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拉萨地块松多榴辉岩主要矿物组合为石榴子石、绿辉石、角闪石、多硅白云母、绿帘石、金红石。石榴子石环带不明显,核部成分均一,从核部到边部,镁铝榴石和钙铝榴石含量降低,可能分别记录了榴辉岩峰期及退变质过程信息。绿辉石显示微弱的成分环带,硬玉含量从核部到边部略有升高,部分绿辉石边部发育韭闪石退变质边,反映了在减压过程中外来流体进入体系的过程。多硅白云母具有高的Si含量(3.5~3.6),其中石榴石包体中的多硅白云母相对基质中的白云母有更高的Si值。本文利用Thermocalc变质相平衡模拟软件,结合详细岩相学观察,在NCKMn FMASHTO体系下,模拟松多含多硅白云母榴辉岩的变质演化过程。其中,榴辉岩峰期矿物组合为g+o+law+phn+ru,石榴石核部最大镁铝榴石值和石榴子石包体中多硅白云母最大Si值确定的榴辉岩峰期温压条件约为620℃,32×105Pa,榴辉岩经历了近等温降压的退变质过程。相平衡模拟结果表明拉萨地块松多榴辉岩经历了超高压变质作用过程,并经历了相对快速的折返过程到中部地壳层次。 相似文献
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榴辉岩中传统地质温压计新解：来自PT视剖面图的证据 总被引：1，自引：1，他引：0
石榴石-单斜辉石(GC)温度计和石榴石-单斜辉石-多硅白云母(GCP)压力计是确定榴辉岩形成温压条件的最常用方法,二者主要依据石榴石、绿辉石和多硅白云母中相组分之间的交换和转换变质反应.依据MORB成分计算的PT视剖面图表明,在不同榴辉岩矿物组合中,控制3个矿物相成分变化的相组分之间的变质反应不同.在低温含绿泥石、滑石和蓝闪石榴辉岩组合中,石榴石和绿辉石的镁含量主要受到含水矿物脱水反应的控制,并都随温度升高而升高,二者之间的铁镁交换反应并不起主要作用.因此,在自然界含有蓝闪石等含水矿物的低温榴辉岩中,由于绿辉石相对富镁而常常导致GC温度计结果偏低.在含有硬柱石的高压-超高压榴辉岩中,石榴石中的钙含量受到硬柱石的控制,随着压力升高或温度降低,硬柱石含量增加,使石榴石中钙降低,此时石榴石-绿辉石-多硅白云母之间的转换反应对石榴石成分的影响会很微弱,由于石榴石相对贫钙而导致GCP压力计结果偏低.在含有蓝晶石的中温高压-超高压榴辉岩中,矿物成分的变化受到石榴石-绿辉石之间的铁镁交换反应和石榴石．绿辉石．多硅白云母-蓝晶石-石英/柯石英之间的一系列转换反应控制,因此,GC和GCP温压计都能给出相对合理的结果.在低压普通角闪石榴辉岩中,石榴石和绿辉石中的镁含量主要反应压力变化,有时并不指示变质作用温度.在含有蓝闪石等含水矿物的低温榴辉岩中,Thermocalc程序中的平均温压(avPT)方法可以给出比较合适的温度,但压力结果与GCP压力计一样也会偏低一些.在蓝闪石和绿帘石等含水矿物消失后的中温蓝晶石榴辉岩中,avPT方法难以给出合理的PT信息.相对来说,视剖面图方法能够给出最多的PT信息,是目前确定变质岩PT条件的最好方法. 相似文献
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榴辉岩常用温压计在应用中应注意的问题 总被引：5，自引：6，他引：5
本文通过再现相平衡实验数据和检查热力学活度模型两种手段,对榴辉岩中几种常用的温压计进行了检验,发现榴辉岩中某些常用温压计存在以下问题:(1)在 Eliis and Green(1979)、Powell(1985)、Krogh(1988)和 Ravna(2000)四种石榴石-单斜辉石温度计中只有 Ravna(2000)的版本能较好的再现相平衡实验数据。(2)将石榴石-单斜辉石温度计应用于含 X_(Jd)>0.55绿辉石的榴辉岩中会出现很大的误差。(3)Green and Hellman(1982)的石榴石-多硅白云母温度计计算的高压含多硅白云母榴辉岩变质温度普遍偏高,但是计算超高压榴辉岩的结果能较好的与 Ravna(2000)的石榴石-单斜辉石温度计计算结果保持一致。(4)Waters and Martin(1993)的石榴石-单斜辉石-多硅白云母压力计、Ravna and Terry(2004)的石榴石-单斜辉石-多硅白云母-蓝晶石-柯石英/石英温压计的精度都受到了 Holland(1990)的单斜辉石活度模型的限制,它们不能适用于绿辉石 X_(Jd)>0.55的榴辉岩,而 Waters and Manin(1996)对 Waters and Martin(1993)的版本做了一个经验校正,弥补了单斜辉石活度模型的缺陷,因此可以适用于绿辉石 X_(Jd)>0.55的榴辉岩。(5)Nakamura and Banno(1997)的石榴石-绿辉石-蓝晶石-柯石英温压计因运用了不恰当的石榴石和铁钙辉石的活度模型,从而使得计算结果与岩相学观察结果不一致。因此,我们建议:对于绿辉石 X_(Jd)<0.55的多硅白云母榴辉岩,可以运用 Waters and Martin(1993)压力计和 Ravna(2000)的温度计联合求解温压;对于含高硬玉组分(X_(Jd)>0.55)绿辉石的超高压多硅白云母榴辉岩,可选用 Waters and Martin(1996)压力计和 Green andHellman(1982)的温度计联合求解温压;对于含有石榴石 绿辉石 蓝晶石 柯石英矿物组合的榴辉岩,在 X_(Jd)<0.55的情况下。可选用 Ravna and Terry(2004)的温压计求解温压。在应用这些温压计时,应注意各温压计的适用温压范围和成分范围,尤其是石榴石 X_(Jd)、Mg~#和绿辉石 X_(Jd)的范围。另外,由于矿物中 Fe~(3 )的含量对温度计算结果影响很大,所以还必须合理地校正所选矿物的 Fe~(3 )。 相似文献
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鱼卡榴辉岩位于柴北缘HP/UHP变质带的西段,榴辉岩呈透镜状或似层状分布在变质泥质岩、花岗质片麻岩及少量大理岩中,主要由石榴石和绿辉石组成,具有含量不等的多硅白云母、角闪石、黝帘石(斜黝帘石或绿帘石)、金红石和石英等。岩相学和矿物化学研究显示榴辉岩经历了3期与俯冲和折返作用有关的变质演化阶段:(1)前榴辉岩相进变质阶段,榴辉岩矿物组合为石榴石(核) 绿帘石 斜长石 角闪石,以包体的形式保存于具有生长环带的石榴石核部,形成的温压条件为p=1.06～1.11GPa,t=560～577℃;(2)榴辉岩相变质阶段,以绿辉石、多硅白云母等矿物围绕石榴石定向分布为特征,其矿物组合为石榴石(边) 绿辉石 多硅白云母±黝帘石,温压估算获得榴辉岩相的变质条件为p=2.35～2.52GPa,t=610～680℃;(3)后榴辉岩相变质阶段,矿物组合为石榴石 角闪石 斜长石,主要存在于围绕榴辉岩透镜体分布的退变榴辉岩(角闪石化榴辉岩)中,形成的温压条件为p=1.09±0.12GPa,t=635±44℃。研究结果显示榴辉岩的pT轨迹具有“发卡”型特点,表明鱼卡榴辉岩经历了快速俯冲和折返的演化历史。 相似文献
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大别山西段含蓝闪石-蓝晶石榴辉岩的相平衡研究 总被引：3，自引：2，他引：3
目前对于大别山西段超高压榴辉岩仍存在一些不清楚的问题和模糊的认识,如蓝闪石和蓝晶石组合的稳定范围,峰期温压条件和矿物组合,以及早期退变质过程的矿物演化和流体作用。本文对取自大别山西段新县高压-超高压榴辉岩单元内不同地点的超高压榴辉岩样品进行了详细的岩石学和矿物学研究,在此基础上使用相平衡定量分析方法的 PT 视剖面图对它们进行了正演模拟计算,结果表明:含蓝闪石和蓝晶石榴辉岩处于相对低温或低压的蓝闪石榴辉岩和相对高温高压的蓝晶石榴辉岩的过渡区,其稳定的温压范围大致为温度590～700℃,压力1.7～3.3GPa,而且压力大于2.5GPa 时温度范围很窄,为600～640℃。由石榴石边缘成分和 PT 视剖面图确定的榴辉岩峰期温压条件为压力2.85～2.95GPa 和温度625～630℃,峰期矿物组合为石榴石 绿辉石 蓝闪石 蓝晶石 硬柱石 柯石英±多硅白云母。峰期之后,榴辉岩经历了快速近等温降压(ITD)的早期高压退变质作用,这是一个非平衡过程,所发生的主要变化如下:柯石英→石英,硬柱石→黝帘石 蓝晶石,在相对富镁岩石中出现滑石,当水含量较高时可以出现钠云母,蓝闪石在原来基础上有一定量的生长,并且绿辉石和多硅白云母很可能只部分地发生了成分变化,而石榴石几乎未发生改变。这样形成了目前观察到的矿物组成为石榴石 绿辉石 蓝闪石 蓝晶石 黝帘石/绿帘石 石英±多硅白云母±钠云母±滑石,它代表了 UHP 榴辉岩在早期高压退变质阶段结束时所具有的矿物组成,这一阶段结束时的温压条件大致为2.0～2.2GPa 和600～630℃;早期高压退变质阶段是脱水过程,流体是内部缓冲的。 相似文献
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柴北缘锡铁山一带榴辉岩的岩石学特征及其退变PT轨迹 总被引：1，自引：1，他引：0
柴北缘锡铁山地区榴辉岩以透镜体的形式存在于花岗质片麻岩和副变质片麻岩中.根据矿物组合的不同,可以分为多硅白云母榴辉岩和角闪石榴辉岩.在多硅白云母榴辉岩中首次发现了柯石英假象.利用榴辉岩中Grt-Cpx-Phn矿物温压计.结合绿辉石中存在柯石英假象包体的现象,得到锡铁山榴辉岩的峰期温压条件为751～791℃,2.71～3.17GPa,证明了锡铁山地区与柴北缘其他地块一样,也经历了超高压变质作用.通过PT视剖面图计算了榴辉岩退变的PT轨迹具有2个阶段演化特征：即先等温降压,然后再降温降压的PT轨迹.详细的岩石学研究探讨了榴辉岩在退变过程中,各矿物的成分和结构的改变过程.石榴石在等温降压过程中成分变化不大,而在角闪石出现后,其边部镁铝榴石含量明显降低,进而形成了韭闪石+斜长石的冠状体.绿辉石在水饱和状态下经过贫硬玉化改造,而后形成了Di+Ab+Amp的后生合晶.多硅白云母分解形成白云母+黑云母及少量石英及钾长石的组合.角闪石随着温压条件的降低由钠钙质闪石逐渐向钙质闪石转化. 相似文献
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西大别熊店地区的榴辉岩多属于高压榴辉岩,主要矿物为石榴石、角闪石、绿辉石、绿泥石、白云母、石英、以及少量金红石及长石。石榴石具有明显的生长环带。本次研究利用榴辉岩样品的全岩成分定量的绘制了P-T视剖面图,根据石榴石的端元成分含量,计算得出了石榴石成分剖面所对应的温压条件。其核部的温压条件为21. 5 × 10 8 Pa ～ 22. 2 × 10 8 Pa,450℃ ～ 463℃,对应的矿物组合为石榴石 + 绿辉石 + 蓝闪石 + 阳起石 + 硬柱石 + 绿泥石 + （白云母 + 水）;边缘的温压条件为6 × 10 8 Pa ～ 8 × 10 8 Pa,610℃ ～ 630℃,该温压条件对应的矿物组合为石榴石 + 普通角闪石 + 斜长石 + 透辉石 ＋ （白云母 + 水）,从而得到石榴石变质演化的P-T轨迹,由此反映出石榴石变质过程是一个升温降压的过程。 相似文献
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北秦岭官坡地区高压—超高压榴辉岩岩相学及变质作用研究 总被引：19，自引：2，他引：19
北秦岭官坡地区的榴辉岩及含柯石英榴辉岩产在帮岭岩群的北侧，主要由绿辉石和石榴石组成，部分石榴石和绿辉石中含柯石英包体。此外还含有退变质的多硅白云母、角闪石、黝帘石和纳长石等矿物，根据变质矿物之间的替代关系及共生组合规律，榴辉岩退变质作用可划分为四个阶段，各阶段代表性矿物组合依次为：柯石英＋绿辉石＋石榴石；石英＋绿辉石＋石榴石；多硅白云母＋绿辉石＋石榴石＋石英；角闪石＋斜长石＋白云母＋黑云母。这四个 相似文献
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Petrology of ultrahigh-pressure eclogites from the ZK703 drillhole in the Donghai, eastern China 总被引：25，自引：0，他引：25
The 558-m-deep ZK703 drillhole located near Donghai in the southern part of the Sulu ultrahigh-pressure metamorphic belt, eastern China, penetrates alternating layers of eclogites, gneisses, jadeite quartzites, garnet peridotites, phengite–quartz schists, and kyanite quartzites. The preservation of ultrahigh-pressure metamorphic minerals and their relics, together with the contact relationship and protolith types of the various rocks indicates that these are metamorphic supracrustal rocks and mafic-ultramafic rock assemblages that have experienced in-situ ultrahigh-pressure metamorphism. The eclogites can be divided into five types based on accessory minerals: rutile eclogite, phengite eclogite, kyanite–phengite eclogite, quartz eclogite, and common eclogite with rare minor minerals. Rutile eclogite forms a thick layer in the drillhole that contains sufficient rutile for potential mining. Two retrograde assemblages are observed in the eclogites: the first stage is characterized by the formation of sodic plagioclase+amphibole symplectite or symplectitic coronas after omphacite and garnet, plagioclase+biotite after garnet or phengite, and plagioclase coronas after kyanite; the second stage involved total replacement of omphacite and garnet by amphibole+albite+epidote+quartz. Peak metamorphic P–T conditions of the eclogites were around 32 to 40 kbar and 720°C to 880°C. The retrograde P–T path of the eclogites is characterized by rapidly decreasing pressure with slightly decreasing temperature. Micro-textures and compositional variations in symplectitic minerals suggest that the decompression breakdown of ultrahigh-pressure minerals is a domainal equilibrium reaction or disequilibrium reaction. The composition of the original minerals and the diffusion rate of elements involved in these reactions controlled the symplectitic mineral compositions. 相似文献
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Prograde and Retrograde Eclogites in the Sambagawa Metamorphic Belt, Besshi District, Japan 总被引：2，自引：1，他引：2
In the Besshi district of the Sambagawa metamorphic belt, thereare two types of eclogites: one occurring in the Sebadani metagabbromass and retrograded from high-temperature anhydrous ecologite,and the other in the basic schists and produced by prograde,dehydration of epidote amphibolite. The Sebadani metagabbro mass was originally layered gabbro,which was once equilibrated in the ecologite facies before emplacementinto the Sambagawa terrain as a hot eclogite mass. Basic schistssurrounding the Sebadani mass, which had suffered the Sambagawametamorphism of albite epidote amphibolite facies, were contact-metamorphosedat high pressure by the emplacement of the Sebadani mass. Asa result, the basic schists were dehydrated to form eclogiticbasic schists, i.e. garnet and omphacite porphyroblast-bearingbasic schists. Thus, two types of ecologite, retrograde andprograde, converged into the same metamorphic condition, 610–650?C, 7–17 kb, in a part of the ecologite facies duringthe Sambagawa metamorphism. Correspondingly, the values of distributioncoefficients of Fe and Mg between garnet and omphacite increasefrom core pairs to rim pairs in the retrograde eclogites anddecrease from core pairs to rim pairs in the prograde ecologites.After this stage, both the prograde and retrograde eclogitesshared a common metamorphic history; they were retrograded viathe epidote amphibolite facies to the greenschist facies. The Sebadani metagabbro mass, as a large tectonic block, hadbeen emplaced into a m?lange zone in the Sambagawa metamorphicbelt after the peak of the Sambagawa metamorphism, probablyfollowing initiation of uplift of the metamorphic rocks fromtheir deep-seated environment. 相似文献
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Petrogenesis and implications of jadeite‐bearing kyanite eclogite from the Sanbagawa belt (SW Japan)
Jadeite‐bearing kyanite eclogite has been discovered in the Iratsu body of the Sanbagawa belt, SW Japan. The jadeite + kyanite assemblage is stable at higher pressure–temperature (P–T) conditions or lower H2O activity [a(H2O)] than paragonite, although paragonite‐bearing eclogite is common in the Sanbagawa belt. The newly discovered eclogite is a massive metagabbro with the peak‐P assemblage garnet + omphacite + jadeite + kyanite + phengite + quartz + rutile. Impure jadeite is exclusively present as inclusions in garnet. The compositional gap between the coexisting omphacite (P2/n) and impure jadeite (C2/c) suggests relatively low metamorphic temperatures of 510–620 °C. Multi‐equilibrium thermobarometry for the assemblage garnet + omphacite + kyanite + phengite + quartz gives peak‐P conditions of ~2.5 GPa, 570 °C. Crystallization of jadeite in the metagabbro is attributed to Na‐ and Al‐rich effective bulk composition due to the persistence of relict Ca‐rich clinopyroxene at the peak‐P stage. By subtracting relict clinopyroxene from the whole‐rock composition, pseudosection modelling satisfactorily reproduces the observed jadeite‐bearing assemblage and mineral compositions at ~2.4–2.5 GPa, 570–610 °C and a(H2O) >0.6. The relatively high pressure conditions derived from the jadeite‐bearing kyanite eclogite are further supported by high residual pressures of quartz inclusions in garnet. The maximum depth of exhumation in the Sanbagawa belt (~80 km) suggests decoupling of the slab–mantle wedge interface at this depth. 相似文献
14.
The (ultra‐) high pressure eclogites from Sumdo area, recorded the subduction and exhumation process of the Paleo‐Tethys oceanic crust. Previous studies showed that there are significant differences in temperature and pressure conditions of the eclogites in four regions, e.g. Sumdo, Xindaduo, Bailang and Jilang. The cause of this differences remains unclear. Studying the peak metamorphic conditions and P‐T path of Sumdo eclogite is of great significance to reveal the subduction and exhumation mechanism of Paleo‐Tethys ocean. In this paper, we choose the Jilang eclogite as an example, which has a mineral assemblage of garnet, omphacite, phengite, hornblende, rutile, epidote, quartz and symplectit (diopside + amphibole + plagioclase), and minor biotite. Garnet has a “dirty” core with abundant mineral inclusions and a “clear” rim with less mineral inclusions, showing typical growth zoning. From the core to the rim, Prp content in garnet increasing while Grs content decreasing. P‐T pseudosection calculated with Domino constrained peak P‐T conditions of Jilang eclogite as 563°C, 2.4 GPa. Combined with petrographical observation, four stages of metamorphism have been recognized: (1) early stage prograde metamorphism represent by the core of garnet and mineral inclusions therein; (2) peak metamorphism represent by the rim of garnet, omphacite, phengite, glaucophane, rutile and quartz; (3) first stage of retrograde metamorphism characterized by decomposition of lawsonite to zoisite; (4) second stage of retrograde metamorphism characterized by symplectites surrounding omphacite and cornona rimmed garnet. Jilang eclogite shows a clockwise P‐T path, and near isothermal decompression during exhumation. It differs from eclogites in other area, which are hosted by garnet‐bearing mica schists or serpentinites. Jilang eclogites are enclosed in metamorphic quartzites, with relatively low P‐T conditions. We infer that the Jilang eclogite was derived from the shallow part of the subduction zone, and was exhumated by low density materials in the subduction channel. 相似文献
15.
Petrology of the Non-mafic UHP Metamorphic Rocks from a Drillhole in the Southern Sulu Orogenic Belt, Eastern-Central China 总被引：9，自引：0，他引：9
ZHANG Zeming XU Zhiqin XU HuifenInstitute of Geology Chinese Academy of Geological Sciences Baiwanzhuang Rd. Beijing E-mail: zzm@ccsd.org.cn. 《《地质学报》英文版》2003,77(2):173-186
The Drillhole ZK703 with a depth of 558 m is located in the Donghai area of the southern Sulu ultrahigh-pressure (UHP) metamorphic belt, eastern China, and penetrates typical UHP eclogites and various non-mafic rocks, including peridotite, gneiss, schist and quartzite. Their protoliths include ultramafic, mafic, intermediate, intermediate-acidic, acidic igneous rocks and sediments. These rocks are intimately interlayered, which are meters to millimeters thick with sharp and nontectonic contacts, suggesting in-situ metamorphism under UHP eclogite facies conditions. The following petrologic features indicate that the non-mafic rocks have experienced early-stage UHP metamorphism together with the eclogites: (1) phengite relics in gneisses and schists contain a high content of Si, up to 3.52 p.f.u. (per formula unit), while amphibolite-facies phengites have considerably low Si content (<3.26 p.f.u.); (2) jadeite relics are found in quartzite and jadeitite; (3) various types of symplectitic coronas and pseud 相似文献
16.
Jadeite–garnet glaucophane schists in the Bizan area,Sambagawa metamorphic belt,eastern Shikoku,Japan: significance and extent of eclogite facies metamorphism 
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下载免费PDF全文 Eclogite facies metamorphic rocks have been discovered from the Bizan area of eastern Shikoku, Sambagawa metamorphic belt. The eclogitic jadeite–garnet glaucophane schists occur as lenticular or sheet‐like bodies in the pelitic schist matrix, with the peak mineral assemblage of garnet + glaucophane + jadeite + phengite + quartz. The jadeitic clinopyroxene (XJd 0.46–0.75) is found exclusively as inclusions in porphyroblastic garnet. The eclogite metamorphism is characterized by prograde development from epidote–blueschist to eclogite facies. Metamorphic P–T conditions estimated using pseudosection modelling are 580–600 °C and 18–20 kbar for eclogite facies. Compared with common mafic eclogites, the jadeite–garnet glaucophane schists have low CaO (4.4–4.5 wt%) and MgO (2.1–2.3 wt%) bulk‐rock compositions. The P–T– pseudosections show that low XCa bulk‐rock compositions favour the appearance of jadeite instead of omphacite under eclogite facies conditions. This is a unique example of low XCa bulk‐rock composition triggered to form jadeite at eclogite facies conditions. Two significant types of eclogitic metamorphism have been distinguished in the Sambagawa metamorphic belt, that is, a low‐T type and subsequent high‐T type eclogitic metamorphic events. The jadeite–garnet glaucophane schists experienced low‐T type eclogite facies metamorphism, and the P–T path is similar to lawsonite‐bearing eclogites recently reported from the Kotsu area in eastern Shikoku. During subduction of the oceanic plate (Izanagi plate), the hangingwall cooled gradually, and the geothermal gradient along the subduction zone progressively decreased and formed low‐T type eclogitic metamorphic rocks. A subsequent warm subduction event associated with an approaching spreading ridge caused the high‐T type eclogitic metamorphism within a single subduction zone. 相似文献
17.
超高压变质岩提供了研究大陆俯冲隧道中岩石的变形机制和流变差异性的窗口。文章使用电子背散射衍射技术分析了大别山超高压变质带的榴辉岩和长英质片麻岩的显微构造。榴辉岩中的石榴子石基本呈无序分布，绿辉石发育较强烈的晶格优选定向，[001]轴的极密平行或近平行于拉伸线理，(100)面的法线近垂直于面理，退变榴辉岩中角闪石的(100)[001]组构可能继承了绿辉石的晶格优选定向。退变榴辉岩和长英质片麻岩中的石英记录了(0001)低温底面滑移和{1010}中温
柱面滑移，反映了超高压变质岩折返到中地壳的韧性变形；而斜长石的(001)<110>和(010)[100]组构形成于折返到下地壳的角闪岩相变质条件（>600℃）。根据主要矿物的流变律计算了俯冲与折返过程中无水矿物的有效黏度变化。俯冲过程中，钠长石=硬玉+石英的分解反应以及石英-柯石英相变导致长英质片麻岩的有效黏度和密度都显著增高，有利于陆壳深俯冲。但是折返过程中由于温度较高，这两个反应带来的有效黏度变化较小。>80 km深度，石榴子石的流变强度>硬玉>绿辉
石>柯石英，俯冲上地壳的流变由柯石英和硬玉控制，下地壳的流变由绿辉石和石榴子石控制。超高压变质岩流变强度的差异有助于上—下地壳力学解耦，使相对低密度、低黏度的上地壳物质在俯冲隧道内快速折返。 相似文献
18.
S. W. Faryad F. Melcher G. Hoinkes J. Puhl T. Meisel W. Frank 《Mineralogy and Petrology》2002,74(1):49-73
Summary Retrograde eclogites and serpentinites from the Hochgr?ssen massif, Styria, are parts of the Speik complex in the Austroalpine
basement nappes of the Eastern Alps. They are in tectonic contact with pre-Alpine gneisses, amphibolites, and Permo-Triassic
quartz phyllites (Rannach Series). The eclogites are derived from ocean-floor basalts with affinities to mid-ocean ridge and
back-arc basin basalts. Fresh eclogites are rare and contain omphacite with a maximum of 39 mol% jadeite content, garnet (Py15–19) and amphibole. Retrograde eclogites consist of amphibole and symplectites of Na-poor clinopyroxene (5–8 mol% Jd) + albite ± amphibole.
Amphiboles are classified as edenite, pargasite, tschermakite, magnesiohornblende and actinolite. In relatively fresh eclogite,
edenite is a common amphibole and texturally coexists with omphacite and garnet. An average temperature of 700 °C was obtained
for eclogite facies metamorphism using garnet-pyroxene thermometry. A minimum pressure of 1.5 GPa is indicated by the maximum
jadeite content in omphacite. Thermobarometric calculations using the TWEEQ program for amphibole in textural equilibrium
with omphacite and garnet give pressures of 1.8–2.2 GPa at 700 °C. The equilibrium assemblage of Na-poor clinopyroxene, albite,
amphibole and zoisite in the symplectites gives a pressure of about 0.6–0.8 GPa at 590–640 °C. 40Ar/39Ar radiometric dating of edenitic amphibole in textural equilibrium with omphacite gave a plateau age of 397.3 ± 7.8 Ma, and
probably indicates retrograde cooling through the closure temperature for amphibole (∼500 °C). The age of the high-pressure
metamorphism thus must be pre-Variscan and points to one of the earliest metamorphic events in the Austroalpine nappes known
to date.
Received June 11, 2000; revised version accepted January 2, 2001 相似文献
19.
Allan F. Wilson 《Contributions to Mineralogy and Petrology》1976,56(3):255-277
Three pairs of coexisting pyroxenes of mafic granulites from each of two locations 100 km apart show large chemical differences, especially in Al, Fe, Mn, Ti and Na. Al content of the pyroxenes at the higher pressure locality is more nearly independent of Al of the host rock than are the pyroxenes from the lower pressure locality. All the data confirm that although no significant difference in temperature has emerged, there was a large difference in pressure between the two localities. Al is found to be a more effective discriminant of metamorphic conditions than
. As the three pairs of pyroxenes cover a wide range of Fe at each locality, the close relationship of Al and Na (and of Ca-tschermak and jadeite) to Fe becomes evident. This shows that a normalizing procedure should be adopted before comparing localities with different Al, Mn, Ti, Na and other elements or derived components such as jadeite and Ca-tschermak. 相似文献
20.
Iron isotopic systematics of UHP eclogites respond to oxidizing fluid during exhumation 总被引：1，自引：0，他引：1 下载免费PDF全文
下载免费PDF全文 D.‐Y. Li Y. L. Xiao W.‐Y. Li X. Zhu H. M. Williams Y.‐L. Li 《Journal of Metamorphic Geology》2016,34(9):987-997
The iron stable isotope compositions (δ56Fe) and iron valence states of ultrahigh‐pressure eclogites from Bixiling in the Dabie orogen belt, China, were measured to trace the changes of geochemical conditions during vertical transportation of earth materials, for example, oxygen fugacity. The bulk Fe3+/ΣFe ratios of retrograde eclogites, determined by Mössbauer spectroscopy, are consistently higher than those of fresh eclogites, suggesting oxidation during retrograde metamorphism and fluid infiltration. The studied eclogites (five samples) display limited mid‐ocean ridge basalts (MORB)‐like (~0.10‰) δ56Fe values, which are indistinguishable from their protoliths, that is, gabbro cumulates formed through differentiation of mantle‐derived basaltic magma. This suggests that Fe isotope fractionation during continental subduction is limited. Garnet separates display limited δ56Fe variation ranging from ?0.08 ± 0.07 ‰ to 0.02 ± 0.07‰, whereas coexisting omphacite displays a large variation of δ56Fe values from 0.15 ± 0.07‰ to 0.47 ± 0.07‰. Omphacite also has highly variable Fe3+/ΣFe ratios from 0.367 ± 0.025 to 0.598 ± 0.024, indicating modification after peak metamorphism. Omphacite from retrograde eclogites has elevated Fe3+/ΣFe ratios (0.54–0.60) compared to that from fresh eclogites (~0.37), whereas garnet displays a narrow range of ferric iron content with Fe3+/ΣFe ratios from 0.039 ± 0.013 to 0.065 ± 0.022. The homogenous δ56Fe values and Fe3+/ΣFe ratios of garnet suggest that it survived the retrograde metamorphism and preserved its Fe‐isotopic features and ferric contents of peak metamorphism. Because of similar diffusion rates of Fe and Mg in garnet and omphacite, and constant Δ26Mgomphacite‐garnet values (1.14 ± 0.04‰), equilibrium iron isotope fractionation between garnet and omphacite was probably achieved during peak metamorphism. Elevated Fe3+/ΣFe ratios of omphacite from retrograde eclogites and variant Δ56Feomphacite‐garnet values of the studied eclogites (0.13 ± 0.10‰ to 0.48 ± 0.10‰) indicate that oxidized geofluid infiltration resulted in the elevation of δ56Fe values of omphacite during retrograde metamorphism. 相似文献