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1.
Vein-controlled retrograde infiltration of H2O-CO2 fluids into Dalradian epidote amphibolite facies rocks of the SW Scottish Highlands under greenschist facies conditions resulted in alteration of calcite-rich marble bands to dolomite and spatially associated 18O enrichment of about 10%. on a scale of metres. Fluid inclusion data indicate that the retrograde fluid was an H2O-salt mixture with a low CO2 content, and that the temperature of the fluid was about 400d? C. Detailed petrographic and textural (backscattered electron imaging) studies at one garnet-grade locality show that advection of fluid into marbles proceeded by a calcite-calcite grain edge flow mechanism, while alteration of non-carbonate wall-rock is associated with veinlets and microcracks. Stable isotopic analysis of carbonates from marble bands provides evidence for advection of isotopic fronts through carbonate wall-rocks perpendicular to dolomite veins, and fluid fluxes in the range 2.4–28.6 m3/m2 have been computed from measured advection distances. Coincidence of isotope and reaction fronts is considered to result from reaction-enhanced kinetics of isotope exchange at the reaction front. Front advection distances are related to the proportion of calcite to quartz in each marble band, with the largest advection distance occurring in nearly pure calcite matrix. This relationship indicates that fluid flow in carbonates is only possible along fluid-calcite-calcite grain edges. However, experimental constraints on dihedral angles in calcite-fluid systems require that pervasive infiltration occurred in response to calcite dissolution initiated at calcite-calcite grain junctions rather than to an open calcite pore geometry. The regional extent of the retrograde infiltration event has been documented from the high δ18O of dolomite-ankerite carbonates from veins and host-rocks over an area of least 50 × 50 km in the SW Scottish Highlands. Isotopically exotic 18O-rich retrograde fluids have moved rapidly upwards through the crust, inducing isotopic exchange and mineral reaction in wall-rocks only where lithology, pore geometry or mineral solubilities, pressure and temperature have been appropriate for pervasive infiltration to occur.  相似文献   

2.
Quartz–calcite sandstones experienced the reaction calcite+ quartz = wollastonite + CO2 during prograde contact metamorphismat P = 1500 bars and T = 560°C. Rocks were in equilibriumduring reaction with a CO2–H2O fluid with XCO2 = 0·14.The transition from calcite-bearing, wollastonite-free to wollastonite-bearing,calcite-free rocks across the wollastonite isograd is only severalmillimeters wide. The wollastonite-forming reaction was drivenby infiltration of quartz–calcite sandstone by chemicallyreactive H2O-rich fluids, and the distribution of wollastonitedirectly images the flow paths of reactive fluids during metamorphism.The mapped distribution of wollastonite and modeling of an O-isotopeprofile across a lithologic contact indicate that the principaldirection of flow was layer-parallel, directed upward, withany cross-layer component of flow <0·1% of the layer-parallelcomponent. Fluid flow was channeled at a scale of 1–100m by pre-metamorphic dikes, thrust and strike-slip faults, foldhinges, bedding, and stratigraphic contacts. Limits on the amountof fluid, based on minimum and maximum estimates for the displacementof the wollastonite reaction front from the fluid source, are(0·7–1·9) x 105 cm3 fluid/cm2 rock. Thesharpness of the wollastonite isograd, the consistency of mineralthermobarometry, the uniform measured 18O–16O fractionationsbetween quartz and calcite, and model calculations all arguefor a close approach to local mineral–fluid equilibriumduring the wollastonite-forming reaction. KEY WORDS: contact metamorphism, fluid flow, wollastonite, oxygen isotopes, reaction front  相似文献   

3.
Metamorphic isograds and time-integrated fluid fluxes were mappedover the 1500 km2 exposure of the Waits River Formation, easternVermont, south of latitude 4430'N. Isograds based on the appearanceof oligoclase, biotite, and amphibole in metacarbonate rocksdefine elongated metamorphic highs centered on the axes of twolarge antiforms. The highest-grade isograd based on the appearanceof diopside is closely associated spatially with synmetamorphicgranitic plutons. Pressure, calculated from mineral equilibria,was fairly uniform in the area, 7 1.5 kb; calculated temperatureincreases from {small tilde} 480C at the lowest grades in thearea to {small tilde} 575C in the diopside zone. CalculatedXco2f equilibrium metamorphic fluid increases from <0-03at the lowest grades to 0.2 in the amphibole zone and decreasesto 0.07 in the diopside zone. Time-integrated fluid fluxesincrease with increasing metamorphic grade, with the followingmean values for each metamorphic zone (in cm3/cm2): ankerite-oligoclasezone, 1 x 104; biotite zone, 7 x 104; amphibole zone, 2 x 105;diopside zone, 7 x 105. The mapped pattern of time-integrated fluxes delineates twolarge deep-seated ({small tilde} 25-km depth) regional metamorphichydrothermal systems, each centered on one of the major antiforms.Fluid flowed subhorizontally perpendicular to the axis of theantiforms from their low-temperature flanks to their hot axialregions and drove prograde decarbonation reactions as they went.Along the axes of the antiforms fluid flow was further focusedaround synmetamorphic granitic intrusions. In the hot axialregion fluid changed direction and flowed subvertically outof the metamorphic terrane, precipitating quartz veins. Estimatesof the total recharge, based on progress of prograde decarbonationreactions, nearly match estimates of the total discharge, basedon measured quartz vein abundance, (2-10) x 1012 cm3 fluid percm system measured parallel to the axes of the antiforms. Withinthe axial regions fluids had lower XCO2 and rocks record greatertime-integrated fluxes close to the intrusions than at positionsmore than {small tilde} 5 km from them. The differences in bothfluid composition and time-integrated flux can be explainedby mixing close to the intrusions of regional metamorphic fluidsof XCO2/ with fluids from another source with XCO2{small tilde}0 in the approximate volume ratio of 1:2.  相似文献   

4.
The Role of Volatiles in the Thermal History of Metamorphic Terranes   总被引：2，自引：0，他引：2  
BRADY  JOHN B. 《Journal of Petrology》1988,29(6):1187-1213
Analytical and numerical solutions to the differential equationsfor the conduction of heat with heat production or with fluidflow have been used to evaluate the role of volatiles in thethermal history of regional metamorphic terranes. The maximumthermal effect from pervasive, single-pass, regional volatileflow may be predicted from a steady-state solution given byBredehoeft & Papadopoulos (1965). For fluid velocity vF(m/s) and connected porosity , combinations of volatile fluxvF (m3 of fluid/m2s) and transport distance L(m) such that vLis greater than 3?6?10–7 should produce regional temperatureincreases due to fluid flow, if the flow persists for l05–106a (depending on the transport distance L). The absolute valueof the temperature increase due to volatile flow will be greaterin regions with higher ambient geothermal gradients. For L=20km, a volatile flux of 1?8 ? 10–11 (m3 of fluid/m2s) orgreater is required to achieve a temperature effect. Few geologicprocesses release volatiles at this rate for extended periodsof time, so regional thermal effects from the single-pass, pervasiveflow of volatiles are unlikely. A new analytical solution forthe steady state temperature distribution between idealizedparallel channels of fluid flow is presented along with theresults of two-dimensional numerical models of channelized fluidflow. Both approaches show that little temperature increaseis expected near channels of fluid flow relative to the rocksbetween the channels, unless the channels exceed 100 m in widthor unless the fluid fluxes are very large and transient. A possiblethermal effect of volatile flow in metamorphic terranes is theproduction of metamorphic hot spots due to focusing of volatilesinto widely spaced channels or conduits exceeding 1 km in width.Given a sufficient fluid flux (exceeding 10–10 m3 of fluid/m2s),thermal gradients of over 100K from center to edge may be producedin such channels during relatively short time intervals (105–106a).  相似文献   

5.
Progress () of the infiltration-driven reaction, 4olivine +5CO2 + H2O = talc + 5magnesite, that occurred during Barrovianregional metamorphism, varies at the cm-scale by a factor of3·5 within an 3 m3 volume of rock. Mineral and stableisotope compositions record that XCO2, 18Ofluid, and 13Cfluidwere uniform within error of measurement in the same rock volume.The conventional interpretation of small-scale variations in in terms of channelized fluid flow cannot explain the uniformityin fluid composition. Small-scale variations in resulted insteadbecause (a) reactant olivine was a solid solution, (b) initiallythere were small-scale variations in the amount and compositionof olivine, and (c) fluid composition was completely homogenizedover the same scale by diffusion–dispersion during infiltrationand subsequent reaction. Assuming isochemical reaction, spatialvariations in image variations in the (Mg + Fe)/Si of the parentrock rather than the geometry of metamorphic fluid flow. Ifinfiltration-driven reactions involve minerals fixed in composition,on the other hand, spatial variations in do directly imagefluid flow paths. The geometry of fluid flow can never be determinedfrom geochemical tracers over a distance smaller than the oneover which fluid composition is completely homogenized by diffusion–dispersion. KEY WORDS: Alpine Barrovian metamorphism; diffusion; metamorphic fluid composition; metamorphic fluid flow; reaction progress  相似文献   

6.
This study explores the origin and geochemical evolution ofapatite, monazite, and xenotime along two metamorphic traverses.The first, from the Kigluaik Mountains, Seward Peninsula, Alaska,consists of a localized (85 cm) orthopyroxene–clinopyroxene-bearingdehydration zone. The second consists of orthopyroxene ±clinopyroxene-bearing granulite facies metabasite layers interlayeredwith metapelites over a 3–4 km traverse, along the ValStrona, Ivrea–Verbano Zone, Northern Italy (IVZ). In bothdehydration zones small Th- and U-poor inclusions of monaziteand/or xenotime occur in the apatite. These inclusions are metasomaticallyinduced and nucleated within the apatite via the coupled substitutionsNa+ + (Y + REE)3+ = 2 Ca2+ and Si4+ + (Y + REE)3+ = P5+ + Ca2+.These are not present in apatite from the original amphibolitefacies gneiss. Apatite, in both dehydration zones, also showsa relative increase in both F and Cl compared with apatite fromthe amphibolite facies zone. Granulite facies metabasites inthe IVZ also contain isolated monazite grains, which range fromuniform to complexly zoned in Th the (13–30·1 mol% ThSiO4). These are the product of breakdown and subsequentmobilization of the lanthanides and actinides from monazite-(Ce)in the metapelite layers into the metabasite layers at the startof granulite facies metamorphism. KEY WORDS: apatite; monazite; xenotime; KCl–NaCl brines; metasomatism; phosphate minerals; charnockite–enderbite; granulite facies metamorphism  相似文献   

7.
FERRY  JOHN M. 《Journal of Petrology》1995,36(4):1039-1053
Contact-mctamorphic assemblages in ophicarbonate from the Bergellaureole correspond either to model isobaric invariant T-XCO2points [Atg-Cal-Di-Tr-Fo (6 samples) and Atg-Cal-Tr-Fo-Dol (2)]or to isobaric univariant T-XCO2, curves [Tr-Cal-Di-Atg (18),Tr-Dol-Atg-Cal (1), Atg-Cal-Fo-Di (1), and Atg-Cal-Tr-Fo (1)].Calcite-dolomite thermometry and mineral-fluid equilibria inthe invariant assemblages record T=440–540C at P=3•5kbar. Equilibrium metamorphic fluids were very H2O rich withX CO2,=0•001–0•027. In the invariant assemblagesTr + Fo were produced by prograde decarbonation-dehydrationreactions. In contrast, measured modes and reaction texturesin samples with univariant assemblages indicate thai Tr wasproduced by carbonation reactions. The apparent paradox of simultaneousdecarbonation reactions in the model isobaric invariant assemblagesand carbonation reactions in univariant assemblages is resolvedby local mineral-fluid equilibrium and fluid flow through ophicarbohatesin the direction of decreasing temperature as the aureole heated.Time-integrated flux (q) was computed from measured reactionprogress in 28 samples for models of both horizontal and verticaldown-temperature flow. Results are similar, with q decreasingrapidly from (0•2–5•1) 105 cm3 fluid/cm2 rock1•3–1•7 km from the intrusion to 0–0•6105cm3/cm2 at 1•8–4•0 km. The decrease in q ismore consistent with vertical than horizontal flow. Variationsin time-integrated flux of more than an order of magnitude arerecorded by samples from the same outcrop. The absence of carbonatein adjacent metaperidotite indicates that flow was confinedto the ophicarbonate. Channelized, spatially heterogeneous,vertical flow can be explained by the brecciation and strongvertical foliation of the ophicarbonate relative to surroundingmassive metaperidotite. Generation of metamorphicfluids by decarbonation-dehydrationreactions within the ophicarbonates explains larger averageflux 1–2 km from the intrusion compared with more distalpoints. KEY WORDS: Bergell; contact metamorphism; fluid flow; ophicarbonate *Telephone: (410) 516-8121. Fax: (410) 516-7933  相似文献   

8.
Prograde metamorphic reactions involving the growth of phyllosilicates and accompanying cleavage development have been investigated in Dalradian metasediments from the biotite zone of eastern Scotland. Crystallization of muscovite within the psammites of the Southern Highland Group is linked to the replacement of plagioclase porphyroclasts. This reaction is triggered by significant alkali metasomatism during active deformation and plays an important role in the formation of a prominent spaced cleavage within the psammites. The Si content of most of these early-formed muscovites is partially buffered by the quartz content of the rock, although close to the Highland Boundary Fault, evidence of greater influence from externally derived fluids on muscovite compositions is preserved. Locally higher fluid fluxes adjacent to the fault are also indicated by a relatively high δ 18O(SMOW) signature in the rocks. The biotite-producing reaction in these greenschist-facies rocks is linked to the later production of a celadonite-poor muscovite which formed as overgrowths around pre-existing white micas. This reaction is sensitive to the initial composition of muscovite and preferentially occurs in quartz-rich metasediments containing a celadonite-rich muscovite. A systematic increase in the progress of the biotite-producing reaction northwards across the biotite zone confirms the presence of high geothermal gradients along the southern margin of the Dalradian block, adjacent to the Highland Boundary Fault. Received: 26 February 1999 / Accepted: 8 November 1999  相似文献   

9.
Peridotites associated with pyroxenites (with rare olivine andspinel) are exposed on the islands of San Jorge and Santa Isabelin the Solomon Islands. Orthopyroxenite occurs in large outcrops(100 m2) whereas websterite and clinopyroxenite occur as layersand veins/dykes in peridotites. The bulk compositions of thepyroxenites are characterized by high Mg2+/(Mg2+ + Fe2+) (0·78–0·91)and low Al2O3 (<2·7 wt %). Low rare earth elementabundances are coupled with large ion lithophile element enrichmentsand positive Sr and Pb anomalies (primitive mantle-normalized)relative to adjacent rare earths. Temperatures of equilibrationfor the pyroxenites are between 950 and 1050°C. These relativelylow temperatures, combined with the occurrence of primary fluidinclusions, suggest that the pyroxenites formed by interactionof peridotite protoliths with an aqueous fluid. Bulk-rock andmineral compositions of the orthopyroxenites are similar tothose of mantle-derived pyroxenites, whereas the websteriteshave closer chemical affinity with crustal arc cumulates. Nevertheless,field relationships plus petrological, textural and geochemicalevidence are consistent with formation of all pyroxenite typesin supra-subduction zone mantle, resulting from metasomatismof peridotite by subducted Pacific Plate-derived fluid. Sucha setting for pyroxenite has not previously been reported indetail. We propose that these processes produce mantle pyroxenitewith compositions similar to crustal pyroxenite. KEY WORDS: mantle metasomatism; pyroxenite; supra-subduction zone  相似文献   

10.
High-pressure and -temperature experiments on a bulk-rock compositionrepresentative of the groundmass of the Soufrière HillsVolcano andesite have allowed the phase equilibria of the systemto be determined; these are then compared with the natural samples.Experimental conditions varied from 825 to 1100°C and from5 to 225 MPa; the main phases observed were clinopyroxene, crystallinesilica, amphibole and plagioclase. A relationship between plagioclasemicrolite size and anorthite content is identified in samplesof the natural andesite. Large crystals (>60 µm2 inarea) have cores of An60–75, whereas small crystals (<60µm2 in area) have cores of An40–60. Experimentalresults show that if the magma is heated to >950°C thehigh-anorthite microlite crystals can form at magma chamberpressures without any need for a change in bulk composition.It is proposed that convective self-mixing occurs within themagma chamber. Geothermometry of coexisting plagioclase–amphibolepairs confirms the complex crystallization history of the naturalsamples. Analysis of natural glass samples has identified compositionalvariations that can be related to the crystallinity of the sampleand also the groundmass plagioclase composition. Rapidly eruptedpumice samples have high glass contents, lower SiO2 glass compositionsand plagioclase microlites that are large in size (>60 µm2)and have a high anorthite content (>An60). Slowly erupteddome samples are highly crystalline and contain numerous plagioclasemicrolites of variable size and composition. KEY WORDS: glass evolution; experiment; Montserrat; plagioclase; self-mixing  相似文献   

11.
Fluid flow at greenschist facies conditions during exhumation of the western Alps occurred in several penecontemporaneous systems, including shear zones at lithological contacts, deformed contacts between serpentinite bodies and metabasalts, albite veins within metabasalts, and calcite + quartz veins within calcareous schists. Fluid flow in shear zones that juxtapose metasediments and ophiolitic rocks within the Piemonte Unit reset O and H isotope ratios. δ18O values are buffered by the wall rocks; however, calculated fluid δ2H values are similar within all the shear zones suggesting that they formed an interconnected network. The similarity of δ2H values of the sheared rocks and those of unsheared calcareous schists suggests that the fluids were derived from, or had equilibrated with, the schists that envelop the ophiolite rocks. Time‐integrated fluid fluxes at the sheared contacts estimated from changes in Si in metabasalts were up to 105 m3 m?2, with the fluid flowing up temperature driven either by topography or seismic pumping. Individual shear zones were active for c. 2–3 Myr, implying average fluid fluxes of up to 10?9 m3 m?2 s?1. Rocks in shear zones within the ophiolite away from contacts with the metasediments show much less marked isotopic and geochemical changes, implying that fluid volumes decreased into the ophiolite unit, consistent with the source of fluids being the metasediments. Fluids were generated by dehydration reactions that were intersected during exhumation and, while many rocks show the affects of fluid–rock interaction, large‐scale fluid flow between major units was not common.  相似文献   

12.
Petrographic and petrologic investigations of upper amphibolitefacies metacarbonates from the East Humboldt Range core complex,Nevada, provide important constraints on P-T-XCO2 conditionsand fluid flow during metamorphism. Three marble assemblagesare observed [(1)dol+cc+bt+cpx+q+ruscapkspamph; (2) cc+bt+cpx+plag+q+sphscapksp;(3) cc+cpx+plag+q+sphscapksp], all of which equilibrated withrelatively CO2-rich fluid compositions, at P-T conditions of6 kbar and 600–750C. The most recent equilibration eventis recorded in some calcsilicate gneisses where retrograde amphiboleand epidotegarnet replace clinopyroxene and plagioclase, respectively.This is attributed to infiltration of H2O-rich fluids at and/orafter peak metamorphic temperatures, which continued as therocks were cooled and rapidly uplifted after a Tertiary extension-relatedheating event. Likely sources for the retrograde fluids are the abundant pegmatiticleucogranites in the area. Volumetric fluid-rock ratios of 0.02–0.4are required to generate the retrograde assemblage, and observedleucogranite proportions are more than adequate to provide therequired volume of fluid. Estimates of retrograde fluid fluxesrange from 0.25 to 5102 cm3/cm2 for a transient temperaturegradient of 5C/m, to 3103 to 7104 cm3/cm2 for a temperaturegradient of 35C/km. These gradients are characteristic of askarn-type contact metamorphic environment and a regional crustalgeotherm, respectively. They imply different time-scales andlength-scales for the retrograde fluid flow system, with theformer more akin to a contact metamorphic setting with local,meter-scale retrograde fluid flow, and the latter to a regionalmetamorphic setting with regionally high mid- and lower-crustaltemperatures and fluid flow throughout a significant thicknessof the middle crust. Higher gradients are considered more likelygiven the proximity of leucogranites to retrogressed calc-silicategneisses, and the resultant relatively small fluxes are consistentwith a magmatic source. The length-scale of reaction within the retrograde fluid flowsystem was of the order of meters to hundreds of meters andinvolved both pervasive and (later) fracture-controlled down-temperatureflow. Retrograde fluid flow in this terrance, as well as othersdominated by magmatic volatiles, is in the form of multiplediscrete bursts of fluid released in a discontinuous mannerpotentially over long periods of time (1–10 Ma) with locallyvariable thermal gradients along the flow path.  相似文献   

13.
Pelitic schists and quartzites in the Picuris Range of northernNew Mexico exhibit mineral 18O and D compositions that indicaterock-buffered isotopic exchange during metamorphism at uniformphysical conditions of T 530C and P 4 kbar. Phase assemblagesand major-element compositions among silicates and oxides areuniform within stratigraphic units, but they change abruptlyacross lithologic contacts, yielding distinctive mineral Mg/Fe2+ratios and inferred f(O2) values. Mineral compositions reflectthe pre-metamorphic compositions of individual rock units. O-and H-isotopic compositions of quartz and muscovite are alsodiscontinuous across lithologic boundaries, showing intra-layerhomogeneity and bulk-rock isotopic compositions retained fromsedimentary protoliths. Uniform 18 OQu-Ms values indicate isotopicequilibrium at peak metamorphic conditions. Sharp discontinuitiesin mineral and fluid isotopic compositions reflect limited isotopicexchange between units. The isotopic system in these units wasprobably one of rock-buffered exchange, in which the sedimentarycompositions of individual rock units exerted the dominant controlon mineral and fluid isotopic composition over short distancesin a relatively closed metamorphic system. Fluid migration duringprogressive metamorphic devolatilization in this simple systemwas probably non-pervasive, and it was probably influenced bycontrasting rock permeability. Consequently, our study suggeststhat pervasive exchange between interlayered units may be uncommonin regionally metamorphosed terrains that show weak initialgeochemical gradients. In contrast, the chemical and isotopichomogenization that attends pervasive fluid flow and high fluidfluxes may be restricted to settings characterized by extremegeochemical gradients, such as interlayered silicates and carbonates,or terrains that host plutonic hydrothermal systems. KEY WORDS: fluids; metamorphism; stable isotopes; New Mexico *Corresponding author. E-mail: jgoodgc{at}sun.cis.smu.edu.. Telephone (214) 768–4140. Fax (214) 768–2701  相似文献   

14.
The Bixiling mafic-ultramafic metamorphic complex is a 1•5km2 tectonic block within biotite gneiss in the southern Dabieultrahigh-pressure terrane, central China. The complex consistsof banded eclogites that contain thin layers of garnet-bearingcumulate ultramafic rock. Except for common eclogitic phases(garnet, omphacite, kyanite, phengite, zoisite and rutilc),banded eclogites contain additional talc and abundant coesiteinclusions in omphacite, zoisite, kyanite and garnet. Some metaultramaficrocks contain magnesite and Ti-clinohumite. Both eclogites andmeta-ultramafic rocks have undergone multi-stage metamorphism.Eclogite facies metamorphisrn occurred at 610–700C andP>27 kbar, whereas amphibolite facies retrograde metamorphismis characterized by symplectites of plagioclase and hornblendeafter omphacite and replacement of tremolite after talc at P<6–15kbar and T <600C. The meta-ultramafic assemblages such asolivine + enstatite + diopside + garnet and Ti-clinohumite +diopside + enstatite + garnet + magnesite olivine formed at700–800C and 47–67 kbar. Investigation of the phaserelations for the system CaO-MgO-SiO2-H2O-CO2 and the experimentallydetermined stabilities of talc, magnesite and Ti-clinohumiteindicate that (1) UHP talc assemblages are restricted to Mg-Algabbro composition and cannot be an important water-bearingphase in the ultramafic mantle, and (2) Ti-clinohumite and magnesiteare stable H2O-bearing and CO2-bearing phases at depths >100km. The mafic-ultramafic cumulates were initially emplaced atcrustal levels, then subducted to great depths during the Triassiccollision of the Sine-Korean and Yangtze cratons. KEY WORDS: eclogite; magnesite; meta-ultramafics; talc; ultrahigh-P metamorphism *Corresponding author  相似文献   

15.
The aim of this study was to investigate the pollution parameters relating to surface and groundwaters and to establish an interaction between these for the area near Yerköy. Three characteristic facies were determined based on the results of hydrochemical analyses: (1) Na+-Cl- facies were greater the deeper the aquifer, (2) Na+-SO42- facies were the greater portion of the shallow alluvium aquifer, and (3) Na+-HCO3- (SO42-) facies represented the western portion of the shallow alluvium aquifer. Based on field and laboratory observations it was found that the water of the River Delice is suitable for irrigation and domestic use whereas the water from the shallow aquifer is extremely saline and considered to have been polluted by local lithological units. Active groundwater circulation and dilution between the alluvium aquifer and the River Delice was observed. Because of the short residence time of the groundwater in this area, the hydrogeochemical concentration and the salinity were found to be low. The other portions of the alluvium aquifer bear higher concentrations of soluble ions.  相似文献   

16.
The Early Cretaceous volcanic rocks of southern Uruguay comprisemafic and felsic volcanics. The position of these outcrops atthe southern edge of the Paraná–Etendeka continentalflood basalt province provides an opportunity to investigatepossible lateral variations in both mafic and more evolved rocktypes towards the margins of such an area of plume-related magmatism.The mafic lavas are divided into two compositionally distinctmagma types. The more voluminous Treinte Y Trés magmatype is similar to the low-Ti basalts of the Paraná floodbasalt province. The Santa Lucía magma type is a distinctand rare basalt type with ocean-island basalt type asthenosphericaffinities (high Nb/La, low 87Sr/86Sri). The felsic volcanicsare divided into two series, the Lavalleja Series and the AigüaSeries. The Lavalleja Series are chemically and isotopicallysimilar to the Paraná–Etendeka low-Ti rhyolites,and are considered to be related to the Treinte Y Tréslavas by extensive fractionation and crustal assimilation. TheAigüa Series have low 143Nd/144Ndi and low 87Sr/86Sri andunlike the rhyolites of the Paraná, are interpreted asmelts of pre-existing mafic lower crust that subsequently underwentextreme fractionation. The differences observed in the felsicsuites may be linked to differences in the volumes of the associatedbasalts and the amounts of extension. KEY WORDS: South America; flood basalts; felsic volcanics; crustal melts; plume  相似文献   

17.
Periclase formed in siliceous dolomitic marbles during contact metamorphism in the Monzoni and Predazzo aureoles, the Dolomites, northern Italy, by infiltration of the carbonate rocks by chemically reactive, H2O-rich fluids at 500 bar and 565-710 °C. The spatial distribution of periclase and oxygen isotope compositions is consistent with reactive fluid flow that was primarily vertical and upward in both aureoles with time-integrated flux ~5,000 and ~300 mol fluid/cm2 rock in the Monzoni and Predazzo aureoles, respectively. The new results for Monzoni and Predazzo are considered along with published studies of 13 other aureoles to draw general conclusions about the direction, amount, and controls on the geometry of reactive fluid flow during contact metamorphism of siliceous carbonate rocks. Flow in 12 aureoles was primarily vertically upward with and without a horizontal component directed away from the pluton. Fluid flow in two of the other three was primarily horizontal, directed from the pluton into the aureole. The direction of flow in the remaining aureole is uncertain. Earlier suggestions that fluid flow is often horizontal, directed toward the pluton, are likely explained by an erroneous assumption that widespread coexisting mineral reactants and products represent arrested prograde decarbonation reactions. With the exception of three samples from one aureole, time-integrated fluid flux was in the range 102-104 mol/cm2. Both the amount and direction of fluid flow are consistent with hydrodynamic models of contact metamorphism. The orientation of bedding and lithologic contacts appears to be the principal control over whether fluid flow was either primarily vertical or horizontal. Other pre-metamorphic structures, including dikes, faults, fold hinges, and fracture zones, served to channel fluid flow as well.  相似文献   

18.
As a pilot study of the role of water in the attenuation ofseismic waves in the Earth's upper mantle, we have performeda series of seismic-frequency torsional forced-oscillation experimentson a natural (Anita Bay) dunite containing accessory hydrousphases, at high temperatures to 1300°C and confining pressure(Pc) of 200 MPa, within a gas-medium high-pressure apparatus.Both oven-dried and pre-fired specimens wrapped in Ni–Fefoil within the (poorly) vented assembly were recovered essentiallydry after 50–100 h of annealing at 1300°C followedby slow staged cooling. The results for those specimens indicatebroadly similar absorption-band viscoelastic behaviour, butwith systematic differences in the frequency dependence of strain-energydissipation Q–1, attributed to differences in the smallvolume fraction of silicate melt and its spatial distribution.In contrast, it has been demonstrated that a new assembly involvinga welded Pt capsule retains aqueous fluid during prolonged exposureto high temperatures—allowing the first high-temperaturetorsional forced-oscillation measurements under high aqueousfluid pore pressure Pf. At temperatures >1000°C, a markedreduction in shear modulus, without concomitant increase inQ–1, is attributed to the widespread wetting of grainboundaries resulting from grain-scale hydrofracturing and themaintenance of conditions of low differential pressure Pd =Pc – Pf . Staged cooling from 1000°C is accompaniedby decreasing Pf and progressive restoration of significantlypositive differential pressure resulting in a microstructuralregime in which the fluid on grain boundaries is increasinglyrestricted to arrays of pores. The more pronounced viscoelasticbehaviour observed within this regime for the Pt-encapsulatedspecimen compared with the essentially dry specimens may reflectboth water-enhanced solid-state relaxation and the direct influenceof the fluid phase. The scenario of overpressurized fluids andhydrofracturing in the Pt-encapsulated dunite specimen may havesome relevance to the high Q–1 and low-velocity zonesobserved in subduction-zone environments. The outcomes of thisexploratory study indicate that the presence of water can havea significant effect on the seismic wave attenuation in theupper mantle and provide the foundation for more detailed studieson the role of water. KEY WORDS: seismic wave attenuation; water; dunite; hydrous mineral; shear modulus; viscoelasticity; olivine; grain-scale hydrofracturing  相似文献   

19.
Metasomatism and fluid flow in ductile fault zones   总被引：8，自引：0，他引：8  
Observed major element metasomatism in 5 amphibolite facies ductile fault zones can be explained as the inevitable consequence of aqueous fluid flow along normal temperature gradients under conditions of local chemical equilibrium. The metasomatism does not require the infiltration of chemically exotic fluids. Calculations suggest that metasomatized ductile fault zones are typically infiltrated by 105 moles H2O/cm2, fluid flow is in the direction of decreasing temperature, and fluids contain about 1.0 molal total chloride. Where available, stable isotopic alteration data confirm both flow direction and fluid fluxes calculated from major element metasomatism. The fluid fluxes inferred from metasomatism do not require large-scale fluid recirculation or mantle sources if significant lateral fluid flow occurs in the deep crust. Time-integrated fluid fluxes are combined with estimates of flow duration to constrain average flow rates and average permeabilities. Rocks in ductile fault zones are probably much more permeable during metasomatism (average permeabilities of 10-17 to 10-15 m2) than rocks normally are during regional metamorphism (10-21 to 10-18 m2). Estimated average fluid flow rates (3.5×10-3 to 0.35 m/yr) are insufficient, however, to significantly elevate ambient temperatures within ductile faults. Fluid flow in the direction of decreasing temperature may increase the ductility of silicate rocks by adding K to the rocks and thereby driving mica-forming reactions.  相似文献   

20.
A complex of crustally derived leucogranitic sills emplacedinto sillimanite-grade psammites in the upper Langtang Valleyof northern Nepal forms part of the Miocene High Himalayan graniteassociation. A series of post-tectonic, subvertical leucograniticdykes intrude the underlying migmatites, providing possiblefeeders to the main granite sills. The leucogranite is peraluminous and alkali-rich, and can besubdivided into a muscovite–biotite and a tourmaline–muscovitefacies. Phase relations suggest that the tourmaline leucogranitescrystallized from a water-undersaturated magma of minimum-meltcomposition at pressures around 3–4 kbar. Potential metasedimentaryprotoliths include a substantial anatectic migmatite complexand a lower-grade mica schist sequence. Isotopic constraintspreclude the migmatites as a source of the granitic melts, whereastrace-element modelling of LILEs (Rb, Sr, and Ba), togetherwith the Nd and Sr isotopic signatures of potential protoliths,strongly suggest that the tourmaline-bearing leucogranites havebeen generated by fluid-absent partial melting of the muscovite-richschists. However, REE and HFSE distributions cannot be reconciledwith equilibrium melting from such a source. Systematic covariationsbetween Rb, Sr, and Ba can be explained by variations in protolithmineralogy and P–T–aH2O. Tourmaline leucogranites with high Rb/Sr ratios represent low-fraction-melts(F{small tilde} 12%) efficiently extracted from their protolithsunder conditions of low water activity, whereas the heterogeneoustwo-mica granites may result from melting under somewhat higheraH2O conditions. The segregation of low-degree melts from sourcewas probably by deformation-enhanced intergranular flow andmagma fracturing, with the mechanisms of migration and emplacementcontrolled by variations in the uppercrustal stress regime duringlate–orogenic extensional collapse of the thickened crust.  相似文献   

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