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1.
Stable isotopes (δ18O, δ2H and 13C) and radioactivity (3H, 14C) have been used in conjunction with chemical data to evaluate the processes generating the chemical composition, reconstruct the origin of the water and groundwater residence time. The Aleppo basin is comprised of two main limestone aquifers: the first one is unconfined of Paleogene age and the second is confined of Upper Cretaceous age. The chemical data indicate that the dissolution of minerals and evaporation are the main processes controlling groundwater mineralization. The groundwater from the two aquifers is characterized by distinctive stable isotope signatures. This difference in water isotopes is interpreted in terms of difference origin and recharge period. Fresh and brackish shallow groundwater were mostly recharged during the Holocene period. The presence of 3H in several groundwater samples of this aquifer gives evidence that groundwater recharge is going on. Brackish water of the deep confined aquifer has depleted stable isotope composition and very low 14C activity that indicates recharge during the late Pleistocene cold period.  相似文献   

2.
The objective of this study was to identify geochemical processes and Quaternary geological events responsible for the variations in groundwater geochemistry observed in a sedimentary rock aquifer system, including brackish to saline groundwater. Inorganic constituents and environmental isotopes were analyzed for 146 groundwater samples. Dissolution of carbonates dominates in recharge areas, resulting in Ca-, Mg-HCO3 groundwater. Further along flow paths, under confined conditions, Ca2+–Na+ ion exchange causes groundwater evolution to Na-HCO3 type. Na-Cl groundwater is also found and it falls on a seawater mixing line. Using conservative tracers, Cl− and Br−, the original Champlain Sea water is shown to have been, in the region, a mixture of about 34% seawater and 66% freshwater, a composition still retained by some groundwater. Na-Cl groundwater thus results from mixing with former Champlain Sea water and also from solute diffusion from overlying marine clay. The system is thus found to be at different stages of desalinization, from the original Champlain Sea water still present in hydraulically stagnant areas of the aquifer to fully flushed conditions in parts, where more flow occurs, especially in recharge zones. The geochemical processes are integrated within the hydrogeological context to produce a conceptual geochemical evolution model for groundwater of the aquifer system.  相似文献   

3.
Stable isotopes (??2H, ??18O and ??13C) and radiocarbon (14C) have been used in conjunction with chemical data to evaluate recharge mechanisms and groundwater residence time, and to identify inter-aquifer mixing in the Djeffara multi-aquifer in semi-arid southeastern Tunisia. The southern part of this basin, the Djeffara of Medenine aquifer system, is comprised of two main aquifers of Triassic and Miocene sandstone. The Triassic aquifer presents two compartments; the first one (west of the Medenine fault system) is unconfined with a well-defined isotope fingerprint; the second compartment is deeper and confined. Multi-tracer results show groundwater of different origins, ages and salinities, and that tectonic features control groundwater flows. Fresh and brackish groundwater from the unconfined part of the Triassic aquifer was mostly recharged during the Holocene. The recharge rates of this aquifer, inferred by 14C ages, are variable and could reach 3.5?mm/year. Brackish water of the deep confined part of the Triassic aquifer has stable isotope composition and 14C content that indicates earlier recharge during late Pleistocene cold periods. Brackish to saline water of the Miocene aquifer presents variable isotope composition. Groundwater flowing through the Medenine fault system is mainly feeding the Miocene aquifer rather than the deep confined part of the Triassic aquifer.  相似文献   

4.
Sources of groundwater recharge to the Badain Jaran Desert in China have been investigated using geochemical and isotopic techniques. Stable isotope compositions (δ18O and δ2H) of shallow groundwater and surface water from oasis lakes evolve from a starting composition considerably depleted compared to local unsaturated zone moisture, confirming inferences from chloride mass balance that direct infiltration of precipitation is not a volumetrically important source of recharge to the shallow aquifer in the study area. Shallow phreatic and deeper confined groundwater bodies appear unconnected based on chemical composition and radiocarbon activities. Hydrogeologic evidence points toward a bordering mountain range (Yabulai) as a likely recharge zone, which is consistent with tracer results. A mean residence time in the range of 1–2 ka for the desert’s southeastern margin is inferred from radiocarbon. These results reveal that some replenishment to the desert aquifer is occurring but at a rate much lower than previously suggested, which is relevant for water resources planning in this ecologically sensitive area.  相似文献   

5.
The chemical and isotopic composition of groundwater from 52 sites in the London (U.K.) area was determined as part of a project aimed at assessing the spatial variation in the age of Chalk groundwater, and in determining the relationship between fracture and matrix groundwater in this dual porosity system.Systematic changes in groundwater chemistry take place in the downgradient direction in response to several chemical processes. These processes include early concentration by evaporation and congruent dissolution of calcite followed by widespread incongruent dissolution and ion exchange in addition to local oxidation-reduction reactions, gypsum dissolution and saline intrusion. As a result of the above processes, Chalk groundwater follows an evolutionary path from Ca bicarbonate type to Na bicarbonate type.The age of Chalk groundwater was modelled using14C, δ13C,3H, δ2H and δ180. There is a general increase in the groundwater age in a downgradient direction with the oldest water found in N central areas of the basin. Groundwater in the unconfined zones and in areas S of the Greenwich fault is almost entirely of unevolved, modem composition. Carbon-14 modelling suggests that Chalk groundwater in the S basin is generally less than 10000 a old while that in the north is generally between 10000 and 25000 a old. The presence of3H in concentrations of up to 7 TU in groundwater which yields ages of several 1000 a, however, indicates that mechanisms exist for the rapid introduction of recent groundwater to the confined aquifer. Results of palaeorecharge temperature determinations using δ2H, δ180 and noble gas analytical results suggest that significant Devensian recharge did indeed occur in the aquifer.A model of the development of the Chalk recognizes that it is a classic dual porosity aquifer in which groundwater flow occurs predominantly in the fracture system. The upper 50 m of the aquifer was flushed with fresh water during the 2–3 × 106 a of the Quaternary and therefore meteoric water largely replaced the Tertiary and Cretaceous marine water that previously saturated the system. Most processes which control the chemistry of the groundwater occur in the matrix where the surface area is exceptionally high. Although fracture flow dominates the flow regime, diffusion from the matrix into the fracture porosity controls the chemistry of Chalk groundwater.  相似文献   

6.
Deep Quaternary groundwater is the main source for industrial, domestic, and agricultural water supply in the North China Plain (NCP). There is currently a regional decline of groundwater levels, deterioration of water quality and environmental geological problems induced by increasing exploitation of the NCP Quaternary aquifer system. To trace sources and transport processes of dissolved Cl− in a regional aquifer system and to reveal hydrogeological characteristics of Quaternary complexes, δ37Cl, δ18O and δD, and chemical compositions (including F−, Cl−, Br−) of the deep groundwater sampled from the northern flow system of the NCP were measured along the west–east groundwater flow paths. The measured δ37Cl values decreased from 0.39‰ to −2.22‰ (SMOC) along the groundwater flow direction, with increasing Cl− concentrations. Marine aerosol input via rainfall is the main source of Cl− in the deep groundwater near the recharge areas, and subsequent evaporation/evapotranspiration appears to be responsible for Cl− accumulation. Mixing of recharge water with water of high-Cl− and low-δ37Cl accounts for the pattern of δ37Cl and Cl− concentration observed in Aquifer-3 along the west–east transect. The water with high-Cl and low-δ37Cl is likely from pore water released from compacted clays induced by over-exploitation of deep groundwater, suggesting that clay is a dominant subsurface source of Cl− for groundwater where a regional depression cone is present in the Quaternary aquifers. The groundwater of Aquifer-4 in the Huang-Hua depression is potentially mixed with an upward flux of Cl− from the Neogene aquifer through subvertical faults. Diffusion and ion filtration are two mechanisms invoked to explain the highly negative δ37Cl data for groundwater of Aquifer-4 in the Yanshan–Haixing areas, which provides new insight into solute migration and the hydraulic relationship in the strongly exploited groundwater system. This study using the conservative solute Cl− provides additional important information for further investigations of the geochemistry of a wide range of reactive solutes in the Quaternary aquifer system, so guiding water resource management.  相似文献   

7.

The Dena rainstorm in Iran in March and April 2019 caused about US$ 8.3?×?109 damage in the country; however, it resulted in the replenishment of half of the dam reservoirs and 35% of ponds and lakes. Also, it increased the volume of groundwater stored in aquifers by 3.6?×?109 m3. In arid and semiarid regions such as most parts of Iran, which usually face water scarcity, getting water from rainstorms is essential for replenishing water resources. This research aims to quantify the direct and indirect effects of the Dena rainstorm on the replenishment of Iran’s groundwater storage using the groundwater balance method and water-table fluctuation method. Studies showed that the main mechanisms for replenishment of groundwater storage due to the rainstorm included increases in precipitation recharge, surface runoff recharge, and artificial recharge, and reductions in irrigation withdrawal and evapotranspiration, while the contribution of each factor is estimated to be about 23, 28, 2, 15, and 32%, respectively.

  相似文献   

8.
The Korba aquifer on the east coast of Cape Bon has been overexploited since the 1960s with a resultant reversal of the hydraulic gradient and a degradation of the quality due to seawater intrusion. In 2008 the authorities introduced integrated water resources planning based on a managed aquifer recharge with treated wastewater. Water quality monitoring was implemented in order to determine the different system components and trace the effectiveness of the artificial recharge. Groundwater samples taken from recharge control piezometers and surrounding farm wells were analyzed for their chemical contents, for their B isotopes, a proven tracer of groundwater salinization and domestic sewage, and their carbamazepine content, an anti-epileptic known to pass through wastewater treatment and so recognized as a pertinent tracer of wastewater contamination. The system equilibrium was permanently disturbed by the different temporal dynamics of continuous processes such as cation exchange, and by threshold processes linked to oxidation–reduction conditions. The B isotopic compositions significantly shifted back-and-forth due to mixing with end-members of various origin. Under the variable contribution of meteoric recharge, the Plio-Quaternary groundwater (δ11B of 35–40.6‰, a mean B concentration of 30 μmol/L, no carbamazepine, n = 7) was subject to seawater intrusion that induced a high δ11B level (δ11B of 41.5–48.0‰, a mean B concentration of 36 μmol/L, and n = 8). Fresh groundwater (δ11B of 19.89‰, B concentration of 2.8 μmol/L, no carbamazepine) was detected close to the recharge site and may represent the deep Miocene pole which feeds the upper Plio-Quaternary aquifer. The managed recharge water (δ11B of 10.67–13.8‰, n = 3) was brackish and of poor quality with a carbamazepine content showing a large short term variability with an average daily level of 328 ± 61 ng/L. A few piezometers in the vicinity of the recharge site gradually acquired a B isotopic composition close to the wastewater signature and showed an increasing carbamazepine content (from 20 to 910 ng/L). The combination of B isotopic signatures with B and carbamazepine contents is a useful tool to assess sources and mixing of treated wastewaters in groundwaters. Effluent quality needs to be greatly improved before injection to prevent further degradation of groundwater quality.  相似文献   

9.
The Complex Terminal (CT) confined aquifer of the Djerid basin, southwestern Tunisia, was studied using major ion concentrations and stable isotope contents in order to (1) investigate the changes on its hydrodynamic functioning due to the long-term over-pumping and the large-scale flood irrigation practices, (2) determine the principal mineralization processes of its fossil groundwater, and (3) examine the mode of recharge of this aquifer and whether it contains part of modern hydrological regime. The observed geochemical patterns indicated that the main mineralization processes affecting the CT groundwater water/rock interactions and mixing. The native Na > Cl and Cl > SO4 > Ca > Na waters, resulting from the dissolution of halite and gypsum and from pyrite oxidation, interacted with those of the underlying and the overlying aquifers without changing their chemical facies. Stable isotope data provided evidences about upward and downward leakage into the CT aquifer and their relationships with anthropogenic activities. They demonstrated that the long-term over-pumping of the CT aquifer, which contributed to the loss of its potentiometric pressure, favored the upward leakage of the artesian deep groundwater along parts of the major faults. Moreover, the large-scale flood irrigation practices in the oases domain, which ensured the recharge of the shallow water table by return flow, enhanced the downward leakage toward the CT aquifer.  相似文献   

10.
Managing transboundary groundwater resources requires accurate and detailed knowledge of aquifers and groundwater bodies. The Pannonian Basin is the largest intracontinental basin in Europe with a continuous succession of more than 7 km of Miocene to Quaternary sediments and with an average geothermal gradient of about 5 °C/100 m. Geographically the Pannonian basin overlaps eight countries (Hungary, Romania, Serbia, Croatia, Slovenia, Austria, Slovakia and Ukraine), so the issue of transboundary cold and thermal water resources is regionally very important. The T-JAM bilateral Hungarian–Slovenian (HU–SLO) project is the first to apply modern isotopic and chemical analyses in the characterization and correlation of a number of shared groundwater resources in the Mura-Zala Sub-basin of the Pannonian. The aims of this work were the identification of groundwater flow paths, the delineation of transboundary aquifers based on thermal and cold groundwater geochemical and isotope properties in the Mura-Zala Basin, and providing input to calibrate a hydraulic numerical model. Following a common groundwater sampling campaign, 24 cold and thermal groundwater samples from seven aquifers were collected for chemical, isotope, gas and noble gas analyses. Chemical analyses, and D, O and C isotopes were used to correlate cross border aquifers. A regional groundwater flow is hydrogeologically possible in some aquifers in the Mura-Zala Basin, and has been confirmed by hydrogeochemistry. The Újfalu (HU) and Mura (SLO) Formations are a part of the active regional thermal groundwater flow system, probably hydraulically separated from the shallower flow system of the Ptuj-Grad (SLO), Zagyva and Somló-Tihany (HU) Formations. The thermal water is of meteoric origin, reductive and alkaline. The predominant water type in the Quaternary and Pliocene aquifers is Ca–Mg–HCO3, changing to Na–HCO3 in the main Pannonian geothermal aquifer, and Na–Cl brine in deeper and older Miocene aquifers. Total dissolved solids and Na content generally increase with depth. Deuterium is in the range −87‰ to −75‰, 18O from −11.9‰ to −10.4‰, while 14C values are less than 6.1 pmC in the samples of the active regional thermal groundwater flow system. These and results of noble gas analyses indicate recharge during the Pleistocene interglacial period with temperatures around 6–7 °C. Regional thermal water resources are limited and environmental isotopes can be used as an early warning in the management of thermal water.  相似文献   

11.
Groundwater is the most important source of water supply in Sidi Bouzid plain located in central Tunisia. Proper understanding of the geochemical evolution of groundwater is important for sustainable development of water resources in this region. A hydrogeochemical survey was conducted on the Mio–Plio–Quaternary aquifer system using stable isotopes, radiocarbon, tritium and major elements, in order to evaluate the groundwater chemistry patterns and the main mineralization processes occurring in this system. The chemical data indicate that dissolution of evaporate minerals and evaporation are the main processes controlling groundwater mineralization. The isotopic data show that groundwater in the study area is a mixture of recent shallow waters located upstream and along Wadi Al Fakka bed and paleowaters located towards plain limits and discharge areas. Low 3H and 14C contents are observed in major part of the plain indicating that recharge of the aquifer occurs mainly through direct infiltration at Wadi Al Fakka while there is no evidence of significant recharge in major part of the plain and mountains piedmonts.  相似文献   

12.
The groundwater extracted from the unconfined Quaternary aquifer is the main source of water supply in El-Tur area. The area is bounded from the east by the elevated basement complex of Southern Sinai and from the west by El-Qabaliyat Ridge. The wadis dissecting these highlands form effective watersheds of the Quaternary aquifer. These wadis form areas of focused recharge. Recharge also occurs directly via the Quaternary sediments covering El-Qaa Plain. Subsurface lateral groundwater flow from the fractured basement contributes significant recharge to the aquifer as well. The aquifer sediment facies affect the type and quality of groundwater. In the eastern part where the aquifer is composed mainly of gravel and coarse sand with fragments of weathered basement, the Na-Cl-SO4 water dominates. In the west where the facies change is rapid and complex, many water types arise. The base exchange index (BEX) is positive in this part reflecting the role of clay minerals in changing the water types via cation exchange. In the east where clays are insignificant in the aquifer, the BEX is negative. In the western part next to El-Qabaliyat Ridge, the wells discharging from the calcareous sand zone have low groundwater salinities compared to the wells discharging from the alluvium. In general, the groundwater salinity increases in the direction of groundwater flow from the northeast to the southwest which reflects the dissolution of aquifer sediments. The concentration relationships between the major ions on one hand and chloride on the other reflect the dissolution of calcium carbonates, precipitation of K- and Mg-bearing minerals, and cation exchange of Ca for Na on clay minerals. The hydrochemical models support these reactions. In addition, they show that the effect of evaporation on the recharge water in the western catchment is about four times its effect on the eastern recharge water which reflects the rapid recharge through the wadis draining the fractured basement. Moreover, the contribution from the eastern catchment in sample No. 23 is more than four-folds the contribution from the western recharge area. The stable isotopes (2H and 18O) show that the Quaternary aquifer is recharging from recent rainfall. However, upward leakage of Paleogene groundwater (depleted in 18O) also occurs. The groundwater level map shows strong overpumping impact especially in the areas close to El-Tur city.  相似文献   

13.
A drilling project was carried out in Syria to assess the potential of the deep groundwater resources of the Cretaceous aquifer, composed of Cenomanian-Turonian limestones and dolomites. In this context, isotope (14C, 3H, δ13C, δ18O, δ2H) and hydrochemical analyses were performed on wells in and around the Aleppo and Steppe basins. The interpretation includes complementary results from published and unpublished literature. The results provide evidence that many new wells pump mixed groundwater from the Cretaceous aquifer and the overlying Paleogene aquifer. Radiocarbon measurements confirmed dominating Pleistocene groundwater in the Cretaceous aquifer and mainly Holocene groundwater in the Paleogene aquifer. Most groundwater in the Cretaceous aquifer seems to be recharged in the western limestone ridges, stretching from Jebel az Zawiyah (south of Idlep) via Jebel Samane (south of Afrin and A’zaz) to the region north of Aleppo, and in the Northern Palmyrides mountain belt. Some recharge also occurs around the basalt plateau of the Jebel al Hass, south east of Aleppo. It is concluded that the Taurus Mountains and the Euphrates River do not recharge the Cretaceous aquifer. The sources of recharge seem to be occasionally occurring intensive winter storms that approach from Siberia.  相似文献   

14.
The Quaternary coastal plain aquifer down gradient of the Wadi Watir catchment is the main source of potable groundwater in the arid region of south Sinai, Egypt. The scarcity of rainfall over the last decade, combined with high groundwater pumping rates, have resulted in water-quality degradation in the main well field and in wells along the coast. Understanding the sources of groundwater salinization and amount of average annual recharge is critical for developing sustainable groundwater management strategies for the long-term prevention of groundwater quality deterioration. A combination of geochemistry, conservative ions (Cl and Br), and isotopic tracers (87/86Sr, δ81Br, δ37Cl), in conjunction with groundwater modeling, is an effective method to assess and manage groundwater resources in the Wadi Watir delta aquifers. High groundwater salinity, including high Cl and Br concentrations, is recorded inland in the deep drilled wells located in the main well field and in wells along the coast. The range of Cl/Br ratios for shallow and deep groundwaters in the delta (∼50–97) fall between the end member values of the recharge water that comes from the up gradient watershed, and evaporated seawater of marine origin, which is significantly different than the ratio in modern seawater (228). The 87/86Sr and δ81Br isotopic values were higher in the recharge water (0.70,723 < 87/86Sr < 0.70,894, +0.94 < δ81Br < +1.28‰), and lower in the deep groundwater (0.70,698 < 87/86Sr < 0.70,705, +0.22‰ < δ81Br < +0.41‰). The δ37Cl isotopic values were lower in the recharge water (−0.48 < δ37Cl < −0.06‰) and higher in the deep groundwater (−0.01 < δ37Cl < +0.22‰). The isotopic values of strontium, chloride, and bromide in groundwater from the Wadi Watir delta aquifers indicate that the main groundwater recharge source comes from the up gradient catchment along the main stream channel entering the delta. The solute-weighted mass balance mixing models show that groundwater in the main well field contains 4–10% deep saline groundwater, and groundwater in some wells along the coast contain 2–6% seawater and 18–29% deep saline groundwater.A three-dimensional, variable-density, flow-and-transport SEAWAT model was developed using groundwater isotopes (87Sr/86Sr, δ37Cl and δ81Br) and calibrated using historical records of groundwater level and salinity. δ18O was used to normalize the evaporative effect on shallow groundwater salinity for model calibration. The model shows how groundwater salinity and hydrologic data can be used in SEAWAT to understand recharge mechanisms, estimate groundwater recharge rates, and simulate the upwelling of deep saline groundwater and seawater intrusion. The model indicates that most of the groundwater recharge occurs near the outlet of the main channel. Average annual recharge to delta alluvial aquifers for 1982 to 2009 is estimated to be 2.16 × 106 m3/yr. The main factors that control groundwater salinity are overpumping and recharge availability.  相似文献   

15.
《Applied Geochemistry》2005,20(2):295-316
A confined aquifer system has developed in argillaceous marine and freshwater sediments of Pliocene–Holocene age in the northeastern Osaka Basin (NEOB) in central Japan. The shallow groundwater (<100 m) in the system is recharged in a northern hilly to mountainous area with dominantly Ca-HCO3 type water, which changes as it flows toward the SW to Mg-HCO3 type and then to Na-HCO3 type water. Comparison of the chemical and Sr isotopic compositions of the groundwater with those of the bulk and exchangeable components of the underground sediments indicates that elements leached from the sediments contribute negligibly to the NEOB aquifer system. Moreover, model calculations show that contributions of paleo-seawater in the deep horizon and of river water at the surface are not major factors of chemical change of the groundwater. Instead, the zonal pattern of the HCO3-dominant groundwater is caused by the loss of Ca2+ from the water as it is exchanged for Mg2+ in clays, followed by loss of Mg + Ca as they are exchanged for Na + K in clays between the Ca-HCO3 type recharge water and the exchangeable cations in the clay layers, which were initially enriched in Na+. Part of this process was reproduced in a chromatographic experiment in which Na type water with high 87Sr/86Sr was obtained from Mg type water with low 87Sr/86Sr by passing it through marine clay packed in a column. The flux of recharge water into the confined aquifer system according to this chromatographic model is estimated to be 0.99 mm/day, which is compatible with the average recharge flux to unconfined groundwater in Japan (1 mm/day).  相似文献   

16.
 The Judea Group, a limestone and dolomite karstic aquifer of late Albian–Turonian age, is one of the most important sources of water in Israel. In the western part of the country, the Judea Group aquifer is also known as the Yarkon–Taninim basin. In the northern Negev, the Judea Group is a recipient for fresh water flowing southward from the Hebron Mountains and of brackish paleowater flowing northward from Sinai. Very little is known of the hydraulic properties of this aquifer. In order to outline assumed natural flow paths that existed in this karstic environment prior to groundwater exploitation, use was made of lithological, structural, and paleomorphological features. A detailed hydrogeological conceptual model of the Judea Group aquifer in northern Negev was established by the geological interpretation of high-resolution seismic reflection and by analysis of lithological evidence from boreholes. Isopach, isolith-contour, and isolith-ratio maps were compiled for the main lithological components. Increase in transmissivity values is inversely proportional with the cumulative thickness of argillaceous components. The lithological and hydraulic evidence provides the basis for subdividing the subsurface into distinctive permeability zones for the upper and lower sections of the aquifer; for outlining possible preferential groundwater flow paths for both subaquifers; and for improving understanding of groundwater-salinty variations that result from lithological variability, direction of groundwater flow paths, groundwater flow rates, and the duration of rock/water interactions. In an earlier conceptual model of the basin, the Judea Group aquifer was regarded as a continuous and undisturbed entity. The present study reveals an intricate groundwater flow pattern that is controlled by lithological and structural factors that create zones of preferential flow. This interpretation bears on the overall evaluation of groundwater resources and their management and exploitation. Received, December 1996 · Revised, October 1997, June 1998 · Accepted, July 1998  相似文献   

17.
A conceptual groundwater flow model was developed for the crystalline aquifers in southeastern part of the Eastern region, Ghana. The objective was to determine approximate levels of groundwater recharge, estimate aquifer hydraulic parameters, and then test various scenarios of groundwater extraction under the current conditions of recharge. A steady state groundwater flow model has been calibrated against measured water levels of 19 wells in the area. The resulting recharge is estimated to range from 8.97 × 10?5 m/d to 7.14 × 10?4 m/d resulting in a basin wide average recharge of about 9.6% of total annual precipitation, which results in a basin wide quantitative recharge of about 2.4 million m3/d in the area. This compares to recharge estimated from the chloride mass balance of 7.6% of precipitation determined in this study. The general groundwater flow in the area has also been determined to conform to the general northeast–southwest structural grain of the country. The implication is that the general hydrogeology is controlled by post genetic structural entities imposed on the rocks to create ingresses for sufficient groundwater storage and transport. Calibrated aquifer hydraulic conductivities range between 0.99 m/d and over 19.4 m/d. There is a significant contribution of groundwater discharge to stream flow in the study area. Increasing groundwater extraction will have an effect on stream flow. This study finds that the current groundwater extraction levels represent only 0.17% of the annual recharge from precipitation, and that groundwater can sustain future increased groundwater demands from population growth and industrialization.  相似文献   

18.
The spatial and temporal changes of the composition of the groundwater from the springs along the Wadi Qilt stream running from the Jerusalem–Ramallah Mountains towards the Jericho Plain is studied during the hydrological year 2006/2007. The residence time and the intensity of recharge play an important role in controlling the chemical composition of spring water which mainly depends on distance from the main recharge area. A very important factor is the oxidation of organics derived from sewage and garbage resulting in variable dissolved CO2 and associated HCO3 − concentration. High CO2 yields lower pH values and thus under-saturation with respect to calcite and dolomite. Low CO2 concentrations result in over-saturation. Only at the beginning and at the end of the rainy season calcite saturation is achieved. The degradation of dissolved organic matter is a major source for increasing water hardness. Besides dissolution of carbonates dissolved species such as nitrate, chloride, and sulfate are leached from soil and aquifer rocks together with only small amounts of Mg. Mg not only originates from carbonates but also from Mg–Cl waters are leached from aquifer rocks. Leaching of Mg–Cl brines is particularly high at the beginning of the winter season and lowest at its end. Two zones of recharge are distinguishable. Zone 1 represented by Ein Fara and Ein Qilt is fed directly through the infiltration of meteoric water and surface runoff from the mountains along the eastern mountain slopes with little groundwater residence time and high flow rate. The second zone is near the western border of Jericho at the foothills, which is mainly fed by the under-groundwater flow from the eastern slopes with low surface infiltration rate. This zone shows higher groundwater residence time and slower flow rate than zone 1. Groundwater residence time and the flow rate within the aquifer systems are controlled by the geological structure of the aquifer, the amount of active recharge to the aquifer, and the recharge mechanism. The results of this study may be useful in increasing the efficiency of freshwater exploitation in the region. Some precautions, however, should be taken in future plans of artificial recharge of the aquifers or surface-water harvesting in the Wadi. Because of evaporation and associated groundwater deterioration, the runoff water should be artificially infiltrated in zones of Wadis with high storage capacity of aquifers. Natural infiltration along the Wadis lead to evaporation losses and less quality of groundwater.  相似文献   

19.
Travel times and flow paths of groundwater from its recharge area to drinking-water production wells will govern how the quality of pumped groundwater responds to contaminations. Here, we studied the 180 km2 Ammer catchment in southwestern Germany, which is extensively used for groundwater production from a carbonate aquifer. Using a 3-D steady-state groundwater model, four alternative representations of discharge and recharge were systematically explored to understand their impact on groundwater travel times and flow paths. More specifically, two recharge maps obtained from different German hydrologic atlases and two plausible alternative discharge scenarios were tested: (1) groundwater flow across the entire streambed of the Ammer River and its main tributaries and (2) groundwater discharge via a few major springs feeding the Ammer River. For each of these scenarios, the groundwater model was first calibrated against water levels, and subsequently travel times and flow paths were calculated for production wells using particle tracking methods. These computed travel times and flow paths were indirectly evaluated using additional data from the wells including measured concentrations of major ions and environmental tracers indicating groundwater age. Different recharge scenarios resulted in a comparable fit to observed water levels, and similar estimates of hydraulic conductivities, flow paths and travel times of groundwater to production wells. Travel times calculated for all scenarios had a plausible order of magnitude which were comparable to apparent groundwater ages modelled using environmental tracers. Scenario with groundwater discharge across the entire streambed of the Ammer River and its tributaries resulted in a better fit to water levels than scenario with discharge at a few springs only. In spite of the poorer fit to water levels, flow paths of groundwater from the latter scenario were more plausible, and these were supported by the observed major ion chemistry at the production wells. We concluded that data commonly used in groundwater modelling such as water levels and apparent groundwater ages may be insufficient to reliably delineate capture zones of wells. Hydrogeochemical information relating only indirectly to groundwater flow such as the major ion chemistry of water sampled at the wells can substantially improve our understanding of the source areas of recharge for production wells.  相似文献   

20.
The hydrodynamic groundwater data and stable isotopes of water have been used jointly for better understanding of upward leakage and mixing processes in the Djerid aquifer system (southwestern Tunisia). The aquifer system is composed of the upper unconfined Plio-Quaternary (PQ) aquifer, the intermediate (semi-)confined Complex Terminal (CT) aquifer and the deeper confined Continental Intercalaire (CI) aquifer. A total of 41 groundwater samples from the CT and PQ aquifers were collected during June 2001. The stable isotope composition of waters establishes that the CT deep groundwater (depleted as compared to present Nefta local rainfall) is ancient water recharged during late Quaternary time. The relatively recent water in the shallow PQ aquifer is composed of mixed water resulting from upward leakage and sporadic meteoric recharge. In order to characterize the meteoric input signal for PQ in the study area, rainfall water samples were collected during 4 years (2000–2003) at the Nefta meteorological station. Weighted mean values of isotopic contents with respect to rainfall amounts have been computed. Despite the short collection period in the study area, results agree with those found in Beni Abbes (southwestern Algerian Sahara) by Fontes on 9 years of rainfall surveillance. Stable isotopic relationships provide clear evidence of shallow PQ aquifer replenishment by deep CT groundwater. The 18O/upward leakage rate allowed the identification of distinctive PQ waters related to CT aquifer configuration (confined in the western part of the study area, semi-permeable in the eastern part). These trends were confirmed by the relation 18O/TDS. The isotope balance model indicated a contribution of up to 75% of the deep CT groundwater to the upper PQ aquifer in the western study area, between Nefta and Hazoua.  相似文献   

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