表土中可能含少量铁的氢氧化物（如纤铁矿）,受尾砂影响的表土中还含少量赤铁矿。城镇表土中磁铁矿的含量明显高于其他3类样品,受尾砂影响的表土中的磁铁矿含量介于石英尾砂和旱地表土之间。城镇表土中磁铁矿的粒径范围较宽,小于1 μm,石英尾砂中磁铁矿的粒径大于0.1 μm,旱地表土中磁铁矿的粒径小于0.1 μm,受尾砂影响的表土中磁铁矿的粒径介于旱地表土与石英尾砂的粒径之间。城镇表土的磁化率与频率磁化率呈负相关,旱地表土的磁化率与频率磁化率呈正相关,而受石英尾砂影响的表土的磁化率与频率磁化率没有明显的相关关系。在城市工业和交通等人类活动的影响下,城镇表土的磁性较旱地表土增强。而在石英砂生产这一人类活动的影响下,受尾砂影响的表土的磁性较旱地表土减弱,这是由石英尾砂中磁性矿物的含量较旱地表土4的少所致。 相似文献
10.
Geophysical methods are widely applied to soils for resolving different tasks in precision agriculture, pollution evaluation, erosion estimation, etc. Environmental magnetic methods were applied in our study on a collection of soil samples from area near Rosslau (Germany), which was gathered on the basis of a field electromagnetic induction study. Magnetic laboratory analyses include magnetic susceptibility, isothermal remanent magnetization (IRM), anhysteretic remanent magnetization (ARM), thermomagnetic analyses for determination of the kind of magnetic minerals present in soils. The results reveal the presence of statistically significant inverse correlations between magnetic susceptibility, as well as remanent magnetizations ARM and IRM, and conductivity values. This maybe ascribed to influence of topography and water regime on the iron oxide forms in soil and the influence of soil moisture on soil conductivity. Magnetic measurements on soil cores showed close correspondence between soil horizons outlined in 1 m-long cores, and depth changes in mass-specific magnetic susceptibility. Existing relationships between magnetic characteristics, soil reaction pH, and nutrients’ content (total nitrogen, carbon and sulphur) have been explored by cluster analysis and general regression model statistics. The results reveal the presence of significant correlations between nutrients’ content, magnetic susceptibility and the grain size sensitive ratio ARM/χ. These are expressed by numerical equations, representing pedotransfer functions, which predict the content of Nitrogen, Carbon and Sulphur through combination of magnetic parameters and soil pH. The obtained pedotransfer functions for the particular case of Gley soils and Fluvisols studied could be used for application of magnetic methods in agricultural practice as a fast and inexpensive proxy evaluation of the content of these nutrition elements. 相似文献
11.
《Physics and Chemistry of the Earth, Part A: Solid Earth and Geodesy》2000,25(5):431-436
Temporal stability of magnetic parameters of anthropogenic ferrimagnetics in model soil conditions was studied. Fly ash from a power plant was used as original contaminant material, while soil reactive medium was modeled by different soil solutions. Changes in mass-specific magnetic susceptibility (χ), percentage frequency dependent magnetic susceptibility (χFD%), hysteresis parameters and thermomagnetic curves were measured for samples which underwent different leaching time periods. Virtually constant magnetic susceptibility values were obtained, independently on the soil medium (acid, neutral). On the other hand, the original highly non-stoichiometric maghemite phase rapidly transformed to stable magnetite. In some cases (model of free-draining soils) further decrease of Curie temperature (Tc) to 550–560°C is observed. 相似文献
12.
Changes in magnetic and chemical properties of soil during the growth of tomato plants (Lycopersicon esculentum) are examined in this study. The synthetic soils, prepared from sand, topsoil and organic material, were treated with magnetite
powder (<5 μm) in order to simulate metal contamination. Six soil treatments were prepared from two soil types: controls,
low-contamination and high-contamination treatments (0.01 and 0.05 g of magnetite powder/kg soil, respectively). Overall,
the contaminated soils had a greater decrease in magnetic susceptibility (MS) than the controls, and the difference in MS
decrease between the treatments was found to be statistically significant for both soil types. Potential reasons for the overall
MS decrease were explored, and among them, trace element uptake by plants probably had a minor contribution as the concentration
differences of Fe and other trace elements (Ni, Mn) between treatments were not statistically significant. In soils, oxidized
and weakly magnetic minerals (maghemite, goethite and hematite) were common after plant growth, when compared with the untreated
(background) soil. Such mineral transformations could have contributed to the overall MS decrease. The results show that exposure
to Fe contaminants can affect plant growth and suggest that plant growth can measurably change the magnetic properties of
their growth media. While the potential variables affecting plant growth were controlled as much as possible, there still
remains the potential that biotic and abiotic chemical reactions could have affected the results. Thus, continuous monitoring
of the changes in soil magnetic and chemical properties in more complex soil–plant systems is needed. 相似文献
13.
Magnetic susceptibility measurements were conducted on 24 vibrocores obtained from an area located off the northeastern coast
of Lantau Island in Hong Kong. High intensities of magnetic susceptibility were detected in the uppermost sections of the
majority of the cores. Several magnetic parameters measured for one of the cores suggest that the variations in the magnetic
characteristics over depth are mainly due to varying concentrations of the magnetic minerals. Since a strong correlation has
been found between magnetic susceptibility and the heavy metals Pb, Cu, Zn and Cr, an anthropogenic contamination origin is
thought to be the cause. The present study shows that magnetic susceptibility is a fast, inexpensive and non-destructive method
for the detection and mapping of contaminated sediments.
Received: 12 August 1997 · Accepted: 18 November 1997 相似文献
14.
武汉市东湖沉积物的磁性特征与重金属含量之间的关系 总被引：6，自引：0，他引：6
对武汉市东湖主湖区的郭郑湖和塘林湖114个沉积物样品的磁化率与代表性样品的频率磁化率系数、磁滞回线参量和重金属元素进行系统分析, 综合区域环境背景, 探讨应用岩石磁性方法技术评价大型城市内陆湖泊沉积物污染程度的可行性及其效果.结果表明, 在主成分中, 郭郑湖沉积物没有一个主成分占绝对优势, 仅有少数重金属元素含量与磁化率相关, 磁化率χ与重金属富集强度的相关性较差; 而塘林湖沉积物有一个“工业源”的主成份占绝对优势, Fe (全铁)、Co、V、Mn、Ti、Ba、Cr、Ni、Cu等元素与饱和等温剩磁SIRM、χ关系密切(相关系数大于0.87).郭郑湖与塘林湖的沉积物的饱和等温剩磁与重金属富集强度的相关程度高于磁化率, 因此, 可以用其(SIRM) 作为环境污染程度的指示参量. 相似文献
15.
Field and dual magnetic susceptibility proxies for heavy metal pollution assessment in the urban soil of Al-Karak City, South Jordan 总被引：1，自引：1，他引：0
A total of 115 urban soil samples collected on grid bases from Al-Karak, South Jordan, were investigated for their field and dual-frequency magnetic susceptibility (χ field, χ d) and heavy metal content using Bartington susceptibility meters and ICP-MS. The upper soils have higher magnetic susceptibility values than lower soils, and large particles contain more heavy metals and higher magnetic susceptibility than smaller particles. This might be attributed to the lack of pedogenesis due to arid climate influence. Within the upper soil all heavy metal showed positive significant correlation with upper soil low-frequency χ dlf. This was evident from the distribution maps produced by Surfer 9.0 for χ dlf and heavy metals. The results showed that higher χ dlf is associated with traffic-dominated sites more than other areas. The frequency-dependent susceptibility (χfd %) falls between 2 and 10 %, which indicate the presence of admixture of fine supermagnetic particles. Mildly correlation exists between χfd % and χ dlf, which implies that soils contain anthropogenic multi-domain grains. Selected samples have been analyzed for their mineral constituents; the results indicate the presence of magnetite as the main magnetic mineral. This confirms the anthropogenic source of pollution mainly from the vehicle-related materials. The results indicate the applicability of magnetic susceptibility for pollution detection. 相似文献
16.
A soil and vegetation survey was undertaken in NW Euboea Island, Greece. The objectives of the study were to establish the geochemical baseline of soil and identify the impact of local geology on threshold values of potentially harmful elements. The studied area is characterized by complex geology comprising metamorphic and ultramafic rocks as well as active hot springs. A total of 117 soil samples were collected from 89 sites at depths of 0–25 cm and 25–50 cm. Eighteen vegetation samples were also collected representing prevalent indigenous perennial species in the region. Soil samples from the present study were enriched in As, Ca, Cu, Mg, Ni with concentrations reaching 233 mg/kg, 38%, 336 mg/kg, 10.8%, 1560 mg/kg respectively. Factor analysis revealed three main factors controlling the chemical composition of soil reflecting the influence of ultramafic rocks (Cr, Ca, Mg, Ni), hot spring deposits (Ca, S, Sr, As) and paedogenesis processes (Fe, Co, V, Mn, Al). The first two of these factors showed significant spatial correlation with the geological features within the study area. Subsequently, baseline concentrations based on statistical and spatial data were estimated within sub-areas reflecting the influence of local geology in soil composition. Concentrations of potentially harmful elements in the plant tissues of indigenous perennial vegetation species showed a wide range of variation from below the detection limit up to 1700 mg/kg for Ni in the hyperaccumulator Alyssum chalcidicum demonstrating that plant species have adapted to the stressful conditions caused by high elemental concentrations in soil. The results of this study can be utilized in future studies at areas of similar geology by providing an objective basis for setting realistic threshold values for pollution assessment and remediation. 相似文献
17.
A. Cachada S. M. Rodrigues C. Mieiro E. Ferreira da Silva E. Pereira A. C. Duarte 《Environmental Geology》2009,57(1):91-98
This study aims at assessing the extent of total mercury (Hg) contamination in urban and agricultural soils under long-term
influence of a chlor-alkali plant, located at about 1 km away from a town centre. Moreover, it aims at identifying the main
factors controlling Hg contents’ distribution and associated potential hazards to environment and human health. The median
value of total Hg for soil surface layer (0–10 cm) was 0.20 mg/kg (data ranging from 0.050 to 4.5 mg/kg) and for subsurface
layer (10–20 cm) 0.18 mg/kg (data ranging from 0.046 to 3.0 mg/kg). The agricultural area showed higher Hg concentrations
(ranging from 0.86 to 4.5 mg/kg) than urban area (ranging from 0.05 to 0.61 mg/kg), with some results exceeding target values
set by the Dutch guidelines. Mercury concentrations observed in the studied area are more likely to be associated with the
influence of the chlor-alkali plant and with the use of historically contaminated sludges and water from a nearby lagoon in
agriculture, than to the impacts of urban development. The statistical correlations between Hg concentrations and soil properties
suggest that anthropogenic metal sources should influence the spatial distribution more than the geological properties. Although
the Hg emissions were drastically reduced 10 years ago, the area under influence of the chlor-alkali plant is still facing
potential health and environmental threats arising from soil contamination. 相似文献
18.
19.
磁化率是环境磁学研究中较常用、较易获得的指标之一,但其解释和意义又最为复杂.对采自中国东部从北到南涵盖中国主要气候带的风化-成壤成因的79个表层土壤样品进行高、低频磁化率和非磁滞剩磁测试并分析其与降水量、年均温等气候参数的关系.结果表明:(1)发育于不同类型母岩的风化-成壤成因表层土壤磁学性质之间存在显著差异,各磁化率参数与气候条件参数之间的关系大不一样,在大空间尺度进行磁学与气候条件的关系研究时,必须充分考虑地质背景与母岩类型的差异.(2)发育于花岗岩的表层土壤非磁滞剩磁磁化率与年降水量和年均温间呈显著负相关关系;而发育于玄武岩的表层土壤非磁滞剩磁磁化率与年降水量呈显著正相关关系.被广泛认可的黄土-古土壤序列磁化率与成壤的关系不一定适用于大空间尺度的其他气候区域.(3)在风化-成壤过程中,磁性颗粒有变细的趋势,但降水强度增大时,一些超细颗粒较易被搬运离开原地,单一磁学参数结果难以反映气候条件及环境变化.(4)风化-成壤成因表层土壤非磁滞剩磁磁化率能较好地反映风化成因土壤的风化程度,但风化-成壤表层土壤磁学性质变化的机制特别是对相应土壤剖面的磁性矿物迁移转化有待深入研究. 相似文献
20.
基于港珠澳大桥、深中通道、虎门大桥等工程的精细化勘察成果,分析了珠江口地区岩土层地质特性,区内岩土层可划分为淤泥质软土层、黏土粉质黏土层、中粗砂层、残积土层、不同程度风化基岩共5大层,结合区内水动力环境、沉积物类型、钻孔对比及地质剖面,将研究区划分为河口砂质沉积区、潮流型泥质沉积区、泥砂混合沉积区、浅海泥砂混合沉积区等4类。珠江口地区岩土层的物性参数特征研究表明,随着深度增大,岩土层含水率降低,快剪黏聚力增大,压缩系数减小,压缩模量增大;原状土十字板抗剪强度Cu与软土含水率w呈幂函数相关,与压缩模量Es、快剪黏聚力c呈线性正相关;孔压静力触探试验比贯入阻力ps与含水率w呈对数相关,与压缩系数a1?2呈幂函数相关,与黏性土、砂类土的快剪黏聚力c呈线性正相关,得到的经验公式可为珠江口地区类似场地工程建设提供参考。 相似文献