首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 578 毫秒
1.
《Applied Geochemistry》2002,17(6):751-779
Uranium concentrations and 234U/238U ratios in saturated-zone and perched ground water were used to investigate hydrologic flow and downgradient dilution and dispersion in the vicinity of Yucca Mountain, a potential high-level radioactive waste disposal site. The U data were obtained by thermal ionization mass spectrometry on more than 280 samples from the Death Valley regional flow system. Large variations in both U concentrations (commonly 0.6–10 μg l−1) and 234U/238U activity ratios (commonly 1.5–6) are present on both local and regional scales; however, ground water with 234U/238U activity ratios from 7 up to 8.06 is restricted largely to samples from Yucca Mountain. Data from ground water in the Tertiary volcanic and Quaternary alluvial aquifers at and adjacent to Yucca Mountain plot in 3 distinct fields of reciprocal U concentration versus 234U/238U activity ratio correlated to different geographic areas. Ground water to the west of Yucca Mountain has large U concentrations and moderate 234U/238U whereas ground water to the east in the Fortymile flow system has similar 234U/238U, but distinctly smaller U concentrations. Ground water beneath the central part of Yucca Mountain has intermediate U concentrations but distinctive 234U/238U activity ratios of about 7–8. Perched water from the lower part of the unsaturated zone at Yucca Mountain has similarly large values of 234U/238U. These U data imply that the Tertiary volcanic aquifer beneath the central part of Yucca Mountain is isolated from north-south regional flow. The similarity of 234U/238U in both saturated- and unsaturated-zone ground water at Yucca Mountain further indicates that saturated-zone ground water beneath Yucca Mountain is dominated by local recharge rather than regional flow. The distinctive 234U/238U signatures also provide a natural tracer of downgradient flow. Elevated 234U/238U in ground water from two water-supply wells east of Yucca Mountain are interpreted as the result of induced flow from 40 a of ground-water withdrawal. Elevated 234U/238U in a borehole south of Yucca Mountain is interpreted as evidence that natural downgradient flow is more likely to follow southerly paths in the structurally anisotropic Tertiary volcanic aquifer where it becomes diluted by regional flow in the Fortymile system.  相似文献   

2.
晋祠泉和兰村泉是山西著名的岩溶大泉,受自然条件变化和人类活动的影响,两个泉于20世纪末相继断流。针对山西省政府提出的要使晋祠、兰村泉水复流的生态修复目标任务,文章在泉域水文地质调查基础上,就泉水复流密切相关的四个关键性岩溶水文地质条件问题开展研究并提出了新认识。核实了目前划定的晋祠—兰村泉域边界,依据最新资料对现行的晋祠、兰村泉域边界提出了7处修正,修改后晋祠泉域面积由2 030 km2变为2 713 km2,兰村泉域面积由2 500 km2变为2 614 km2。汾河二库在蓄水后库区的主体部分划归到晋祠泉域而非兰村泉域,其渗漏补给是造成近年来晋祠泉域区域岩溶地下水位大幅回升的主要原因。确定了晋祠泉域内盘道—马家山断裂带是一个岩溶水强富水带,也是岩溶地下水从北部中、上寒武统含水岩组向南部中奥陶统含水岩组的转换带。圈定了晋祠泉域:玉门河南峪村—杜儿平煤矿东侧—官地矿与白家庄矿交界处—龙山—明仙村东—晋祠泉的岩溶地下水强径流带。这些认识是开展晋祠—兰村泉域岩溶地下水资源评价、地下水开发管理和保护的基础,更是制定晋祠、兰村泉水复流方案的重要依据。  相似文献   

3.
The goal of this study is to explain the origin of 234U–238U fractionation in groundwater from sedimentary aquifers of the St. Lawrence Lowlands (Quebec, Canada), and its relationship with 3He/4He ratios, to gain insight regarding the evolution of groundwater in the region. (234U/238U) activity ratios, or (234U/238U)act, were measured in 23 groundwater samples from shallow Quaternary unconsolidated sediments and from the deeper fractured regional aquifer of the Becancour River watershed. The lowest (234U/238U)act, 1.14 ± 0.01, was measured in Ca–HCO3-type freshwater from the Quaternary Shallower Aquifer, where bulk dissolution of the carbonate allows U to migrate into water with little 234U–238U isotopic fractionation. The (234U/238U)act increases to 6.07 ± 0.14 in Na–HCO3–Cl-type groundwater. Preferential migration of 234U into water by α-recoil is the underlying process responsible for this isotopic fractionation. An inverse relationship between (234U/238U)act and 3He/4He ratios has been observed. This relationship reflects the mixing of newly recharged water, with (234U/238U)act close to the secular equilibrium and containing atmospheric/tritiogenic helium, and mildly-mineralized older water (14C ages of 6.6 kyrs), with (234U/238U)act of ≥6.07 and large amounts of radiogenic 4He, in excess of the steady-state amount produced in situ. The simultaneous fractionation of (234U/238U)act and the addition of excess 4He could be locally controlled by stress-induced rock fracturing. This process increases the surface area of the aquifer matrix exposed to pore water, from which produced 4He and 234U can be released by α-recoil and diffusion. This process would also facilitate the release of radiogenic helium at rates greater than those supported by steady-state U–Th production in the rock. Consequently, sources internal to the aquifers could cause the radiogenic 4He excesses measured in groundwater.  相似文献   

4.
A fractionation of uranium (U) series into parent–daughter pairs – 234U and 238U – always occurs in natural waters, and the disequilibria between these is commonly used as a tracer of groundwater flow. We report here an interpretation of the U-content and U isotope disequilibria in groundwater sampled from the deep Complexe Terminal and Continental Intercalaire aquifers of southern Tunisia. Variations in both the contents of these isotopes (0.006–2.4 ppb) and 234U/238U activity ratios (ARs) (1.7–15.4) were observed. The data could be plotted in two distinct fields of reciprocal U concentration versus 234U/238U AR according to groundwater flow and regional bedrock differences. An initial assessment aimed at verifying whether the results of this investigation support those of previous hydrogeological and isotope studies, thereby suggesting that the disequilibrium between U isotopes in groundwater may represent a useful tool for hydrogeological investigations of deep and fossil groundwater. In addition, the disequilibrium can be used for quantifying the recharge or mixing rates between different formations with the aim of delineating the preferential outflow pattern or determining residence times of waters.  相似文献   

5.
晋祠泉出露于山西太原西山悬瓮山下，由难老泉、圣母泉、善利泉组成。1954—1958年实测泉水平均流量为l.94 m3/s。与晋祠泉同处山前断裂带的平泉于1978年成为特大岩溶水自流井水源地，自流量最大达到1.56 m3/s。由于这些自流井的开采，使晋祠泉的流量急剧下降，1994年4月30日断流。研究山西太原晋祠泉—平泉水力联系对晋祠泉复流方案制定具有重要意义。本文以晋祠泉、平泉为研究对象，通过样品采集、水质监测，综合运用水化学（离子比例、硫同位素、氢氧同位素）方法。揭示晋祠泉—平泉水文地球化学特征和环境同位素特征，反映地下水流系统的特征、水力联系特征。得出1980—1992年，晋祠泉地下水水位的变化呈稳定下降趋势，主要原因是有太原化学工业公司、开化沟、淸徐县平泉村和梁泉村等水源地大量开采岩溶地下水，导致地下水水位下降。晋祠—平泉一带岩溶地下水氢氧同位素值较接近，说明这一带岩溶地下水补给来源与补给途径相近。水质监测分析得出晋祠泉与平泉各个离子变化趋势基本一致。说明晋祠与平泉存在紧密的水力联系，因此晋祠泉与平泉必然存在一个比较强的导水通道。可以通过在晋祠泉下游导水通道上帷幕灌浆，提高晋祠泉水水位，使晋祠泉出流。  相似文献   

6.
This study presents the temporal and spatial variability of 234U/238U activity ratios in the Shu River and provides interpretation to explain the downstream changes of uranium and the 234U/238U activity ratios in the study area. The positive linear correlation (R 2 = 0.98, p < 0.001) between uranium concentration and specific electrical conductance is consistent with rock weathering and leaching as the major contributor of dissolved uranium in the studied area of the river. The 234U/238U activity ratio ranged between ~1.6 in the upper reaches of the river to ~1.15 furthest downstream. Activity ratios at specific sampling points do not show significant seasonal variability.  相似文献   

7.
山西太原西山汾河二库的泉域归属及其渗漏量计算   总被引：1，自引：1，他引：0  
山西省汾河二库是建于汾河中上游的一座大型水库。由于水库处于晋祠兰村泉域交界地带的碳酸盐岩河段,水库蓄水并淹没了天然条件下出流的悬泉寺泉群,造成库区岩溶水文地质条件发生根本性改变,直接影响到泉域岩溶水的水资源评价、开发管理和以泉水复流为目标的生态修复的措施制定。本文针对汾河二库修建后的以下两个问题开展了讨论。第一,利用最新调查与勘探资料分析二库修建对岩溶水文地质条件的影响,并对二库库区的泉域归属问题进行了划定,认为悬泉寺泉水的出流受控于汾河河谷内向西倾斜的下奥陶统区域相对隔水层的阻水作用,汾河二库蓄水水位提高近40 m,天然条件下挟持于晋祠-兰村泉域间相对独立循环的悬泉寺泉域降落漏斗被“充满”,泉水消失,形成对岩溶地下水渗漏反补给,水库渗漏水量通过中奥陶统主要进入晋祠泉域,汾河二库以寺头-下槐间下奥陶统出露的地段为界,下槐泉以上划归晋祠泉域,下槐泉以下则划归兰村泉域;第二,利用二库上游寨上水文站、下游的上兰村水文站资料和二库蓄水水位系列资料,由均衡法建立了二库蓄水水位与渗漏量之间的非线性方程,并据此预测,当二库水位提高至905.7 m时的渗漏量为2.862 m3·s-1,而对兰村泉域岩溶水及山前西张水源地的补给量有限。   相似文献   

8.
The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio 234U/238U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.  相似文献   

9.
The radioactive and physical characteristics of Syrian hot waters were studied. The concentration of uranium, its daughters and the 234U/238U-activity ratios in the hot waters were measured by gamma and alpha ray spectroscopy. The 234U/238U-activity ratios showed that uranium in Syrian hot waters are in an equilibrium state. Some anomalous observations of these ratios were explained by former leaching of the uranium from Cretaceous phosphates by underground water. Also, the results showed that the temperature of the studied hot waters was independent of the contained radioelements. The temperature of hot waters is explained by the passing of these waters near the hot spot or by the relationship between the geological deposit of the aquifer rocks and the waters rather than the contents of the radioelements.  相似文献   

10.
曹丁涛 《中国岩溶》2007,26(4):347-355
在邵庄— 双庙水源地勘察评价过程中,应用U同位素场分析得到如下认识: ( 1)本区不同类型水体的U同位素具有不同的组成特征,主要表现为大气降水、山区岩溶水的U含量、I ( 234U) /I ( 238U)比值及Iex (234 U) 均较低;第四系孔隙水U含量和I ex ( 234U ) 均较高,但I (234 U) /I (238 U) 比值较低;隐伏岩溶水的U含量较低,介于孔隙水与大气降水之间,而I (234 U) /I (238 U) 比值与I ex (234U) 均较高; 地表水的U含量较高,但I (234 U) /I (238U) 比值低, Ie x (234U) 也较低; ( 2)蜀山背斜岩溶水系统具有大气降水、第四系孔隙水和深层岩溶水三源补给特征; ( 3)蜀山背斜岩溶水系统与双庙地垒岩溶水系统基本不存在水力联系,且二者补给条件也不同,蜀山背斜岩溶水系统与第四系孔隙水联系密切,接受上层孔隙水越流补给,径流条件好;双庙地垒岩溶水系统相对较封闭,与第四系孔隙水联系较弱,主要靠兖西奥灰水源地侧向径流补给,且径流条件相对较差。   相似文献   

11.
Factors controlling the groundwater transport of U, Th, Ra, and Rn   总被引：1，自引：0，他引：1  
A model for the groundwater transport of naturally occurring U, Th, Ra, and Rn nuclides in the238U and232Th decay series is discussed. The model developed here takes into account transport by advection and the physico-chemical processes of weathering, decay, α-recoil, and sorption at the water-rock interface. It describes the evolution along a flowline of the activities of the238U and232Th decay series nuclides in groundwater. Simple sets of relationships governing the activities of the various species in solution are derived, and these can be used both to calculate effective retardation factors and to interpret groundwater data. For the activities of each nuclide, a general solution to the transport equation has been obtained, which shows that the activities reach a constant value after a distance ϰi, characteristic of each nuclide. Where ϰi is much longer than the aquifer length, (for238U,234U, and232Th), the activities grow linearly with distance. Where gKi is short compared to the aquifer length, (for234Th,230Th,228Th,228Ra, and224Ra), the activities rapidly reach a constant or quasi-constant activity value. For226Ra and222Rn, the limiting activity is reached after 1 km. High δ234U values (proportional to the ratioɛ234Th/W238U) can be obtained through high recoil fraction and/or low weathering rates. The activity ratios230Th/232Th,228Ra/226Ra and224Ra/226Ra have been considered in the cases where either weathering or recoil is the predominant process of input from the mineral grain. Typical values for weathering rates and recoil fractions for a sandy aquifer indicate that recoil is the dominant process for Th isotopic ratios in the water. Measured data for Ra isotope activity ratios indicate that recoil is the process generally controlling the Ra isotopic composition in water. Higher isotopic ratios can be explained by different desorption kinetics of Ra. However, the model does not provide an explanation for228Ra/226Ra and224Ra/226Ra activity ratios less than unity. From the model, the highest222Rn emanation equals 2ɛ. This is in agreement with the hypothesis that222Rn activity can be used as a first approximation for input by recoil (Krishnaswamiet al 1982). However, high222Rn emanation cannot be explained by production from the surface layer as formulated in the model. Other possibilities involve models including surface precipitation, where the surface layer is not in steady-state.  相似文献   

12.
The isotopic (U-Pb, 238U-235U, 234U-238U) and chemical study of whole-rock samples and finegrained fractions of rocks in a vertical section of the terrigenous sequence at the Dybryn uranium deposit in the Khiagda ore field shows that a wide U-Pb isotopic age range (26.9-6.5 Ma) is caused by oxidation and disturbance of the U-Pb isotopic system in combination with protracted uranium ore deposition. The oxidation of rocks resulted in the loss of uranium relative to lead and eventually to an overestimated 206Pb/238U age at sites with a low U content. The 238U/235U ratios in the studied samples are within the range of 137.74–137.88. Samples with a high uranium content are characterized by a decreasing 238U/235U ratio with a decrease in 207Pb/235U and 206Pb/238U ages. A nonequilibrium 234U/238U ratio in most studied samples furnishes evidence for young (<1.5 Ma) transformation of the Miocene uranium ore, which is responsible for uranium migration and its redeposition.  相似文献   

13.
Wet climatic episodes are known to have prevailed in the Egyptian Sahara several times during the late Quaternary, most recently during the Holocene 8000 yr ago. Earlier wet episodes have been recognized as having occurred during the past 300,000 yr and have been dated by U-series methods in speleothems and in lake travertines. We show here that the times of enhanced groundwater movement can also be determined by 230Th/234U dating of secondary U in ores of uranium, iron, and phosphate. We also present evidence that such acceleration of groundwater movements is indicated by relatively low 234U/238U activity ratios in the secondary uranium. Our new data show that pluvial periods in Egypt occurred during marine oxygen isotope stages 4, 5, 6, and 7 and therefore are consistent with the view that the wet episodes are the results of migration of the tropical monsoonal belt driven primarily by the 23,000-yr precession cycle of the Milankovich curve, modulated by the 100,000-yr eccentricity cycle.  相似文献   

14.
The solution of radioelements and radiogenic 4He by groundwaters in fractured rocks is dependent upon the radioelement distribution in the rock matrix and the extent of the rock-water interface. The 234U238U activity ratio and the dissolved U, Rn and He contents of such groundwaters respond to changes in the flow regime with time. Although 234U238U activity ratios change with groundwater residence time as a consequence of 234Th-recoil induced solution of 234U, the activity ratio is strongly influenced by the U distribution within fractures, by the extent of the rock-water interface and by the amount of 238U in solution. A model for the quantitative evaluation of these effects is presented.Groundwaters from depths up to 880 m in the Stripa granite have variable dissolved uranium contents and 234U238U activity ratios. The uranium geochemistry is primarily determined by variations in flow path rather than by groundwater age.Dissolved radiogenic 4He in the groundwaters increases with their depth of origin, and is dependent upon the U content of the granite and upon its fracture porosity. It increases with groundwater residence time but movement of 4He by diffusion and transport processes make the actual groundwater age indeterminate.  相似文献   

15.
Approximately one thousand drilled wells were investigated for their natural radioactivity. The determinations of 238U, 234U, 226Ra and 222Rn from 310 samples showed a high state of radioactive disequilibrium between the members of the uranium series present in water. The 238U226Ra activity ratio usually fell in the range 1–20 and the 238U222Rn activity ratio in the range 1–20 × 10?4, the highest activity ratios being from samples with an elevated uranium content. The 234U238U activity ratio varied between 0.76 and 4.67, the most frequent values showing a 60% excess of 234U in the samples. Most of the 234U238U activity ratios near unity were found in samples with a high uranium content. Several drilled wells with anomalously high uranium contents were found in southern Finland. The average 226Ra and 222Rn contents of these wells were not exceptionally high, which suggests high mobility of uranium in groundwater from the areas involved.  相似文献   

16.
This paper presents results of hydrochemical and isotopic analyses of groundwater (fracture water) and porewater, and physical property and water content measurements of bedrock core at the Chalk River Laboratories (CRL) site in Ontario. Density and water contents were determined and water-loss porosity values were calculated for core samples. Average and standard deviations of density and water-loss porosity of 50 core samples from four boreholes are 2.73 ± 12 g/cc and 1.32 ± 1.24 percent. Respective median values are 2.68 and 0.83 indicating a positive skewness in the distributions. Groundwater samples from four deep boreholes were analyzed for strontium (87Sr/86Sr) and uranium (234U/238U) isotope ratios. Oxygen and hydrogen isotope analyses and selected solute concentrations determined by CRL are included for comparison. Groundwater from borehole CRG-1 in a zone between approximately +60 and −240 m elevation is relatively depleted in δ18O and δ2H perhaps reflecting a slug of water recharged during colder climatic conditions. Porewater was extracted from core samples by centrifugation and analyzed for major dissolved ions and for strontium and uranium isotopes. On average, the extracted water contains 15 times larger concentration of solutes than the groundwater. 234U/238U and correlation of 87Sr/86Sr with Rb/Sr values indicate that the porewater may be substantially older than the groundwater. Results of this study show that the Precambrian gneisses at Chalk River are similar in physical properties and hydrochemical aspects to crystalline rocks being considered for the construction of nuclear waste repositories in other regions.  相似文献   

17.
A mathematical model to calculate the234U/238U activity ratio (AR) in an aqueous phase in contact with rock/soil is presented. The model relies on the supply of238U by dissolution and that of234U by dissolution and preferential release from radiation damaged regions (recoil tracks). The model predicts that values of234U/238U AR>1 in the aqueous phase can be obtained only from weathering “virgin” surfaces. Thus, to account for the observed steady-state supply of234U excess to the oceans by the preferential leaching model, ‘virgin’ rock/soil surfaces would have to be continually exposed and weathered. The238U concentration and234U/238U AR in continental waters allow us to estimate the exposure rates of “virgin” rock/soil surfaces.  相似文献   

18.
The ability to detect hydrologic variation in large arctic river systems is of major importance in understanding and predicting effects of climate change in high-latitude environments. Monitoring uranium isotopes (234U and 238U) in river water of the Yukon River Basin of Alaska and northwestern Canada (2001?C2005) has enhanced the ability to identify water sources to rivers, as well as detect flow changes that have occurred over the 5-year study. Uranium isotopic data for the Yukon River and major tributaries (the Porcupine and Tanana rivers) identify several sources that contribute to river flow, including: deep groundwater, seasonally frozen river-valley alluvium groundwater, and high-elevation glacial melt water. The main-stem Yukon River exhibits patterns of uranium isotopic variation at several locations that reflect input from ice melt and shallow groundwater in the spring, as well as a multi-year pattern of increased variability in timing and relative amount of water supplied from higher elevations within the basin. Results of this study demonstrate both the utility of uranium isotopes in revealing sources of water in large river systems and of incorporating uranium isotope analysis in long-term monitoring of arctic river systems that attempt to assess the effects of climate change.  相似文献   

19.
Bulk dissolution rates for sediment from ODP Site 984A in the North Atlantic are determined using the 234U/238U activity ratios of pore water, bulk sediment, and leachates. Site 984A is one of only several sites where closely spaced pore water samples were obtained from the upper 60 meters of the core; the sedimentation rate is high (11-15 cm/ka), hence the sediments in the upper 60 meters are less than 500 ka old. The sediment is clayey silt and composed mostly of detritus derived from Iceland with a significant component of biogenic carbonate (up to 30%).The pore water 234U/238U activity ratios are higher than seawater values, in the range of 1.2 to 1.6, while the bulk sediment 234U/238U activity ratios are close to 1.0. The 234U/238U of the pore water reflects a balance between the mineral dissolution rate and the supply rate of excess 234U to the pore fluid by α-recoil injection of 234Th. The fraction of 238U decays that result in α-recoil injection of 234U to pore fluid is estimated to be 0.10 to 0.20 based on the 234U/238U of insoluble residue fractions. The calculated bulk dissolution rates, in units of g/g/yr are in the range of 4 × 10−7 to 2 × 10−6 yr−1. There is significant down-hole variability in pore water 234U/238U activity ratios (and hence dissolution rates) on a scale of ca. 10 m. The inferred bulk dissolution rate constants are 100 to 104 times slower than laboratory-determined rates, 100 times faster than rates inferred for older sediments based on Sr isotopes, and similar to weathering rates determined for terrestrial soils of similar age. The results of this study suggest that U isotopes can be used to measure in situ dissolution rates in fine-grained clastic materials.The rate estimates for sediments from ODP Site 984 confirm the strong dependence of reactivity on the age of the solid material: the bulk dissolution rate (Rd) of soils and deep-sea sediments can be approximately described by the expression Rd ≈ 0.1 Age−1 for ages spanning 1000 to 5 × 108 yr. The age of the material, which encompasses the grain size, surface area, and other chemical factors that contribute to the rate of dissolution, appears to be a much stronger determinant of dissolution rate than any single physical or chemical property of the system.  相似文献   

20.
The uranium (U) content and 234U/238U activity ratio were determined for water samples collected from Korea's Han River in spring, summer, and winter 2006 to provide data that might constrain the origin of U isotope fractionation in river water and the link between U isotope systematics in river waters and the lithological nature of the corresponding bedrock. The large difference in the major dissolved loads between the two major branches of the Han River, the North Han River (NHR) and South Han River (SHR), is reflected in the contrasting U content and 234U/238U activity ratio between the tributaries: low U content (0.08–0.75 nM; average, 0.34 nM) and small 234U/238U activity ratio (1.03–1.22; average, 1.09) in the NHR; and high U content (0.65–1.98 nM; average, 1.44 nM) and large 234U/238U activity ratio (1.05–1.45; average, 1.24) in the SHR. The large spatial differences in U content and 234U/238U activity ratio are closely related to both lithological differences between the two tributaries and groundwater input. The low U content and small 234U/238U activity ratio in the NHR arise mainly from a combination of surface and meteoric weathering of the dominant silicate rocks in this branch and congruent dissolution of already weathered (secular equilibrium) materials. In contrast, the high U content and large 234U/238U activity ratio in the SHR are ascribed to the dissolution of carbonates and black shales along with significant inputs of deep groundwater.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号