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1.
The effect of the injection of pure oxygen instead of air in a membrane bioreactor for the elimination of bisphenol A is investigated. A dynamic experiment was developed in a pilot plant where the aerobic reactor was continuously spiked with 1 mg L?1 of bisphenol A. Air was injected for 10 days and then pure oxygen was injected for another 10 days. The bisphenol A concentration was determined in aqueous phases and activated sludge using simple and sensitive analytical methods based on different extraction procedures and liquid chromatography tandem mass spectrometry analysis. Enzymatic activity was also determined and toxicity tests were performed to discard that the spiked bisphenol A concentration could negatively affect the microorganisms in the bioreactor and, thus, the membrane bioreactor performance. The effluent bisphenol A concentration increased up to 0.26 mg L?1 after 4 days in the air injection treatment, and up to 0.48 mg L?1 after only 12 h in the oxygen injection treatment. In both cases, this was followed by a decrease in concentration despite the continuous spiking of bisphenol A into the bioreactor. In presence of pure oxygen, bisphenol A concentration reached background levels (below the limit of quantification) after 5 days. In contrast, when using air a total of 10 days were required to reach background levels. The injection of pure oxygen instead of air is an important innovation in wastewater treatment, allowing permanent elimination of organic contaminants, avoiding their return to the environment and ensuring the safety of water.  相似文献   

2.
Liquefaction of soils is a natural phenomenon associated with a dramatic loss of the soil shear strength in undrained conditions due to a development of excess pore water pressure. It usually causes extensive damages to buildings and infrastructures during earthquakes. Thus, it is important to evaluate extent of influential parameters on the liquefaction phenomenon of soils in order to clearly understand the different mechanisms leading to its triggering. The soil gradation is one of the most important parameters affecting the liquefaction phenomenon. In this context, a series of undrained compression triaxial tests were carried out on eighteen natural loose (Dr = 25%) sandy samples containing low plastic fines content of 2% (Ip = 5%) considering different extreme sizes (1.6 mm ≤ Dmax ≤ 4 mm and 0.001 mm ≤ Dmin ≤ 0.63 mm) and two mean grain size ranges (0.25 mm ≤ D50 ≤ 1.0 mm) and (1.0 mm ≤ D50 ≤ 2.5 mm). The initial confining pressure for all tests was kept constant (P′c = 100 kPa). The obtained test results indicate that the mean grain size (D50) and extreme grain sizes (Dmax and Dmin) have a significant influence on the undrained shear strength (known as liquefaction resistance) and appear as pertinent factors for the prediction of the undrained shear strength for the soil gradation under study. The undrained shear strength and the excess pore water pressure can be correlated to the extreme grain sizes (Dmax and Dmin) and the mean grain size (D50) of tested wet deposited samples.  相似文献   

3.
In order to promote the plasma technology for commercial application and improve the energy efficiency of non-thermal plasma, a series of experiments on energy efficiency of plasma reactor were carried out for volatile organic compounds removal. This research adopts a pipe-line reaction device with plasma generated by dielectric barrier discharge technology to examine the effects of different experimental parameters, including medium packing, electric field strength, the pollutant initial concentration, and gas velocity, on the energy efficiency. In the study, four kinds of packed materials were packed into the plasma reactor: a complex catalyst, Ba0.8Sr0.2Zr0.1Ti0.9O3, MnO2/γ-Al2O3, and γ-Al2O3. Through optimizing the experimental parameters, the best decomposition efficiency of toluene and the best energy efficiency were achieved. The experimental results show that the energy efficiency has a trend from increasing to decreasing with increasing pollutant gas velocity, and the energy efficiency changes from increasing to decreasing with the increasing of initial concentration of pollutants, and the decomposition efficiency and the energy efficiency have the same order from high to low with different packed materials in the plasma reactors, in turn, packed with complex catalyst, Ba0.8Sr0.2Zr0.1Ti0.9O3, MnO2/γ-Al2O3, γ-Al2O3 and no padding. The optimized parameters for toluene decomposition are: the gas flow rate of 2 mL/min, the initial concentration range of 1500–2000 mg/m3, the field strength intensity of 9.6 kV/cm, and the plasma reactor packed with a complex catalyst, which results in the best energy efficiency of 10 g/kWh. This research provides not only a new way to develop the plasma technology, but also a reference for the commercial application.  相似文献   

4.
In this study, the characteristics of sewage of small community were determined for 6 months to ascertain the type of treatment required in subtropical conditions. The results demarcated sewage of this community as a medium-strength wastewater (chemical oxygen demand: 475 mg/L, biochemical oxygen demand: 240 mg/L and total suspended solids: 434 mg/L). Chemical oxygen demand to sulphate ratio of the sewage (11.6) established that it was amenable to anaerobic digestion. The temperature, strength, biodegradability and components of sewage were suitable for anaerobic digestion, and thus, upflow anaerobic sludge blanket reactor (UASB) was selected for its treatment. These reactors are often shutdown in small communities due to environmental and/or socio-economic factors. The ability of two UASB reactors, seeded with cow dung (UASBCD) and activated sludge of a dairy treatment plant (UASBASDIT) to restart after a long idle period of 12 months, was investigated along with sludge analysis by scanning electron microscope. Biomass in both reactors reactivated rapidly after shutdown period and within 30 days after substrate feeding achieved uniform removal efficiencies for chemical oxygen demand, total suspended solids, total dissolved solids, chloride and oil and grease. Chemical oxygen demand removal efficiency of both reactors became uniform and remained close to 80% after 30 days through reactivation of microbes in sludge bed due to adequate food and temperature conditions. During restart-up, at an average organic loading rate of 0.902 kg COD/m3 per day, methane yields of 0.091 and 0.084 m3/kg COD removed were achieved for UASBCD and UASBASDIT reactors, respectively.  相似文献   

5.
Bubble growth strongly affects the physical properties of degassing magmas and their eruption dynamics. Natural samples and products from quench experiments provide only a snapshot of the final state of volatile exsolution, leaving the processes occurring during its early stages unconstrained. In order to fill this gap, we present in situ high-temperature observations of bubble growth in magmas of different compositions (basalt, andesite and rhyodacite) at 1,100 to 1,240 °C and 0.1 MPa (1 bar), obtained using a moissanite cell apparatus. The data show that nucleation occurs at very small degrees of supersaturaturation (<60 MPa in basalt and andesite, 200 MPa in rhyodacite), probably due to heterogeneous nucleation of bubbles occurring simultaneously with the nucleation of crystals. During the early stages of exsolution, melt degassing is the driving mechanism of bubble growth, with coalescence becoming increasingly important as exsolution progresses. Ostwald ripening occurs only at the end of the process and only in basaltic melt. The average bubble growth rate (G R) ranges from 3.4 × 10?6 to 5.2 × 10?7 mm/s, with basalt and andesite showing faster growth rates than rhyodacite. The bubble number density (N B) at nucleation ranges from 7.9 × 104 mm?3 to 1.8 × 105 mm?3 and decreases exponentially over time. While the rhyodacite melt maintained a well-sorted bubble size distribution (BSD) through time, the BSDs of basalt and andesite are much more inhomogeneous. Our experimental observations demonstrate that bubble growth cannot be ascribed to a single mechanism but is rather a combination of many processes, which depend on the physical properties of the melt. Depending on coalescence rate, annealing of bubbles following a single nucleation event can produce complex bubble size distributions. In natural samples, such BSDs may be misinterpreted as resulting from several separate nucleation events. Incipient crystallization upon cooling of a magma may allow bubble nucleation already at very small degrees of supersaturation and could therefore be an important trigger for volatile release and explosive eruptions.  相似文献   

6.
Constraining magnitudes of mechanical and thermo-mechanical parameters of rocks and shear zones are the important goals in structural geology and tectonics (Talbot in J Struct Geol 21:949–957, 1999). Such parameters aid dynamic scaling of analogue tectonic models (Ramberg in Gravity, deformation and the Earth’s crust in theory, experiments and geological applications, 2nd edn. Academic Press, London, 1981), which are useful to unravel tectonics in further details (Schultz-Ela and Walsh in J Struct Geol 24:247–275, 2002). The channel flow extrusion of the Higher Himalayan Shear Zone (HHSZ, = Higher Himalaya) can be explained by a top-to-S/SW simple shear (i.e. the D2 deformation) in combination with a pressure gradient induced flow against gravity. Presuming its Newtonian incompressible rheology with parallel inclined boundaries, the viscosity (μ) of this shear zone along a part of the Himalayan chain through India, Nepal and Bhutan is estimated to vary widely between ~1016 and 1023 Pa s, and its Prandtl number (P r ) within ~1021–1028. The estimates utilized ranges of known thickness (6–58 km) of the HHSZ, that of its top subzone of ductile shear of normal shear sense (STDSU: 0.35–9.4 km), total rate of slip of its two boundaries (0.7–131 mm year?1), pressure gradient (0.02–6 kb km?1), density (2.2–3.1 g cm?3) and thermal diffusivity (0.5 × 10?6–2.1 × 10?6 m s?2) along the orogenic trend. Considering most of the parameters specifically for the Sutlej section (India), the calculated viscosity (μ) and the Prandtl number (P r ) of the HHSZ are deduced to be μ: ~1017–1023 Pa s and P r  ~ 1022–1028. The upper limits of the estimated viscosity ranges are broadly in conformity with a strong Tibetan mid-crust from where a part of the HHSZ rocks extruded. On the other hand, their complete ranges match with those for its constituent main rock types and partly with those for the superstructure and the infrastructure. The estimated mechanical and thermo-mechanical parameters of the HHSZ will help to build dynamically scaled analogue models for the Himalayan deformation of the D2–phase.  相似文献   

7.
To comparatively study the biodegradation of phthalic acid esters (PAEs) in sewage sludge by composting with pig manure or with rice straw, four composting modes were designed: Mode 1 (sewage sludge + pig manure + intermittent aeration), Mode 2 (sewage sludge + pig manure + continuous aeration), Mode 3 (sewage sludge + rice straw + intermittent aeration) and Mode 4 (sewage sludge + rice straw + continuous aeration). Physicochemical parameters of composts were measured according to standard methods and PAEs were analyzed by gas chromatography coupled with mass spectrometry (GC/MS). The biodegradation of each PAE was also discussed. The results showed that Mode 1 was the best mode to biodegrade PAEs, which might be related to the wide class of indigenous microbial communities in pig manure and high efficiency of intermittent ventilation for providing oxygen. During the biodegradation process, di(2-ethylhexyl) phthalate was the most abundant and decisive for the removal of total PAEs. It showed a first-order kinetic degradation model. In conclusion, composting with pig manure could be suggested as an effective detoxification process for the removal of PAEs from sewage sludge, providing a safe end product.  相似文献   

8.
A particle–bubble attachment apparatus, similar to that used by Whelan and Brown [Bull. Inst. Min. Met. Trans. 65 (1956) 181] is developed to study free falling glass beads (dp=131 μm) with different surface treatment attaching to a stationary air bubble (db=3 mm). The entire process of the particle–bubble attachment is photographically recorded using a high framing-rate camera and analyzed frame by frame. It is found that the hydrophilic particle slides on the top half of the bubble, and then the particle leaves the bubble, as anticipated. The particle sliding velocity increases with increasing angular position on the bubble surface. For the hydrophobic particle, it was found that the particle slides over the entire bubble surface without detaching from the bubble. The sliding velocity, however, reaches a maximum at an angular position of 90–100°, and then slows down to zero. A smaller sliding velocity is obtained for the hydrophobic particle than that of the hydrophilic particle at a given angular position. The attachment efficiency for the hydrophobic particle reduces with increasing initial angular positions, suggesting that the hydrophobicity alone does not directly guarantee the attachment to a bubble. Adding surfactant (sodium dodecyl sulfate [SDS]) to the test solution makes the hydrophobic particle become less hydrophobic or even hydrophilic, thereby decreasing the attachment efficiency. A much longer induction time is obtained in our present work than that reported in the literature. A simplified particle sliding velocity and attachment model is developed, and a good agreement between the theoretical prediction and experimental measurement is obtained.  相似文献   

9.
Wastewater treatment using moving bed membrane bioreactor technology was tested with real urban wastewater at a pilot plant, combining moving bed treatment as a biological process with hybrid biomass (suspended and fixed) and the advantages of a membrane separation system. The evolution of the kinetic constants of the hybrid biomass and organic matter removal were studied in a pilot plant under different operational conditions, by varying hydraulic retention time (HRT), mixed liquor suspended solids (MLSS) and temperature, and considering the attached biomass of the carrier and the dispersed biomass of the flocs to reproduce real treatment conditions. The rates of organic matter removal were 97.73 ± 0.81 % of biochemical oxygen demand (BOD5), 93.44 ± 2.13 % of chemical oxygen demand (COD), 94.41 ± 2.26 % of BOD5 and 87.62 ± 2.47 % of COD using 24.00 ± 0.39 and 10.00 ± 0.07 h of HRT, respectively. The influence of the environmental variables and operational conditions on kinetic constants was studied; it was determined that the most influential variable for the decay coefficient for heterotrophic biomass was HRT (0.34 ± 0.14 and 0.31 ± 0.10 days?1 with 10.00 ± 0.07 and 24.00 ± 0.39 h of HRT, respectively), while for heterotrophic biomass yield, this was temperature (0.61 ± 0.04 and 0.52 ± 0.06 with 10.00 ± 0.07 and 24.00 ± 0.39 h of HRT, respectively). The results show that introducing carriers in an MBR system provides similar results for organic matter removal, but with a lower concentration of MLSS.  相似文献   

10.
The objective of this study was to evaluate the effect of mine tailings composition on shear behavior and shear strength of co-mixed mine waste rock and tailings (WR&T). Crushed gravel was used as a synthetic waste rock and mixed with four types of tailings: (1) fine-grained garnet, (2) coarse-grained garnet, (3) copper, and (4) soda ash. Co-mixed WR&T specimens were prepared to target mixture ratios of mass of waste rock to mass of tailings (R) such that tailings “just filled” interparticle void space of the waste rock (i.e., optimum mixture ratio, R opt). Triaxial compression tests were conducted on waste rock, tailings, and mixed waste at effective confining stresses (\(\sigma_{\text{c}}^{{\prime }}\)) ranging from 5 to 40 kPa to represent stresses anticipated in final earthen covers for waste containment facilities. Waste rock and co-mixed WR&T specimens were 150 mm in diameter by 300 mm tall, whereas tailings specimens were 38 mm in diameter by 76 mm tall. Shear strength was quantified using effective stress friction angles (?′) from undrained tests: ?′ for waste rock was 37°, ?′ for tailings ranged from 34° to 41°, and ?′ for WR&T mixtures ranged from 38° to 40°. Thus, shear strength of co-mixed WR&T was comparable to waste rock regardless of tailings composition. Shear behavior of WR&T mixtures was a function of R and tailings composition. Tailings influenced shear behavior for R < R opt and when tailings predominantly were silt. Shear behavior was influenced by waste rock for R ≥ R opt and when tailings predominantly were sand or included clay particles.  相似文献   

11.
We present a network flow model to compute transport, through a pore network, of a compositional fluid consisting of water with a dissolved hydrocarbon gas. The model captures single-phase flow (below local bubble point conditions) as well as the genesis and migration of the gas phase when bubble point conditions are achieved locally. Constant temperature computational tests were run on simulated 2D and 3D micro-networks near bubble point pressure conditions. In the 2D simulations which employed a homogeneous network, negligible capillary pressure, and linear relative permeability relations, the observed concentration of CO2 dissolved in the liquid phase throughout the medium was linearly related to the liquid pressure. In the case of no gravity, the saturation of the gas phase throughout the medium was also linearly related to the liquid pressure; under gravity, the relationship became nonlinear in regions where buoyancy forces were significant. The 3D heterogeneous network model had nonnegligible capillary pressure and nonlinear relative permeability functions. While 100 % of the CO2 entered the 3D network dissolved in the liquid phase, 25 % of the void space was occupied by gas phase and 47 % of the CO2 exiting the outlet face did so via the gaseous phase after 500 s of simulation time.  相似文献   

12.
This paper presents an experimental study on a deeply dewatered sewage sludge produced by using a new technique of membrane filter press. The experiments involve measurements of sludge composition, basic physical properties, shear strength, water permeability, and leaching toxicity. The measurements of shear strength and permeability were also performed on the sludge specimens soaked in a low acid leachate or distilled water for 1 and 2 months. This is to investigate the influence of chemical change in pore fluid as a result of rainfall infiltration or leachate seepage at landfills. Comparison tests were also carried out on silty clay that is commonly used for landfill cover material. The experimental results show that the deeply dewatered sludge contains 66 % organic content and 85 % water content (dry mass basis). The undrained shear strength of the sludge is >25 kPa even after 2-month soaking in the leachate and distilled water, meeting the requirement of the Chinese standard [CJ/T249-2007, Disposal of sludge from municipal wastewater treatment plant: sludge quality for co-landfilling. Ministry of Building and Construction, P.R. China (in Chinese), 2007]. The measured cohesion and friction angle for the sludge are >20 kPa and 22.3°, respectively. The soaking of sludge specimens in either leachate or distilled water resulted in an increase in frictional angle by several degrees. The water permeability for the sludge ranges from 0.68 × 10?8 to 1.3 × 10?8 cm/s, and permeability after 2-month soaking is less than the minimum requirement for the barrier layer of landfill covers (i.e., 1.0 × 10?7 cm/s). The concentrations of heavy metals leaching from the dewatered sludge are lower than the limit values of leaching toxicity for the wastewater discharge standard of China. The experimental results indicate that deeply dewatered sludge can be used as an alternative material for the barrier layer of landfill covers.  相似文献   

13.
The aim of this research was to evaluate the efficiency of electrocoagulation (EC) for the removal of natural organic matter (NOM) by using iron (Fe) and aluminum (Al) electrodes. The effects of several operational parameters such as initial pH (3–10), time of electrolysis (5–30 min), initial concentration of organic matter (10–50 mg NOM/L), current density (0.25–1.25 mA/cm2), type of electrode material (n = 4, 2 sides × 11 cm × 10 cm, wall thickness = 2 mm, distance between each electrode = 5 mm), and type of connection of electrodes (bipolar and monopolar configurations) were explored for the removal of NOM from synthetic humic acid solution in a 2 L laboratory-scale EC cells (A s/V = 0.110 cm?1). The optimum conditions for the process were identified as pH = 3 and 7, electrolysis time = 20 and 10 min for Fe and Al electrodes, respectively. Using both electrodes at current density = 0.25 mA/cm2 and initial concentration of organic matter = 50 mg/L, a NOM removal efficiency of almost 100% could be achieved in the bipolar mode. Based on the optimum conditions, specific reactor electrical energy consumptions were 14.90 kWh/kg Al (or 0.092 kWh/m3) and 2.88 kWh/kg Fe (or 0.11 kWh/m3). Specific electrode consumptions were obtained to be 0.0062 and 0.0382 kg/m3, and operating costs of the EC system were preliminary estimated at 0.057 and 0.119 $/m3 for Al and Fe electrodes, respectively.  相似文献   

14.
Assessment of groundwater quality in and around Vedaraniyam,South India   总被引：1，自引：1，他引：0  
Groundwater from 47 wells were analyzed on the basis of hydrochemical parameters like pH, electric conductivity, total dissolved solids, Ca2+, Mg2+, Na+, K+, Cl?, CO3 2?, HCO3 ?, NO3 ?, PO4 3? and F? in the Cauvery delta of Vedaraniyam coast. Further, water quality index (WQI), sodium percentage (Na %), sodium absorption ratio, residual sodium carbonate, permeability index and Kelley’s ratio were evaluated to understand the suitability of water for drinking and irrigation purposes. The result shows significant difference in the quality of water along the coastal stretch. The order of dominance of major ions is as follows: Na+ ≥ Mg2+ ≥ Ca2+ ≥ K+ and Cl? ≥ HCO3 ? ≥ CO3 2? ≥ PO4 3? ≥ F?. Na/Cl, Cl/HCO3 ratio and Revelle index confirmed that 60–70 % of the samples were affected by saline water intrusion. WQI showed that 36 % of the samples were good for drinking and the remaining were poor and unsuitable for drinking purpose. The degradation of groundwater quality was found to be mainly due to over-exploitation, brackish aquaculture practice, fertilizer input from agriculture and also due to domestic sewage.  相似文献   

15.
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16.
The rapid growth of Riyadh—capital of Saudi Arabia—is pushing the area to more pollution and incentive for reorganization. The aim of this research is to assess air pollutants in southeast of Riyadh and detect opinion of the population about their environment. The assessment was done by analyzing 405 questionnaires, evaluating thermal band of Landsat 8, and spatial analyzing of particular matter and chemicals in 19 air samples by geostatistical tool in the ArcMap. Most of the inhabitants stated that they are suffering from bad odor, sewage leakage, and dust mainly from a cement factory. The thermal band of Landsat clarified the location of the pollution sources mainly the 1st industrial city, Yammama Cement Factory, and power plant in Farouq area. The ordinary kriging maps showed that the highest concentration of PM10 (>403 μg/m3) lied to the northern and western side of the study area and caused a health issue to most inhabitants.  相似文献   

17.
Saturated hydraulic conductivity (K s) is one of the most important parameters determining groundwater flow and contaminant transport in both unsaturated and saturated porous media. The hand-held air permeameter technique was investigated for high-resolution hydraulic conductivity determination on borehole cores using a spatial resolution of ～0.05 m. The suitability of such air permeameter measurements on friable to poorly indurated sediments was tested to improve the spatial prediction of classical laboratory-based K s measurements obtained at a much lower spatial resolution (～2 m). In total, 368 K s measurements were made on ～350 m of borehole cores originating from the Campine basin, northern Belgium, while ～5,230 air permeability measurements were performed on the same cores, resulting in a K s range of seven orders of magnitude. Cross-validation demonstrated that, using air permeameter data as the secondary variable for laboratory based K s measurements, the performance increased from R 2?=?0.35 for ordinary kriging (laboratory K s only) to R 2?=?0.61 for co-kriging. The separate treatment of horizontal and vertical hydraulic conductivity revealed considerable anisotropy in certain lithostratigraphical units, while others were clearly isotropic at the sample scale. Air permeameter measurements on borehole cores provide a cost-effective way to improve spatial predictions of traditional laboratory based K s.  相似文献   

18.
Microorganisms, organic matter, heavy metals are the main pollutants in sewage water. The increasing water demand pressurized people to use the sewage water. Different systems, chemicals and physical treatments were used in sewage water treatment. The aim of this work is to study the effect and correlations of primary (Ca(OH)2 filtration and H2O2) and secondary (dissolved oxygen, organic matter, conductivity, pH and OD) factors on fungi present in sewage water in addition to proving the sequence of the system used in the current study. After treatment, fungi were examined, identified on Czapek agar and analyzed using multivariate tools (CANOCO: DCA and CCA) and R software. The treatment includes two main steps: liming filtration and oxidation, respectively. All parameters were negatively or positively correlated (organic matter, pH, conductivity %, optical density, fungal CFU ml?1, dissolved oxygen). Heavy metals were decreased due to the application of Ca(OH)2 and H2O2, respectively. There were two main groups of fungi. The larger was correlated with the organic matter, whereas the second was tolerating calcium hydroxide concentrations. Aspergillus sydowii tolerated hydrogen peroxide (0.2 mll?1(33%); Ca(OH)2, 0.25 gl?1). Sequential steps treatment was healthy and economically efficient. The proposed system improved water characteristics. The recommended amount of Ca(OH)2 and H2O2 was 0.25 gl?1 and 0.2 mll?1(33%), respectively, and can remove more than 99.9% of fungal CFUs. The current study minimized the optimum dose of hydrogen peroxide used in the disinfection of sewage water from 1.5 (Mohamed in Chem Eng J 119:161–165, 2006) to 0.2 mll?1 of H2O2 (the current study).  相似文献   

19.
In this study, the preprocessing of the gamma test was used to select the appropriate input combination into two models including the support vector regression (SVR) model and artificial neural networks (ANNs) to predict the stream flow drought index (SDI) of different timescales (i.e., 3, 6, 9, 12, and 24 months) in Latian watershed, Iran, which is one of the most important sources of water for the large metropolitan Tehran. The variables used included SDI t , SDI t ? 1, SDI t ? 2, SDI t ? 3, and SDI t ? 4 monthly delays. Two variables including SDI t and SDI t ? 1 with lower gamma values were identified as the most optimal combination of variables in all drought timescales. The results showed that the gamma test was able to correctly identify the right combination for the forecasting of 6, 9, and 12 months SDI using the ANN model. Also, the gamma test was considered in selecting the appropriate inputs for identifying the values of 9, 12, and 24 months SDI in SVR. The support vector machine approach showed a better efficiency in the forecast of long-term droughts compared to the artificial neural network. In total, among forecasts made for 30 scenarios, the support vector machine model only in scenario 3 of SDI3, scenario 1 of SDI6, and scenarios 2 and 3 of SDI24 represented poorer efficiency compared to the artificial neural network (MLP layer), but in other scenarios, the results of SVR had better efficiency.  相似文献   

20.
Three (Cr1?x Al x )N (x = 0.33, 0.5, 0.66) coatings were deposited on Ni-super alloy IN718 using reactive magnetron sputtering. The oxidation behavior of all coatings at 900 °C up to 500 h in air was studied. Furthermore, the corrosion behavior of the (Cr0.33,Al0.66)N coating at 900 °C (corrosion type I) by spraying a uniform salt scale of Na2SO4 on the sample surface (1 mg/cm2) was investigated. It was found that the coated samples indicate significantly higher oxidation and corrosion resistance compared to uncoated Ni super alloy. This is mainly due to the formation of protective Cr2O3 and Al2O3 layers on the coating surface. With the increase of Al content, the coatings exhibited improved oxidation resistance. The formation of thin and adherent Al2O3 scale on the surface of Al rich coating is the reason for its better oxidation behavior. The detailed structures of the oxide scales and the interdiffusion between coating and substrate were studied using energy dispersive X-ray spectroscopy-analysis.  相似文献   

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