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1.
The kimberlites of the Kharamai field intruded through the Siberian Traps shortly after their eruption in Permo-Triassic time. The composition and thermal state of the subcontinental lithospheric mantle (SCLM) beneath the Kharamai field in lower Triassic time have been reconstructed using major- and trace-element analyses of 345 Cr-pyrope garnet xenocrysts from six of the kimberlites, supplemented by a small suite of mantle-derived peridotite xenoliths. The data define a geotherm lying near a 38 mW/m2 conductive model to a depth of ca 170 km, where the base of the depleted lithosphere is defined by a marked increase in melt-related metasomatism and by an inflected geotherm. Compared to the SCLM sampled by Devonian (pre-Trap) kimberlites in the same and adjacent terranes, the Kharamai SCLM in Triassic time was warmer and was cooling from a previous thermal high. It was also thinner than the SCLM beneath the Daldyn and Alakit kimberlite fields, and had been strongly metasomatised. The metasomatism lowered the mean Fo content of olivine (from ≥Fo93 to Fo92), greatly reduced the proportion of subcalcic harzburgites, and increased the proportion of fertile lherzolites, especially in the depth range of 80–130 km. The overall pattern of metasomatism is similar to that observed in the SCLM sampled by the Group I kimberlites of the SW Kaapvaal Craton, and inferred to be related to the Karoo thermal event. These observations suggest that events such as the eruption of the Karoo basalts and Siberian Traps change the composition of the SCLM, but do not necessarily destroy it, at distances of several hundred kilometres from the main eruption centres.  相似文献   

2.
This study examines the major element composition of mantle-derived garnets recovered from heavy mineral concentrates of several Proterozoic kimberlites of the diamondiferous Wajrakarur Kimberlite Field (WKF) and the almost barren Narayanpet Kimberlite Field (NKF) in the Eastern Dharwar Craton of southern India. Concentrate garnets are abundant in the WKF kimberlites, and notably rare in the NKF kimberlites. Chemical characteristics of the pyropes indicate that the lithology of the sub-continental lithospheric mantle (SCLM) beneath both the kimberlite fields was mainly lherzolitic at the time of kimberlite eruption. A subset of green pyropes from the WKF is marked by high CaO and Cr2O3 contents, which imply contribution from a wehrlitic source. The lithological information on SCLM, when studied alongside geobarometry of lherzolite and harzburgite xenoliths, indicates that there are thin layers of harzburgite within a dominantly lherzolitic mantle in the depth interval of 115–190 km beneath the WKF. In addition, wehrlite and olivine clinopyroxenite occur locally in the depth range of 120–130 km. Mantle geotherm derived from xenoliths constrains the depth of graphite–diamond transition to 155 km beneath the kimberlite fields. Diamond in the WKF thus could have been derived from both lherzolitic and harzburgitic lithologies below this depth. The rarity of diamond and garnet xenocrysts in the NKF strongly suggest sampling of shallower (<155 km depth) mantle, and possibly a shallower source of kimberlite magma than at the WKF.  相似文献   

3.
The diamondiferous Letlhakane kimberlites are intruded into the Proterozoic Magondi Belt of Botswana. Given the general correlation of diamondiferous kimberlites with Archaean cratons, the apparent tectonic setting of these kimberlites is somewhat anomalous. Xenoliths in kimberlite diatremes provide a window into the underlying crust and upper mantle and, with the aid of detailed petrological and geochemical study, can help unravel problems of tectonic setting. To provide relevant data on the deep mantle under eastern Botswana we have studied peridotite xenoliths from the Letlhakane kimberlites. The mantle-derived xenolith suite at Letlhakane includes peridotites, pyroxenites, eclogites, megacrysts, MARID and glimmerite xenoliths. Peridotite xenoliths are represented by garnet-bearing harzburgites and lherzolites as well as spinel-bearing lherzolite xenoliths. Most peridotites are coarse, but some are intensely deformed. Both garnet harzburgites and garnet lherzolites are in many cases variably metasomatised and show the introduction of metasomatic phlogopite, clinopyroxene and ilmenite. The petrography and mineral chemistry of these xenoliths are comparable to that of peridotite xenoliths from the Kaapvaal craton. Calculated temperature-depth relations show a well-developed correlation between the textures of xenoliths and P-T conditions, with the highest temperatures and pressures calculated for the deformed xenoliths. This is comparable to xenoliths from the Kaapvaal craton. However, the P-T gap evident between low-T coarse peridotites and high-T deformed peridotites from the Kaapvaal craton is not seen in the Letlhakane xenoliths. The P-T data indicate the presence of lithospheric mantle beneath Letlhakane, which is at least 150 km thick and which had a 40mW/m2 continental geotherm at the time of pipe emplacement. The peridotite xenoliths were in internal Nd isotopic equilibrium at the time of pipe emplacement but a lherzolite xenolith with a relatively low calculated temperature of equilibration shows evidence for remnant isotopic disequilibrium. Both harzburgite and lherzolite xenoliths bear trace element and isotopic signatures of variously enriched mantle (low Sm/Nd, high Rb/Sr), stabilised in subcontinental lithosphere since the Archaean. It is therefore apparent that the Letlhakane kimberlites are underlain by old, cold and very thick lithosphere, probably related to the Zimbabwe craton. The eastern extremity of the Proterozoic Magondi Belt into which the kimberlites intrude is interpreted as a superficial feature not rooted in the mantle. Received: 19 March 1996 / Accepted: 16 October 1996  相似文献   

4.
Mantle xenoliths in within-plate Cenozoic alkaline mafic lavas from NE Spain are used to assess the local subcontinental lithospheric mantle geotherm and the influence of melting and metasomatism on its oxidation state. The xenoliths are mainly anhydrous spinel lherzolites and harzburgites and gradations between, with minor pyroxenites. Most types show protogranular textures, but transitional protogranular–porphyroclastic and equigranular lherzolites also exist. Different thermometers used in the estimates provide higher subsolidus equilibrium temperatures for harzburgites (1,062 ± 29°C) than for lherzolites (972 ± 89°C), although there is overlap; the lowest temperatures correspond to porphyroclastic lherzolites, whereas pyroxenites give the highest temperatures (up to 1,257°C). Maximum pressures for subsolidus equilibrium of peridotites are at 2.0–1.8 GPa. Later they followed adiabatic decompression and harzburgites registered lower pressures (1.02 ± 0.19 GPa) than lherzolites (1.41 ± 0.27 GPa). One pyroxenite gives values consistent with the spinel lherzolite field (1.08 GPa). The shallowest barometric data are in agreement with the highest local conductive geotherms, which implies that the lithosphere–asthenosphere boundary is at 70–60 km minimum depth. Higher equilibrium temperatures for the harzburgites could be explained by the existence of mafic magma bodies or dykes at the lower crust–mantle boundary. Paleo-fO2 conditions during partial melting as inferred from the covariation between V and MgO concentrations are mainly between QFM−1 and QFM−2 in log units. However, most thermobarometric fO2 estimates are between QFM−1 and QFM+1, suggesting oxidation caused by later metasomatism during uplift and cooling.  相似文献   

5.
Mantle xenoliths entrained in Quaternary alkaline basalts from the Turkana Depression in southern Ethiopia (the East Africa Rift) were studied for their geochemical and Sr–Nd–Pb isotopic compositions to constrain the evolution of the lithosphere. The investigated mantle xenoliths are spinel lherzolites in composition with a protogranular texture. They can be classified into two types: anhydrous and hydrous spinel lherzolites; the latter group characterized by the occurrences of pargasite and phlogopite. The compositions of whole-rock basaltic component (CaO = 3.8–5.6 wt%, Al2O3 = 2.5–4.1 wt%, and MgO = 34.7–38.1 wt%), spinel (Cr# = 0.062–0.117, Al2O3 = 59.0–64.4 wt%) and clinopyroxene (Mg# = 88.4–91.7, Al2O3 = 5.2–6.7 wt%) indicate that the lherzolites are fertile and have not experienced significant partial melting. Both types are characterized by depleted 87Sr/86Sr (0.70180–0.70295) and high 143Nd/144Nd (0.51299–0.51348) with wide ranges of 206Pb/204Pb (17.86–19.68) isotopic compositions. The variations of geochemical and isotopic compositions can be explained by silicate metasomatism induced by different degree of magma infiltrations from ascending mantle plume. The thermobarometric estimations suggest that the spinel lherzolites were derived from depths of 50–70 km (15.6–22.2 kb) and entrained in the alkaline magma at 847–1,052°C. Most of the spinel lherzolites from this study record an elevated geotherm (60–90 mW/m2) that is related to the presence of rising mantle plume in an active tectonic setting. Sm–Nd isotopic systematic gives a mean TDM model age of 0.95 Ga, interpreted as the minimum depletion age of the subcontinental lithosphere beneath the region.  相似文献   

6.
Low-Ca garnet harzburgite xenoliths contain garnets that are deficient in Ca relative to those that have equilibrated with diopside in the iherzolite assemblage. Minor proportions of these harzburgites are of wide-spread occurrence in xenolith suites from the Kaapvaal craton and are of particular interest because of their relation to diamond host rocks. The harzburgite xenoliths are predominantly coarse but one specimen from Jagersfontein and another from Premier have deformed textures similar to those of high-temperature peridotites. Analyses for many elements in the harzburgites and associated iherzolites form concordant overlapping trends. On the average, however, the harzburgites are deficient in Si, Ca, Al and Fe but enriched in Mg and Ni relative to the lherzolites. Both the harzburgites and lherzolites are enstatite-rich with mg numbers [100.Mg/(Mg+Fetotal)] greater than 92 and in these respects differ markedly from residues generated by extraction of MORB. Equilibration temperatures and depths calculated for the harzburgites have the ranges 600–1,400°C and 50–200 km. Those of deepest origin overlap the interval between low-and high-temperature lherzolites that commonly is observed in temperature-depth plots for the Kaapvaal craton, suggesting that some harzburgites may be concentrated relative to lherzolites at the base of the lithosphere. The low-Ca harzburgites and lherzolite xenoliths have overlapping depths of origin, gradational bulk chemical characteristics and similar textures, and therefore both are believed to have formed as residues of Archaen melting events. The harzburgites differ from the lherzolites only in that they are more depleted. Garnets and associated minerals in harzburgite xenoliths differ from minerals of the same assemblage that are included in diamonds in that the latter are more Cr-rich, Mg-rich and Ca-poor. Coarse crystals of low-Ca garnet with the compositional characteristics of diamond inclusions commonly occur as disaggregated grains in diamondiferous kimberlites. Their host rocks are presumed to have been harzburgites and dunites. The differences in composition between the disaggregated grains that are similar to diamond inclusions and those comprising xenoliths imply some differences in origin. Possibly the disaggregated harzburgites with diamond-inclusion mineralogy have undergone repeated partial melting and depletion near the base of the lithosphere subsequent to their primary depletion and aggregation in the craton. Equilibration with magnesite may have reduced the Ca contents of their garnets and decomposition of the magnesite during eruption may have caused their disaggregation.  相似文献   

7.
Mafic xenoliths of garnet pyroxenite and eclogite from the Wajrakarur, Narayanpet and Raichur kimberlite fields in the Archaean Eastern Dharwar Craton (EDC) of southern India have been studied. The composition of clinopyroxene shows transition from omphacite (3–6 wt% Na2O) in eclogites to Ca pyroxene (<3 wt% Na2O) in garnet pyroxenites. Some of the xenoliths have additional phases such as kyanite, enstatite, chromian spinel or rutile as discrete grains. Clinopyroxene in a rutile eclogite has an XMg value of 0.70, which is unusually low compared to the XMg range of 0.91–0.97 for all other samples. Garnet in the rutile eclogite is also highly iron-rich with an end member composition of Prp26.5Alm52.5Grs14.7Adr5.1TiAdr0.3Sps1.0Uv0.1. Garnets in several xenoliths are Cr-rich with up to 8 mol% knorringite component. Geothermobarometric calculations in Cr-rich xenoliths yield different P–T ranges for eclogites and garnet pyroxenites with average P–T conditions of 36 kbar and 1080 °C, and 27 kbar and 830 °C, respectively. The calculated P–T ranges approximate to a 45 mW m?2 model geotherm, which is on the higher side of the typical range of xenolith/xenocryst geotherms (35–45 mW m?2) for several Archaean cratons in the world. This indicates that the EDC was hotter than many other shield regions of the world in the mid-Proterozoic period when kimberlites intruded the craton. Textural and mineral chemical characteristics of the mafic xenoliths favour a magmatic cumulate process for their origin as opposed to subducted and metamorphosed oceanic crust.  相似文献   

8.
The petrology and geochemistry of some new occurrences of Mesoproterozoic diamondiferous hypabyssal-facies kimberlites from the Chigicherla, Wajrakarur-Lattavaram and Kalyandurg clusters of the Wajrakarur kimberlite field (WKF), Eastern Dharwar craton (EDC), southern India, are reported. The kimberlites contain two generations of olivine, and multiple groundmass phases including phlogopite, spinel, calcite, dolomite, apatite, perovskite, apatite and rare titanite, and xenocrysts of eclogitic garnet and picro-ilmenite. Since many of the silicate minerals in these kimberlites have been subjected to carbonisation and alteration, the compositions of the groundmass oxide minerals play a crucial role in their characterisation and in understanding melt compositions. While there is no evidence for significant crustal contamination in these kimberlites, some limited effects of ilmenite entrainment are evident in samples from the Kalyandurg cluster. Geochemical studies reveal that the WKF kimberlites are less differentiated and more primitive than those from the Narayanpet kimberlite field (NKF), Eastern Dharwar craton. Highly fractionated (La/Yb = 108–145) chondrite-normalised distribution patterns with La abundances of 500–1,000 × chondrite and low heavy rare earth elements (HREE) abundances of 5–10 × chondrite are characteristic of these rocks. Metasomatism by percolating melts from the convecting mantle, rather than by subduction-related processes, is inferred to have occurred in their source regions based on incompatible element signatures. While the majority of the Eastern Dharwar craton kimberlites are similar to the Group I kimberlites of southern Africa in terms of petrology, geochemistry and Sr–Nd isotope systematics, others show the geochemical traits of Group II kimberlites or an overlap between Group I and II kimberlites. Rare earth element (REE)-based semi-quantitative forward modelling of batch melting of southern African Group I and II kimberlite source compositions involving a metasomatised garnet lherzolite and very low degrees of partial melting demonstrate that (1) WKF and NKF kimberlites display a relatively far greater range in the degree of melting than those from the on-craton occurrences from southern Africa and are similar to that of world-wide melilitites, (2) different degrees of partial melting of a common source cannot account for the genesis of all the EDC kimberlites, (3) multiple and highly heterogeneous kimberlite sources involve in the sub-continental lithospheric mantle (SCLM) in the Eastern Dharwar craton and (4) WKF and NKF kimberlites generation is a resultant of complex interplay between the heterogeneous sources and their different degrees of partial melting. These observations are consistent with the recent results obtained from inversion modelling of REE concentrations from EDC kimberlites in that both the forward as wells as inverse melting models necessitate a dominantly lithospheric, and not asthenospheric, mantle source regions. The invading metasomatic (enriching) melts percolating from the convecting (asthenosphere) mantle impart an OIB-like isotopic signature to the final melt products.  相似文献   

9.
Previous studies of samples of subcontinental lithospheric mantle (SCLM) that underlay the North China Craton (NCC) during the Paleozoic have documented the presence of thick Archean SCLM at this time. In contrast, samples of SCLM underlying the NCC during the Cenozoic are characterized by evidence for melt depletion during the Proterozoic, and relatively recent juvenile additions to the lithosphere. These observations, coupled with geophysical evidence for relatively thin lithosphere at present, have led to the conclusion that the SCLM underlying the NCC was thinned and modified subsequent to the late Paleozoic. In order to extend the view into both the Paleozoic and modern SCLM underlying the NCC, we examine mantle xenoliths and xenocrystic chromites extracted from three Paleozoic kimberlites (Tieling, Fuxian and Mengyin), and mantle xenoliths extracted from one Cenozoic basaltic center (Kuandian). Geochemical data suggest that most of the Kuandian xenoliths are residues of small degrees of partial melting from chemically primitive mantle. Sr-Nd-Hf isotopic analyses indicate that the samples were removed from long-term depleted SCLM that had later been variably enriched in incompatible elements. Osmium isotopic compositions of the two most refractory xenoliths are depleted relative to the modern convecting upper mantle and have model melt depletion ages that indicate melt depletion during Paleoproterozoic. Other relatively depleted xenoliths have Os isotopic compositions consistent with the modern convecting upper mantle. This observation is generally consistent with earlier data for xenoliths from other Cenozoic volcanic systems in the NCC and surrounding cratons. Thus, the present SCLM underlying the NCC has a complex age structure, but does not appear to retain materials with Archean melt depletion ages. Results for what are presumed to be early Paleozoic xenoliths from Teiling are generally highly depleted in melt components, e.g. have low Al2O3, but have also been metasomatically altered. Enrichment in light rare earth elements, low εNd values (∼−10), and relatively high 87Sr/86Sr (0.707-0.710) are consistent with a past episode of metasomatism. Despite the metasomatic event, 187Os/188Os ratios are low and consistent with a late Archean melt depletion event. Thus, like results for xenoliths from other early Paleozoic volcanic centers within the NCC, these rocks sample dominantly Archean SCLM. The mechanism for lithospheric thinning is still uncertain. The complex age structure currently underlying the NCC requires either variable melt depletion over the entire history of this SCLM, or the present lithospheric material was partly or wholly extruded under the NCC from elsewhere by the plate collisions (collision with the Yangtze Craton and/or NNW subduction of the Pacific plate) that may have caused the thinning to take place.  相似文献   

10.
The compositional structure and thermal state of the subcontinental lithospheric mantle (SCLM) beneath the Kalahari Craton and the surrounding mobile belts have been mapped in space and time using >3400 garnet xenocrysts from >50 kimberlites intruded over the period 520–80 Ma. The trace-element patterns of many garnets reflect the metasomatic refertilisation of originally highly depleted harzburgites and lherzolites, and much of the lateral and vertical heterogeneity observed in the SCLM within the craton is the product of such metasomatism. The most depleted, and possibly least modified, SCLM was sampled beneath the Limpopo Belt by early Paleozoic kimberlites; the SCLM beneath other parts of the craton may represent similar material modified by metasomatism during Phanerozoic time. In the SW part of the craton, the SCLM sampled by “Group 2” kimberlites (>110 Ma) is thicker, cooler and less metasomatised than that sampled by “Group 1” kimberlites (mostly ≤95 Ma) in the same area. Therefore, the extensively studied xenolith suite from the Group 1 kimberlites probably is not representative of primary Archean SCLM compositions. The relatively fertile SCLM beneath the mobile belts surrounding the craton is interpreted as largely Archean SCLM, metasomatised and mixed with younger material during Paleoproterozoic to Mesoproterozoic rifting and compression. This implies that at least some of the observed secular evolution in SCLM composition worldwide may reflect the reworking of Archean SCLM. There are strong correlations between mantle composition and the lateral variations in seismic velocity shown by detailed tomographic studies. Areas of relatively low Vp within the craton largely reflect the progressive refertilisation of the Archean root during episodes of intraplate magmatism, including the Bushveld (2 Ga) and Karroo (ca. 180 Ma) events; areas of high Vp map out the distribution of relatively less metasomatised Archean SCLM. The relatively low Vp of the SCLM beneath the mobile belts around the craton is consistent with its fertile composition. The seismic data may be used to map the lateral extent of different types of SCLM, taking into account the small lateral variations in the geotherm identified using the techniques described here.  相似文献   

11.
Groundmass perovskite has been dated by LA-ICPMS in 135 kimberlites and related rocks from 110 localities across southern Africa. Sr and/or Nd isotopes have been analysed by LA-MC-ICPMS in a subset of these and integrated with published data. The age distribution shows peaks at 1,600–1,800, 1,000–1,200, 500–800 and 50–130 Ma. The major “bloom” of Group I kimberlites at ca 90 ± 10 Ma was preceded by a slow build-up in magmatic activity from ca 180 Ma. The main pulse of Group II kimberlites at 120–130 Ma was a distinct episode within this build-up. Comparison of the isotopic data with seismic tomography images suggests that metasomatized subcontinental lithospheric mantle (SCLM) with very low ε Nd and high 87Sr/86Sr, (the isotopic signature of Group II kimberlites) was focused in low-Vs zones along translithospheric structures. Such metasomatized zones existed as early as 1,800 Ma, but were only sporadically tapped until the magmatic build-up began at ca 180 Ma, and contributed little to the kimberlitic magmas after ca 110 Ma. We suggest that these metasomatized volumes resided in the deep SCLM and that their low-melting point components were “burned off” by rising temperatures, presumably during an asthenospheric upwelling that led to SCLM thinning and a rise in the ambient geotherm between 120 and 90 Ma. The younger Group I kimberlites therefore rarely interacted with such SCLM, but had improved access to shallower volumes of differently metasomatized, ancient SCLM with low 87Sr/86Sr and intermediate ε Nd (0–5). The kimberlite compositions therefore reflect the evolution of the SCLM of southern Africa, with metasomatic-enrichment events from as early as 1.8 Ga, through a major thermal and compositional change at ca 110 Ma, and the major kimberlite “bloom” around 90 Ma.  相似文献   

12.
 Ultramafic xenoliths are found in Kishyuku Lava, Fukue-jima, Southwest Japan. These include spinel lherzolite, harzburgite and dunite, as well as pyroxenite. The compositions of the constituent minerals of the peridotite xenoliths are in the range of upper mantle peridotites. Variable Cr/(Cr+Al) ratios (0.1–0.5) of spinel, together with a limited range in olivine composition (Fo90–Fo92), indicate that the xenoliths are derived from slightly to highly depleted residual mantle. The combination of previously published clinopyroxene-olivine geothermobarometry and clinopyroxene-orthopyroxene geothermometry applied to the xenoliths yields a high geotherm of 1070° C at 1.0 GPa up to 1200° C at 2.2 GPa. Existence of such depleted upper mantle is compatible with the existing model of asthenospheric injection during the rifting of the Northeast China and the Japan Sea. The high geotherm is caused by thermal perturbation due to the injection of the hot asthenosphere and/or post-rifting uprise of mantle diapirs since 11 Ma. Received: 15 May 1995 / Accepted: 3 January 1996  相似文献   

13.
The composition, structure and thermal state of the lithosphere beneath the Slave craton have been studied by analysing over 300 peridotitic mantle xenoliths or multiphase xenocrysts entrained within kimberlites in the Lac de Gras area. These xenoliths are derived from seven kimberlites located on the Ekati Diamond Mine™ property and define a detailed stratigraphic profile through the central Slave lithosphere from less than 120 km down to 200 km. Two dominant peridotite types are present, namely garnet-bearing harzburgite and lherzolite with rare occurrences of chromite-facies peridotite, websterite and wehrlite. The pressures and temperatures (P–T's) defined by the entire data-set range from 28 to 62 kbar and 650 to 1250 °C, respectively, and approximately intersect the diamond stability field at 900 °C and 42 kbar. There is no apparent change in the geotherm with depth that is discernable beyond the resolution of the various thermobarometers. The peridotites can be divided into two compositional zones—a shallow layer dominated by garnet harzburgite that straddles the diamond–graphite boundary and a deeper layer that is strongly dominated by garnet lherzolite. Compositionally, the harzburgites (and to a lesser extent, the shallow lherzolites) are ultra-depleted relative to the more fertile deeper layer, irrespective of whether they reside within the graphite or diamond stability field. This ultra-depleted layer beneath Ekati continues to 150 km.  相似文献   

14.
Minor magmatic intrusions of kimberlite, melilitite and cpx-melilitite occur in the southern part of the Kola Peninsula, Russia, on the Terskii Coast and near the town of Kandalaksha. They yield K-Ar ages of 382 ± 14 Ma and 365 ± 16 Ma, similar to the magmatic rocks from the Kola Alkaline Province. The Terskii Coast kimberlites have mineralogical and geochemical affinities with group 1 kimberlites, whereas the Kandalaksha monticellite kimberlite more closely resembles calcite kimberlites. The lower Al2O3 content in the Kola kimberlites indicates a strongly depleted harzburgitic source, while higher Al2O3 in the melilitites suggests a lherzolitic source. The Terskii Coast kimberlites are anomalously potassic and significantly enriched in P and Ba compared to other group 1 kimberlites. In contrast, the melilitites are sodic and are anomalously depleted in P compared to worldwide melilitites. Trace element patterns of the Kola kimberlites and melilitites indicate the presence of K- and P-rich phases in the mantle source. To account for the K-troughs shown by both magma types, a K-rich phase such as phlogopite is thought to be residual in their sources; however, the anomalous K-enrichment in the Terskii Coast kimberlites may indicate that an additional metasomatic K-rich phase (e.g. K-richterite and/or a complex K-Ba-phosphate) existed in the kimberlite source. The P-depletion in the melilitites may suggest that a phosphate phase such as apatite remained residual in the melilititic source. However, anomalous P-enrichment in the kimberlites cannot be explained by complete melting of the same phase because the kimberlites are a smaller degree melt; thus, it is most likely that another metasomatic phosphate mineral existed in the source of the kimberlites. The Kola kimberlites and melilitites are all strongly LREE-enriched but the kimberlites have a steeper REE pattern and are significantly more depleted in HREE, indicating a higher proportion of garnet in their source. Higher Nb/Y ratios and lower SiO2 values in the kimberlites indicate that they were a smaller degree partial melt than the melilitites. The presence of diamonds in the Terskii Coast kimberlites indicates a relatively deep origin, while the melilitites originated from shallower depth. The non-diamondiferous Kandalaksha monticellite kimberlite has lower abundances of all incompatible trace elements, suggesting a higher degree of partial melting and/or a less enriched and shallower source than the Terskii Coast kimberlites. The 87Sr/86Sri, 143Nd/144Ndi and Pb isotope compositions confirm that the Terskii Coast kimberlites have close affinities with group 1 kimberlites and were derived from an asthenospheric mantle source, while the Kandalaksha monticellite kimberlite and Terskii Coast melilitites were derived from lithospheric mantle. Impact of a Devonian asthenospheric mantle plume on the base of the Archaean-Proterozoic lithosphere of the Kola Peninsula caused widespread emplacement of kimberlites, melilitites, ultramafic lamprophyres and other more fractionated alkaline magmas. The nature of the mantle affected by metasomatism associated with the plume and, in particular, the depth of melting and the stability of the metasomatic phases, gave rise to the observed differences between kimberlites and the related melilitites and other magmas. Received: 3 March 1997 / Accepted: 7 October 1997  相似文献   

15.
The mineral chemistry, major and trace element, and Sr–Nd isotopic composition of Cr-diopside, spinel peridotite xenoliths from the Estancia Lote 17 locality in southern Patagonia document a strong carbonatitic metasomatism of the backarc continental lithosphere. The Lote 17 peridotite xenolith suite consists of hydrous spinel lherzolite, wehrlite, and olivine websterite, and anhydrous harzburgite and lherzolite. Two-pyroxene thermometry indicates equilibration temperatures ranging from 870 to 1015 °C and the lack of plagioclase or garnet suggests the xenoliths originated from between ˜40 and 60 km depth. All of the xenoliths are LILE- and LREE-enriched, but have relatively low 87Sr/86Sr (0.70294 to 0.70342) and high ɛNd (+3.0 to +6.6), indicating recent trace element enrichment (∼25 Ma, based on the low 87Sr/86Sr and high Rb concentrations of phlogopite separates) in the long-term, melt-depleted Patagonian lithosphere. Lote 17 peridotite xenoliths are divided into two basic groups. Group 1 xenoliths consist of fertile peridotites that contain hydrous phases (amphibole ± phlogopite ± apatite). Group 1 xenoliths are further subdivided into three groups (a, b, and c) based on distinctive textures and whole-rock chemistry. Group 1 xenolith mineralogy and chemistry are consistent with a complex metasomatic history involving variable extents of recent carbonatite metasomatism (high Ca/Al, Nb/La, Zr/Hf, low Ti/Eu) that has overprinted earlier metasomatic events. Group 2 xenoliths consist of infertile, anhydrous harzburgites and record cryptic metasomatism that is attributed to CO2-rich fluids liberated from Group 1 carbonatite metasomatic reactions. Extremely variable incompatible trace element ratios and depleted Sr–Nd isotopic compositions of Lote 17 peridotite xenoliths indicate that the continental lithosphere was neither the primary source nor an enriched lithospheric contaminant for Neogene Patagonian plateau lavas. Neogene plateau magmatism associated with formation of asthenospheric slab windows may have triggered this occurrence of “intraplate-type” carbonatite metasomatism in an active continental backarc setting. Received: 26 January 2000 / Accepted: 1 March 2000  相似文献   

16.
More than 99% of mineral inclusions in diamonds from the River Ranch pipe in the Late Archean Limpopo Mobile Belt (Zimbabwe), are phases of harzburgitic paragenesis, namely olivine (Fo92–93), orthopyroxene (Mg# = 93), G10 garnets and chromites. The diamond inclusion (DI) chemistry demonstrates a limited overlap with River Ranch kimberlite macrocrysts: the DI garnets are more Ca-undersaturated, and DI spinel and garnet are more Mg-rich. Most River Ranch diamond inclusions were equilibrated at T = 1080–1320 °C, P = 47–61 kbar, and f O2 between IW and WM buffers. The P/T profile beneath the Limpopo Mobile Belt (LMB) is consistent with a paleo-heat flow of 41–42 mW/m2, similar to calculations for Roberts Victor, but hotter than for the Finsch, Kimberley, Koffiefontein and Premier Mines. This is ascribed to the younger tectonothermal age of the LMB and its proximity to Late Archean oceans. Like diamond inclusions from all other kimberlites studied, the River Ranch DI have a lithospheric affinity and therefore indicate that an ancient, chemically depleted, thick (at least 200 km) mantle root existed beneath the Limpopo Mobile Belt 530–540 Ma ago. The mantle root might have developed beneath the continental Central Zone of the LMB as early as the Archean, and could be alien to the overthrust allochthonous sheet of the Limpopo Belt. Oxygen fugacity estimates for diamond inclusions at River Ranch are similar to other diamondiferous harzburgites beneath the Kaapvaal craton, indicating that the Kaapvaal mantle as a whole was well buffered and homogeneous with respect to f O2 at the time of peridotitic diamond crystallization. Received: 11 January 1995 / Accepted: 10 June 1997  相似文献   

17.
Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. P–T estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m2. Calculated seismic velocities (Vp) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm3. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (LaN/YbN=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton.  相似文献   

18.
Dunitic xenoliths from late Palaeogene, alkaline basalt flows on Ubekendt Ejland, West Greenland contain olivine with 100 × Mg/(Mg + Fe), or Mg#, between 92.0 and 93.7. Orthopyroxene has very low Al2O3 and CaO contents (0.024–1.639 and 0.062–0.275 wt%, respectively). Spinel has 100 × Cr/(Cr + Al), or Cr#, between 46.98 and 95.67. Clinopyroxene is absent. The osmium isotopic composition of olivine and spinel mineral separates shows a considerable span of 187Os/188Os values. The most unradiogenic 187Os/188Os value of 0.1046 corresponds to a Re-depletion age of ca. 3.3 Gy, while the most radiogenic value of 0.1336 is higher than present-day chondrite. The Os isotopic composition of the xenoliths is consistent with their origin as restites from a melt extraction event in the Archaean, followed by one or more subsequent metasomatic event(s). The high Cr# in spinel and low modal pyroxene of the Ubekendt Ejland xenoliths are similar to values of some highly depleted mantle peridotites from arc settings. However, highly depleted, arc-related peridotites have higher Cr# in spinel for a given proportion of modal olivine, compared to cratonic xenolith suites from Greenland, which instead form coherent trends with abyssal peridotites, dredged from modern mid-ocean ridges. This suggests that depleted cratonic harzburgites and dunites from shallow lithospheric mantle represent the residue from dry melting in the Archaean.  相似文献   

19.
‘Lower crustal’ suite xenoliths in basaltic and kimberlitic magmas are dominated by mafic granulites and may also include eclogites and garnet pyroxenites. Pressures of up to 25 kbar obtained from such xenoliths are well in excess of an upper value of c. 12 kbar for exposed granulite terranes. Palaeogeotherms constructed from xenoliths for the lower crust beneath the Phanerozoic fold belts of eastern Australia (SEA) and beneath the eastern margin of the Australian craton (EMAC) indicate two distinct thermal regimes. The two geotherms have similar form, with the EMAC curve displaced c. 150°C to lower temperatures. Reaction microstructures show the partial re-equilibration of primary igneous assemblages to granulite and eclogite assemblages and are interpreted to reflect the cooling from magmatic temperatures. Variations in mineral compositions and zoning are used to constrain further the history of several EMAC xenoliths to near-isobaric trajectories. Detailed graphical models are constructed to predict compositional changes for isobaric P–T paths (at 7, 14 & 21 kbar) to transform an SEA-type geotherm to a cratonic geotherm. The models show that for the assemblage grt + cpx ± ky + plag + qtz, the changes associated with falling temperature in Xgr, Xjd (increase) and Xan (decrease) will be greater at higher pressures. These results indicate that discernible zoning is more likely to be preserved in the higher pressure xenoliths. The zoning recorded in clinopyroxene from mafic granulite xenoliths over the pressure range c. 12–22 kbar suggests isobaric cooling of a large crustal thickness (30–35 km). An isobaric cooling path is consistent with magma accretion models for the transition of a crust–mantle boundary from an SEA-type geotherm to a cratonic geotherm. The coexistence of granulite and eclogite over the depth range 35–75 km beneath the EMAC indicates that the granulite to eclogite transition in the lower crust is controlled by P–T conditions, bulk chemistry and kinetic factors. At shallower crustal levels, typified by exposed granulite terranes, isobaric cooling may not result in the transition to eclogite.  相似文献   

20.
The Kuruman Kimberlite Province is comprised of 16 small pipes and dikes and contains some of the oldest known kimberlites (>1.6 Ga). In this study, 12 intrusions are subdivided into three groups with distinct petrology, age, and geochemical and isotopic compositions: (1) kimberlites with groundmass perovskites defining a Pb–Pb isochron age of 1787 ± 69 Ma, (2) orangeite with a U–Pb perovskite age of 124 ± 16 Ma, and (3) ultramafic lamprophyres (aillikite and mela-aillikite) with a zircon U–Pb age of 1642 ± 46 Ma. The magma type varies across the Province, with kimberlites in the east, lamprophyres in the west and orangeite and ultramafic lamprophyres to the south. Differences in the age and petrogenesis of the X007 orangeite and Clarksdale and Aalwynkop aillikites suggest that these intrusions are probably unrelated to the Kuruman Province. Kimberlite and orangeite whole-rock major and trace element compositions are similar to other South African localities. Compositionally, the aillikites typically lie off kimberlite and orangeite trends. Groundmass mineral chemistry of the kimberlites has some features more typical of orangeites. Kimberlite whole-rock Sr and Nd isotopes show zoning across the Province. When the kimberlites erupted at ~1.8 Ga, they sampled a core volume (ca 50 km across) of relatively depleted SCLM that was partially surrounded by a rim of more metasomatized mantle. This zonation may have been related to the development of the adjacent Kheis Belt (oldest rocks ~2.0 Ga), as weaker zones surrounding the more resistant core section of SCLM were more extensively metasomatized.  相似文献   

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