首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 156 毫秒
1.
《Lithos》2007,93(1-2):175-198
The Neoproterozoic (∼ 820 Ma) Aries micaceous kimberlite intrudes the central Kimberley Basin, northern Western Australia, and has yielded a suite of 27 serpentinised ultramafic xenoliths, including spinel-bearing and rare, metasomatised, phlogopite–biotite and rutile-bearing types, along with minor granite xenoliths. Proton-microprobe trace-element analysis of pyrope and chromian spinel grains derived from heavy mineral concentrates from the kimberlite has been used to define a ∼ 35–40 mW/m2 Proterozoic geotherm for the central Kimberley Craton. Lherzolitic chromian pyrope highly depleted in Zr and Y, and Cr-rich magnesiochromite xenocrysts (class 1), probably were derived from depleted garnet peridotite mantle at ∼ 150 km depth. Sampling of shallower levels of the lithospheric mantle by kimberlite magmas in the north and north-extension lobes entrained high-Fe chromite xenocrysts (class 2), and aluminous spinel-bearing xenoliths, where both spinel compositions are anomalously Fe-rich for spinels from mantle xenoliths. This Fe-enrichment may have resulted from Fe–Mg exchange with olivine during slow cooling of the peridotite host rocks. Fine exsolution rods of aluminous spinel in diopside and zircon in rutile grains in spinel- and rutile-bearing serpentinised ultramafic xenoliths, respectively, suggest nearly isobaric cooling of host rocks in the lithospheric mantle, and indicate that at least some aluminous spinel in spinel-facies peridotites formed through exsolution from chromian diopside. Fe–Ti-rich metasomatism in the spinel-facies Kimberley mantle probably produced high-Ti phlogopite–biotite + rutile and Ti, V, Zn, Ni-enriched aluminous spinel ± ilmenite associations in several ultramafic xenoliths. U–Pb SHRIMP 207Pb/206Pb zircon ages for one granite (1851 ± 10 Ma) and two serpentinised ultramafic xenoliths (1845 ± 30 Ma; 1861 ± 31 Ma) indicate that the granitic basement and lower crust beneath the central Kimberley Basin are at least Palaeoproterozoic in age. However, Hf-isotope analyses of the zircons in the ultramafic xenoliths suggest that the underlying lithospheric mantle is at least late Archean in age.  相似文献   

2.
In Venezuela, kimberlites have so far only been found in the Guaniamo region, where they occur as high diamond grade sheets in massive to steeply foliated Paleoproterozoic granitoid rocks. The emplacement age of the Guaniamo kimberlites is 712±6 Ma, i.e., Neoproterozoic. The Guaniamo kimberlites contain a high abundance of mantle minerals, with greater than 30% olivine macrocrysts. The principal kimberlite indicator minerals found are pyrope garnet and chromian spinel, with the overwhelming majority of the garnets being of the peridotite association. Chrome-diopside is rare, and picroilmenite is uncommon. Chemically, the Guaniamo kimberlites are characterized by high MgO contents, with low Al2O3 and TiO2 contents and higher than average FeO and K2O contents. These rocks have above average Ni, Cr, Co, Th, Nb, Ta, Sr and LREE concentrations and very low P, Y and, particularly, Zr and Hf contents. The Nb/Zr ratio is very distinctive and is similar to that of the Aries, Australia kimberlite. The Guaniamo kimberlites are similar in petrography, mineralogy and mantle mineral content to ilmenite-free Group 2 mica kimberlites of South Africa. The Nd-Sr isotopic characteristics of Guaniamo kimberlites are distinct from both kimberlite Group 1 and Group 2, being more similar to transitional type kimberlites, and in particular to diamondiferous kimberlites of the Arkhangelsk Diamond Province, Russia. The Guaniamo kimberlites form part of a compositional spectrum between other standard kimberlite reference groups. They formed from metasomatised subcontinental lithospheric mantle and it is likely that subduction of oceanic crust was the source of this metasomatised material, and also of the eclogitic component, which is dominant in Guaniamo diamonds.  相似文献   

3.
The Buffalo Hills kimberlites define a province of kimberlite magmatism occurring within and adjacent to Proterozoic crystalline basement termed the Buffalo Head Terrane in north-central Alberta, Canada. The kimberlites are distinguished by a diverse xenocryst suite and most contain some quantity of diamond. The xenocryst assemblage in the province is atypical for diamondiferous kimberlite, including an overall paucity of mantle indicator minerals and the near-absence of compositionally subcalcic peridotitic garnet (G10). The most diamond-rich bodies are distinguished by the presence of slightly subcalcic, chromium-rich garnet and the general absence of picroilmenite, with the majority forming a small cluster in the northwestern part of the province. Barren and near-barren pipes tend to occur to the south, with increasing proximity to the basement structure known as the Peace River Arch. Niobian picroilmenite, compositionally restricted low-to moderate-Cr peridotitic garnet, and megacrystal titanian pyrope occur in kimberlites closest to the arch. Major element data for clinopyroxene and trace element data for garnet from diamond-rich and diamond-poor kimberlites suggests that metasomatism of lithospheric peridotite within the diamond stability field may have caused destruction of diamond, and diamond source rocks proximal to the arch were the most affected.  相似文献   

4.
Ultramafic xenoliths were found in recent alkali basalts from São Tomé Island. These include spinel peridotites (lherzolites, harzburgites and dunites) and pyroxenites (orthopyroxenites and clinopyroxenites). Textures and mineral compositions indicate that pyroxenites originated from crystal/liquid separation processes operating on magmas similar to those giving rise to their present host rocks whereas spinel peridotite xenoliths had an accidental origin; Fo (>89) and Ni (>0.36 wt.%) contents in olivines, Mg# (91–95) of orthopyroxenes and low Ti in clinopyroxene (primary crystals: TiO2<0.06 wt.%) and in spinel (TiO2<0.1 wt.%) are within the range reported for abyssal peridotites, indicating São Tomé spinel peridotites represent refractory residues of melting. Nevertheless, the lack of correlation between mineral chemistry and modal composition suggests that spinel peridotite xenoliths are not simple residues and were affected by infiltration of fluid/melts within the mantle. The wide temperature range obtained for spinel peridotites (700 to >1150 °C) is compatible with a long period of pre-entrainment cooling supporting Fitton's [Tectonophysics 94 (1983) 473] hypothesis that proposes oceanic lithosphere uprising in the Cameroon Volcanic Line prior to the initiation of the current thermal regime, related to São Tomé magmatism. The association of upper mantle (peridotite) xenoliths with igneous cumulates (pyroxenites) suggests that the spinel peridotite suite originated in the uppermost mantle above the São Tomé magma storage zone(s), probably in a region of high strain rate, near the boundary between the mantle and the overlying oceanic crust.  相似文献   

5.
Manganoan ilmenite was identified in Juina, Brazil kimberlitic rocks among other megacrysts. It forms oval, elongated, rimless grains comprising 8–30 wt.% of the heavy fraction. Internally the grains are homogeneous. The chemical composition of Mn-ilmenite is almost stoichiometric for ilmenite except for an unusually high manganese content, with MnO = 0.63–2.49 wt.% (up to 11 wt.% in inclusions in diamond) and an elevated vanadium admixture (V2O3 = 0.21–0.43 wt.%). By the composition, Mn-ilmenite megacrysts and inclusions in diamond are almost identical. The concentrations of trace elements in Mn-ilmenite, compared to picroilmenite, are much greater and their variations are very wide. Chondrite-normalized distribution of trace elements in Mn-ilmenite megacrysts is similar to the distribution in Mn-ilmenites included in diamond. This confirms that Mn-ilmenite in kimberlites is genetically related to diamond. The finds of Mn-ilmenite known before in kimberlitic and related rocks are late- or postmagmatic, metasomatic phases. They either form reaction rims on grains of picroilmenite or other ore minerals, or compose laths in groundmass. In contrast to those finds, Mn-ilmenite megacrysts in Juina kimberlites are a primary mineral phase with a homogeneous internal structure obtained under stable conditions of growth within lower mantle and/or transition zone. In addition to pyrope garnet, chromian spinel, picroilmenite, chrome-diopside, and magnesian olivine, manganoan ilmenite may be considered as another kimberlite/diamond indicator mineral.  相似文献   

6.
ARAI  SHOJI 《Journal of Petrology》1980,21(1):141-165
Dunite, harzburgite and chromitite of alpine-type ultramaficcomplexes emplaced in the Paleozoic sediments in the Sangun—Yamaguchizone, western Japan, are massive and almost lacking in layeredstructure. Constituent minerals are more or less deformed andequilibrated at a relatively low temperature, about 700 °Cor lower. Chromian spinels in ultramafic rocks from dunite—harzburgite—chromititecomplexes in the Sangun—Yamaguchi zone are characterizedby the uniformity of the Cr/Cr + Al ratio, around 0.5, regardlessof locality and rock type, which is in contrast to the widevariation of the ratio of chromian spinel from the ordinaryalpine-type dunite—harzburgite complex. Mg/Mg + Fe" ratioof chromian spinel, on the other hand, is variable in parallelto the volume per cent of chromian spinel in ultramafic rocks.Olivine in ultramafic rocks is uniform in chemical composition,from Fo88 to Fo92, except for that in chromitite, of which itis Fo95 to Fo97. Primary chemical compositions (especially the Mg/Mg + Fe" ratio)of the constituent minerals have been modified to some extentby element redistribution at low temperature (700 °C orlower), the degree of modification depending on the volume ratioof the minerals. For example, the Mg/Mg + Fe" ratio of chromianspinel in peridotitic rocks has been lowered substantially,and inversely, that of olivine in chromitite has been raised.Primary Mg/Mg + Fe" ratios of olivine and chromian spinel canbe estimated, assuming a certain value of high temperature,e.g. 1200 °C, and the partition coefficient between olivineand chromian spinel at that temperature. As a result, the Mg/Mg+ Fe" ratio of olivine (0.88 to 0.92), and that of chromianspinel (0.78 to 0.80) were uniform, irrespective of rock typeand locality, at the high-temperature stage. Dunite—harzburgite—chromitite complexes in the Sangun—Yamaguchizone were accumulated as refractory residue after the relativelylarge-scaled partial fusion of some primordial peridotites,which resulted in the chemical uniformity of the residual minerals.They may have initially constituted the lowest part of an ophioliticsuite as ultramafic tectonite and been emplaced as dismemberedportions after the disruption of the parent body.  相似文献   

7.
First data on the geologic and geochemical compositions of kimberlites from nine kimberlite pipes of southwestern Angola are presented. In the north of the study area, there are the Chikolongo and Chicuatite kimberlite pipes; in the south, a bunch of four Galange pipes (I–IV); and in the central part, the Ochinjau, Palue, and Viniaty pipes. By geochemical parameters, these rocks are referred to as classical kimberlites: They bear mantle inclusions of ultrabasites, eclogites, various barophilic minerals (including ones of diamond facies), and diamonds. The kimberlite pipes are composed of petrographically diverse rocks: tuffstones, tuff breccias, kimberlite breccias, autolithic kimberlite breccias, and massive porphyritic kimberlites. In mineralogical, petrographic, and geochemical compositions the studied kimberlites are most similar to group I kimberlites of South Africa and Fe-Ti-kimberlites of the Arkhangel’sk diamondiferous province. Comparison of the mineralogical compositions of kimberlites from southwestern Angola showed that the portion of mantle (including diamondiferous) material of depth facies in kimberlite pipes regularly increases in the S-N direction. The northern diamond-bearing kimberlite pipes are localized in large destructive zones of NE strike, and the central and southern diamond-free pipes, in faults of N-S strike.  相似文献   

8.
Prospecting for kimberlites and related rocks in till-covered terrains requires a methodology for recovering a few small grains within tens of kilograms samples, necessitating 1 ppb sensitivity or better. As part of reconnaissance survey for the kimberlite indicator minerals, i.e. pyrope garnet, picroilmenite, chromite and chromian diopside, the Geological Survey of Finland (GTK) developed such a system by significantly modifying and augmenting a 3″ Knelson Concentrator that accomplishes nearly complete recovery of moderately heavy minerals (>0.25 mm) from till samples.Diamondiferous kimberlites occur in the eastern Finland around the Kaavi–Kuopio and Kuhmo areas and much of the rest of the Karelian craton remains prospective based on the empirical evidence necessary for diamond preservation: thick (>200 km) lithospheric mantle, low heat flow and Archaean age rocks. A target area in Lapland, 20×50 km in size, was selected for a pilot study to test extraction of chromite for the (1) discrimination of regionally and locally derived populations, and (2) recognition of possible kimberlitic/lamproitic chromites. Area selection was based on the regional occurrence of a variety of mantle-derived rocks, the recovery of a chromian pyrope grain from till in 1996 and most importantly, the well-established Quaternary stratigraphy in the region. The sample material consisted of sixty-two 80-kg excavator and 40-kg shovel samples. Approximately 1000 chromite grains, almost exclusively 0.25–0.5 mm in diameter, were recovered and analysed by electron microprobe.Tills in the sampling area proved to contain at least two compositional populations of chromite. The first is present in almost every sample and is apparently derived from layered mafic intrusions distal to and up-ice from the study area. The second population consists of chromites with low Ti, high Cr and Mg similar to inclusions in diamond. It is present in approximately one third of the samples, concentrated in a couple of clusters within the target area and is therefore considered to be of more local derivation. Since no high-Ti, high-Cr chromites diagnostic for kimberlites and lamproites were present in the samples, the source for the low-Ti, high-Cr, high-Mg chromite grains remains uncertain, but is probably not kimberlitic. Although this apparently is a negative outcome for diamond exploration in the target area, the main goal of the study was realised by showing the applicability of the system to heavy mineral separation from Quaternary glacial deposits.  相似文献   

9.
Kimberlite sills emplaced in granite located near the town of Wemindji (Quebec, Canada) range from 2 cm to 1.2 m in thickness. The sills exhibit a wide variation in macroscopic appearance from fine-grained aphanitic dolomitic hypabyssal kimberlite to ilmenite/garnet macrocrystal hypabyssal kimberlite. Diatreme or crater facies rocks are not present. Multiple intrusions are present within the sills, and graded bedding and erosional features such as cross-bedding are common. The sills exhibit a wide range in their modal mineralogy with respect to the abundances of spinel, apatite, phlogopite and dolomite. Olivine is the dominant macrocryst, with an average composition of Fo90. Garnet macrocrysts are low chrome (2–3 wt. %) pyrope (G1/G9 garnet). Ilmenite occurs as rounded macrocrysts (7–13 wt. % MgO). Phlogopite microphenocrysts are Ti-poor and represent a solid solution between phlogopite and kinoshitalite end members. Spinel compositions mainly represent the Cr-poor members of the qandilite–ulvöspinel–magnetite series. The principle carbonate comprising the groundmass is dolomite, with lesser later-forming calcite. Accessory minerals include apatite, Sr-rich calcite, Nb-rich rutile, baddeleyite, monazite-(Ce) and barite. While some of these accessory minerals are atypical of kimberlites in general, it is expected that differentiation products of an evolved carbonate-rich kimberlite magma will crystallize these phases. The Wemindji kimberlites offer insight into the process of crystal fractionation and differentiation in evolved kimberlite magmas. The macroscopic textural features observed in the Wemindji sills are interpreted to represent flow differentiation of a mantle-derived, very fluid, low viscosity carbonate-rich kimberlite. The diverse modes and textural features result entirely from flow differentiation and multiple intrusions of different batches of genetically related kimberlite magma. The mineralogy of the Wemindji kimberlites has some similarities to that of the Wesselton and Benfontein calcite kimberlite sills but differs in detail with respect to dominant carbonate (i.e. dolomite versus calcite), and the character of the rare earth-bearing accessory minerals (i.e. monazite-(Ce) versus rare earth fluorocarbonates).  相似文献   

10.
Cr-poor and Cr-rich megacryst suites, both comprising of varying proportions of megacrysts of orthopyroxene, clinopyroxene, garnet, olivine, ilmenite and a number of subordinate phases, coexist in many kimberlites, with wide geographic distribution. In rare instances, the two suites occur together on the scale of individual megacryst hand specimens. Deformation textures are common to both suites, suggesting an origin related to the formation of the sheared peridotites that also occur in kimberlites. Textures and compositions of the latter are interpreted to reflect deformation and metasomatism within the thermal aureole surrounding the kimberlite magma in the mantle. The megacrysts crystallized in this thermal aureole in pegmatitic veins representing small volumes of liquids derived from the host kimberlite magma, which were injected into a surrounding fracture network prior to kimberlite eruption. Close similarities between compositions of Cr-rich megacryst phases and those in granular lherzolites are consistent with early crystallization from a primitive kimberlite liquid. The low-Cr megacryst suite subsequently crystallized from residual Cr-depleted liquids. However, the Cr-poor suite also reflects the imprint of contamination by liquids formed by melting of inhomogeneously distributed mantle phases with low melting temperatures, such as calcite and phlogopite, present within the thermal aureole surrounding the kimberlite magma reservoir. Such carbonate-rich melts migrated into, and mixed with some, but not all, of the kimberlite liquids injected into the mantle fracture network. Contamination by the carbonate-rich melts changed the Ca–Mg and Mg–Fe crystal–liquid distribution coefficient, resulting in the crystallization of relatively Fe-rich and Ca-poor phases. The implied higher crystal-melt Mg–Fe distribution coefficient for carbonate-rich magmas accounts for the generation of small volumes of Mg-rich liquids that are highly enriched in incompatible elements (i.e. primary kimberlite magmas). The inferred metasomatic origin for the sheared peridotites implies that this suite provides little or no information regarding vertical changes in the thermal, chemical and mechanical characteristics of the mantle.  相似文献   

11.
作者研究发现山东胜利1号、辽宁50号、51号及42号岩体中,见有纯橄岩、石榴二辉橄榄岩、尖晶二辉橄榄岩及云母橄榄岩包体;河北涉县及山东红旗2号金伯利岩中见有榴辉岩包体。包体形态为浑圆状、椭圆状,其大小为1-15cm。纯橄岩和石榴二辉橄榄岩比其寄主金伯利岩富含Cr_2O_3、NiO_3、贫CaO、CO_2、K_2O、Na_2O、TiO_2和Al_2O_3,其稀土配分模式为LREE富集型。根据深源岩石包体的温度、压力条件的估算,认为纯橄岩和石榴二辉橄榄岩来自上地幔深处,为上地幔局部熔融的残余物,而河北涉县金伯利岩中榴辉岩包体来自下地壳,云母橄榄岩类为软流圈顶部的地幔交代作用带上的岩石,尖晶二辉橄榄岩是来自上地幔较浅部位,它们为金伯利岩浆的偶然捕虏体。  相似文献   

12.
Mineralogical and chemical relationships indicate that the majority of ilmenites recovered from Group I kimberlites crystallized directly from the kimberlite magma in two contrasting P-T regimes: Ilmenites of the discrete nodule association formed in pegmatitic veins and apophyses surrounding the kimberlite magma at depth. Compositional ranges of the discrete nodule assemblage reflect essentially isobaric crystallization across the thermal aureole about the magma reservoir. Early crystallization of high pressure Cr-rich phases (garnet, clinopyroxene and possibly spinel) could result in later forming megacryst ilmenites being Cr-poor. During ascent of the kimberlite magma (essentially identical to the liquid injected into the pegmatitic veins), crystallization of garnet and clinopyroxene would be inhibited as a result of the expansion of the olivine phase field. The magma would not undergo Crdepletion, with the result that later crystallizing (ground-mass) ilmenites would be Cr-rich relative to associated ilmenite megacrysts.Rare ilmenite inclusions in diamonds show chemical affinities with those of the discrete nodule suite. It is proposed that large Type IIa diamonds may be late-crystallizing members of the discrete nodule assemblage. They are in other words related to the kimberlite event itself, and would represent a third diamond paragenesis, distinctly younger than those related to peridotites and eclogites.The mode of formation of rare MARID suite and metasomatized mantle xenoliths is not clearly understood, although mineralogical and chemical evidence point to a direct or indirect link to the host kimberlite.  相似文献   

13.
The Kuruman Kimberlite Province is comprised of 16 small pipes and dikes and contains some of the oldest known kimberlites (>1.6 Ga). In this study, 12 intrusions are subdivided into three groups with distinct petrology, age, and geochemical and isotopic compositions: (1) kimberlites with groundmass perovskites defining a Pb–Pb isochron age of 1787 ± 69 Ma, (2) orangeite with a U–Pb perovskite age of 124 ± 16 Ma, and (3) ultramafic lamprophyres (aillikite and mela-aillikite) with a zircon U–Pb age of 1642 ± 46 Ma. The magma type varies across the Province, with kimberlites in the east, lamprophyres in the west and orangeite and ultramafic lamprophyres to the south. Differences in the age and petrogenesis of the X007 orangeite and Clarksdale and Aalwynkop aillikites suggest that these intrusions are probably unrelated to the Kuruman Province. Kimberlite and orangeite whole-rock major and trace element compositions are similar to other South African localities. Compositionally, the aillikites typically lie off kimberlite and orangeite trends. Groundmass mineral chemistry of the kimberlites has some features more typical of orangeites. Kimberlite whole-rock Sr and Nd isotopes show zoning across the Province. When the kimberlites erupted at ~1.8 Ga, they sampled a core volume (ca 50 km across) of relatively depleted SCLM that was partially surrounded by a rim of more metasomatized mantle. This zonation may have been related to the development of the adjacent Kheis Belt (oldest rocks ~2.0 Ga), as weaker zones surrounding the more resistant core section of SCLM were more extensively metasomatized.  相似文献   

14.
The petrology and geochemistry of some new occurrences of Mesoproterozoic diamondiferous hypabyssal-facies kimberlites from the Chigicherla, Wajrakarur-Lattavaram and Kalyandurg clusters of the Wajrakarur kimberlite field (WKF), Eastern Dharwar craton (EDC), southern India, are reported. The kimberlites contain two generations of olivine, and multiple groundmass phases including phlogopite, spinel, calcite, dolomite, apatite, perovskite, apatite and rare titanite, and xenocrysts of eclogitic garnet and picro-ilmenite. Since many of the silicate minerals in these kimberlites have been subjected to carbonisation and alteration, the compositions of the groundmass oxide minerals play a crucial role in their characterisation and in understanding melt compositions. While there is no evidence for significant crustal contamination in these kimberlites, some limited effects of ilmenite entrainment are evident in samples from the Kalyandurg cluster. Geochemical studies reveal that the WKF kimberlites are less differentiated and more primitive than those from the Narayanpet kimberlite field (NKF), Eastern Dharwar craton. Highly fractionated (La/Yb = 108–145) chondrite-normalised distribution patterns with La abundances of 500–1,000 × chondrite and low heavy rare earth elements (HREE) abundances of 5–10 × chondrite are characteristic of these rocks. Metasomatism by percolating melts from the convecting mantle, rather than by subduction-related processes, is inferred to have occurred in their source regions based on incompatible element signatures. While the majority of the Eastern Dharwar craton kimberlites are similar to the Group I kimberlites of southern Africa in terms of petrology, geochemistry and Sr–Nd isotope systematics, others show the geochemical traits of Group II kimberlites or an overlap between Group I and II kimberlites. Rare earth element (REE)-based semi-quantitative forward modelling of batch melting of southern African Group I and II kimberlite source compositions involving a metasomatised garnet lherzolite and very low degrees of partial melting demonstrate that (1) WKF and NKF kimberlites display a relatively far greater range in the degree of melting than those from the on-craton occurrences from southern Africa and are similar to that of world-wide melilitites, (2) different degrees of partial melting of a common source cannot account for the genesis of all the EDC kimberlites, (3) multiple and highly heterogeneous kimberlite sources involve in the sub-continental lithospheric mantle (SCLM) in the Eastern Dharwar craton and (4) WKF and NKF kimberlites generation is a resultant of complex interplay between the heterogeneous sources and their different degrees of partial melting. These observations are consistent with the recent results obtained from inversion modelling of REE concentrations from EDC kimberlites in that both the forward as wells as inverse melting models necessitate a dominantly lithospheric, and not asthenospheric, mantle source regions. The invading metasomatic (enriching) melts percolating from the convecting (asthenosphere) mantle impart an OIB-like isotopic signature to the final melt products.  相似文献   

15.
Ultrabasic rocks with Niggli values for si between 26 and 100, and k between 0.6 and 1 have been chosen for the study of the distribution of 23 major and minor constituents between phlogopite and the host rock. The rocks include kimberlites, carbonatites and lamprophyres which contain abundant zoned micas and a few zoned spinels. Chemical variations in zoned mica and spinel were determined by electron probe microanalysis, and distribution coefficients for Al, Ti, Fe, Cr, Mg, Mn, and Ni were calculated between mica and spinel for the average composition of the mica and spinel, and for chemically-related and adjacent zones. The spinel changes from chromite in the centre to chromian ulvöspinel in the rim, and the mica from chromian phlogopite, through titaniferous biotite to chromium-poor phlogopite. Distribution coefficients for Cr and Fe between adjacent zones in spinel (0.8 and 0.02 for Cr; 1.1 and 3.1 for Fe) and in mica (0.4 and 0.1 for Cr; 2 and 0.3 for Fe) show more variation than the distribution coefficients between the cogenetic phlogopite and chromite (0.04 for Cr, 0.2 for Fe), and biotite and ulvöspinel (0.08 for Cr; 0.2 for Fe). It is concluded that distribution coefficients for major and minor constituents between related zones are more meaningful than those calculated from the average chemical composition of zoned minerals.The results indicate that phlogopite is the principal carrier of potassium, rubidium, aluminium, fluorine and primary water in kimberlite and carbonatite. Minor elements, such as chlorine, lithium, barium, nickel, chromium, titanium and zinc are present mainly in the mica, whereas sodium, strontium, calcium, carbon and manganese are more abundant in other minerals.  相似文献   

16.
西村岩管是在苏北地区发现的第一个金伯利岩管,颠覆了苏北地区无金伯利岩的历史。从岩石学、地球化学和伴生矿物等方面分析了西村岩管的地质特征,并进一步探讨其金刚石找矿意义。从区域背景和金刚石形成条件看,西村地区具备了金伯利岩侵位和金刚石矿形成的基本地质条件,而西村岩管为金刚石矿就位提供了母岩条件;西村金伯利岩与山东、辽宁金伯利岩具有相似的地球化学特征,是幔源岩浆低程度部分熔融的产物,且在岩浆上升过程中普遍遭受了壳源物质的混染,后期碳酸盐化现象普遍发育;其相容元素含量与山东金伯利角砾岩相似,均为典型的金伯利岩型配分模式,稀土元素表现为轻、重稀土元素强烈分馏的特征;伴生指示矿物主要为榴辉岩型含铬镁铝榴石、富铬透辉石和富镁铬尖晶石,其特征均表现出含矿金伯利岩的特点。  相似文献   

17.
镁铝榴石是金刚石的常见伴生矿物,由于经常在自然重砂中出现,因此利用重砂法来寻找金刚石原生矿是一种有效的方法。但是镁铝榴石不仅在金伯利岩中,而且往往在某些基性、超基性、以及某些高级变质岩中出现,使找矿工作复杂化。为此,探寻与金刚石有成因联系的镁铝榴石和其他镁铝榴石之区别是很必要的。  相似文献   

18.
Various combinations of diamond, moissanite, zircon, quartz, corundum, rutile, titanite, almandine garnet, kyanite, and andalusite have been recovered from the Dangqiong peridotites. More than 80 grains of diamond have been recovered, most of which are pale yellow to reddish-orange to colorless. The grains are all 100-200 μm in size and mostly anhedral, but with a range of morphologies including elongated, octahedral and subhedral varieties. Their identification was confirmed by a characteristic shift in the Raman spectra between 1325 cm~(-1) and 1333 cm~(-1), mostly at 1331.51 cm~(-1) or 1326.96 cm~(-1). Integration of the mineralogical, petrological and geochemical data for the Dongqiong peridotites suggests a multi-stage formation for this body and similar ophiolites in the Yarlung-Zangbo suture zone. Chromian spinel grains and perhaps small bodies of chromitite crystallized at various depths in the upper mantle, and encapsulated the UHP, highly reduced and crustal minerals. Some oceanic crustal slabs containing the chromian spinel and their inclusion were later trapped in suprasubduction zones(SSZ), where they were modified by island arc tholeiitic and boninitic magmas, thus changing the chromian spinel compositions and depositing chromitite ores in melt channels.  相似文献   

19.
This study presents mineralogical and thermobarometric data for equilibrium peridotite assemblages from the V. Grib kimberlite pipe of the Arkhangelsk diamond province. We provided the first constraints on the composition, structure, thermal state, and lower boundary of the lithospheric mantle beneath the V. Grib kimberlite pipe. It was found that phlogopite-free and phlogopite-bearing peridotite xenoliths can be distinguished by their mineral chemistry. The occurrence of phlogopite in peridotites may represent evidence for modal metasomatism responsible for variation in the mineral composition of phlogopite-pyrope and pyrope peridotites. On the basis of P-T estimates, we conclude that modal metasomatism may have affected the entire thickness of the lithospheric mantle beneath the V. Grib kimberlite pipe. Comparison of our results with the available data from the literature shows strong vertical and lateral mantle heterogeneity beneath kimberlite pipes of the Lomonosov deposit and the V. Grib pipe.  相似文献   

20.
Ultrabasic Xenoliths and Lava from the Lashaine Volcano, Northern Tanzania   总被引：1，自引：3，他引：1  
The Lashaine tuff-ring consists of carbonatite tuff and glassyscoria of ankaramitic composition. The pyroclastics encloseejected blocks of country-rock metamorphic rocks and a suiteof ultramafic blocks which are divisible into two groups. Thefirst group, characterized by xenomorphic granular textures,contains rocks comprising varying combinations of pyrope garnet,spinel, magnesian olivine and orthopyroxene, chromiferous diopside,and phlogopite. Analyses are given for garnet lherzolite, lherzolite,harzburgite, and wehrlite and their separate phases. The chemistryof the garnet lherzolite and its phases resembles that of garnetperidotite nodules in kimberlite diatremes, and the A12O2 contentand Ca/Ca+Mg ratio of the clinopyroxenes in the lherzolite andwehrlite indicate more affinities with those in mantle-derivedrocks rather than with peridotites derived by accumulation froma basaltic melt. The phlogopite in a mica garnet lherzolite,that otherwise resembles other mantle garnet peridotites, isan unusual variety containing > 9 per cent TiO2. The othergroup of ultramafic xenoliths, characterized by cumulate andidiomorphic textures, comprises pyroxenite, with or withoutolivine, mica and amphibole, and mica dunite. Analyses are givenfor a mica dunite and its separate phases. The pressure andtemperature of formation of the various rock-types are estimated,and the relationship of the rocks to each other and to the hostlava is discussed. The chemistry of the host lava is discussedin the light of current experimental data and also in relationto the Northern Tanzania volcanic province. The significanceof the presence of mica in the upper mantle is also discussed.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号