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1.
This work consists in estimating the role of climatic conditions in the degradation of two French limestones, tuffeau and Richemont stone, used in the construction and the restoration of the Castle of Chambord, the largest castle in the Loire Valley, France. Meteorological data, air temperature, air relative humidity and rainfall were statistically analysed in combination with stone data from thermal–humidity sensors inserted into the walls. The climatic conditions of the surrounding area were described to assess their role in enhancing the degradation of the stones through three weathering processes: thermal stress, condensation and freezing–thawing. The damage risks due to the weathering processes were taken into account not only through the bulk effects on the stone surfaces, but also their effects were extended to investigate the damage that occurs within the porous structure of the stone. Field observations showed that the main patterns of degradation affecting the stones of the castle are biological colonization and stone detachment in the form of stone spalling and exfoliation. The results of the analysis show that there is no risk of damage to the stones due to thermal stress. Moreover, the two stones experience similar overall trends against freezing–thawing processes. Finally, this study clearly highlights the important role of condensation in the degradation of the stones of the castle.  相似文献   

2.
Kerogen is an important organic matter fraction widely spread in soils and sediments. It plays a major role in the sorption and sequestration of hydrophobic organic contaminants （HOCs） such as trichlorobenzene （TCB）. It is known that kerogen is geochemically heterogeneous due to the differences in source materials and diagenesis history. We hypothesized that kerogen derived from different source materials and diagenetic history exhibits different sorption properties for TCB. We employed two different kerogen materials （coals） as the original materials and two series of kerogen for a given series with an identical source material but different alteration history were yielded through thermal treatment at temperature ranging from 200 to 500℃. The original and treated materials were characterized for their physicochemical properties. Sorption experiments were conducted with batch reactor systems using 1, 3, 5-TCB as the HOCs sorbates and the original and treated materials as the sorbents.  相似文献   

3.
1 Introduction Because clay minerals have the characteristics ofadsorption, ion exchange capability and expandingcapacity, they are highly capable of adsorbing allkinds of pollutants in waters, thus making soilspossess self-purification functions. Clay m…  相似文献   

4.
The stress-strain behaviour and mechanical properties were investigated on rocksalt samples collected from Guma rocksalt Mine, District Mandi, Himachal Pradesh, India. Cylindrical samples cored perpendicular to the bedding planes, were compressed using an automated closed loop servo-controlled testing machine at stress rates ranging from 9.12×10−3 MPa/minute to 9.12 MPa/minute. The effects of stress rate on stress-strain behaviour as well as on mechanical properties were investigated by controlling the time of deformation. The stress-strain behaviour of rocksalts were verified by theoretical analysis with the help of the derivation of equations for Maxwell and Kelvin-Voigt Models connected in series.  相似文献   

5.
A series of strontium- and barium-doped alumina samples were prepared by hydrolysis, in neutral medium, starting from commercial Al2O3, SrCO3, and BaCO3 materials. The precursors thus obtained were calcined under air at 700 °C; then, the bulk and surface properties of the resulting mixed oxides were characterized by nitrogen physisorption, X-ray diffraction (XRD), hydrogen temperature-programmed reduction (H2-TPR), thermogravimetry (TGA), and differential thermal analysis (DTA). Contrary to SrCO3, an addition of BaCO3 to α-Al2O3 increases slightly the specific surface area. XRD patterns essentially reveal the characteristic reflections assigned to α-Al2O3. In agreement with TGA and XRD analysis, strontium and barium carbonates remain after calcination at 700 °C, their decomposition starting above 800 °C. Let us note that this decomposition occurs more readily on AlSr-100 than on AlBa-100 with no apparent relationship with the evolution observed on the specific surface areas. H2-TPR experiments underline a significant bulk reduction of barium and strontium carbonates taking place significantly above 900 °C with similar trend noticed during TGA regarding their thermal decomposition. However, the most relevant observation is related to a sharp enhancement of the reducibility of AlSr-y with the appearance two reduction ranges highlighting the existence of different types of interactions with strontium and the alumina substrate.  相似文献   

6.
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7.
On the basis of researches over several years on biostratigraphy of Changhsingian at Meishan Section D in Changxing County, the abundant materials were accumulated. This paper studies the escostratigraphy and establishes 7 community zones (CZ), in ascending order, Sinoplatysomus-Gernitzina-Clarkina subcarinata, Tapashanites-Nodosaria-Clarkina subcarinata,Crurithyris-Geinitzina-Clarkina subcarinata,Glomospira-Clarkina changxingensis, Colaniella-Clarkina changxingensis,Rotodiscoceras-Palaeofusulina-Hindeodus typicalis,Clarkina meishanensis-Hypophiceras.The habitat type (HT) is diffent from upper shallow sea to the lower part of the lower shallow sea.  相似文献   

8.
KAN Jing  YANG Bin 《地质学报》2014,88(Z2):86-87
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9.
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10.
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11.
The Gandise massif in Tibet, China, is one of the most important copper-multimetal metallogenic belt of Tibet region( Hou, et al,2001 ; Qu, et al, 2001 ;  相似文献   

12.
A better understanding of how hydrocarbons and other fluids such as brine move in the reservoirs within the Kov Field will enable the improved application of secondary recovery methods such as water and gas injections and also highlight areas within the field that have remaining hydrocarbons. This work focuses on the two major sandstone reservoir intervals, the AG-I and the AG-II all within the Agbada Formation, since they showed prominent amplitude changes. In the AG-I Formation, the results obtained from the production data and rock physics modeling show an increase in the amplitude impedance (AI) contrast around injection wells and a decrease in AI contrast around production wells due to fluid replacement, and it also deals with the pressure changes in correlation to the water injection performed to maintain the reservoir pressure, while in the AG-II Formation, the effect of hydrocarbon production serves to visualize and map the oil-water contact (OWC) as it evolves with the production time; the OWC is not observable on later seismic vintages because the reservoir drops below the OWC. Conclusively, the effect of hydrocarbon production throughout the reservoir and across the entire Field would be beneficial in mapping fluid changes in the Kov Field, which can be utilized for enhanced oil recovery and improved reservoir management.  相似文献   

13.
This preliminary work reported here dealt with potential impacts of wastewater irrigation on soils and crops sampled along the Koshk River canal in the suburban area of Shiraz City, Iran. It also attempts to assess the extent of heavy metal contamination in soils and crops and human exposure risk. For this purpose, samples including soils and plants were collected from two wastewater irrigated sites and a tubewell-irrigated site （marked by A, B and C）. Concentrations of the six heavy metals Ni, Pb, Cd, Zn, Cr and Cu were determined by AAS. Physical and chemical properties of soil samples were also determined. The PLIs and CF for soils and HQ （Hazard quotient） for some vegetables were calculated. The results showed that organic matter content increased from 22% to 30 % in wastewater-irrigated soils as compared to tubewell water irrigated and admixture water irrigated ones. The soil pH was raised by 2 units as a result of wastewater irrigation at site A compared to sites B and C. Wastewater irrigation also result in relatively high concentrations of Ni, Pb and Zn （275.5, 441.3 and 177 mg/kg, respectively） in wastewater irrigated soils over tubewell water irrigated soils. These levels are higher than the maximum permissible limits in unpolluted soils, indicating that a degree of contamination has occurred. This was confirmed by calculated PLIs and contamination factors in soil samples, The results also showed some crops cultivated at sites A and B contained high levels of Ni and Cd beyond the maximum permissible concentrations and those cultivated at site C. The concentrations of these heavy metals are within or very close to the critical levels. HQ indices and daily intake calculated in respect of metal contents in some vegetables （spinach, lettuce and celery） showed that toxic risk due to Cd in these vegetables and crops was greater than one. This study generally concludes that although the content of heavy metals did not reach toxic level, extensive use of untreated wastewater drawn from the Koshk River has obviously increased the contamination of Ni and Pb in soils and Cd in some vegetables cultivated along the canal, causing potential health risk in the long-term scense for consumers or local residents.  相似文献   

14.
The Blato aquifer is situated on the western side of the island of Korčula, southern Dalmatia, Croatia. The terrain is built of karstified carbonate rocks, mostly of the Cretaceous age. In the Blatsko karst polje there are four water supply wells with a total yield of about 60 l/s. The catchment area is 28 km2. The whole terrain is tectonically disturbed and compressed; the most permeable fracture system is perpendicular to the structural “b” axes, which gives rise to a general groundwater direction towards the island’s northern coast. Average precipitation is 850 mm/year, but when there is less than 700 mm/year there is a high possibility of sea-water intrusion during the summer season. The risk significantly increases when dry years repeat. Hydrochemical research has shown that two main pollution sources occur at different hydrological moments: sea-water intrusion happens in the dry summer period when there is maximal extraction and almost no recharge; and the washing of nitrates and other humanly caused pollution indicators from the soil and epikarst belt during the rainy season. All factors must be taken into account when planning management and protection of such a sensitive environment.  相似文献   

15.
Late Quaternary stratigraphy and sedimentation in the Middle Ganga Plain (MGP) (Uttar Pradesh–Bihar) have influenced groundwater arsenic contamination. Arsenic contaminated aquifers are pervasive within narrow entrenched channels and flood plains (T0-Surface) of fine-grained grey to black coloured argillaceous organic rich Holocene sediments (Newer Alluvium). Contaminated aquifers are often located close to distribution of abandoned or existing channels and swamps. The Pleistocene Older Alluvium upland terraces (T2-Surface) made up of oxidized yellowish brown sediments with calcareous and ferruginous concretions and the aquifers within it are free of arsenic contamination. MGP sediments are mainly derived from the Himalaya with minor inputs from the Peninsular India. The potential source of arsenic in MGP is mainly from the Himalaya. The contaminated aquifers in the Terai belt of Nepal are closely comparable in nature and age to those of the MGP. Arsenic was transported from disseminated sources as adsorbed on dispersed phases of hydrated-iron-oxidea and later on released to groundwater mainly by reductive dissolution of hydrated-iron-oxide and corresponding oxidation of organic matter in aquifer. Strong reducing nature of groundwater is indicated by high concentration of dissolved iron (11.06 mg/l). Even within the arsenic-affected areas, dugwells are found to be arsenic safe due to oxyginated nature.  相似文献   

16.
Groundwater arsenic survey in Cachar and Karimganj districts of Barak Valley, Assam shows that people in these two districts are drinking arsenic-contaminated (max. 350 μg/l) groundwater. 66% of tubewells in these two districts have arsenic concentration above the WHO guideline value of 10 μg/l and 26% tubewells have arsenic above 50 μg/l, the Indian standards for arsenic in drinking water. 90% of installed tubewells in these two districts are shallow depth (14–40 m). Shallow tubewells were installed in Holocene Newer Alluvium aquifers are characterised by grey to black coloured fine grained organic rich argillaceous sediments and are mostly arsenic contamination in groundwater. Plio-Pleistocene Older Alluvium aquifers composed of shale, ferruginous sandstone, mottle clay, pebble and boulder beds, which at higher location or with thin cover of Newer Alluvium sediments are safe in arsenic contamination in groundwater. 91% of tubewell water samples show significantly higher concentrations of iron beyond its permissible limit of 1 mg/l. The iron content in these two districts varies from 0.5 to as much as 48 mg/l. Most of the arsenic contaminated villages of Cachar and Karimganj districts are located in entrenched channels and flood plains of Newer Alluvium sediments in Barak-Surma-Langai Rivers system. However, deeper tubewells (>60 m) in Plio-Pleistocene Older Alluvium aquifers would be a better option for arsenic-safe groundwater. The arsenic in groundwater is getting released from associated Holocene sediments which were likely deposited from the surrounding Tertiary Barail hill range.  相似文献   

17.
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18.
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19.
This paper describes the application of magnetotelluric (MT) method to investigate Björkö impact structure located at west of Stockholm, Sweden. This structure has formed in crystalline rocks ca. 1.2 Ga ago and located relatively close to the district heating infrastructure of the Stockholm region, as the largest district heating system in Europe. Since impact structures mostly contain fractured rock volumes in the form of breccia formations, the occurred brecciation zones in this region are more favorable potential targets for geothermal investigations. The main objective is evaluating the capability of the study area to have potential for geothermal resources by mapping the subsurface structure. To image electrical characteristic of underground layers, 1D and 2D bimodal inversions of TE and TM modes of MT data are performed. The results are also compared with the outputs of the inversion of the determinant data (yielding a direction-independent average of the subsurface conductivity) along the same profiles, proving good accordance of the outputs. The processed resistivity sections at depth along with measuring various rock physical properties across two drilled boreholes at Björkö and Midsommar islands localized two conductors at depths of 1 km and from 2.5 to 4.5 km, which may be attributed to be a potential zone for geothermal energy retrieval.  相似文献   

20.
This study presents a chronology of historical and measured flood events in the Papaloapan River basin of Mexico during 450 years. Twenty-eight historical floods were recorded during the period 1550–1948 on this river and one flood event (1969) in the instrumental era (1949–2000), of which 14 were extraordinary floods and only 15 were catastrophic ones. There were several flood-rich decades during 1860–1870, 1880–1890, 1920–1930 and 1940–1950. Wavelet analysis found a significant flooding periodicity of 58 years. The wavelet coherence analysis found that flooding had an in-phase relationship with the Atlantic Multidecadal Oscillation and also with the Pacific Decadal Oscillation. Logistic regression corroborated that there exists a positive relationship between floods events and these two natural climatic oscillations. The logistic regression model predicted correctly 92% of flood events.  相似文献   

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