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1.
The Coolgarra Batholith in north‐east Queensland is composed of the Go Sam and Nettle granite suites which were emplaced approximately 314 Ma ago. Initial 87Sr/86Sr ratios of the Nettle Suite appear to be marginally above 0.710, a value characteristic of a wide range of Late Palaeozoic felsic igneous rocks in the region. This suite appears to have been derived from an extensive isotopically homogeneous crustal source distinct from rocks which crop out in the Palaeozoic Hodgkinson Basin or Precambrian Georgetown Inlier. Higher and more variable initial 87Sr/86Sr ratios (0.727–0.744) of the Go Sam Suite are attributed to a combination of magmatic and hydrothermal processes. Isotopic data, thus, cannot be used to constrain the nature of the Go Sam source rocks. Tungsten (with or without tin) mineralization is associated with the Nettle Suite plutons, with which it shares a common age, whereas the Go Sam Suite is characterized by prominent tin mineralization. One tin occurrence is the same age as, or only slightly younger than, the Nettle Suite tungsten (with or without tin) mineralization. Another tin deposit yields an age of 301 Ma, suggesting the presence of a significantly younger granite at depth.  相似文献   

2.
The paper presents original authors' data on the O, H, C, S, and Sr isotopic composition of water and sediments from the basins into which the Aral Sea split after its catastrophic shoaling: Chernyshev Bay (CB), the basin of the Great Aral in the north, Lake Tshchebas (LT), and Minor Sea (MS). The data indicate that the δ18О, δD, δ13C, and δ34S of the water correlate with the mineralization (S) of the basins (as of 2014): for CB, S = 135.6‰, δ18О = 4.8 ± 0.1‰, δD = 5 ± 2‰, δ13C (dissolved inorganic carbon, DIC) = 3.5 ± 0.1‰, δ34S = 14.5‰; for LT, S = 83.8‰, δ18О = 2.0 ± 0.1‰, δD =–13.5 ± 1.5‰, δ13C = 2.0 ± 0.1‰, δ34S = 14.2‰; and for MS, S = 9.2‰, δ18О =–2.0 ± 0.1‰, δD =–29 ± 1‰, δ13C =–0.5 ± 0.5‰, δ34S = 13.1‰. The oxygen and hydrogen isotopic composition of the groundwaters are similar to those in MS and principally different from the artesian waters fed by atmospheric precipitation. The mineralization, δ13С, and δ34S of the groundwaters broadly vary, reflecting interaction with the host rocks. The average δ13С values of the shell and detrital carbonates sampled at the modern dried off zones of the basins are similar: 0.8 ± 0.8‰ for CB, 0.8 ± 1.4‰ for LT, and –0.4 ± 0.3‰ for MS. The oxygen isotopic composition of the carbonates varies much more broadly, and the average values are as follows: 34.2 ± 0.2‰ for CB, 32.0 ± 2.2‰ for LT, and 28.2 ± 0.9‰ for MS. These values correlate with the δ18O of the water of the corresponding basins. The carbonate cement of the Late Eocene sandstone of the Chengan Formation, which makes up the wave-cut terrace at CB, has anomalously low δ13С up to –38.5‰, suggesting origin near a submarine methane seep. The δ34S of the mirabilite and gypsum (11.0 to 16.6‰) from the bottom sediments and young dried off zone also decrease from CB to MS in response to increasing content of sulfates brought by the Syr-Darya River (δ34S = 9.1 to 9.9‰) and weakening sulfate reduction. The 87Sr/86Sr ratio in the water and carbonates of the Aral basins do not differ, within the analytical error, and is 0.70914 ± 0.00003 on average. This value indicate that the dominant Sr source of the Aral Sea is Mesozoic–Cenozoic carbonate rocks. The Rb–Sr systems of the silicate component of the bottom silt (which is likely dominated by eolian sediments) of MS and LT plot on the Т = 160 ± 5 Ma, I0 = 0.7091 ± 0.0001, pseudochron. The Rb–Sr systems of CB are less ordered, and the silt is likely a mixture of eolian and alluvial sediments.  相似文献   

3.
This work addresses the isotopic heterogeneity of the Archean lithospheric mantle by the example of high-Mg, moderate-alkali, LILE and LREE-enriched Panozero sanukitoid massif, which is located in the Central Karelia, southeastern Baltic Shield. Initial Nd and Sr isotope characteristics were determined for mantle source of the massif. ?Nd(T) in the source are plotted below DM line, varying from + 0.7 to + 1.4 (+1.1, on average). The 87Sr/86Sr(T) ～ 0.7017 significantly exceeds that of depleted mantle and reflects change of Rb/Sr ratio in the source due to metasomatic reworking of mantle. Data on Pb isotope composition of potassium feldspars indicate that source of monzonites of the Panozero Massif had lower μ (238U/204Pb) = 8 and higher (238Th/232U) = 4.05 relative to primitive mantle.  相似文献   

4.
Sr, Nd and O Isotopic Studies on the Genesis of the Huashan Granite Complex   总被引：1，自引：0，他引：1  
Systematical Sr, Nd and O isotopic studies were made on the Huashan granite complex in Guangxi. Incombination with the studies of geological, petrological and geochemical data, it is believed that the complexconsists of granites of three stages. with different geneses and different source materials. They are not the prod-ucts of differentiation and evolution of one single consanguineous magma. Granites of the 1st stage are of theIndosinian syntectic type or I type, also derived from a mixed mantle-crustal source. Those of the 2nd stage areof the early Yanshanian syntectic type or I type. also derived from a mixed mantle-crustal source, and those ofthe 3rd stage are of the late Yanshanian transformed type or S type. derived from a crustal source.  相似文献   

5.
Sm-Nd and Rb-Sr whole-rock isochron dating of the samples of cumulated gabbro, diabase and andesitic porphyrite from the Armantai ophiolite, Xinjiang, yielded the ages of 561 ± 41 Ma (εNd(t) = 6.1) and 392 ± 17 Ma [(87Sr/86Sr)i = 0.7041], which stand for the ages of creation and later metamorphism of the ophiolites, respectively. The creation environment of the Armantai ophiolites seems to a back-arc basin caused by the southward subduction of the palaeo-Asia Ocean. This project was specially granted by the State under the Key Scientific and Technological Program for the “Eight Five-Year Plan” period.  相似文献   

6.
The Sr,Nd and Pb isotopic characteristics of the Wudang basic dyke swarms and basic volcanics of the Yaolinghe Group show that they were derived from the same multi-component mixing source in the mantle.The Wudang basic dyke swarms have(^87Sr/^86Sr)i=0.6905-0.7061,εNd(t)=-1.9-5.0,△^208Pb/^204Pb=35.49-190.26,△^207Pb/^204Pb=Th/Ta and a wide range of La/Yb ratios;and the basic volcanics of the Yaolinghe Group have(^87Sr/^86Sr)i=0.6487-0.7075,εNd(t)=0.11-3.94，△^208Pb/^204Pb=-81.58-219.95,△^207Pb/^204Pb=4.44-16.68and higher Th/Ta and La/Yb ratios,indicating that their source is a mixture of DM and EMⅡ,and the basic volcanics of the Yaolinghe Group were contaminated by crust materials en rout to the surface.Based on the geochemical features of continental tholeiitic basalts and being products of differen tacies derived from the same source,it can be concluded that an important rifting event in the South Qinling basement block occurred during Neoproterozoic,followed by a setting of oceanic basic in the Early Paleozoic.  相似文献   

7.
The current use of untreated river water for drinking purposes by the population of French Guiana has important impacts on public health. Consequently, groundwater is of major importance as a possible alternative drinking water supply to reduce these impacts. Since French Guiana belongs to the Guyana Shield, sustainable water management can be expected to depend increasingly on water from fissured aquifers in hard rocks. Groundwater samples were collected from shallow drill holes in the densely populated coastal area, and deeper wells in the basement (around Cayenne and along the Maroni and Oyapock rivers). This study reports on major and trace elements for which Na+ and Ca2+ excess with regard to Cl reflect the role of water-rock interaction, as well as Sr and Nd isotopes that reflect the role of the different lithologies. δ18O and δD in waters give constraints on the water cycle (recharge and evaporation processes).  相似文献   

8.
The Lajimiao norite-gabbro complex, as a part of the ophiolites on the southern side of the North Qinling belt, consists of gabbro and norite-gabbro. They were derived from different magma series: the gabbro was derived from tholeiitic magma series with higher TiO2, REE abundance and Fe3+/Fe2+ ratio ; norite-gabbro was derived from calc-alkali magma series with lower TiO2, Fe3+/Fe2+ ratio and REE abundance and much lower HREE abundance, which suggests that the source of the norite-gabbro magma was deeper and controlled by eclogite facies. Geochemical characteristics of both plutonic rocks are similar to those of island-arc basalts, such as relatively high contents of Ba, Pb and Sr and relatively low contents of Nb, Zr and N j.The Sr, Nd isotopic characteristics of the Lajimiao norite-gabbro complex are similar to those of ophiolites. Its εNd values are constant, about+2; whereas εst values have wide variation from - 6.4 to +31.2 and positively correlate with Na2O, H2O+ and CO2 contents and the Fe3+/Fe  相似文献   

9.
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10.
In order to elucidate the origin and migration of basinal brines in the Bachu Bulge, Tarim Basin, we have carried out analyses on chemical composition, and boron, hydrogen and oxygen isotopes of formation waters together with the XRD of clay minerals from the Paleozoic strata. The waters show Ca, B, Li and Sr enrichment and SO4 depletion in the Carboniferous and Ordovician and K enrichment in part of the Ordovician relative to seawater. The relationship between δD and δ^18O shows that all the data of the waters decline towards the Global Meteoric Water Line with the intersection of them close to the present-day local meteoric water, suggesting that modern meteoric water has mixed with evaporated seawater. The ^87Sr/^86Sr ratios range from 0.7090 to 0.7011, significantly higher than those of the contemporary seawater. The δ^11B values range from ＋19.7 to ＋32.3‰, showing a decrease with the depth and B concentrations. The results suggest that isotopically distinct B and Sr were derived from external sources. However, since the percentages of illite are shown to increase with depth among clay minerals in the study area, i.e., illite is due to precipitation rather than leaching during deeper burial, it is unlikely for illite to have contributed a significant amount of B to the waters. Thus, B with low δ^11B values is interpreted to have been added mainly from thermal degradation of kerogen or the basalts in the Cambrian and Lower Ordovician.  相似文献   

11.
Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.  相似文献   

12.
According to isotopic analysis of rocks of the Reft gabbro–diorite–tonalite complex (Middle Urals), gabbro and related diorite and dikes and vein-shaped bodies of plagiogranitoids, crosscutting gabbro, are similar to the depleted mantle substance in εNd(T) = 8.6–9.7 and εHf(T) = 15.9–17.9. Their model Hf ages are correlated with the time of crystallization. Here, the tonalites and quartz diorites constituting most of the Reft massif are characterized by lower values: εNd(T) = 3.7–6.0, εHf(T) = 11.1–12.7, and T DM values significantly exceeding the age datings. This is evidence that Neoproterozoic crustal rocks were a source of parental magma for these rocks. The primary 87Sr/86Sr ratio in rocks of both groups is highly variable (0.70348–0.70495). The data obtained allow us to reach the conclusion that the Reft gabbro–diorite–tonalite complex was formed as a result of nearly synchronous processes occurring in the crust and the mantle within a limited area.  相似文献   

13.
Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types:slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely corroded and replaced secondary calcic karstic rocks. The carbon, oxygen and strontium isotope compositions of the various karst rocks are analyzed systematically and compared to rocks without karst corrosion. The results indicate that(1) the Huanglong Formation in the eastern Sichuan Basin was a restricted bay supplied and controlled by freshwater in which mudmicrite and mud-dolomicrite exhibit low δ13C and δ18O values and high 87Sr/86 Sr ratios;(2) all types of karstic rocks in the paleokarst reservoirs of the Huanglong Formation in the research area are affected by atmospheric freshwater with the δ13C and δ18O values and 87Sr/86 Sr ratios in the original formation approaching those of atmospheric freshwater, which reflects ancient hydrological conditions, fluid properties, isotopic source and the fractionation effect;(3) the intensely corroded and replaced secondary limestone is affected by a variety of diagenetic fluids, often reflected by δ13C and δ18O values, while the 87Sr/86 Sr ratios exhibit the strong degree of the corrosion;(4) after comparing the 87Sr/86 Sr ratios of each type of karst rock, the diagenetic fluids are determined to be mainly atmospheric freshwater, and depending on the strength of corrosion, and the low 87Sr/86 Sr ratio fluids in the layer will participate in the karst process. The carbon, oxygen, and strontium isotopes of different karstic reservoirs can provide meaningful geochemical information for forecasting and evaluating the development and distribution rules of the Huanglong Formation at the margin of the eastern Sichuan Basin in time and space.  相似文献   

14.
The activity of the Damavand volcano (Central Alborz, northern Iran) began 1.8 Ma ago and continued up to 7 ka BP. Although the volcanic suite is clearly of shoshonitic affinity, only two petrographic types can be distinguished in the studied lavas: (1) weakly differentiated absarokites (49 < %SiO2 < 51), scattered around the volcano but with a regional extension, (2) highly differentiated banakites (59 < %SiO2 < 63), which form the bulk of the 4,000 m thick volcanic pile. All lavas are alkalic (3.7 < %K2O < 5), REE and LILE-rich (e.g., 85 < La < 148 ppm; 9 < Th < 32 ppm) and show highly fractionated REE patterns (69 < La/Yb < 115) and pronounced Nb–Ta negative anomalies. The absarokites are characterised by Sr (0.7045–0.7046) and Nd (0.51266–0.51269) isotope compositions close to the Bulk Earth values, and distinct from those of the banakites (0.7047 < 87Sr/86Sr < 0.7049, 0.51258 < 143Nd/144Nd < 0.51262). The Pb isotope ratios are also slightly lower in the absarokites than in the banakites (18.71 < 206Pb/204Pb < 18.77, 15.62 < 207Pb/204Pb < 15.63, 38.85 < 208Pb/204Pb < 38.91, and 18.77 < 206Pb/204Pb < 18.84, 15.62 < 207Pb/204Pb < 15.64, 38.94 < 208Pb/204Pb < 39.06, respectively). Overall, there is a clear tendency towards higher Sr, Pb and lower Nd isotope ratios with increasing degree of differentiation. This study suggests that the absarokites result from a low degree of partial melting (∼5%) of a highly metasomatized mantle source, which inherited its characteristics from an old subduction setting. The initiation of volcanic activity 1.8 Ma ago results from variations in the lithospheric thermal regime, probably related to lithospheric delamination as proposed for Anatolia (Pearce et al. 1990). The banakites are mainly generated by extensive fractional crystallisation (∼70%) of the absarokitic magma, with a limited amount (a few percents) of assimilation of an old crustal component, in the form of bulk assimilation or AFC processes, which both can explain the Sr, Nd and Pb isotope data.  相似文献   

15.
The Pohrenk fluorite mineralisation which makes up Central Anatolia’s most extensive fluorite region is Lutetian aged, and hosted in carbonate rocks that have undergone occasional karstification and silicification along a N–S fault trend. Fluid inclusion values and the position of fluorites in the Tb/La–Tb/Ca diagram show that mineralisation occurred in a hydrothermal environment with homogenisation temperatures ranging from 78.1–363°C. The presence of fluorite as a space filler in carbonate rocks and its association with silicification indicates that the solutions contained considerable amounts of Si alongside F (fluorine). The Pohrenk fluorite samples have 143Nd/144Nd values of between 0.512349 and 0.512497, whilst 87Sr/86Sr values vary between 0.708161 and 0.708772. These values indicate a mantle origin where continental contamination could occur. When the Nd–Sr values are compared to magmatic and young volcanics, the Pohrenk fluorites are seen to be enriched and exhibit similar isotopic signatures to Upper Cretaceous aged magmatics, Early-Middle Miocene volcanics and Mio-Quaternary volcanics.  相似文献   

16.
Doklady Earth Sciences - A mineralogical-geochemical study of globular phyllosilicates (GPS) of the glauconite-illite series of the Dolgokta Formation from the stratigraphic well Chunkinskaya Well...  相似文献   

17.
Geologic, petrographic and petrochemical studies of the late Mesozoic K-rich melanocratic dykes, including lamprophyres, andesite porphyrites and dacite-porphyry in the gold field system in the Jiaodong Peninsula, China, have shown that these dykes are characterized by rich potassium and alkali but poor titanium. They belong to an ultra-high potassic, shoshonitic and high potassic calc-alkaline rock series. The parental magma has relatively high initial strontium ratios ((87Sr/86Sr)i=0.70895-0.71140) and low (143Nd/144Nd)i ratios (varying from 0.51135 to 0.51231); and its δ18OSMow. whole rock values vary from +5.8‰ to +10.6‰ with a mean of+7.1‰. These features suggest that the source region of the magma is an enriched mantle wedge transformed from a continental lithosphere mantle which has experienced metasomatism by mantle-derived fluids with H2O-dominated fluids that were provided during the underthrusting of an ocean crust. The initial magma was generated by low-degree partial melting of the enri  相似文献   

18.
Doklady Earth Sciences -  相似文献   

19.
Carbonate, largely in the form of dolomite, is found throughout the host rocks and ores of the Nchanga mine of the Zambian Copperbelt. Dolomite samples from the hanging wall of the mineralization show low concentrations of rare-earth elements (REE) and roof-shaped, upward convex, shale-normalized REE patterns, with positive Eu*SN anomalies (1.54 and 1.39) and marginally negative Ce anomalies (Ce*SN 0.98,0.93). In contrast, dolomite samples associated with copper and cobalt mineralization show a significant rotation of the REE profile, with HREE enrichment, and La/LuSN ratios <1 (0.06–0.42). These samples also tend to show variable but predominantly negative Eu*SN and positive cerium anomalies and an upwardly concave MREE distribution (Gd-Er). Malachite samples from the Lower Orebody show roof-tile-normalized REE patterns with negative europium anomalies (Eu*SN 0.65–0.80) and negative cerium anomalies (Ce*SN 0.86–0.9). The carbonate 87Sr/86Sr signature correlates with the associated REE values. The uppermost dolomite samples show Neoproterozoic seawater-like 87Sr/86Sr ratios ranging from 0.7111 to 0.7116, whereas carbonate from Cu–Co mineralized samples show relatively low concentrations of strontium and more radiogenic 87Sr/86Sr, ranging between 0.7136–0.7469. The malachite samples show low concentrations of strontium, but give a highly radiogenic 87Sr/86Sr of 0.7735, the most radiogenic 87Sr/86Sr ratio. These new data suggest that the origin and timing of carbonate precipitation at Nchanga is reflected in the REE and Sr isotope chemistry. The upper dolomite samples show a modified, but essentially seawater-like signature, whereas the rotation of the REE profile, the MREE enrichment, the development of a negative Eu*SN anomaly and more radiogenic 87Sr/86Sr suggests the dolomite in the Cu–Co mineralized samples precipitated from basinal brines which had undergone significant fluid–rock interaction. Petrographic, REE, and 87Sr/86Sr data for malachite are consistent with the original sulfide Lower Orebody being subject to a later oxidizing event.  相似文献   

20.
Biotite igneous ages and well‐defined isochron ages of plutons from the composite Blue Tier Batholith and the Coles Bay area in northeastern Tasmania range from 395 to 370 Ma. The older limit of this range, for the George River granodiorite, is considerably older than any age previously recorded for NE Tasmania. The ages of the youngest plutons (Mt Paris and Anchor granites), which host cassiterite ores, record pervasive hydrothermal alteration events. The initial 87Sr/80Sr ratios of the granitoids range from 0.7061 to 0.7136 and suggest different protolith compositions, consistent with mineralogical and geochemical characteristics of each pluton. The S‐type garnetbiotite granites (Ansons Bay and Booby alia granites) have initial ratios greater than 0.7119, indicative of enriched, high Rb/Sr ratio, crustal source‐rocks of Proterozoic age (1700–800 Ma). The S‐type biotite granites (Poimena and Pearson granites) have relatively high initial 87Sr/86Sr ratios (0.7070, 0.7105) but overlap with those of the I‐type granodiorites (George River, Scamander Tier, Pyengana and Coles Bay granodiorites) which are in the range of 0.7061 to 0.7073. The initial ratios of the enriched altered plutons are poorly constrained, and on both hand‐specimen and thin‐section scales, reveal open‐system Sr isotopic patterns.

Isochron ages for the arenite‐lutite and lutite sedimentary associations of the Mathinna Beds, which are intruded by the granitoids, reflect an approach to Sr isotopic equilibrium during regional metamorphism. The metamorphic age (401 ± 7 Ma) of the early Pragian arenite‐lutite association indicates a relatively small time interval between deposition, regional metamorphism and granitoid intrusion. The isotopic age for the lutite sedimentary association (423 ± 22 Ma) is tentatively correlated with a Benambran‐age burial metamorphic event that has not previously been recorded in Tasmania.  相似文献   

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