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1.
Most rare-metal granites in South China host major W deposits with few or without Ta–Nb mineralization. However, the Yashan granitic pluton, located in the Yichun area of western Jiangxi province, South China, hosts a major Nb–Ta deposit with minor W mineralization. It is thus important for understanding the diversity of W and Nb–Ta mineralization associated with rare-metal granites. The Yashan pluton consists of multi-stage intrusive units, including the protolithionite (-muscovite) granite, Li-mica granite and topaz–lepidolite granite from the early to late stages. Bulk-rock REE contents and La/Yb ratios decrease from protolithionite granite to Li-mica granite to topaz–lepidolite granite, suggesting the dominant plagioclase fractionation. This variation, together with increasing Li, Rb, Cs and Ta but decreasing Nb/Ta and Zr/Hf ratios, is consistent with the magmatic evolution. In the Yashan pluton, micas are protolithionite, muscovite, Li-mica and lepidolite, and zircons show wide concentration ranges of ZrO2, HfO2, UO2, ThO2, Y2O3 and P2O5. Compositional variations of minerals, such as increasing F, Rb and Li in mica and increasing Hf, U and P in zircon are also in concert with the magmatic evolution from protolithionite granite to Li-mica granite to topaz–lepidolite granite. The most evolved topaz–lepidolite granite has the highest bulk-rock Li, Rb, Cs, F and P contents, consistent with the highest contents of these elements and the lowest Nb/Ta ratio in mica and the lowest Zr/Hf ratio in zircon. Ta–Nb enrichment was closely related to the enrichment of volatile elements (i.e. Li, F and P) in the melt during magmatic evolution, which raised the proportion of non-bridging oxygens (NBOs) in the melt. The rims of zoned micas in the Li-mica and topaz–lepidolite granites contain lower Rb, Cs, Nb and Ta and much lower F and W than the cores and/or mantles, indicating an exotic aqueous fluid during hydrothermal evolution. Some columbite-group minerals may have formed from exotic aqueous fluids which were originally depleted in F, Rb, Cs, Nb, Ta and W, but such fluids were not responsible for Ta–Nb enrichment in the Yashan granite. The interaction of hydrothermal fluids with previously existing micas may have played an important role in leaching, concentrating and transporting W, Fe and Ti. Ta–Nb enrichment was associated with highly evolved magmas, but W mineralization is closely related to hydrothermal fluid. Thus these magmatic and hydrothermal processes explain the diversity of W and Ta–Nb mineralizations in the rare-metal granites. 相似文献
2.
The Late Paleozoic intraplate magmatism of the Selenga-Vitim structural zone of the Baikal region (Khamar-Daban Range) produced
granitoids of different geochemical types: palingenic calc-alkaline granitoids, subalkaline monzogranites, and rare-metal
Li-F granitoids and their subvolcanic analogues. Subalkaline and rare-metal granitoids occur in the periphery of the Late
Paleozoic magmatic zone. Rare metal granite magmatism is manifested in this region as nearly N-S trending intrusive-dike belts
comprising multiphase intrusions (Kharagul, Urugudei, and Bitu-Dzhida massifs) with an exposed area of ∼10 km2 and an age of formation from 311 to 321 Ma and series of accompanying dikes. The early phases of the intrusions are made
up of biotite granites usually with fluorite, which are changed during the late stage by typical topazbearing rare-metal amazonite-albite
granites. In the subvolcanic facies, thicker subalkaline dikes of monzonite porphyry, granite porphyry, and elvan are changed
by ongonites, topaz rhyolites, and topazites, which occasionally serve as cement in eruptive and fluid-explosive breccias.
The development of multiphase intrusions from early biotite granites to late amazonite-albite granites with Li-F mica was
accompanied by an increase in SiO2 and, especially, Na2O contents, whereas the level of (FeO + Fe2O3), CaO, and K2O declined. Geochemical evolution includes an increase in the same direction in the contents of F, Li, Rb, Cs, Sn, Be, Ta,
and Pb and a decrease in Ba, Sr, Zn, Zr, Th, and U. Similar evolution is also characteristic of the subvolcanic rocks, which
emphasizes the genetic relation of the whole intrusive-dike complex of the Khamar-Daban province. Significant differences
were detected in the distribution of K, Ba, Sr, and Zr between the calc-alkaline granitoids and rare-metal Li-F granites.
The continental crust-normalized patterns of the raremetal granites show positive anomalies for Li, Rb, Nb, and Pb. The rare-metal
Li-F granites could not be produced by palingenesis only, and their formation required specific conditions causing extensive
accumulation of characteristic trace elements. During the evolution of granite melts, Li, Rb, Ta, Nb, Sn, W, and F are extensively
accumulated in late intrusive phases, which indicates an important role of the processes of magmatic and fluid-magmatic differentiation
during their formation. The composition and isotope geochemical characteristics of the supposed magma source material correspond
to the ancient Precambrian continental crust with a mean model age of more than 1200 Ma. 相似文献
3.
G. P. Zaraisky A. M. Aksyuk V. N. Devyatova O. V. Udoratina V. Yu. Chevychelov 《Petrology》2009,17(1):25-45
The Zr-Hf geochemical indicator, i.e., the Zr/Hf ratio (in wt %) in granitic rocks is proposed to be used as the most reliable indicator of the fractionation and ore potential of rare-metal granites. It was empirically determined that the fractional crystallization of granitic magma according to the scheme granodiorite → biotite granite → leucogranite → Li-F granite is associated with a decrease in the Zr/Hf ratio of the granites. The reason for this is the stronger affinity of Hf than Zr to granitic melt. This was confirmed by experiments on Zr and Hf distribution between granitic melt and crystals of Hf-bearing zircon (T = 800°C, P= 1 kbar). The application of the Zr/Hf indicator was tested at three classic territories of rare-metal granites: eastern Transbaikalia, central Kazakhstan, and the Erzgebirge in the Czech Republic and Germany. The reference Kukul’bei complex of rare-metal granites in eastern Transbaikalia (J3) is characterized by a uniquely high degree of fractionation of the parental granitic melt, with the granites and their vein derivatives forming three intrusive phases. The biotite granites of phase 1 are barren, the leucogranites of phase 2 are accompanied by greisen Sn-W mineral deposits (Spokoininskoe and others), and the final dome-shaped stocks of amazonite Li-F granites of phase 3 host (in their upper parts) Ta deposits of the “apogranite” type: Orlovka, Etyka, and Achikan. The Kukul’bei Complex includes also dikes of ongonites, elvanes, amazonite granites, and miarolitic pegmatites. All granitic rocks of the complex are roughly coeval and have an age of 142±0.6 Ma. The Zr/Hf ratio of the rocks systematically decreases from intrusive phase 1 (40–25) to phases 2 (20–30) and 3 (10–2). Compared to other granite series, the granites of the Kukul’bei Complex are enriched in Rb, Li, Cs, Be, Sn, W, Mo, Ta, Nb, Bi, and F but are depleted in Mg, Ca, Fe, Ti, P, Sr, Ba, V, Co, Ni, Cr, Zr, REE, and Y. From earlier to later intrusive phases, the rocks become progressively more strongly enriched or depleted in these elements, and their Zr/Hf ratio systematically decreases from 40 to 2. This ratio serves as a reliable indicator of genetic links, degree of fractionation, and rare-metal potential of granites. Greisen Sn, W, Mo, and Be deposits are expected to accompany granites with Zr/Hf < 25, whereas granites related to Ta deposits should have Zr/Hf < 5. 相似文献
4.
The dike belt and separate intrusive bodies of the Abdar–Khoshutula series were formed in the NE-trending linear zone, southwest of the Daurian–Khentei batholith, in the peripheral part of the Early Mesozoic magmatic area, on the western termination of the Mongol–Okhotsk belt. The granitoids of this series are subdivided into following geochemical types: anatectic granitoids of the calc-alkaline and subalkaline series, alkaline rocks, and plumasite rare-metal leucogranites (Li–F granites). The entire series was formed within approximately 12–15 Ma. Its geochemical evolution follows two trends, which correspond to two stages of the granitoid magmatism. The early stage was responsible for the formation of granitoids of two phases of the Khoshutulinsky Pluton and alkaline syenites with similar trace element distribution patterns. However, syenites, as agpaitic rocks, are significantly enriched in Ba, Zr, and Hf. The late stage of the intrusive- dike series resulted in the formation of the dike belt and Abdar Massif of rare-metal granites. These rocks show enrichment in Li, Rb, Cs, Nb, Ta, Sn, and Y, and deep negative anomalies of Ba, Sr, La, and Ce, which are best expressed in the late amazonite–albite granites of the Abdar intrusion and ongonites of the dike belt. The intrusive-dike series in the magmatic areas of different age of Mongolia and Baikal region are characterized by the wide compositional variations, serve as important indicators of mantle-crustal interaction and differentiation of granitoid magmas, and could highlight the nature of zonal areas within the Central Asian Fold Belt. Obtained geochemical data indicate a potential opportunity to concentrate trace and ore components during long-term evolution of the intrusive-subvolcanic complexes, which could be indicators of the evolution of the ore-magmatic systems bearing rare-metal mineralization. 相似文献
5.
内蒙古东七一山钨多金属矿位于北山造山带东段,是一个以钨为主,共伴生锡、钼、铷、铍、铌、钽、铁和萤石的综合型矿床。本次工作对含矿花岗质杂岩开展了岩石学、地球化学、锆石U-Pb及辉钼矿Re-Os年代学研究。富W-Sn-Mo花岗岩岩性为细粒似斑状二长花岗岩、中细粒似斑状二长花岗岩、花岗斑岩,结晶年龄分别为220.6±1.6Ma、220.4±1.3Ma和220.0±1.1Ma。富Rb-Be-Nb-Ta花岗岩岩性为中粗粒钠长石化似斑状二长花岗岩,结晶年龄为219.9±1.9Ma。辉钼矿Re-Os定年获得加权平均年龄为211±1Ma(MSWD=0.83),说明成岩成矿发生在晚三叠世。含矿花岗质杂岩均具有高硅、富碱、贫铁镁钙特征,为高钾钙碱性花岗岩。其中,富W-Sn-Mo花岗岩为准铝质-过铝质花岗岩;而富Rb-Be-Nb-Ta花岗岩为强过铝质花岗岩。杂岩体轻重稀土具一定分馏,呈现显著的负Eu异常,均富集Rb、K、U、Ta,强烈亏损Ba、Nb、Sr、P、Ti、Zr、Hf。与富W-Sn-Mo花岗岩相比,富Rb-Be-Nb-Ta花岗岩具更低的稀土总量,更显著的Eu负异常,并显示微弱的稀土四分组效应,更高的Li、Ta含量,更低的P、Ti、Zr、Hf、W、Mo、Bi含量。时空关系和地球化学特征表明,杂岩体为同一次岩浆活动不同演化阶段的产物,均经历了较高程度的结晶分异和较强的熔体-流体相互作用。相比而言,富Rb-Be-Nb-Ta花岗岩比富W-Sn-Mo花岗岩结晶分异程度更高,熔体-流体作用更强,花岗质岩浆的高程度分离结晶和熔体-流体相互作用是形成该杂岩体并促使成矿的重要控制因素。 相似文献
6.
福建沿海中生代变质带中花岗质岩石的地球化学 总被引：12，自引：1，他引：12
福建东南沿海中生代变质带的花岗质岩石分布于东山、晋江和莆田等广大地区。花岗岩中常包含黑云母、石榴子石或白云母。但地球化学研究表明，这些花岗岩属于钙碱性或高钾钙碱性，以低Rb、Zr、Hf、Nb、Y、Ga含量和Rb/Sr比值，以及高Ba、Sr丰度为特征，属于典型的Ⅰ型花岗岩。它们的稀土总量普遍较低，具有轻稀土富集、铕中等亏损的稀土分布模式。本带三个地区花岗岩的微量元素组成存在一定差异，但具有相似的Sr、Nd同位素组成，以高εNd(t)(-4.49～-3.15)和低ISr(0.7055-0.7074)、tDM(1.19-1.29Ga)为特征。地球化学研究显示本带花岗岩形成于相同的构造背景－大型边缘火山弧环境。其母岩浆是由类似于麻源群的古老火成变质岩部分熔融产生的熔融体与同期的幔源玄武质岩浆发生一定程度混合而成。不同地区或同一地区花岗岩地球化学组成上的差异是不同程度的部分熔融和结晶分异的结果。 相似文献
7.
G. P. Zaraisky A. M. Aksyuk V. N. Devyatova O. V. Udoratina V. Yu. Chevychelov 《Petrology》2008,16(7):710-736
The concept of granitic melt fractionation as the main process in the concentration of rare elements in granites calls for
the development of a reliable method to determine the evolutionary sequences of granite series. We propose to use for this
purpose a zirconium-hafnium indicator, the Zr/Hf weight ratio in granitic rocks (Zaraisky et al., 1999, 2000). By the example
of three classic regions of rare-metal deposits, eastern Transbaikalia, central Kazakhstan, and Erzgebirge (Czech Republic
and Germany), it was empirically shown that the Zr/Hf ratio of granites decreases during the fractional crystallization of
granite magmas in the sequence granodiorite → biotite granite → leucogranite → lithium-fluorine granite. The reason is the
higher affinity of Hf compared with Zr to a granite melt. This implies that the crystallization and settling of accessory
zircon will cause the progressive enrichment of Hf relative to Zr in the residual melt. As a result, the Zr/Hf ratio decreases
regularly in the series of sequential phases of granite intrusion related to a single magma chamber from granodiorite to biotite
granite, leucogranite, and Li-F granite (from 45-30 to 10-2). Our experimental investigations supported the preferential enrichment
of haplogranite melt in Hf and zircon crystals in equilibrium with melt in Zr (T= 800°C and P = 1 kbar). The Zr/Hf indicator was tested by the example of the wellknown Kukulbei rare-metal granite complex of eastern
Transbaikalia (J3), which is unique in the degree of fractionation of initial granite melt with the formation of three phases
of granite emplacement and vein derivatives. An important feature of the complex is its “short” differentiation trend. It
was supposed that the granite magma of the first phase is parental, and the later phases forming small intrusive bodies in
large massifs of biotite granites of the first phase are sequential products of its crystallization differentiation in a magma
chamber. The biotite granites of the first phase are barren. The leucocratic granites of the second phase are accompanied
by tin-tungsten greisen deposits (e.g., Spokoininskoe), and the upper part of cupola-like stocks of Li-F amazonite granites
of the third phase host apogranite-type tantalum deposits (Orlovka, Etyka, and Achikan). In addition to three granite phases,
the Kukulbei complex includes dikes of ongonites, elvans, amazonite granites, and chamber miarolitic pegmatites. All of the
granitic rocks of the complex have similar isotopic ages of 142± 0.6 Ma. The Zr/Hf ratio decreases systematically from phase
1 (40–25), to phase 2 (20–10), and phase 3 (10–2). The ongonites, elvans, and pegmatites have similar Zr/Hf ratios (15-5),
falling between the ranges of leucocratic muscovite granites and Li-F granites. Compared with other granite series, the granitic
rocks of the Kukulbei complex show specific petrographic and geochemical features: they are strongly enriched in Rb, Li, Cs,
Be, Sn, W, Mo, Ta, Nb, Bi, and F but depleted in Mg, Ca, Fe, Ti, P, Sr, Ba, V, Co, Ni, Cr, Zr, REE, and Y. From the early
to late intrusion phases, the degree of enrichment and depletion in these element groups increases regularly. This is accompanied
by a significant decrease (from 40 to 2) in Zr/Hf, which can be used as a reliable indicator of genetic relations, degree
of fractionation, and rare-metal potential of granites. Granites with Zr/Hf values lower than 25 are promising for prospecting
for Sn, W, Mo, and Be greisen deposits, whereas the formation of Ta deposits requires Zr/Hf values lower than 10. 相似文献
8.
吉南老岭地区早白垩世铝质A型花岗岩的厘定及其构造意义 总被引：1，自引：0，他引：1
主微量元素分析和LA-ICP-MS锆石U-Pb年龄显示吉南老岭地区的头道、老岭、上绿水桥和高台子岩体为一套早白垩世铝质A型花岗岩.主要岩性为钾长花岗岩、晶洞钾长花岗岩、花岗斑岩和花岗岩.LA-ICP-MS锆石U-Pb年龄为121~125Ma.主量元素具有富Si、alk, 贫Fe、Mg、Ca、Ti的特征; 微量元素亏损Ba、Sr、Ti、Nb、Ta、P, 富集K、Rb、Th等不相容元素; 稀土元素具有中等到强烈的负铕异常及右倾海鸥型的球粒陨石标准化稀土配分模式.元素地球化学特征表明岩体为铝质A型花岗岩(A/CNK=0.82~1.15, A/NK=1.00~1.28).岩石具有较低的不相容元素Ce/Nb、Y/Nb、Yb/Ta比值, 为A1型非造山花岗岩.研究表明吉南老岭地区早白垩世时处于非造山的伸展构造环境, 是华北板块东部早白垩世伸展地球动力学背景在吉林南部地区的岩浆活动体现. 相似文献
9.
通过对龙王山灰白色细粒石英闪长岩和灰白色细粒二长花岗岩样品进行LA-ICP-MS锆石U-Pb测年结果属于晚志留世侵入岩。岩石地球化学特征表明,为高钾过铝质-准铝质碱钙性岩;稀土元素Eu具有弱负异常特征;微量元素中Ta、Nb、gr、Sr、Ti、P相对贫化,Rb、Th、Hf、Ba、Sc、K、Ce、Nd、Sm含量相对富集。Rb／Sr平均值为0．30,介于上地幔值与地壳值之间,反映出壳幔源的特点,为s型花岗岩。综合分析该期花岗岩是弧陆碰撞向陆陆碰撞转化阶段构造背景下形成的同碰撞花岗岩。 相似文献
10.
L. F. Syritso E. V. Badanina V. S. Abushkevich E. V. Volkova E. V. Shuklina 《Petrology》2012,20(6):567-592
The results of study of chemical composition, mineral-forming medium, P-T conditions of crystallization, and the age characteristics of subvolcanic felsic rocks that are spatially associated with rare-metal granite massifs in the ore units of Transbaikalia (Sherlovaya Gora, Khangilay, Bukuka, Belukha, and Shumilovka) give grounds for defining cogenetic volcanoplutonic associations. These associations within the studied region consist of rare-metal granites, ongonites, rhyolites, ongorhyolites, and trachyrhyodacites, which have much in common, but also many differences. The common chemical features of these rocks are their peraluminium signature, low mafic index and basicity, as well as enrichment (as compared to crust) in trace lithophile elements (Li, Rb, Nb, Ta, Sn, W, and F), the low contents of Zr, REE, and Sr, and the similar distribution of trace and refractory elements. At the same time, these rocks differ in the proportions of sodium and potassium, levels of concentrations of lithophile trace and refractory elements, REE distribution patterns, P-T regimes of crystallization, and the volatile composition. The composition of melts from all types of the studied rocks and trace element distribution between melts and rocks were studied on the basis of ion-microprobe analysis of rehomogenized glasses of melt inclusions in quartz. The highest concentrations of lithophile trace elements in the melt, including Cs (up to 300 ppm), Rb (up to 1002 ppm), U (up to 42 ppm), and Th, were found in the trachyrhyodacites of the Bukuka-Belukha ore unit; in terms of Li content this melt is comparable with the Ary-Bulak ongonites (690 and 715 ppm Li, respectively), and differ by an order of magnitude in the contents of refractory and rare-earth elements (total REE 94.4 and 5.44 ppm, respectively), which is indicative of a lower differentiation degree of this melt as compared to ongonites. Potassic rhyolites are peculiar in the low content of lithophile trace elements, but residual melt reveals notable enrichment in Li (up to 130 ppm) and Nb (up to 120 ppm). The accumulation of U in the residual melt of the trachyrhyodacitic and rhyolitic magmas of Eastern Transbaikalia may indicate their high potential for postmagmatic uranium ore formation. Isotope-geochronological studies (Rb-Sr isotope system) of the Sherlovaya Gora ore unit showed that the entire complex of volcanoplutonic association (granites, ongonites, rhyolites, and ongorhyolites) formed almost simultaneously within an interval of 4 Ma: from 145.7 ± 1.3 Ma at IRSr = 0.70507 ± 20 and MSWD = 0.48 to 141.5 ± 1.0 Ma at IRSr = 0.70359 ± 63 Ma and MSWD = 0.24. A spatial association of the subvolcanic rock complex with rare-metal granite massifs, their formation within a common age interval, geochemical features, and P-T conditions of crystallization suggest that they are genetically related but were derived from variably evolved sources, which originated from a single protolith under the action of mantle plume that existed beneath Central Asia at that time (Yarmolyuk and Kovalenko, 2003). 相似文献
11.
云南个旧锡矿是全球最大的锡多金属矿床之一,但矿区内同时代花岗岩成锡矿潜力差异显著,其控制因素仍不清楚。本文选取贫矿的龙岔河似斑状花岗岩和成锡矿的老厂-卡房(后文简称老-卡)花岗岩为研究对象,通过全岩地球化学成分和黑云母成分分析,系统研究个旧矿区不同花岗岩成锡矿潜力差异的控制因素。测试结果表明,龙岔河花岗岩和老-卡花岗岩具有相似的、以表壳物质为主的岩浆源区以及较高的初始熔融温度,表明岩浆源区和熔融条件不是控制二者成矿潜力差异的主要原因。黑云母成分显示老-卡花岗岩和龙岔河花岗岩均具有较低的氧逸度,岩浆演化过程中锡为不相容元素,有利于锡在残余熔体中富集,表明氧逸度条件也不是导致成矿潜力差异的关键因素。龙岔河花岗岩发育角闪石、榍石、黑云母,而老-卡花岗岩发育岩浆白云母,指示后者分异程度更高。此外,与龙岔河花岗岩相比,老-卡花岗岩具有富硅,贫钛、铁、镁、钙和稀土元素特征,稀土元素呈现“海鸥式”配分模式,并且具有较低的Nb/Ta、Zr/Hf、K/Rb和较高的Rb/Sr比值,同样指示老-卡花岗岩具有更高的结晶分异程度。并且相比于龙岔河花岗岩为准铝质的特征,老-卡花岗岩的过铝质特征有利于锡分配进入岩浆出溶的流体相中富集成矿。因此,岩浆性质和演化程度是导致个旧地区不同花岗岩成矿潜力差异的主要原因,龙岔河花岗岩形成锡矿化的潜力较小。 相似文献
12.
滇西腾冲-梁河地块石英闪长岩-二长花岗岩锆石U-Pb年龄、Hf同位素特征及其地质意义 总被引：2，自引：0，他引：2
高黎贡-腾梁花岗岩带是冈底斯花岗岩带的东延部分。腾梁花岗岩中辉长-闪长质包体、花岗岩、石英闪长岩密切共生。辉长-闪长质包体的结构构造、矿物学特征表明,它们是岩浆快速冷凝结晶的产物。地球化学数据显示,辉长-闪长质包体为钙碱性系列,具有低SiO2、高MgO和Mg#的特征,富集Rb、Sr、Th、Ba和Ce,亏损Nb、Ta、P、Zr、Yb和Y;寄主花岗岩为中钾—高钾钙碱性系列,准铝质到弱过铝质,富集Rb、Th、Zr和Hf,亏损Nb、Ta、Ti、Sr、P和Ba,具有中等程度的负Eu异常;石英闪长岩介于二者之间。锆石U-PbLA-ICP-MS定年显示,石英闪长岩形成年龄为127.10±0.96Ma,花岗岩形成年龄为123.8±2.5Ma。结合辉长-闪长质包体形成年龄为122.6Ma,三者年龄基本一致,从年代学角度为花岗岩、辉长-闪长质包体和石英闪长岩岩浆混合作用成因提供了证据。石英闪长岩锆石εHf(t)值变化于-7.61～-3.80。结合辉长-闪长质包体、花岗岩的εHf(t)值及地球化学特征,认为花岗岩来源于古老地壳的部分熔融,辉长-闪长质包体来源于地幔楔橄榄岩部分熔融,石英闪长岩为幔源岩浆与古老地壳部分熔融的岩浆完全混合的产物。腾梁地块早白垩世侵入岩很可能与班公湖-怒江洋壳岩石圈向南俯冲的动力学背景有关。 相似文献
13.
小兴安岭霍吉河钼矿区含矿花岗岩类特征及成矿年龄 总被引：5，自引：3，他引：2
黑龙江霍吉河钼矿区内含矿花岗岩类岩石组合为黑云母二长花岗岩、二长花岗岩和花岗细晶岩,属高钾钙碱性岩-钾玄岩系列准铝质-过铝质岩石,具有轻稀土富集、重稀土亏损分馏模式;富集不相容元素(Cs、Th)并表现为Ta和Nb负异常以及Pb、Sr正异常,显示俯冲带地球化学特征.含矿岩浆岩明显富集Mo、Cu、Pb、Zn、W、Cr等金属元素.岩石全岩铅同位素来源比较复杂,具有混合成因铅特征.辉钼矿Re-Os模式年龄为180.7±2.5Ma和181.3±2.6Ma,钼矿成矿时代为早侏罗世.霍吉河钼矿是在蒙古-鄂霍茨克洋和古太平洋相向联合俯冲作用下,导致霍吉河地区发生地壳增生和壳幔相互作用以及后来的拆沉作用,形成了该区花岗质岩石和钼矿床.高度演化的花岗岩体(脉)可以作为今后本区钼矿床的找矿方向. 相似文献
14.
Characteristics of geochemical evolution of trace elements and REE in Gejiu granites,Yunnan Province
Jie Lu 《中国地球化学学报》1988,7(2):155-169
The evolution characteristics of Gejiu granites, Yunnan Province are described in terms of their petrology, especially their
trace elements and REE geochemistry. The three major types of Gejiu granites: porphyritic biotite monzonitic granite (stage
I), medium-coarse-grained biotite-K-feldspar granite (stage II) and two-mica alkali-feldspar granite (stage III) are thought
to have been formed successively from the same granite magma source through fractional crystallization (Rayliegh fractionation),
because linear correlations are found between log(Rb/Sr)-log Sn, log(Rb/Ba)-log Sn, log(Rb/Ba)-log(Rb/Sr), log La-log Sr,
log Ce-log Sr, log Eu-log Sr, etc. In addition, the characteristics of REE distribution patterns in these three major types
of granites also reflect the magmatic differentiation features of Gejiu granites. Of the three major types, the two-mica alkali-feldspar
granite of stage III underwent the strongest differentiation, and thus has the closest genetic relationship with the Gejiu
tin-polymetallic ore deposit. Such tin-polymetal mineralized granites are characterized by high Rb/Sr and Rb/Ba ratios, low
K/Rb and ΣCe/ΣY ratios and remarkable Eu depletion. 相似文献
15.
I. A. Andreeva 《Petrology》2016,24(5):462-476
Melt inclusions were studied by various methods, including electron and ion microprobe analysis, to determine the compositions of melts and mechanisms of formation of rare-metal peralkaline granites of the Khaldzan Buregtey massif in Mongolia. Primary crystalline and coexisting melt inclusions were found in quartz from the rare-metal granites of intrusive phase V. Among the crystalline inclusions, we identified potassium feldspar, albite, tuhualite, titanite, fluorite, and diverse rare-metal phases, including minerals of zirconium (zircon and gittinsite), niobium (pyrochlore), and rare earth elements (parisite). The observed crystalline inclusions reproduce almost the whole suite of major and accessory minerals of the rare-metal granites, which supports the possibility of their crystallization from a magmatic melt. Melt inclusions in quartz from these rocks are completely crystallized. Their daughter mineral assemblage includes quartz, microcline, aegirine, arfvedsonite, polylithionite, a zirconosilicate, pyrochlore, and a rare-earth fluorocarbonate. The melt inclusions were homogenized in an internally heated gas vessel at a temperature of 850°C and a pressure of 3 kbar. After the experiments, many inclusions were homogeneous and consisted of silicate glass. In addition to silicate glass, some inclusions contained tiny quench zircon crystals confined to the boundary of inclusions, which indicates that the melts were saturated in zircon. In a few inclusions, glass coexisted with a CO2 phase. This allowed us to estimate the content of CO2 in the inclusion as 1.5 wt %. The composition of glasses from the homogeneous melt inclusions is similar to the composition of the rare-metal granites, in particular, with respect to SiO2 (68–74 wt %), TiO2 (0.5–0.9 wt %), FeO (2.2–4.6 wt %), MgO (0.02 wt %), and Na2O + K2O (up to 8.5 wt %). On the other hand, the glasses of melt inclusions appeared to be strongly depleted compared with the rocks in CaO (0.22 and 4 wt %, respectively) and Al2O3 (5.5–7.0 and 9.6 wt %, respectively). The agpaitic index is 1.1–1.7. The melts contain up to 3 wt % H2O and 2–4 wt % F. The trace element analysis of glasses from homogenized melt inclusions in quartz showed that the rare-metal granites were formed from extensively evolved rare-metal alkaline melts with high contents of Zr, Nb, Th, U, Ta, Hf, Rb, Pb, Y, and REE, which reflects the metallogenic signature of the Khaldzan Buregtey deposit. The development of unique rare metal Zr–Nb–REE mineralization in these rocks is related to the prolonged crystallization differentiation of melts and assimilation of enclosing carbonate rocks. 相似文献
16.
皖南及邻区早白垩世中—晚期酸性岩浆岩产于扬子陆块江南古隆起东段,岩体类型为花岗岩、碱长花岗岩及钾长花岗岩。岩体含有丰富的锆石、富F的萤石及富含稀土的磷钇矿、独居石、褐帘石等矿物。主量元素具较高含量的SiO2和K2O,较低含量的TiO2、MgO、CaO,高(Na2O+K2O)/Al2O3值,高FeOT/MgO比;富集REE(Eu亏损),HREE亏损不严重,稀土配分模式表现为海鸥型;明显富集Zr、Nb、Rb、Ta、Y、Yb,显著亏损Cr、Co、Ni、V、Ba、Sr。地化特征分析认为早白垩世中—晚期花岗岩为A2型花岗岩,产生于造山后的伸展环境,是正常安山质地壳在皖南印支期加厚地壳熔融结束之后继续受地幔物质底侵部分熔融所形成。 相似文献
17.
锂（Li）是一种战略关键金属,岩浆阶段主要在花岗质岩石中得到富集和结晶。由于具有不相容和富挥发性等性质,锂对花岗岩的成岩成矿具有重要的制约。文章利用电子探针、LA-ICP-MS 等分析手段,对湖南香花岭地区癞子岭和尖峰岭花岗岩进行系统岩相学、主微量和矿物学研究,结果表明：（1）花岗质岩浆结晶分异过程中,Li 含量逐渐升高,大幅度降低了熔体粘度,增大了结晶温度区间,花岗质岩浆得到充分结晶分异,导致花岗岩的垂直分带;（2）花岗岩中Li 与稀有金属含量呈正相关关系,Li 与Ta、Nb、Sn 等稀有金属具有协同成矿作用;（3）花岗岩中云母类矿物具有向富Li 演化的趋势,以铁锂云母为主,随着铁锂云母的结晶,Nb、Ta、Sn 等稀有金属相继析出,导致晚期云母中Ta、Nb 等含量降低。熔体中H2O、F 等对花岗质岩浆的性质和结晶分异有较大影响,但不足以致使花岗岩呈垂直分带。 相似文献
18.
New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This complex is characterized by discontinuous ring-shaped outcrops cut by later faulting. The A-type rocks of the AIC are late Neoproterozoic post-collisional granites, including alkali feldspar granite, alkaline granite and peralkaline granite. They represent the outer zones of the AIC, surrounding a core of older rocks including monzogranite, syenogranite and granophyre granite. The sharp contacts between A-type granites of the outer zone and the different granitic rocks of the inner zone suggest that the AIC was emplaced as different phases over a time interval, following complete crystallization of earlier batches. The A-type granites represent the late intrusive phases of the AIC, which were emplaced during tectonic extension, as shown by the emplacement of dykes synchronous with the granite emplacement and the presence of cataclastic features. The A-type granites consist of K-feldspars, quartz, albite, amphiboles and sodic pyroxene with a wide variety of accessory minerals, including Fe-Ti oxides, zircon, allanite, fluorite, monazite, titanite, apatite, columbite, xenotime and epidote. They are highly evolved(71.3–75.8 wt% SiO_2) and display the typical geochemical characteristics of post-collisional, within-plate granites. They are rare-metal granites enriched in total alkalis, Nb, Zr, Y, Ga, Ta, REE with low CaO, MgO, Ba, and Sr. Eu-negative anomalies(Eu/Eu* = 0.17–0.37) of the A-type granites reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interactions. The chemical characteristics indicate that the A-type granites of the AIC represent products of extreme fractional crystallization involving alkali feldspar, quartz and, to a lesser extent, ferromagnesian minerals. The parent magma was derived from the partial melting of a juvenile crustal protolith with a mantle contribution. Accumulation of residual volatile-rich melt and exsolved fluids in the late stage of the magma evolution produced pegmatite and quartz veins that cut the peripheries of the AIC. Post-magmatic alteration related to the final stages of the evolution of the A-type granitic magma, indicated by alterations of sodic amphibole and sodic pyroxene, hematitization and partial albitization. 相似文献
19.
L.G. Kuznetsova A.M. Spiridonov S.I. Dril’ Z.I. Kulikova 《Russian Geology and Geophysics》2012,53(10):1077-1089
We studied the geologic position, geodynamic setting, petrology, and geochemistry of veined lepidolitic granitoids from the Mungutiyn Tsagaan Durulj (MTD) occurrence (central Mongolia), found within the area of Mesozoic intraplate rare-metal magmatism. It has been established that their trace-element enrichment resulted from the intense effect of fluids rich in F, K, Li, Rb, Cs, Sn, Be, and W, which arrived from a deep magma chamber of rare-metal granitic melts, on leucogranites with originally weak rare-metal mineralization. Very high contents of F, rare alkali metals, Sn, Be, and W, characteristic of MTD granitoids, are close only to those in greisens of rare-metal granites and topaz-lepidolite-albitic pegmatites. The difference from the greisens in each case might be due to the features of the original rocks. The difference between the greisenized MTD leucogranites and the topaz-lepidolite-albitic pegmatites is more radical: Along with evident petrographic distinctions, it includes an evolution trend toward the albite norm decrease, not typical of Li–F igneous rocks; rock shearing and gneissosity, which must have contributed to their chemical transformation according to this trend; and stably lower contents of Nb and Ta (trace elements which usually accumulate during crystallization fractionation of F–Li granitic melts and are poorly soluble in magmatic fluids). The greisenized MTD granitoids are not only high-grade rare-metal ores of Li, Rb, F, and Sn but are also regarded as an indicator of a deep concealed pluton of rare-metal granites. 相似文献
20.
Mohamed Abdel-Moneim Mohamed 《Arabian Journal of Geosciences》2012,5(4):697-712
The Neoproterozoic pluton of Gabal Gharib granite Eastern Desert of Egypt is intruded in subduction-related calc-alkaline granitic rocks of granodiorite to adamellite composition. A zone of metasomatized granite was developed along the contacts at the expense of the calc-alkaline granite. The granite of Gabal Gharib is hypersolvus, composed mainly of orthoclase-microperthite, quartz, and interstitial arfvedsonite. Fluorite, zircon, ilmenite, allanite, and astrophyllite are the main accessories. Pegmatite pods as well as miarolitic cavities (mineral-lined cavities) are common and ranging in size from a few millimeters to 50?cm. Rare-metal minerals such as columbite, cassiterite, and fluorite have been identified from the miarolitic cavities. Geochemical studies revealed that Gabal Gharib granite is a highly fractionated granite, homogeneous in composition, with high contents of SiO2, and alkalis, high Ga/Al, and Fe/Mg ratios, and low concentrations of Al, Mg, and CaO relative to granodiorite?Cadamellite country rocks. Gabal Gharib granite is metaluminous to peralkaline with ASI (0.94?C1.07). Trace element characteristics of Gabal Gharib granite include abundances of Rb, Nb, Ta, Sn, Th, U, Y, Ga, Zn, rare earth elements (REEs, except Eu), and F, and depletion in Sr, and Ba relative to granodiorite?Cadamellite country rocks. It has the geochemical characteristic of anorogenic A-type granite. The uniform trends of differentiation, normal REE distribution patterns, and low calculated tetrad effects of REE (<0.2) indicate that the effect of post-magmatic subsolidus processes were minimal in the studied granite. Fluid inclusions were studied in quartz crystals from Gabal Gharib granite, quartz pods, and metasomatized granite. The study revealed the presence of high-temperature (480?C550°C), high-salinity (19.45?C39.13?wt.% NaCl eq.) primary inclusions in both metasomatized and rare-metal granites coexisting with melt inclusions and medium-temperature (350?C450°C), medium-salinity (10?C16?wt.% NaCl esq.) aqueous inclusions coexisting hydrocarbon-bearing inclusions. Hydrocarbon is represented by magmatic CH4 in Gabal Gharib granite, while heavier aliphatic compounds may be present in quartz pods. Melt inclusions with temperatures of homogenization >600°C were also reported. Petrographic, geochemical, and fluid inclusion studies constrain that the peralkaline anorogenic granite of Gabal Gharib was derived from highly evolved magma probably originated by fractional crystallization of mantle source. 相似文献